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Title: Mechanistic Analysis of Mechano-Electrochemical Interaction in Silicon Electrodes with Surface Film

Abstract

High-capacity anode materials for lithium-ion batteries, such as silicon, are prone to large volume change during lithiation/delithiation which may cause particle cracking and disintegration, thereby resulting in severe capacity fade and reduction in cycle life. In this work, a stochastic analysis is presented in order to understand the mechano-electrochemical interaction in silicon active particles along with a surface film during cycling. Amorphous silicon particles exhibiting single-phase lithiation incur lower amount of cracking as compared to crystalline silicon particles exhibiting two-phase lithiation for the same degree of volumetric expansion. Rupture of the brittle surface film is observed for both amorphous and crystalline silicon particles and is attributed to the large volumetric expansion of the silicon active particle with lithiation. The mechanical property of the surface film plays an important role in determining the amount of degradation in the particle/film assembly. A strategy to ameliorate particle cracking in silicon active particles is proposed.

Authors:
 [1];  [1]
  1. Purdue Univ., West Lafayette, IN (United States)
Publication Date:
Research Org.:
Texas A & M Univ., College Station, TX (United States). Texas A & M Engineering Experiment Station
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1425963
Grant/Contract Number:  
EE0007766
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 164; Journal Issue: 14; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Verma, Ankit, and Mukherjee, Partha P. Mechanistic Analysis of Mechano-Electrochemical Interaction in Silicon Electrodes with Surface Film. United States: N. p., 2017. Web. doi:10.1149/2.0391714jes.
Verma, Ankit, & Mukherjee, Partha P. Mechanistic Analysis of Mechano-Electrochemical Interaction in Silicon Electrodes with Surface Film. United States. doi:10.1149/2.0391714jes.
Verma, Ankit, and Mukherjee, Partha P. Fri . "Mechanistic Analysis of Mechano-Electrochemical Interaction in Silicon Electrodes with Surface Film". United States. doi:10.1149/2.0391714jes. https://www.osti.gov/servlets/purl/1425963.
@article{osti_1425963,
title = {Mechanistic Analysis of Mechano-Electrochemical Interaction in Silicon Electrodes with Surface Film},
author = {Verma, Ankit and Mukherjee, Partha P.},
abstractNote = {High-capacity anode materials for lithium-ion batteries, such as silicon, are prone to large volume change during lithiation/delithiation which may cause particle cracking and disintegration, thereby resulting in severe capacity fade and reduction in cycle life. In this work, a stochastic analysis is presented in order to understand the mechano-electrochemical interaction in silicon active particles along with a surface film during cycling. Amorphous silicon particles exhibiting single-phase lithiation incur lower amount of cracking as compared to crystalline silicon particles exhibiting two-phase lithiation for the same degree of volumetric expansion. Rupture of the brittle surface film is observed for both amorphous and crystalline silicon particles and is attributed to the large volumetric expansion of the silicon active particle with lithiation. The mechanical property of the surface film plays an important role in determining the amount of degradation in the particle/film assembly. A strategy to ameliorate particle cracking in silicon active particles is proposed.},
doi = {10.1149/2.0391714jes},
journal = {Journal of the Electrochemical Society},
number = 14,
volume = 164,
place = {United States},
year = {2017},
month = {11}
}

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