skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles

Abstract

Stable and redox active metal–organic frameworks were constructed by incorporating Zr 6 clusters and redox-active TTF-based linkers, which allow in situ generation and stabilization of ultra-small noble metal nanoparticles for heterogenous catalysis.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [1];  [2]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [2]
  1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093
  2. Department of Chemistry, College Station, USA
  3. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS), Dalian 116023, China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1591948
Grant/Contract Number:  
FE0026472; SC0001015
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Su, Jian, Yuan, Shuai, Wang, Tao, Lollar, Christina Tori, Zuo, Jing-Lin, Zhang, Jiangwei, and Zhou, Hong-Cai. Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles. United Kingdom: N. p., 2020. Web. doi:10.1039/C9SC06009J.
Su, Jian, Yuan, Shuai, Wang, Tao, Lollar, Christina Tori, Zuo, Jing-Lin, Zhang, Jiangwei, & Zhou, Hong-Cai. Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles. United Kingdom. doi:10.1039/C9SC06009J.
Su, Jian, Yuan, Shuai, Wang, Tao, Lollar, Christina Tori, Zuo, Jing-Lin, Zhang, Jiangwei, and Zhou, Hong-Cai. Wed . "Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles". United Kingdom. doi:10.1039/C9SC06009J.
@article{osti_1591948,
title = {Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles},
author = {Su, Jian and Yuan, Shuai and Wang, Tao and Lollar, Christina Tori and Zuo, Jing-Lin and Zhang, Jiangwei and Zhou, Hong-Cai},
abstractNote = {Stable and redox active metal–organic frameworks were constructed by incorporating Zr 6 clusters and redox-active TTF-based linkers, which allow in situ generation and stabilization of ultra-small noble metal nanoparticles for heterogenous catalysis.},
doi = {10.1039/C9SC06009J},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SC06009J

Save / Share:

Works referenced in this record:

Molecular Conductors and Superconductors Based on Trihalides of BEDT-TTF and Some of Its Analogues
journal, November 2004

  • Shibaeva, Rimma P.; Yagubskii, Eduard B.
  • Chemical Reviews, Vol. 104, Issue 11
  • DOI: 10.1021/cr0306642

Disparate Downstream Reactions Mediated by an Ionically Controlled Supramolecular Tristate Switch
journal, May 2018

  • Park, Jung Su; Park, Jihye; Yang, Yun Jae
  • Journal of the American Chemical Society, Vol. 140, Issue 24
  • DOI: 10.1021/jacs.8b02867

Redox Activities of Metal–Organic Frameworks Incorporating Rare-Earth Metal Chains and Tetrathiafulvalene Linkers
journal, February 2019


Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis
journal, January 2017

  • Yang, Qihao; Xu, Qiang; Jiang, Hai-Long
  • Chemical Society Reviews, Vol. 46, Issue 15
  • DOI: 10.1039/C6CS00724D

Stable Metal-Organic Frameworks: Design, Synthesis, and Applications
journal, February 2018


Enhanced Hydrogen Storage by Palladium Nanoparticles Fabricated in a Redox-Active Metal-Organic Framework
journal, March 2009

  • Cheon, Young Eun; Suh, Myunghyun Paik
  • Angewandte Chemie International Edition, Vol. 48, Issue 16
  • DOI: 10.1002/anie.200805494

Etching Growth under Surface Confinement: An Effective Strategy To Prepare Mesocrystalline Pd Nanocorolla
journal, October 2011

  • Huang, Xiaoqing; Tang, Shaoheng; Yang, Jing
  • Journal of the American Chemical Society, Vol. 133, Issue 40
  • DOI: 10.1021/ja207788h

A spectroscopic and electrochemical investigation of a tetrathiafulvalene series of metal–organic frameworks
journal, November 2018


Redox-Active Porous Metal-Organic Framework Producing Silver Nanoparticles from AgI Ions at Room Temperature
journal, February 2005

  • Moon, Hoi Ri; Kim, Ji Hyun; Suh, Myunghyun Paik
  • Angewandte Chemie International Edition, Vol. 44, Issue 8
  • DOI: 10.1002/anie.200461408

Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium
journal, February 2018

  • Ziebel, Michael E.; Darago, Lucy E.; Long, Jeffrey R.
  • Journal of the American Chemical Society, Vol. 140, Issue 8
  • DOI: 10.1021/jacs.7b13510

