Light-activated Gigahertz Ferroelectric Domain Dynamics
Abstract
Using time- and spatially-resolved hard X-ray diffraction microscopy, the striking structural and electrical dynamics upon optical excitation of a single crystal of BaTiO3 are simultaneously captured on sub-nanoseconds and nanoscale within individual ferroelectric domains and across walls. A large emergent photo-induced electric field of up to 20 million volts per meter is discovered in a surface layer of the crystal, which then drives polarization and lattice dynamics that are dramatically distinct in a surface layer versus bulk regions. A dynamical phase-field modeling (DPFM) method is developed that reveals the microscopic origin of these dynamics, leading to GHz polarization and elastic waves travelling in the crystal with sonic speeds and spatially varying frequencies. The advance of spatiotemporal imaging and dynamical modeling tools open opportunities of disentangling ultrafast processes in complex mesoscale structures such as ferroelectric domains
- Authors:
-
- Pennsylvania State Univ., University Park, PA (United States). Materials Research Inst. and Dept. of Materials Science and Engineering
- Pennsylvania State Univ., University Park, PA (United States). Materials Research Inst. and Dept. of Materials Science and Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Pennsylvania State Univ., University Park, PA (United States). Materials Research Inst. and Dept. of Materials Science and Engineering; Pennsylvania State Univ., University Park, PA (United States). Dept. of Physics
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1426228
- Alternate Identifier(s):
- OSTI ID: 1422652
- Grant/Contract Number:
- AC02-06CH11357; SC0012375; DMR-1420620; DMR-1410714
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Letters
- Additional Journal Information:
- Journal Volume: 120; Journal ID: ISSN 0031-9007
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Akamatsu, Hirofumii, Yuan, Yakun, Stoica, Vladimir A., Stone, Greg, Yang, Tiannan, Hong, Zijian, Lei, Shiming, Zhu, Yi, Haislmaier, Ryan C., Freeland, John W., Chen, Long-Qing, Wen, Haidan, and Gopalan, Venkatraman. Light-activated Gigahertz Ferroelectric Domain Dynamics. United States: N. p., 2018.
Web. doi:10.1103/PhysRevLett.120.096101.
Akamatsu, Hirofumii, Yuan, Yakun, Stoica, Vladimir A., Stone, Greg, Yang, Tiannan, Hong, Zijian, Lei, Shiming, Zhu, Yi, Haislmaier, Ryan C., Freeland, John W., Chen, Long-Qing, Wen, Haidan, & Gopalan, Venkatraman. Light-activated Gigahertz Ferroelectric Domain Dynamics. United States. https://doi.org/10.1103/PhysRevLett.120.096101
Akamatsu, Hirofumii, Yuan, Yakun, Stoica, Vladimir A., Stone, Greg, Yang, Tiannan, Hong, Zijian, Lei, Shiming, Zhu, Yi, Haislmaier, Ryan C., Freeland, John W., Chen, Long-Qing, Wen, Haidan, and Gopalan, Venkatraman. Mon .
"Light-activated Gigahertz Ferroelectric Domain Dynamics". United States. https://doi.org/10.1103/PhysRevLett.120.096101. https://www.osti.gov/servlets/purl/1426228.
@article{osti_1426228,
title = {Light-activated Gigahertz Ferroelectric Domain Dynamics},
author = {Akamatsu, Hirofumii and Yuan, Yakun and Stoica, Vladimir A. and Stone, Greg and Yang, Tiannan and Hong, Zijian and Lei, Shiming and Zhu, Yi and Haislmaier, Ryan C. and Freeland, John W. and Chen, Long-Qing and Wen, Haidan and Gopalan, Venkatraman},
abstractNote = {Using time- and spatially-resolved hard X-ray diffraction microscopy, the striking structural and electrical dynamics upon optical excitation of a single crystal of BaTiO3 are simultaneously captured on sub-nanoseconds and nanoscale within individual ferroelectric domains and across walls. A large emergent photo-induced electric field of up to 20 million volts per meter is discovered in a surface layer of the crystal, which then drives polarization and lattice dynamics that are dramatically distinct in a surface layer versus bulk regions. A dynamical phase-field modeling (DPFM) method is developed that reveals the microscopic origin of these dynamics, leading to GHz polarization and elastic waves travelling in the crystal with sonic speeds and spatially varying frequencies. The advance of spatiotemporal imaging and dynamical modeling tools open opportunities of disentangling ultrafast processes in complex mesoscale structures such as ferroelectric domains},
doi = {10.1103/PhysRevLett.120.096101},
journal = {Physical Review Letters},
number = ,
volume = 120,
place = {United States},
year = {Mon Feb 26 00:00:00 EST 2018},
month = {Mon Feb 26 00:00:00 EST 2018}
}
Web of Science
Works referenced in this record:
Field-Dependent Domain Distortion and Interlayer Polarization Distribution in Superlattices
journal, January 2013
- Chen, Pice; Cosgriff, Margaret P.; Zhang, Qingteng
- Physical Review Letters, Vol. 110, Issue 4
Ultrafast Photovoltaic Response in Ferroelectric Nanolayers
journal, February 2012
- Daranciang, Dan; Highland, Matthew J.; Wen, Haidan
- Physical Review Letters, Vol. 108, Issue 8
Mesoscopic structural phase progression in photo-excited VO2 revealed by time-resolved x-ray diffraction microscopy
journal, February 2016
- Zhu, Yi; Cai, Zhonghou; Chen, Pice
- Scientific Reports, Vol. 6, Issue 1
A phenomenological thermodynamic potential for BaTiO3 single crystals
journal, September 2005
- Li, Y. L.; Cross, L. E.; Chen, L. Q.
