Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries
Abstract
Rational construction of atomic-scale interfaces in multiphase nanocomposites is an intriguing and challenging approach to developing advanced catalysts for both oxygen reduction (ORR) and evolution reactions (OER). In this paper, a hybrid of interpenetrating metallic Co and spinel Co3O4 “Janus” nanoparticles stitched in porous graphitized shells (Co/Co3O4@PGS) is synthesized via ionic exchange and redox between Co2+ and 2D metal–organic-framework nanosheets. This strategy is proven to effectively establish highways for the transfer of electrons and reactants within the hybrid through interfacial engineering. Specifically, the phase interpenetration of mixed Co species and encapsulating porous graphitized shells provides an optimal charge/mass transport environment. Furthermore, the defect-rich interfaces act as atomic-traps to achieve exceptional adsorption capability for oxygen reactants. Finally, robust coupling between Co and N through intimate covalent bonds prohibits the detachment of nanoparticles. As a result, Co/Co3O4@PGS outperforms state-of-the-art noble-metal catalysts with a positive half-wave potential of 0.89 V for ORR and a low potential of 1.58 V at 10 mA cm-2 for OER. Finally, in a practical demonstration, ultrastable cyclability with a record lifetime of over 800 h at 10 mA cm-2 is achieved by Zn–air batteries with Co/Co3O4@PGS within the rechargeable air electrode.
- Authors:
-
- National Center for Nanoscience and Technology, Beijing (China). CAS Key Lab. for Nanosystem and Hierarchical Fabrication. CAS Center for Excellence in Nanoscience; Univ. of Chinese Academy of Sciences, Beijing (China); Univ. of Waterloo, ON (Canada). Dept. of Chemical Engineering. Waterloo Inst. for Nanotechnology. Waterloo Inst. for Sustainable Energy
- Univ. of Waterloo, ON (Canada). Dept. of Chemical Engineering. Waterloo Inst. for Nanotechnology. Waterloo Inst. for Sustainable Energy
- Henan Normal Univ., Xinxiang (China). School of Chemistry and Chemical Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
- National Center for Nanoscience and Technology, Beijing (China). CAS Key Lab. for Nanosystem and Hierarchical Fabrication. CAS Center for Excellence in Nanoscience; Univ. of Chinese Academy of Sciences, Beijing (China)
- Publication Date:
- Research Org.:
- Univ. of Waterloo, ON (Canada); National Center for Nanoscience and Technology, Beijing (China); Henan Normal Univ., Xinxiang (China); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE; Natural Sciences and Engineering Research Council of Canada (NSERC); National Natural Science Foundation of China (NSFC); 111 Project (China); Chinese Academy of Sciences (CAS)
- OSTI Identifier:
- 1425093
- Report Number(s):
- BNL-203305-2018-JAAM
Journal ID: ISSN 1614-6832; TRN: US1802042
- Grant/Contract Number:
- SC0012704; 21573083; D17007; XDA09040101
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 15; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; interpenetrating phases; metal-organic frameworks; bifunctional electrocatalysts; Zn-air batteries
Citation Formats
Jiang, Yi, Deng, Ya-Ping, Fu, Jing, Lee, Dong Un, Liang, Ruilin, Cano, Zachary Paul, Liu, Yangshuai, Bai, Zhengyu, Hwang, Sooyeon, Yang, Lin, Su, Dong, Chu, Weiguo, and Chen, Zhongwei. Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries. United States: N. p., 2018.
Web. doi:10.1002/aenm.201702900.
Jiang, Yi, Deng, Ya-Ping, Fu, Jing, Lee, Dong Un, Liang, Ruilin, Cano, Zachary Paul, Liu, Yangshuai, Bai, Zhengyu, Hwang, Sooyeon, Yang, Lin, Su, Dong, Chu, Weiguo, & Chen, Zhongwei. Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries. United States. https://doi.org/10.1002/aenm.201702900
Jiang, Yi, Deng, Ya-Ping, Fu, Jing, Lee, Dong Un, Liang, Ruilin, Cano, Zachary Paul, Liu, Yangshuai, Bai, Zhengyu, Hwang, Sooyeon, Yang, Lin, Su, Dong, Chu, Weiguo, and Chen, Zhongwei. Wed .
"Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries". United States. https://doi.org/10.1002/aenm.201702900. https://www.osti.gov/servlets/purl/1425093.