Selective Vapor Pressure Dependent Proton Transport in a Metal–Organic Framework with Two Distinct Hydrophilic Pores
journal, February 2018

  • Park, Sarah S.; Rieth, Adam J.; Hendon, Christopher H.
  • Journal of the American Chemical Society, Vol. 140, Issue 6
  • DOI: 10.1021/jacs.7b12784

Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
journal, October 2013

  • Feng, Dawei; Chung, Wan-Chun; Wei, Zhangwen
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja408084j

Development of a UiO-Type Thin Film Electrocatalysis Platform with Redox-Active Linkers
journal, February 2018

  • Johnson, Ben A.; Bhunia, Asamanjoy; Fei, Honghan
  • Journal of the American Chemical Society, Vol. 140, Issue 8
  • DOI: 10.1021/jacs.7b13077

Cocrystals Strategy towards Materials for Near-Infrared Photothermal Conversion and Imaging
journal, March 2018

  • Wang, Yu; Zhu, Weigang; Du, Wenna
  • Angewandte Chemie International Edition, Vol. 57, Issue 15
  • DOI: 10.1002/anie.201712949

Flexible Zirconium MOFs as Bromine-Nanocontainers for Bromination Reactions under Ambient Conditions
journal, October 2017

  • Pang, Jiandong; Yuan, Shuai; Du, Dongying
  • Angewandte Chemie International Edition, Vol. 56, Issue 46
  • DOI: 10.1002/anie.201709186

An Organic Mixed-Valence Ligand for Multistate Redox-Active Coordination Networks
journal, March 2018

  • Ha, Joo Yeon; Koo, Jin Young; Ohtsu, Hiroyoshi
  • Angewandte Chemie International Edition, Vol. 57, Issue 17
  • DOI: 10.1002/anie.201713035

Photo- and Electronically Switchable Spin-Crossover Iron(II) Metal-Organic Frameworks Based on a Tetrathiafulvalene Ligand
journal, April 2017

  • Wang, Hai-Ying; Ge, Jing-Yuan; Hua, Carol
  • Angewandte Chemie International Edition, Vol. 56, Issue 20
  • DOI: 10.1002/anie.201611824

Nanoparticle Core/Shell Architectures within MOF Crystals Synthesized by Reaction Diffusion
journal, June 2012

  • Wei, Yanhu; Han, Shuangbing; Walker, David A.
  • Angewandte Chemie International Edition, Vol. 51, Issue 30
  • DOI: 10.1002/anie.201202549

Introduction to Metal–Organic Frameworks
journal, September 2011

  • Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 673-674
  • DOI: 10.1021/cr300014x

Incorporation of Fused Tetrathiafulvalenes (TTFs) into Polythiophene Architectures:  Varying the Electroactive Dominance of the TTF Species in Hybrid Systems
journal, February 2006

  • Berridge, Rory; Skabara, Peter J.; Pozo-Gonzalo, Cristina
  • The Journal of Physical Chemistry B, Vol. 110, Issue 7
  • DOI: 10.1021/jp057256h

Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
journal, December 2017


Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework
journal, July 2018

  • Souto, Manuel; Romero, Jorge; Calbo, Joaquín
  • Journal of the American Chemical Society, Vol. 140, Issue 33
  • DOI: 10.1021/jacs.8b05890

Reversible Redox Activity in Multicomponent Metal–Organic Frameworks Constructed from Trinuclear Copper Pyrazolate Building Blocks
journal, June 2017

  • Tu, Binbin; Pang, Qingqing; Xu, Huoshu
  • Journal of the American Chemical Society, Vol. 139, Issue 23
  • DOI: 10.1021/jacs.7b03578

Mixed Valency in a 3D Semiconducting Iron–Fluoranilate Coordination Polymer
journal, July 2017


The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels
journal, March 2017

  • Park, Sarah S.; Hendon, Christopher H.; Fielding, Alistair J.
  • Journal of the American Chemical Society, Vol. 139, Issue 10
  • DOI: 10.1021/jacs.6b13176

Metal-Nanoparticle-Catalyzed Hydrogen Generation from Formic Acid
journal, May 2017


Reversible Capture and Release of Cl 2 and Br 2 with a Redox-Active Metal–Organic Framework
journal, April 2017

  • Tulchinsky, Yuri; Hendon, Christopher H.; Lomachenko, Kirill A.
  • Journal of the American Chemical Society, Vol. 139, Issue 16
  • DOI: 10.1021/jacs.7b02161

