Combined Rotating Disk Slurry Electrodeposition–Spontaneous Galvanic Displacement for Pt-M (M = Co, Ni, and Cu) Catalyst Synthesis for the Oxygen Reduction Reaction in Alkaline Media

Soto Pérez, Joesene J.; Peña-Duarte, Armando; Trinidad, Pedro; Quintana, Gerardo; Zhao, Xueru; Sasaki, Kotaro; José Yacamán, Miguel; Mendoza-Cruz, Rubén; Cabrera, Carlos R.

doi:10.1021/acsaem.2c02843

Title: Combined Rotating Disk Slurry Electrodeposition–Spontaneous Galvanic Displacement for Pt-M (M = Co, Ni, and Cu) Catalyst Synthesis for the Oxygen Reduction Reaction in Alkaline Media

Abstract

Here, platinum-modified first-row transition-metal catalyst (M = Ni, Co, and Cu) nanoparticles on a carbon black Vulcan XC-72R (CBV) support were synthesized using rotating disk slurry electrodeposition (RoDSE) followed by spontaneous galvanic displacement (SGD) reactions. These RoDSE–SGD catalysts were evaluated for the oxygen reduction reaction (ORR) in 0.1 M KOH using rotating disk electrode techniques. The Ni and Co RoDSEs were done by using an electrochemical applied potential of -0.75 V versus the RHE and for Cu, -0.80 V versus the RHE using a CBV slurry solution containing 0.1 M KClO₄. These metal nanoparticles on CBV (M/CBV) catalysts were modified with a Pt precursor via a spontaneous galvanic displacement (SGD) reaction, producing a Pt-M/CBV material to catalyze the ORR in an alkaline medium. High-resolution scanning transmission electron microscopy (HR-STEM) analysis indicates that the PtM/CBV samples include M clusters and Pt single atoms. The ORR characterization measurements were done under a controlled temperature (25.0 °C) and with a mass loading of 100 μg/cm² on a glassy carbon (GC) rotating disk electrode at 1600 rpm. The PtCo/CBV showed the highest ORR mass activity of 0.741 A/mgPt at 0.90 V versus the reversible hydrogen electrode (RHE) compared with commercial Pt/CBV. The M/CBV RoDSEmore »« less

Authors:

Soto Pérez, Joesene J. ^[1];

^[2]; Trinidad, Pedro ^[3]; Quintana, Gerardo ^[3]; Zhao, Xueru ^[4];

^[4]; José Yacamán, Miguel ^[5];

^[6];

^[2]

Univ. of Puerto Rico, PR (United States); Cornell Univ., Ithaca, NY (United States)
Univ. of Texas at El Paso, TX (United States)
Univ. of Puerto Rico, PR (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Northern Arizona Univ., Flagstaff, AZ (United States)
Universidad Nacional Autónoma de México (Mexico)

Publication Date:: Thu Dec 01 00:00:00 EST 2022

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Science Foundation (NSF)

OSTI Identifier:: 1913830

Report Number(s):: BNL-223883-2023-JAAM
Journal ID: ISSN 2574-0962

Grant/Contract Number:: SC0012704; DMR-1827622

Resource Type:: Accepted Manuscript

Journal Name:: ACS Applied Energy Materials

Additional Journal Information:: Journal Volume: 5; Journal Issue: 12; Journal ID: ISSN 2574-0962

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 30 DIRECT ENERGY CONVERSION; ORR; electrodeposition; electrocatalysis; interfaces; in situ XAS; first-row transition metals; OER

Citation Formats


                    Soto Pérez, Joesene J., Peña-Duarte, Armando, Trinidad, Pedro, Quintana, Gerardo, Zhao, Xueru, Sasaki, Kotaro, José Yacamán, Miguel, Mendoza-Cruz, Rubén, and Cabrera, Carlos R. Combined Rotating Disk Slurry Electrodeposition–Spontaneous Galvanic Displacement for Pt-M (M = Co, Ni, and Cu) Catalyst Synthesis for the Oxygen Reduction Reaction in Alkaline Media.  United States: N. p., 2022. 
Web.  doi:10.1021/acsaem.2c02843.