- Journal of Applied Physics, Vol. 98, Issue 6
Surface Layer in BaTiO 3 Single Crystals
journal, September 1961
- Fatuzzo, Ennio; Merz, Walter J.
- Journal of Applied Physics, Vol. 32, Issue 9
Aperiodic topological order in the domain configurations of functional materials
journal, March 2017
- Huang, Fei-Ting; Cheong, Sang-Wook
- Nature Reviews Materials, Vol. 2, Issue 3
Multiple-time-scale analysis of nonlinear modes in ferroelectric
journal, February 2010
- Bandyopadhyay, A. K.; Ray, P. C.; Vu-Quoc, Loc
- Physical Review B, Vol. 81, Issue 6
Switching Time in Ferroelectric BaTiO 3 and Its Dependence on Crystal Thickness
journal, August 1956
- Merz, Walter J.
- Journal of Applied Physics, Vol. 27, Issue 8
Electromechanical Properties of Oxygen‐Octahedra Ferroelectric Crystals
journal, February 1972
- Yamada, Tomoaki
- Journal of Applied Physics, Vol. 43, Issue 2
Electronic Origin of Ultrafast Photoinduced Strain in
journal, January 2013
- Wen, Haidan; Chen, Pice; Cosgriff, Margaret P.
- Physical Review Letters, Vol. 110, Issue 3
Ferroelastic domain switching dynamics under electrical and mechanical excitations
journal, May 2014
- Gao, Peng; Britson, Jason; Nelson, Christopher T.
- Nature Communications, Vol. 5, Issue 1
Beyond crystallography: Diffractive imaging using coherent x-ray light sources
journal, April 2015
- Miao, J.; Ishikawa, T.; Robinson, I. K.
- Science, Vol. 348, Issue 6234
Surface Space-Charge Layers in Barium Titanate
journal, May 1956
- Chynoweth, A. G.
- Physical Review, Vol. 102, Issue 3
Lattice‐Dynamical Theory of Switching in Barium Titanate Single Crystals
journal, June 1967
- Nettleton, R. E.
- Journal of Applied Physics, Vol. 38, Issue 7
Magnetoelectric domain control in multiferroic TbMnO3
journal, June 2015
- Matsubara, M.; Manz, S.; Mochizuki, M.
- Science, Vol. 348, Issue 6239
Stability of the unswitched polarization state of ultrathin epitaxial in large electric fields
journal, July 2009
- Grigoriev, Alexei; Sichel, Rebecca J.; Jo, Ji Young
- Physical Review B, Vol. 80, Issue 1
Ultrafast light-induced symmetry changes in single BaTiO 3 nanowires
journal, January 2017
- Kuo, Yi-Hong; Nah, Sanghee; He, Kai
- Journal of Materials Chemistry C, Vol. 5, Issue 6
Ferroelectric domain wall motion induced by polarized light
journal, March 2015
- Rubio-Marcos, Fernando; Del Campo, Adolfo; Marchet, Pascal
- Nature Communications, Vol. 6, Issue 1
Optically enhanced coherent transport in YBa2Cu3O6.5 by ultrafast redistribution of interlayer coupling
journal, May 2014
- Hu, W.; Kaiser, S.; Nicoletti, D.
- Nature Materials, Vol. 13, Issue 7
Ultrafast terahertz-field-driven ionic response in ferroelectric
journal, November 2016
- Chen, F.; Zhu, Y.; Liu, S.
- Physical Review B, Vol. 94, Issue 18
Two-photon absorption and anisotropic transient energy transfer in BaTiO_3 with 1-psec excitation
journal, January 1990
- Boggess, Thomas F.; White, Jeffrey O.; Valley, George C.
- Journal of the Optical Society of America B, Vol. 7, Issue 12
High dielectric constant ceramics
journal, November 1946
- von Hippel, A.; Breckenridge, R. G.; Chesley, F. G.
