DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Polythiophene coated aromatic polyimide enabled ultrafast and sustainable lithium ion batteries

Abstract

Organic composite electrode materials based on aromatic polyimide (PI) and electron conductive polythiophene (PT) have been prepared by a facilein situchemical oxidation polymerization method. The optimized composite electrode PI30PT delivers a remarkable high-rate cyclability, achieving a high capacity of 89.6 mA h g-1at 20 C with capacity retention of 94% after 1000 cycles.

Authors:
 [1]; ORCiD logo [2];  [3]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [3]
  1. Univ. of Tennessee, Knoxville, TN (United States); Shandong Univ., Jinan (China)
  2. Shandong Univ., Jinan (China)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  5. Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1427661
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 5; Journal Issue: 46; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Lyu, Hailong, Liu, Jiurong, Mahurin, Shannon, Dai, Sheng, Guo, Zhanhu, and Sun, Xiao-Guang. Polythiophene coated aromatic polyimide enabled ultrafast and sustainable lithium ion batteries. United States: N. p., 2017. Web. doi:10.1039/C7TA07893E.
Lyu, Hailong, Liu, Jiurong, Mahurin, Shannon, Dai, Sheng, Guo, Zhanhu, & Sun, Xiao-Guang. Polythiophene coated aromatic polyimide enabled ultrafast and sustainable lithium ion batteries. United States. https://doi.org/10.1039/C7TA07893E
Lyu, Hailong, Liu, Jiurong, Mahurin, Shannon, Dai, Sheng, Guo, Zhanhu, and Sun, Xiao-Guang. Tue . "Polythiophene coated aromatic polyimide enabled ultrafast and sustainable lithium ion batteries". United States. https://doi.org/10.1039/C7TA07893E. https://www.osti.gov/servlets/purl/1427661.
@article{osti_1427661,
title = {Polythiophene coated aromatic polyimide enabled ultrafast and sustainable lithium ion batteries},
author = {Lyu, Hailong and Liu, Jiurong and Mahurin, Shannon and Dai, Sheng and Guo, Zhanhu and Sun, Xiao-Guang},
abstractNote = {Organic composite electrode materials based on aromatic polyimide (PI) and electron conductive polythiophene (PT) have been prepared by a facilein situchemical oxidation polymerization method. The optimized composite electrode PI30PT delivers a remarkable high-rate cyclability, achieving a high capacity of 89.6 mA h g-1at 20 C with capacity retention of 94% after 1000 cycles.},
doi = {10.1039/C7TA07893E},
journal = {Journal of Materials Chemistry. A},
number = 46,
volume = 5,
place = {United States},
year = {Tue Oct 31 00:00:00 EDT 2017},
month = {Tue Oct 31 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 24 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Towards sustainable and versatile energy storage devices: an overview of organic electrode materials
journal, January 2013

  • Song, Zhiping; Zhou, Haoshen
  • Energy & Environmental Science, Vol. 6, Issue 8, p. 2280-2301
  • DOI: 10.1039/c3ee40709h

Rechargeable batteries with organic radical cathodes
journal, June 2002


Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

How Many Lithium Ions Can Be Inserted onto Fused C 6 Aromatic Ring Systems?
journal, April 2012

  • Han, Xiaoyan; Qing, Guangyan; Sun, Jutang
  • Angewandte Chemie International Edition, Vol. 51, Issue 21
  • DOI: 10.1002/anie.201109187

Polymers for electronics and spintronics
journal, January 2013

  • Bujak, Piotr; Kulszewicz-Bajer, Irena; Zagorska, Malgorzata
  • Chemical Society Reviews, Vol. 42, Issue 23
  • DOI: 10.1039/c3cs60257e

Factors affecting the battery performance of anthraquinone-based organic cathode materials
journal, January 2012

  • Xu, Wu; Read, Adam; Koech, Phillip K.
  • Journal of Materials Chemistry, Vol. 22, Issue 9
  • DOI: 10.1039/c2jm15764k

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Powering up the Future: Radical Polymers for Battery Applications
journal, December 2012

  • Janoschka, Tobias; Hager, Martin D.; Schubert, Ulrich S.
  • Advanced Materials, Vol. 24, Issue 48
  • DOI: 10.1002/adma.201203119

Perylene-polyimide-Based Organic Electrode Materials for Rechargeable Lithium Batteries
journal, September 2013

  • Sharma, Pavan; Damien, Dijo; Nagarajan, Kalaivanan
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 19
  • DOI: 10.1021/jz4017359

Superior radical polymer cathode material with a two-electron process redox reaction promoted by graphene
journal, January 2012

  • Guo, Wei; Yin, Ya-Xia; Xin, Sen
  • Energy Environ. Sci., Vol. 5, Issue 1
  • DOI: 10.1039/C1EE02148F