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                    Soto Pérez, Joesene J., Peña-Duarte, Armando, Trinidad, Pedro, Quintana, Gerardo, Zhao, Xueru, Sasaki, Kotaro, José Yacamán, Miguel, Mendoza-Cruz, Rubén, & Cabrera, Carlos R. Combined Rotating Disk Slurry Electrodeposition–Spontaneous Galvanic Displacement for Pt-M (M = Co, Ni, and Cu) Catalyst Synthesis for the Oxygen Reduction Reaction in Alkaline Media.  United States.  https://doi.org/10.1021/acsaem.2c02843

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                    Soto Pérez, Joesene J., Peña-Duarte, Armando, Trinidad, Pedro, Quintana, Gerardo, Zhao, Xueru, Sasaki, Kotaro, José Yacamán, Miguel, Mendoza-Cruz, Rubén, and Cabrera, Carlos R. Thu .  
"Combined Rotating Disk Slurry Electrodeposition–Spontaneous Galvanic Displacement for Pt-M (M = Co, Ni, and Cu) Catalyst Synthesis for the Oxygen Reduction Reaction in Alkaline Media".  United States.  https://doi.org/10.1021/acsaem.2c02843.  https://www.osti.gov/servlets/purl/1913830.

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@article{osti_1913830,

  title        = {Combined Rotating Disk Slurry Electrodeposition–Spontaneous Galvanic Displacement for Pt-M (M = Co, Ni, and Cu) Catalyst Synthesis for the Oxygen Reduction Reaction in Alkaline Media},

  author       = {Soto Pérez, Joesene J. and Peña-Duarte, Armando and Trinidad, Pedro and Quintana, Gerardo and Zhao, Xueru and Sasaki, Kotaro and José Yacamán, Miguel and Mendoza-Cruz, Rubén and Cabrera, Carlos R.},

  abstractNote = {Here, platinum-modified first-row transition-metal catalyst (M = Ni, Co, and Cu) nanoparticles on a carbon black Vulcan XC-72R (CBV) support were synthesized using rotating disk slurry electrodeposition (RoDSE) followed by spontaneous galvanic displacement (SGD) reactions. These RoDSE–SGD catalysts were evaluated for the oxygen reduction reaction (ORR) in 0.1 M KOH using rotating disk electrode techniques. The Ni and Co RoDSEs were done by using an electrochemical applied potential of -0.75 V versus the RHE and for Cu, -0.80 V versus the RHE using a CBV slurry solution containing 0.1 M KClO4. These metal nanoparticles on CBV (M/CBV) catalysts were modified with a Pt precursor via a spontaneous galvanic displacement (SGD) reaction, producing a Pt-M/CBV material to catalyze the ORR in an alkaline medium. High-resolution scanning transmission electron microscopy (HR-STEM) analysis indicates that the PtM/CBV samples include M clusters and Pt single atoms. The ORR characterization measurements were done under a controlled temperature (25.0 °C) and with a mass loading of 100 μg/cm2 on a glassy carbon (GC) rotating disk electrode at 1600 rpm. The PtCo/CBV showed the highest ORR mass activity of 0.741 A/mgPt at 0.90 V versus the reversible hydrogen electrode (RHE) compared with commercial Pt/CBV. The M/CBV RoDSE catalysts were also tested for the oxygen evolution reaction (OER), and Ni/CBV provided the lowest overpotential of 450 mV at 10 mA/cm2disk in 0.1 M KOH.},

  doi          = {10.1021/acsaem.2c02843},

  journal      = {ACS Applied Energy Materials},

  number       = 12,

  volume       = 5,

  place        = {United States},

  year         = {Thu Dec 01 00:00:00 EST 2022},

  month        = {Thu Dec 01 00:00:00 EST 2022}

}

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Title: Combined Rotating Disk Slurry Electrodeposition–Spontaneous Galvanic Displacement for Pt-M (M = Co, Ni, and Cu) Catalyst Synthesis for the Oxygen Reduction Reaction in Alkaline Media

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Proton Exchange Membrane Fuel Cells (PEMFCs): Advances and Challenges journal, September 2021

Surface Engineering of Carbon-Supported Platinum as a Route to Electrocatalysts with Superior Durability and Activity for PEMFC Cathodes journal, January 2022

Synergistic Mn-Co catalyst outperforms Pt on high-rate oxygen reduction for alkaline polymer electrolyte fuel cells journal, April 2019

Core–Shell CuPd@NiPd Nanoparticles: Coupling Lateral Strain with Electronic Interaction toward High-Efficiency Electrocatalysis journal, July 2022

