Suppressing Li Dendrite Formation in Li 2 S‐P 2 S 5 Solid Electrolyte by LiI Incorporation
Abstract
Abstract Solid electrolytes have been considered as a promising approach for Li dendrite prevention because of their high mechanical strength and high Li transference number. However, recent reports indicate that Li dendrites also form in Li 2 S‐P 2 S 5 based sulfide electrolytes at current densities much lower than that in the conventional liquid electrolytes. The methods of suppressing dendrite formation in sulfide electrolytes have rarely been reported because the mechanism for the “unexpected” dendrite formation is unclear, limiting the successful utilization of high‐energy Li anode with these electrolytes. Herein, the authors demonstrate that the Li dendrite formation in Li 2 S‐P 2 S 5 glass can be effectively suppressed by tuning the composition of the solid electrolyte interphase (SEI) at the Li/electrolyte interface through incorporating LiI into the electrolyte. This approach introduces high ionic conductivity but electronic insulation of LiI in the SEI, and more importantly, improves the mobility of Li atoms, promoting the Li depositon at the interface and thus suppresses dendrite growth. It is shown that the critical current density is improved significantly after incorporating LiI into Li 2 S‐P 2 S 5 glass, reaching 3.90 mA cm −2 at 100 °C after adding 30 mol%more »
- Authors:
-
[1]
- Department of Chemical and Biomolecular Engineering University of Maryland College Park MD 20740 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1425509
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Name: Advanced Energy Materials Journal Volume: 8 Journal Issue: 18; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Han, Fudong, Yue, Jie, Zhu, Xiangyang, and Wang, Chunsheng. Suppressing Li Dendrite Formation in Li 2 S‐P 2 S 5 Solid Electrolyte by LiI Incorporation. Germany: N. p., 2018.
Web. doi:10.1002/aenm.201703644.
Han, Fudong, Yue, Jie, Zhu, Xiangyang, & Wang, Chunsheng. Suppressing Li Dendrite Formation in Li 2 S‐P 2 S 5 Solid Electrolyte by LiI Incorporation. Germany. https://doi.org/10.1002/aenm.201703644
Han, Fudong, Yue, Jie, Zhu, Xiangyang, and Wang, Chunsheng. Mon .
"Suppressing Li Dendrite Formation in Li 2 S‐P 2 S 5 Solid Electrolyte by LiI Incorporation". Germany. https://doi.org/10.1002/aenm.201703644.
@article{osti_1425509,
title = {Suppressing Li Dendrite Formation in Li 2 S‐P 2 S 5 Solid Electrolyte by LiI Incorporation},
author = {Han, Fudong and Yue, Jie and Zhu, Xiangyang and Wang, Chunsheng},
abstractNote = {Abstract Solid electrolytes have been considered as a promising approach for Li dendrite prevention because of their high mechanical strength and high Li transference number. However, recent reports indicate that Li dendrites also form in Li 2 S‐P 2 S 5 based sulfide electrolytes at current densities much lower than that in the conventional liquid electrolytes. The methods of suppressing dendrite formation in sulfide electrolytes have rarely been reported because the mechanism for the “unexpected” dendrite formation is unclear, limiting the successful utilization of high‐energy Li anode with these electrolytes. Herein, the authors demonstrate that the Li dendrite formation in Li 2 S‐P 2 S 5 glass can be effectively suppressed by tuning the composition of the solid electrolyte interphase (SEI) at the Li/electrolyte interface through incorporating LiI into the electrolyte. This approach introduces high ionic conductivity but electronic insulation of LiI in the SEI, and more importantly, improves the mobility of Li atoms, promoting the Li depositon at the interface and thus suppresses dendrite growth. It is shown that the critical current density is improved significantly after incorporating LiI into Li 2 S‐P 2 S 5 glass, reaching 3.90 mA cm −2 at 100 °C after adding 30 mol% LiI. Stable cycling of the Li‐Li cells for 200 h is also achieved at 1.50 mA cm −2 at 100 °C.},
doi = {10.1002/aenm.201703644},
journal = {Advanced Energy Materials},
number = 18,
volume = 8,
place = {Germany},
year = {Mon Mar 12 00:00:00 EDT 2018},
month = {Mon Mar 12 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/aenm.201703644
https://doi.org/10.1002/aenm.201703644
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 252 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Lithium ion conductivity in Li 2 S–P 2 S 5 glasses – building units and local structure evolution during the crystallization of superionic conductors Li 3 PS 4 , Li 7 P 3 S 11 and Li 4 P 2 S 7
journal, January 2017
- Dietrich, Christian; Weber, Dominik A.; Sedlmaier, Stefan J.