Ligand Redox Non-innocence in the Stoichiometric Oxidation of Mn 2 (2,5-dioxidoterephthalate) (Mn-MOF-74)
journal, February 2014

  • Cozzolino, Anthony F.; Brozek, Carl K.; Palmer, Ryan D.
  • Journal of the American Chemical Society, Vol. 136, Issue 9
  • DOI: 10.1021/ja411808r

Redox Active Metal- and Covalent Organic Frameworks for Energy Storage: Balancing Porosity and Electrical Conductivity
journal, September 2017

  • Zhang, Yugen; Riduan, Siti Nurhanna; Wang, Jinquan
  • Chemistry - A European Journal, Vol. 23, Issue 65
  • DOI: 10.1002/chem.201702919

Functional coordination polymers based on redox-active tetrathiafulvalene and its derivatives
journal, August 2017


An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors
journal, January 2017

  • Stassen, Ivo; Burtch, Nicholas; Talin, Alec
  • Chemical Society Reviews, Vol. 46, Issue 11
  • DOI: 10.1039/C7CS00122C

A Redox-Active Bistable Molecular Switch Mounted inside a Metal–Organic Framework
journal, October 2016

  • Chen, Qishui; Sun, Junling; Li, Peng
  • Journal of the American Chemical Society, Vol. 138, Issue 43
  • DOI: 10.1021/jacs.6b09880

Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry
journal, September 2018

  • Pedersen, Kasper S.; Perlepe, Panagiota; Aubrey, Michael L.
  • Nature Chemistry, Vol. 10, Issue 10
  • DOI: 10.1038/s41557-018-0107-7

High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012

  • Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 134, Issue 31
  • DOI: 10.1021/ja3059827

Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
journal, January 2015

  • Park, Sarah S.; Hontz, Eric R.; Sun, Lei
  • Journal of the American Chemical Society, Vol. 137, Issue 5
  • DOI: 10.1021/ja512437u

Metal-Organic Frameworks for Energy Applications
journal, January 2017


Flexible and Redox-Active Coordination Polymer: Control of the Network Structure by Pendant Arms of a Macrocyclic Complex
journal, July 2010

  • Moon, Hoi Ri; Suh, Myunghyun Paik
  • European Journal of Inorganic Chemistry, Vol. 2010, Issue 24
  • DOI: 10.1002/ejic.201000555

Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound
journal, November 2000

  • Coronado, Eugenio; Galán-Mascarós, José R.; Gómez-García, Carlos J.
  • Nature, Vol. 408, Issue 6811
  • DOI: 10.1038/35044035

Multifunctional Metal–Organic Frameworks Based on Redox-Active Rhenium Octahedral Clusters
journal, February 2018


Dynamic and Redox Active Pillared Bilayer Open Framework:  Single-Crystal-to-Single-Crystal Transformations upon Guest Removal, Guest Exchange, and Framework Oxidation
journal, December 2004

  • Choi, Hye Jin; Suh, Myunghyun Paik
  • Journal of the American Chemical Society, Vol. 126, Issue 48
  • DOI: 10.1021/ja0466715

Electron transfer in a new highly conducting donor-acceptor complex
journal, February 1973

  • Ferraris, John.; Cowan, D. O.; Walatka, V.
  • Journal of the American Chemical Society, Vol. 95, Issue 3
  • DOI: 10.1021/ja00784a066

Charge-Transfer within Zr-Based Metal–Organic Framework: The Role of Polar Node
journal, February 2018

  • Van Wyk, Andrea; Smith, Tanner; Park, Jaehong
  • Journal of the American Chemical Society, Vol. 140, Issue 8
  • DOI: 10.1021/jacs.7b13211

Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound
journal, February 2015

  • Hod, Idan; Bury, Wojciech; Gardner, Daniel M.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 4
  • DOI: 10.1021/acs.jpclett.5b00019

The MOF-driven synthesis of supported palladium clusters with catalytic activity for carbene-mediated chemistry
journal, June 2017

  • Fortea-Pérez, Francisco R.; Mon, Marta; Ferrando-Soria, Jesús
  • Nature Materials, Vol. 16, Issue 7
  • DOI: 10.1038/nmat4910

Binuclear gadolinium(iii) coordination complex based on bridging tetrathiafulvalenecarboxylate radical cations
journal, January 2009