Designing high performance Pt monolayer core–shell electrocatalysts for fuel cells journal, June 2020

Nonprecious transition metal nitrides as efficient oxygen reduction electrocatalysts for alkaline fuel cells journal, February 2022

Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni, and Co journal, January 1999

Oxygen Evolution Reaction in Alkaline Environment: Material Challenges and Solutions journal, March 2022

Host, Suppressor, and Promoter—The Roles of Ni and Fe on Oxygen Evolution Reaction Activity and Stability of NiFe Alloy Thin Films in Alkaline Media journal, August 2021

Pt/C Catalyst Preparation Using Rotating Disk-Slurry Electrode (RoDSE) Technique journal, July 2007

Platinum Electrodeposition at High Surface Area Carbon Vulcan-XC-72R Material Using a Rotating Disk-Slurry Electrode Technique journal, January 2010

Silver–Palladium Electrodeposition on Unsupported Vulcan XC-72R for Oxygen Reduction Reaction in Alkaline Media journal, June 2019

Iron Quantum Dots Electro-Assembling on Vulcan XC-72R: Hydrogen Peroxide Generation for Space Applications journal, June 2021

Glucose oxidation reaction at palladium-carbon nano-onions in alkaline media journal, July 2020

Potential dependent Ag nanoparticle electrodeposition on Vulcan XC-72R carbon support for alkaline oxygen reduction reaction journal, June 2021

Iridium and Ruthenium Electrodeposition at Platinum Nanopowder Using the Rotating Disc Slurry Electrode Technique journal, October 2011

Platinum Electrodeposition on Unsupported Single Wall Carbon Nanotubes and Its Application as Methane Sensing Material journal, December 2012

Platinum Electrodeposition on Unsupported Carbon Nano-Onions journal, November 2012

Platinum Electrodeposition at Unsupported Electrochemically Reduced Nanographene Oxide for Enhanced Ammonia Oxidation journal, January 2014

Rotating disk slurry electrodeposition of platinum at Y-zeolite/carbon Vulcan XC-72R for methanol oxidation in alkaline media journal, January 2015

Manufacture of Pd/Carbon Vulcan XC-72R Nanoflakes Catalysts for Ethanol Oxidation Reaction in Alkaline Media by RoDSE Method journal, January 2017

Rotating Disk Slurry Au Electrodeposition at Unsupported Carbon Vulcan XC-72 and Ce3+ Impregnation for Ethanol Oxidation in Alkaline Media journal, November 2016

RoDSE Synthesized Fine Tailored Au Nanoparticles from Au(X) 4 – (X = Cl – , Br – , and OH – ) on Unsupported Vulcan XC-72R for Ethanol Oxidation Reaction in Alkaline Media journal, December 2018

Molecular Insight of the Critical Role of Ni in Pt-Based Nanocatalysts for Improving the Oxygen Reduction Reaction Probed Using an In Situ SERS Borrowing Strategy journal, January 2021

Synergistic Bimetallic Metallic Organic Framework-Derived Pt–Co Oxygen Reduction Electrocatalysts journal, September 2020

High-Loading Pt–Co/C Catalyst with Enhanced Durability toward the Oxygen Reduction Reaction through Surface Au Modification journal, May 2020

Intermetallic PtCu Nanoframes as Efficient Oxygen Reduction Electrocatalysts journal, September 2020

Electrochemical behavior of the carbon black Vulcan XC-72R: Influence of the surface chemistry journal, April 2018

Catalytic Nanoarchitectures--the Importance of Nothing and the Unimportance of Periodicity journal, March 2003

The Chemical State of Sulfur in Carbon‐Supported Fuel‐Cell Electrodes journal, March 1996

Spontaneous galvanic displacement of Pt nanostructures on nickel foam: Synthesis, characterization and use for hydrogen evolution reaction journal, April 2018

Carbon supports for phosphoric acid fuel cell electrocatalysts: alternative materials and methods of evaluation journal, November 1981

A Practical Beginner’s Guide to Cyclic Voltammetry journal, November 2017

Structure of Pt/Ru Catalysts Using X-ray Absorption Near Edge Structure Studies journal, April 2001

Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts journal, January 2012

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal, June 2005

In Situ / Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy journal, September 2020

In Situ X-ray Absorption Spectroscopy of PtNi-Nanowire/Vulcan XC-72R under Oxygen Reduction Reaction in Alkaline Media journal, July 2021