Polythiophene-coated Fe3O4 superparamagnetic nanocomposite: Synthesis and application as a new sorbent for solid-phase extraction
journal, April 2013


Polyimides: Promising Energy-Storage Materials
journal, September 2010

  • Song, Zhiping; Zhan, Hui; Zhou, Yunhong
  • Angewandte Chemie International Edition, Vol. 49, Issue 45
  • DOI: 10.1002/anie.201002439

Voltammetry on fractals
journal, October 1995


Sulfur/Polythiophene with a Core/Shell Structure: Synthesis and Electrochemical Properties of the Cathode for Rechargeable Lithium Batteries
journal, March 2011

  • Wu, Feng; Chen, Junzheng; Chen, Renjie
  • The Journal of Physical Chemistry C, Vol. 115, Issue 13, p. 6057-6063
  • DOI: 10.1021/jp1114724

Carbon composite spun fibers with in situ formed multicomponent nanoparticles for a lithium-ion battery anode with enhanced performance
journal, January 2016

  • Lyu, Hailong; Liu, Jiurong; Qiu, Song
  • Journal of Materials Chemistry A, Vol. 4, Issue 25
  • DOI: 10.1039/C6TA02083F

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

Porous polythiophene as a cathode material for lithium batteries with high capacity and good cycling stability
journal, January 2012


Organic Nanohybrids for Fast and Sustainable Energy Storage
journal, February 2014


High performance Cr, N-codoped mesoporous TiO 2 microspheres for lithium-ion batteries
journal, January 2014

  • Bi, Zhonghe; Paranthaman, M. Parans; Guo, Bingkun
  • J. Mater. Chem. A, Vol. 2, Issue 6
  • DOI: 10.1039/C3TA14535B

Ionic Liquid-Based Rechargeable Lithium Metal-Polymer Cells Assembled with Polyaniline/Carbon Nanotube Composite Cathode
journal, January 2007

  • Sivakkumar, S. R.; MacFarlane, Douglas R.; Forsyth, Maria
  • Journal of The Electrochemical Society, Vol. 154, Issue 9
  • DOI: 10.1149/1.2750443

Polyaniline/Carbon Nanotube Composite Cathode for Rechargeable Lithium Polymer Batteries Assembled with Gel Polymer Electrolyte
journal, January 2007

  • Sivakkumar, S. R.; Kim, Dong-Won
  • Journal of The Electrochemical Society, Vol. 154, Issue 2
  • DOI: 10.1149/1.2404901

Carbonyls: Powerful Organic Materials for Secondary Batteries
journal, April 2015

  • Häupler, Bernhard; Wild, Andreas; Schubert, Ulrich S.
  • Advanced Energy Materials, Vol. 5, Issue 11
  • DOI: 10.1002/aenm.201402034

Electrochemistry of Poly(3,4-alkylenedioxythiophene) Derivatives
journal, June 2003

  • Groenendaal, L.; Zotti, G.; Aubert, P. -H.
  • Advanced Materials, Vol. 15, Issue 11
  • DOI: 10.1002/adma.200300376

Advanced materials based on new structurally designed poly(naphthylimide-amide)s
journal, September 2014

  • Constantin, Catalin-Paul; Damaceanu, Mariana-Dana; Bruma, Maria
  • Polymer International, Vol. 64, Issue 3
  • DOI: 10.1002/pi.4792

Porous Spheres Assembled from Polythiophene (PTh)-Coated Ultrathin MnO 2 Nanosheets with Enhanced Lithium Storage Capabilities
journal, June 2010

  • Xiao, Wei; Chen, Jun Song; Lu, Qing
  • The Journal of Physical Chemistry C, Vol. 114, Issue 27
  • DOI: 10.1021/jp104227e

Naphthalene-based Polyimide Derivatives as Organic Electrode Materials for Lithium-ion Batteries
journal, March 2017


A flexible electrode based on a three-dimensional graphene network-supported polyimide for lithium-ion batteries
journal, January 2014

  • Meng, Yuena; Wu, Haiping; Zhang, Yajie
  • J. Mater. Chem. A, Vol. 2, Issue 28
  • DOI: 10.1039/C4TA00364K

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


An Organic Pigment as a High-Performance Cathode for Sodium-Ion Batteries
journal, June 2014

  • Luo, Wei; Allen, Marshall; Raju, Vadivukarasi
  • Advanced Energy Materials, Vol. 4, Issue 15
  • DOI: 10.1002/aenm.201400554

Polyanthraquinone-Based Organic Cathode for High-Performance Rechargeable Magnesium-Ion Batteries
journal, May 2016

  • Pan, Baofei; Huang, Jinhua; Feng, Zhenxing
  • Advanced Energy Materials, Vol. 6, Issue 14
  • DOI: 10.1002/aenm.201600140

