Ultrafast Electric Field Pulse Control of Giant Temperature Change in Ferroelectrics
Abstract
There is a surge of interest in developing environmentally friendly solid-state-based cooling technology. Here, we point out that a fast cooling rate (≈10^11 K/s) can be achieved by driving solid crystals to a high-temperature phase with a properly designed electric field pulse. Specifically, we predict that an ultrafast electric field pulse can cause a giant temperature decrease up to 32 K in PbTiO3 occurring on few picosecond time scales. We explain the underlying physics of this giant electric field pulse-induced temperature change with the concept of internal energy redistribution: the electric field does work on a ferroelectric crystal and redistributes its internal energy, and the way the kinetic energy is redistributed determines the temperature change and strongly depends on the electric field temporal profile. This concept is supported by our all-atom molecular dynamics simulations of PbTiO3 and BaTiO3. Moreover, this internal energy redistribution concept can also be applied to understand electrocaloric effect. We further propose new strategies for inducing giant cooling effect with ultrafast electric field pulse. This Letter offers a general framework to understand electric-field-induced temperature change and highlights the opportunities of electric field engineering for controlled design of fast and efficient cooling technology.
- Authors:
-
- Univ. of Pennsylvania, Philadelphia, PA (United States). Makineni Theoretical Lab., Dept. of Chemistry
- Carnegie Inst. for Science, Washington, DC (United States). Geophysical Lab.
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Univ. of Pennsylvania, Philadelphia, PA (United States)
- Sponsoring Org.:
- USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1424723
- Alternate Identifier(s):
- OSTI ID: 1418732; OSTI ID: 1867850
- Grant/Contract Number:
- AC02-76SF00515; FG02-07ER46431
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Letters
- Additional Journal Information:
- Journal Volume: 120; Journal Issue: 5; Journal ID: ISSN 0031-9007
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 42 ENGINEERING; Ferroelectrics; Electrocaloric effect; ferroelectrics, electrocaloric
Citation Formats
Qi, Y., Liu, S., Lindenberg, A. M., and Rappe, A. M. Ultrafast Electric Field Pulse Control of Giant Temperature Change in Ferroelectrics. United States: N. p., 2018.
Web. doi:10.1103/physrevlett.120.055901.
Qi, Y., Liu, S., Lindenberg, A. M., & Rappe, A. M. Ultrafast Electric Field Pulse Control of Giant Temperature Change in Ferroelectrics. United States. https://doi.org/10.1103/physrevlett.120.055901
Qi, Y., Liu, S., Lindenberg, A. M., and Rappe, A. M. Tue .
"Ultrafast Electric Field Pulse Control of Giant Temperature Change in Ferroelectrics". United States. https://doi.org/10.1103/physrevlett.120.055901. https://www.osti.gov/servlets/purl/1424723.
@article{osti_1424723,
title = {Ultrafast Electric Field Pulse Control of Giant Temperature Change in Ferroelectrics},
author = {Qi, Y. and Liu, S. and Lindenberg, A. M. and Rappe, A. M.},
abstractNote = {There is a surge of interest in developing environmentally friendly solid-state-based cooling technology. Here, we point out that a fast cooling rate (≈10^11 K/s) can be achieved by driving solid crystals to a high-temperature phase with a properly designed electric field pulse. Specifically, we predict that an ultrafast electric field pulse can cause a giant temperature decrease up to 32 K in PbTiO3 occurring on few picosecond time scales. We explain the underlying physics of this giant electric field pulse-induced temperature change with the concept of internal energy redistribution: the electric field does work on a ferroelectric crystal and redistributes its internal energy, and the way the kinetic energy is redistributed determines the temperature change and strongly depends on the electric field temporal profile. This concept is supported by our all-atom molecular dynamics simulations of PbTiO3 and BaTiO3. Moreover, this internal energy redistribution concept can also be applied to understand electrocaloric effect. We further propose new strategies for inducing giant cooling effect with ultrafast electric field pulse. This Letter offers a general framework to understand electric-field-induced temperature change and highlights the opportunities of electric field engineering for controlled design of fast and efficient cooling technology.},
doi = {10.1103/physrevlett.120.055901},
journal = {Physical Review Letters},
number = 5,
volume = 120,
place = {United States},
year = {Tue Jan 30 00:00:00 EST 2018},
month = {Tue Jan 30 00:00:00 EST 2018}
}
Web of Science
Figures / Tables:
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