Corrosion behavior of copper alloys in chloride media journal, August 2009

Corrosion of copper alloys in KOH, NaOH, NaCl, and HCl electrolyte solutions and its impact to the mechanical properties journal, April 2021

Electrochemical oxidation of nickel in alkaline solutions: a voltammetric study and modelling journal, January 1998

Quartz Crystal Electrogravimetry with Controlled Hydrodynamics: Applications to the Study of Nickel Electrodeposition journal, September 1994

Roles of Mo Surface Dopants in Enhancing the ORR Performance of Octahedral PtNi Nanoparticles journal, January 2018

Electrochemical Study of Bulk and Monolayer Copper in Alkaline Solution journal, January 2016

Recent Advances in the Understanding of Nickel-Based Catalysts for the Oxidation of Hydrogen-Containing Fuels in Alkaline Media journal, May 2020

Effect of pH and Water Structure on the Oxygen Reduction Reaction on platinum electrodes journal, July 2017

Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion journal, September 2015

Oxygen Reduction Kinetics in Low and Medium Temperature Acid Environment: Correlation of Water Activation and Surface Properties in Supported Pt and Pt Alloy Electrocatalysts journal, July 2004

Kinetics and mechanism of the electrochemical reduction of molecular oxygen on platinum in KOH: influence of preferred crystallographic orientation journal, June 1994

Oxygen electroreduction on titanium-supported thin Pt films in alkaline solution journal, January 1997

Combinatorial Studies of Palladium-Based Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells journal, February 2020

Templated-Assisted Synthesis of Structurally Ordered Intermetallic Pt3Co with Ultralow Loading Supported on 3D Porous Carbon for Oxygen Reduction Reaction journal, August 2021

Hydrogen production for energy: An overview
journal, February 2020

Does the Green Hydrogen Economy Have a Water Problem?
journal, August 2021

Proton Exchange Membrane Fuel Cells (PEMFCs): Advances and Challenges
journal, September 2021

Surface Engineering of Carbon-Supported Platinum as a Route to Electrocatalysts with Superior Durability and Activity for PEMFC Cathodes
journal, January 2022

Synergistic Mn-Co catalyst outperforms Pt on high-rate oxygen reduction for alkaline polymer electrolyte fuel cells
journal, April 2019

Core–Shell CuPd@NiPd Nanoparticles: Coupling Lateral Strain with Electronic Interaction toward High-Efficiency Electrocatalysis
journal, July 2022

Designing high performance Pt monolayer core–shell electrocatalysts for fuel cells
journal, June 2020

Nonprecious transition metal nitrides as efficient oxygen reduction electrocatalysts for alkaline fuel cells
journal, February 2022

Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni, and Co
journal, January 1999

Oxygen Evolution Reaction in Alkaline Environment: Material Challenges and Solutions
journal, March 2022

Host, Suppressor, and Promoter—The Roles of Ni and Fe on Oxygen Evolution Reaction Activity and Stability of NiFe Alloy Thin Films in Alkaline Media
journal, August 2021

Pt/C Catalyst Preparation Using Rotating Disk-Slurry Electrode (RoDSE) Technique
journal, July 2007

Platinum Electrodeposition at High Surface Area Carbon Vulcan-XC-72R Material Using a Rotating Disk-Slurry Electrode Technique
journal, January 2010

Silver–Palladium Electrodeposition on Unsupported Vulcan XC-72R for Oxygen Reduction Reaction in Alkaline Media
journal, June 2019

Iron Quantum Dots Electro-Assembling on Vulcan XC-72R: Hydrogen Peroxide Generation for Space Applications
journal, June 2021

Glucose oxidation reaction at palladium-carbon nano-onions in alkaline media
journal, July 2020

Potential dependent Ag nanoparticle electrodeposition on Vulcan XC-72R carbon support for alkaline oxygen reduction reaction
journal, June 2021

Iridium and Ruthenium Electrodeposition at Platinum Nanopowder Using the Rotating Disc Slurry Electrode Technique
journal, October 2011

Platinum Electrodeposition on Unsupported Single Wall Carbon Nanotubes and Its Application as Methane Sensing Material
journal, December 2012

Platinum Electrodeposition on Unsupported Carbon Nano-Onions
journal, November 2012