- Journal of Materials Chemistry A, Vol. 5, Issue 34
Elastic Properties of the Solid Electrolyte Li 7 La 3 Zr 2 O 12 (LLZO)
journal, December 2015
- Yu, Seungho; Schmidt, Robert D.; Garcia-Mendez, Regina
- Chemistry of Materials, Vol. 28, Issue 1
Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte
journal, March 2016
- Wenzel, Sebastian; Weber, Dominik A.; Leichtweiss, Thomas
- Solid State Ionics, Vol. 286
Interface-Engineered All-Solid-State Li-Ion Batteries Based on Garnet-Type Fast Li + Conductors
journal, July 2016
- van den Broek, Jan; Afyon, Semih; Rupp, Jennifer L. M.
- Advanced Energy Materials, Vol. 6, Issue 19
Recent Developments of the Lithium Metal Anode for Rechargeable Non-Aqueous Batteries
journal, July 2016
- Zhang, Kai; Lee, Gi-Hyeok; Park, Mihui
- Advanced Energy Materials, Vol. 6, Issue 20
Effect of Surface Microstructure on Electrochemical Performance of Garnet Solid Electrolytes
journal, January 2015
- Cheng, Lei; Chen, Wei; Kunz, Martin
- ACS Applied Materials & Interfaces, Vol. 7, Issue 3
Solid Electrolyte: the Key for High-Voltage Lithium Batteries
journal, October 2014
- Li, Juchuan; Ma, Cheng; Chi, Miaofang
- Advanced Energy Materials, Vol. 5, Issue 4
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations
journal, October 2015
- Zhu, Yizhou; He, Xingfeng; Mo, Yifei
- ACS Applied Materials & Interfaces, Vol. 7, Issue 42
One-pot liquid phase synthesis of (100− x )Li 3 PS 4 – x LiI solid electrolytes
journal, October 2017
- Phuc, Nguyen Huu Huy; Hirahara, Eito; Morikawa, Kei
- Journal of Power Sources, Vol. 365
A High-Voltage, Solid-State Battery System
journal, January 1969
- Liang, Charles C.; Epstein, James; Boyle, Gerard H.
- Journal of The Electrochemical Society, Vol. 116, Issue 10
A solid future for battery development
journal, September 2016
- Janek, Jürgen; Zeier, Wolfgang G.
- Nature Energy, Vol. 1, Issue 9
Li 7 La 3 Zr 2 O 12 Interface Modification for Li Dendrite Prevention
journal, April 2016
- Tsai, Chih-Long; Roddatis, Vladimir; Chandran, C. Vinod
- ACS Applied Materials & Interfaces, Vol. 8, Issue 16
Highly Stable Operation of Lithium Metal Batteries Enabled by the Formation of a Transient High-Concentration Electrolyte Layer
journal, February 2016
- Zheng, Jianming; Yan, Pengfei; Mei, Donghai
- Advanced Energy Materials, Vol. 6, Issue 8
Impedance characterization reveals mixed conducting interphases between sulfidic superionic conductors and lithium metal electrodes
journal, June 2017
- Bron, Philipp; Roling, Bernhard; Dehnen, Stefanie
- Journal of Power Sources, Vol. 352
Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density
journal, January 2016
- Sharafi, Asma; Meyer, Harry M.; Nanda, Jagjit
- Journal of Power Sources, Vol. 302
Stable Artificial Solid Electrolyte Interphases for Lithium Batteries
journal, May 2017
- Ma, Lin; Kim, Mun Sek; Archer, Lynden A.
- Chemistry of Materials, Vol. 29, Issue 10
A Battery Made from a Single Material
journal, April 2015
- Han, Fudong; Gao, Tao; Zhu, Yujie
- Advanced Materials, Vol. 27, Issue 23
Controlling and correlating the effect of grain size with the mechanical and electrochemical properties of Li 7 La 3 Zr 2 O 12 solid-state electrolyte
journal, January 2017
- Sharafi, Asma; Haslam, Catherine G.; Kerns, Robert D.
- J. Mater. Chem. A, Vol. 5, Issue 40
Direct Observation of the Interfacial Instability of the Fast Ionic Conductor Li 10 GeP 2 S 12 at the Lithium Metal Anode
journal, March 2016
- Wenzel, Sebastian; Randau, Simon; Leichtweiß, Thomas
- Chemistry of Materials, Vol. 28, Issue 7
SiO 2 Hollow Nanosphere-Based Composite Solid Electrolyte for Lithium Metal Batteries to Suppress Lithium Dendrite Growth and Enhance Cycle Life
journal, January 2016
- Zhou, Dong; Liu, Ruliang; He, Yan-Bing
- Advanced Energy Materials, Vol. 6, Issue 7
Electronic excitations of LiI within many-body perturbation theory
journal, August 2014
- Gao, Yan-Min; Jiang, Yun-Feng; Wang, Neng-Ping
- Physica B: Condensed Matter, Vol. 447
Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery
journal, July 2013
- Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Scientific Reports, Vol. 3, Issue 1
Grain boundary modification to suppress lithium penetration through garnet-type solid electrolyte
journal, September 2017
- Hongahally Basappa, Rajendra; Ito, Tomoko; Morimura, Takao
- Journal of Power Sources, Vol. 363
Structure, ionic conductivity and electrochemical stability of Li2S–P2S5–LiI glass and glass–ceramic electrolytes
journal, March 2012
- Ujiie, Satoshi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Solid State Ionics, Vol. 211
Superionic conduction in Li 2 S - P 2 S 5 - LiI - glasses
journal, October 1981
- Mercier, René; Malugani, Jean-Pierre; Fahys, Bernard
- Solid State Ionics, Vol. 5
High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016
- Kato, Yuki; Hori, Satoshi; Saito, Toshiya
- Nature Energy, Vol. 1, Issue 4
An Iodide-Based Li 7 P 2 S 8 I Superionic Conductor
journal, January 2015
- Rangasamy, Ezhiylmurugan; Liu, Zengcai; Gobet, Mallory
- Journal of the American Chemical Society, Vol. 137, Issue 4
Solid-state lithium battery with graphite anode
journal, March 2003
- Takada, K.