@article{osti_1425093,
title = {Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries},
author = {Jiang, Yi and Deng, Ya-Ping and Fu, Jing and Lee, Dong Un and Liang, Ruilin and Cano, Zachary Paul and Liu, Yangshuai and Bai, Zhengyu and Hwang, Sooyeon and Yang, Lin and Su, Dong and Chu, Weiguo and Chen, Zhongwei},
abstractNote = {Rational construction of atomic-scale interfaces in multiphase nanocomposites is an intriguing and challenging approach to developing advanced catalysts for both oxygen reduction (ORR) and evolution reactions (OER). In this paper, a hybrid of interpenetrating metallic Co and spinel Co3O4 “Janus” nanoparticles stitched in porous graphitized shells (Co/Co3O4@PGS) is synthesized via ionic exchange and redox between Co2+ and 2D metal–organic-framework nanosheets. This strategy is proven to effectively establish highways for the transfer of electrons and reactants within the hybrid through interfacial engineering. Specifically, the phase interpenetration of mixed Co species and encapsulating porous graphitized shells provides an optimal charge/mass transport environment. Furthermore, the defect-rich interfaces act as atomic-traps to achieve exceptional adsorption capability for oxygen reactants. Finally, robust coupling between Co and N through intimate covalent bonds prohibits the detachment of nanoparticles. As a result, Co/Co3O4@PGS outperforms state-of-the-art noble-metal catalysts with a positive half-wave potential of 0.89 V for ORR and a low potential of 1.58 V at 10 mA cm-2 for OER. Finally, in a practical demonstration, ultrastable cyclability with a record lifetime of over 800 h at 10 mA cm-2 is achieved by Zn–air batteries with Co/Co3O4@PGS within the rechargeable air electrode.},
doi = {10.1002/aenm.201702900},
journal = {Advanced Energy Materials},
number = 15,
volume = 8,
place = {United States},
year = {Wed Jan 31 00:00:00 EST 2018},
month = {Wed Jan 31 00:00:00 EST 2018}
}
Web of Science
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- Journal of Materials Chemistry A, Vol. 7, Issue 9
Bimetallic NiCo/CNF encapsulated in a N-doped carbon shell as an electrocatalyst for Zn–air batteries and water splitting
journal, January 2019
- Gebremariam, Tesfaye Tadesse; Chen, Fuyi; Jin, Yachao
- Catalysis Science & Technology, Vol. 9, Issue 10
Confined Co 9 S 8 into a defective carbon matrix as a bifunctional oxygen electrocatalyst for rechargeable zinc–air batteries
journal, January 2019
- Meng, Lu; Zhan, Ling; Jiang, Hongliang
- Catalysis Science & Technology, Vol. 9, Issue 20
Hierarchical Co 3 O 4 nanorods anchored on nitrogen doped reduced graphene oxide: a highly efficient bifunctional electrocatalyst for rechargeable Zn–air batteries
journal, January 2020
- Sanchez, Jaime S.; Maça, Rudi Ruben; Pendashteh, Afshin
- Catalysis Science & Technology, Vol. 10, Issue 5
N-Doped porous tremella-like Fe 3 C/C electrocatalysts derived from metal–organic frameworks for oxygen reduction reaction
journal, January 2020
- Yang, Xinxin; Sun, Xiang; Rauf, Muhammad
- Dalton Transactions, Vol. 49, Issue 3
Heteroatom-doped nanoporous carbon initiated from bimetallic molecular framework micro-rods for supercapacitor electrodes
journal, January 2019
- Wang, Qiang; Liang, Hongwei; Wu, Dun
- RSC Advances, Vol. 9, Issue 31
Hierarchical tri-functional electrocatalysts derived from bimetallic–imidazolate framework for overall water splitting and rechargeable zinc–air batteries
journal, January 2019
- Ahn, Sung Hoon; Manthiram, Arumugam
- Journal of Materials Chemistry A, Vol. 7, Issue 14
Cu and Co nanoparticle-Co-decorated N-doped graphene nanosheets: a high efficiency bifunctional electrocatalyst for rechargeable Zn–air batteries
journal, January 2019
- Liu, Peitao; Hu, Yating; Liu, Xiaokai
- Journal of Materials Chemistry A, Vol. 7, Issue 20
Toward a new generation of low cost, efficient, and durable metal–air flow batteries
journal, January 2019
- Yu, Wentao; Shang, Wenxu; Tan, Peng
- Journal of Materials Chemistry A, Vol. 7, Issue 47
Metal-organic framework-derived structures for next-generation rechargeable batteries
journal, December 2018
- Shi, Wenhui; Xu, Xilian; Zhang, Lin
- Functional Materials Letters, Vol. 11, Issue 06
Tuning Interfacial Structures for Better Catalysis of Water Electrolysis
journal, May 2019
- Xiang, Rui; Peng, Lishan; Wei, Zidong
- Chemistry – A European Journal, Vol. 25, Issue 42