Universal quinone electrodes for long cycle life aqueous rechargeable batteries
journal, June 2017

  • Liang, Yanliang; Jing, Yan; Gheytani, Saman
  • Nature Materials, Vol. 16, Issue 8
  • DOI: 10.1038/nmat4919

Organic Electrode Materials for Rechargeable Lithium Batteries
journal, May 2012

  • Liang, Yanliang; Tao, Zhanliang; Chen, Jun
  • Advanced Energy Materials, Vol. 2, Issue 7
  • DOI: 10.1002/aenm.201100795

Organic Radical Battery Approaching Practical Use
journal, March 2011

  • Nakahara, Kentaro; Oyaizu, Kenichi; Nishide, Hiroyuki
  • Chemistry Letters, Vol. 40, Issue 3
  • DOI: 10.1246/cl.2011.222

A long-life lithium-ion battery with a highly porous TiNb 2 O 7 anode for large-scale electrical energy storage
journal, January 2014

  • Guo, Bingkun; Yu, Xiqian; Sun, Xiao-Guang
  • Energy Environ. Sci., Vol. 7, Issue 7
  • DOI: 10.1039/C4EE00508B

Structural origins of capacity fading in lithium-polyimide batteries
journal, January 2017

  • Shestakov, A. F.; Yarmolenko, O. V.; Ignatova, A. A.
  • Journal of Materials Chemistry A, Vol. 5, Issue 14
  • DOI: 10.1039/C6TA10520C

TEMPO-Based Catholyte for High-Energy Density Nonaqueous Redox Flow Batteries
journal, October 2014

  • Wei, Xiaoliang; Xu, Wu; Vijayakumar, Murugesan
  • Advanced Materials, Vol. 26, Issue 45
  • DOI: 10.1002/adma.201403746

Polymer–Graphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries
journal, April 2012

  • Song, Zhiping; Xu, Terrence; Gordin, Mikhail L.
  • Nano Letters, Vol. 12, Issue 5
  • DOI: 10.1021/nl2039666

A Novel Conductive Polymer-Sulfur Composite Cathode Material for Rechargeable Lithium Batteries
journal, July 2002


Flexible and Binder-Free Organic Cathode for High-Performance Lithium-Ion Batteries
journal, March 2014

  • Wu, Haiping; Shevlin, Stephen A.; Meng, Qinghai
  • Advanced Materials, Vol. 26, Issue 20
  • DOI: 10.1002/adma.201305452

Sulfur–Polythiophene Composite Cathode Materials for Rechargeable Lithium Batteries
journal, January 2010

  • Wu, Feng; Wu, Shengxian; Chen, Renjie
  • Electrochemical and Solid-State Letters, Vol. 13, Issue 4
  • DOI: 10.1149/1.3290668

Polymer-Based Organic Batteries
journal, August 2016


Three-dimensional graphene/polyimide composite-derived flexible high-performance organic cathode for rechargeable lithium and sodium batteries
journal, January 2017

  • Huang, Yanshan; Li, Ke; Liu, Jingjing
  • Journal of Materials Chemistry A, Vol. 5, Issue 6
  • DOI: 10.1039/C6TA09754E

A polyimide derivative containing different carbonyl groups for flexible lithium ion batteries
journal, January 2016

  • Wu, H. P.; Yang, Q.; Meng, Q. H.
  • Journal of Materials Chemistry A, Vol. 4, Issue 6
  • DOI: 10.1039/C5TA07246H

Electroactive materials for organic electronics: preparation strategies, structural aspects and characterization techniques
journal, January 2010

  • Pron, Adam; Gawrys, Pawel; Zagorska, Malgorzata
  • Chemical Society Reviews, Vol. 39, Issue 7
  • DOI: 10.1039/b907999h

Works referencing / citing this record:

Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes
journal, July 2019

  • Peng, Huiling; Yu, Qianchuan; Wang, Shengping
  • Advanced Science, Vol. 6, Issue 17
  • DOI: 10.1002/advs.201900431

Aromatic Polyimide/Graphene Composite Organic Cathodes for Fast and Sustainable Lithium-Ion Batteries
journal, January 2018


Recent Progress in Polymeric Carbonyl-Based Electrode Materials for Lithium and Sodium Ion Batteries
journal, November 2018

  • Amin, Kamran; Mao, Lijuan; Wei, Zhixiang
  • Macromolecular Rapid Communications, Vol. 40, Issue 1
  • DOI: 10.1002/marc.201800565

Hydrothermally self-templated synthesis of rectangular polyimide submicrotubes and promising potentials in electrochemical energy storage
journal, January 2020

  • Lei, Sheng; Cui, Xun; Liu, Xufei
  • Chemical Communications, Vol. 56, Issue 9
  • DOI: 10.1039/c9cc09526h