Platinum Electrodeposition at Unsupported Electrochemically Reduced Nanographene Oxide for Enhanced Ammonia Oxidation
journal, January 2014

Rotating disk slurry electrodeposition of platinum at Y-zeolite/carbon Vulcan XC-72R for methanol oxidation in alkaline media
journal, January 2015

Manufacture of Pd/Carbon Vulcan XC-72R Nanoflakes Catalysts for Ethanol Oxidation Reaction in Alkaline Media by RoDSE Method
journal, January 2017

Rotating Disk Slurry Au Electrodeposition at Unsupported Carbon Vulcan XC-72 and Ce3+ Impregnation for Ethanol Oxidation in Alkaline Media
journal, November 2016

RoDSE Synthesized Fine Tailored Au Nanoparticles from Au(X) ₄ ^– (X = Cl ^– , Br ^– , and OH ^– ) on Unsupported Vulcan XC-72R for Ethanol Oxidation Reaction in Alkaline Media
journal, December 2018

Molecular Insight of the Critical Role of Ni in Pt-Based Nanocatalysts for Improving the Oxygen Reduction Reaction Probed Using an In Situ SERS Borrowing Strategy
journal, January 2021

Synergistic Bimetallic Metallic Organic Framework-Derived Pt–Co Oxygen Reduction Electrocatalysts
journal, September 2020

High-Loading Pt–Co/C Catalyst with Enhanced Durability toward the Oxygen Reduction Reaction through Surface Au Modification
journal, May 2020

Intermetallic PtCu Nanoframes as Efficient Oxygen Reduction Electrocatalysts
journal, September 2020

Electrochemical behavior of the carbon black Vulcan XC-72R: Influence of the surface chemistry
journal, April 2018

Catalytic Nanoarchitectures--the Importance of Nothing and the Unimportance of Periodicity
journal, March 2003

The Chemical State of Sulfur in Carbon‐Supported Fuel‐Cell Electrodes
journal, March 1996

Spontaneous galvanic displacement of Pt nanostructures on nickel foam: Synthesis, characterization and use for hydrogen evolution reaction
journal, April 2018

Carbon supports for phosphoric acid fuel cell electrocatalysts: alternative materials and methods of evaluation
journal, November 1981

A Practical Beginner’s Guide to Cyclic Voltammetry
journal, November 2017

Structure of Pt/Ru Catalysts Using X-ray Absorption Near Edge Structure Studies
journal, April 2001

Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts
journal, January 2012

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

In Situ / Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy
journal, September 2020

In Situ X-ray Absorption Spectroscopy of PtNi-Nanowire/Vulcan XC-72R under Oxygen Reduction Reaction in Alkaline Media
journal, July 2021

Corrosion behavior of copper alloys in chloride media
journal, August 2009

Corrosion of copper alloys in KOH, NaOH, NaCl, and HCl electrolyte solutions and its impact to the mechanical properties
journal, April 2021

Electrochemical oxidation of nickel in alkaline solutions: a voltammetric study and modelling
journal, January 1998

Quartz Crystal Electrogravimetry with Controlled Hydrodynamics: Applications to the Study of Nickel Electrodeposition
journal, September 1994

Roles of Mo Surface Dopants in Enhancing the ORR Performance of Octahedral PtNi Nanoparticles
journal, January 2018

Electrochemical Study of Bulk and Monolayer Copper in Alkaline Solution
journal, January 2016

Recent Advances in the Understanding of Nickel-Based Catalysts for the Oxidation of Hydrogen-Containing Fuels in Alkaline Media
journal, May 2020

Effect of pH and Water Structure on the Oxygen Reduction Reaction on platinum electrodes
journal, July 2017

Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion
journal, September 2015

Oxygen Reduction Kinetics in Low and Medium Temperature Acid Environment: Correlation of Water Activation and Surface Properties in Supported Pt and Pt Alloy Electrocatalysts
journal, July 2004

Kinetics and mechanism of the electrochemical reduction of molecular oxygen on platinum in KOH: influence of preferred crystallographic orientation
journal, June 1994

Oxygen electroreduction on titanium-supported thin Pt films in alkaline solution
journal, January 1997

Combinatorial Studies of Palladium-Based Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells
journal, February 2020

Templated-Assisted Synthesis of Structurally Ordered Intermetallic Pt₃Co with Ultralow Loading Supported on 3D Porous Carbon for Oxygen Reduction Reaction
journal, August 2021