- Solid State Ionics, Vol. 158, Issue 3-4
Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution
journal, May 2017
- Markevich, Elena; Salitra, Gregory; Chesneau, Frederick
- ACS Energy Letters, Vol. 2, Issue 6
Onset of dendritic growth in lithium/polymer cells
journal, July 2001
- Rosso, M.; Gobron, T.; Brissot, C.
- Journal of Power Sources, Vol. 97-98
The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces
journal, January 2005
- Monroe, Charles; Newman, John
- Journal of The Electrochemical Society, Vol. 152, Issue 2
Thin film rechargeable Li batteries
journal, August 1994
- Jones, Steven D.; Akridge, James R.; Shokoohi, Frough K.
- Solid State Ionics, Vol. 69, Issue 3-4, p. 357-368
Effect of Gold Layer on Interface Resistance between Lithium Metal Anode and Li 6.25 Al 0.25 La 3 Zr 2 O 12 Solid Electrolyte
journal, January 2017
- Wakasugi, Jungo; Munakata, Hirokazu; Kanamura, Kiyoshi
- Journal of The Electrochemical Society, Vol. 164, Issue 6
Effect of Processing Conditions of 75Li2S-25P2S5 Solid Electrolyte on its DC Electrochemical Behavior
journal, May 2017
- Garcia-Mendez, Regina; Mizuno, Fuminori; Zhang, Ruigang
- Electrochimica Acta, Vol. 237
The Electrochemical Characteristics and Applicability of an Amorphous Sulfide-Based Solid Ion Conductor for the Next-Generation Solid-State Lithium Secondary Batteries
journal, May 2016
- Aihara, Yuichi; Ito, Seitaro; Omoda, Ryo
- Frontiers in Energy Research, Vol. 4
Tunable Ionic and Electronic Conduction of Lithium Nitride via Phosphorus and Arsenic Substitution: A First-Principles Study
journal, September 2010
- Wu, Shunnian; Neo, Su San; Dong, Zhili
- The Journal of Physical Chemistry C, Vol. 114, Issue 39
Dendritic growth mechanisms in lithium/polymer cells
journal, September 1999
- Brissot, C.; Rosso, M.; Chazalviel, J. -N.
- Journal of Power Sources, Vol. 81-82
Electrochemical Stability of Li 10 GeP 2 S 12 and Li 7 La 3 Zr 2 O 12 Solid Electrolytes
journal, January 2016
- Han, Fudong; Zhu, Yizhou; He, Xingfeng
- Advanced Energy Materials, Vol. 6, Issue 8
Li 4 PS 4 I: A Li + Superionic Conductor Synthesized by a Solvent-Based Soft Chemistry Approach
journal, February 2017
- Sedlmaier, Stefan J.; Indris, Sylvio; Dietrich, Christian
- Chemistry of Materials, Vol. 29, Issue 4
Excellent Compatibility of Solvate Ionic Liquids with Sulfide Solid Electrolytes: Toward Favorable Ionic Contacts in Bulk-Type All-Solid-State Lithium-Ion Batteries
journal, August 2015
- Oh, Dae Yang; Nam, Young Jin; Park, Kern Ho
- Advanced Energy Materials, Vol. 5, Issue 22
In situ SEM study of a lithium deposition and dissolution mechanism in a bulk-type solid-state cell with a Li2S–P2S5 solid electrolyte
journal, January 2013
- Nagao, Motohiro; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Physical Chemistry Chemical Physics, Vol. 15, Issue 42
Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes
journal, July 2017
- Porz, Lukas; Swamy, Tushar; Sheldon, Brian W.
- Advanced Energy Materials, Vol. 7, Issue 20
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries
journal, December 2017
- Albertus, Paul; Babinec, Susan; Litzelman, Scott
- Nature Energy, Vol. 3, Issue 1
Preparation and ionic conductivity of (100−x)(0.8Li2S·0.2P2S5)·xLiI glass–ceramic electrolytes
journal, October 2012
- Ujiie, Satoshi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Journal of Solid State Electrochemistry, Vol. 17, Issue 3
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
journal, August 2014
- Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A.
- Nature Materials, Vol. 13, Issue 10