  • Pointillart, Fabrice; Le Gal, Yann; Golhen, Stéphane
  • Chemical Communications, Issue 25
  • DOI: 10.1039/b901932d

Electron delocalization and charge mobility as a function of reduction in a metal–organic framework
journal, June 2018


Synthesis of Densely Packaged, Ultrasmall Pt 0 2 Clusters within a Thioether-Functionalized MOF: Catalytic Activity in Industrial Reactions at Low Temperature
journal, April 2018

  • Mon, Marta; Rivero-Crespo, Miguel A.; Ferrando-Soria, Jesús
  • Angewandte Chemie International Edition, Vol. 57, Issue 21
  • DOI: 10.1002/anie.201801957

Mixed-Valence Li/Fe-Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties
journal, April 2007

  • Férey, Gérard; Millange, Franck; Morcrette, Mathieu
  • Angewandte Chemie, Vol. 119, Issue 18
  • DOI: 10.1002/ange.200605163

Metal–Organic Frameworks for Separations
journal, September 2011

  • Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
  • Chemical Reviews, Vol. 112, Issue 2, p. 869-932
  • DOI: 10.1021/cr200190s

Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges
journal, December 2017


Nanomaterials derived from metal–organic frameworks
journal, December 2017


Multifunctional Fourfold Interpenetrating Diamondoid Network: Gas Separation and Fabrication of Palladium Nanoparticles
journal, March 2008

  • Cheon, Young Eun; Suh, Myunghyun Paik
  • Chemistry - A European Journal, Vol. 14, Issue 13
  • DOI: 10.1002/chem.200701813

Synthesis and Doping of a Multifunctional Tetrathiafulvalene- Substituted Poly(isocyanide)
journal, October 2007

  • Gomar-Nadal, Elba; Mugica, Laurent; Vidal-Gancedo, José
  • Macromolecules, Vol. 40, Issue 21
  • DOI: 10.1021/ma0710986

Control the Structure of Zr-Tetracarboxylate Frameworks through Steric Tuning
journal, November 2017

  • Pang, Jiandong; Yuan, Shuai; Qin, Junsheng
  • Journal of the American Chemical Society, Vol. 139, Issue 46
  • DOI: 10.1021/jacs.7b09973

Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism
journal, December 2013

  • Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E.
  • Chemistry of Materials, Vol. 25, Issue 24
  • DOI: 10.1021/cm403726v

Monitoring the Solid-State Electrochemistry of Cu(2,7-AQDC) (AQDC = Anthraquinone Dicarboxylate) in a Lithium Battery: Coexistence of Metal and Ligand Redox Activities in a Metal–Organic Framework
journal, November 2014

  • Zhang, Zhongyue; Yoshikawa, Hirofumi; Awaga, Kunio
  • Journal of the American Chemical Society, Vol. 136, Issue 46
  • DOI: 10.1021/ja508197w

Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks
journal, January 2019

  • Xie, Lilia S.; Alexandrov, Eugeny V.; Skorupskii, Grigorii
  • Chemical Science, Vol. 10, Issue 37
  • DOI: 10.1039/C9SC03348C

A Redox-Active Two-Dimensional Coordination Polymer:  Preparation of Silver and Gold Nanoparticles and Crystal Dynamics on Guest Removal
journal, April 2006

  • Suh, Myunghyun Paik; Moon, Hoi Ri; Lee, Eun Young
  • Journal of the American Chemical Society, Vol. 128, Issue 14
  • DOI: 10.1021/ja056963l

Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016

  • Sun, Lei; Campbell, Michael G.; Dincă, Mircea
  • Angewandte Chemie International Edition, Vol. 55, Issue 11
  • DOI: 10.1002/anie.201506219

Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives
journal, January 2016


Ultrathin two-dimensional metal-organic framework nanosheets for functional electronic devices
journal, December 2018


Lanthanide Ion and Tetrathiafulvalene-Based Ligand as a “Magic” Couple toward Luminescence, Single Molecule Magnets, and Magnetostructural Correlations
journal, October 2015

  • Pointillart, Fabrice; le Guennic, Boris; Cador, Olivier
  • Accounts of Chemical Research, Vol. 48, Issue 11
  • DOI: 10.1021/acs.accounts.5b00296

Magnetic TTF-Based Charge-Transfer Complexes
journal, November 2004

  • Enoki, Toshiaki; Miyazaki, Akira
  • Chemical Reviews, Vol. 104, Issue 11
  • DOI: 10.1021/cr0306438