- Industrial & Engineering Chemistry, Vol. 38, Issue 11
Low- and high-order nonlinear optical properties of BaTiO_3 and SrTiO_3 nanoparticles
journal, January 2008
- Ganeev, R. A.; Suzuki, M.; Baba, M.
- Journal of the Optical Society of America B, Vol. 25, Issue 3
Structures of the ferroelectric phases of barium titanate
journal, March 1993
- Kwei, G. H.; Lawson, A. C.; Billinge, S. J. L.
- The Journal of Physical Chemistry, Vol. 97, Issue 10
Domain Dynamics During Ferroelectric Switching
journal, November 2011
- Nelson, C. T.; Gao, P.; Jokisaari, J. R.
- Science, Vol. 334, Issue 6058
Nanosecond Domain Wall Dynamics in Ferroelectric Thin Films
journal, May 2006
- Grigoriev, Alexei; Do, Dal-Hyun; Kim, Dong Min
- Physical Review Letters, Vol. 96, Issue 18
Nonlinear optical absorption in undoped and cerium-doped BaTiO3 thin films using Z-scan technique
journal, February 2000
- Zhang, W. F.; Huang, Y. B.; Zhang, M. S.
- Applied Physics Letters, Vol. 76, Issue 8
Lattice Dynamics of Laser Excited Ferroelectric BaTiO 3
journal, February 2012
- Issenmann, D.; Schleef, S.; Ibrahimkutty, S.
- Acta Physica Polonica A, Vol. 121, Issue 2
Dynamics of the laser-induced ferroelectric excitation in BaTiO3 studied by x-ray diffraction
journal, January 2007
- Istomin, Konstantin; Kotaidis, Vassilios; Plech, Anton
- Applied Physics Letters, Vol. 90, Issue 2
Effect of electrical boundary conditions on ferroelectric domain structures in thin films
journal, July 2002
- Li, Y. L.; Hu, S. Y.; Liu, Z. K.
- Applied Physics Letters, Vol. 81, Issue 3
Structural and electronic recovery pathways of a photoexcited ultrathin VO film
journal, October 2013
- Wen, Haidan; Guo, Lu; Barnes, Eftihia
- Physical Review B, Vol. 88, Issue 16
Nanosecond Structural Visualization of the Reproducibility of Polarization Switching in Ferroelectrics
journal, November 2006
- Grigoriev, Alexei; Do, Dal-Hyun; Kim, Dong Min
- Integrated Ferroelectrics, Vol. 85, Issue 1
Thermal expansion, polarization and phase diagrams of Ba 1− y Bi 2 y /3 Ti 1− x Zr x O 3 and Ba 1− y La y Ti 1− y /4 O 3 compounds
journal, January 2009
- Gorev, Michail; Bondarev, Vitaly; Flerov, Igor
- Journal of Physics: Condensed Matter, Vol. 21, Issue 7
Imaging Local Polarization in Ferroelectric Thin Films by Coherent X-Ray Bragg Projection Ptychography
journal, April 2013
- Hruszkewycz, S. O.; Highland, M. J.; Holt, M. V.
- Physical Review Letters, Vol. 110, Issue 17, Article No. 177601
Nonlinear optical absorption and refraction of epitaxial Ba0.6Sr0.4TiO3 thin films on (001) MgO substrates
journal, December 2005
- Liu, S. W.; Xu, J.; Guzun, D.
- Applied Physics B, Vol. 82, Issue 3
Phase-field model of domain structures in ferroelectric thin films
journal, June 2001
- Li, Y. L.; Hu, S. Y.; Liu, Z. K.
- Applied Physics Letters, Vol. 78, Issue 24
Light Waves at the Boundary of Nonlinear Media
journal, October 1962
- Bloembergen, N.; Pershan, P. S.
- Physical Review, Vol. 128, Issue 2
Low-energy structural dynamics of ferroelectric domain walls in hexagonal rare-earth manganites
journal, May 2017
- Wu, Xiaoyu; Petralanda, Urko; Zheng, Lu
- Science Advances, Vol. 3, Issue 5
Space Charge Layer Near the Surface of a Ferroelectric
journal, April 1955
- Känzig, Werner
- Physical Review, Vol. 98, Issue 2
Visualization of nanocrystal breathing modes at extreme strains
journal, March 2015
- Szilagyi, Erzsi; Wittenberg, Joshua S.; Miller, Timothy A.
- Nature Communications, Vol. 6, Issue 1
Dynamics and Control in Complex Transition Metal Oxides
journal, July 2014
- Zhang, J.; Averitt, R. D.
- Annual Review of Materials Research, Vol. 44, Issue 1
High contrast 3D imaging of surfaces near the wavelength limit using tabletop EUV ptychography
journal, November 2015
- Zhang, Bosheng; Gardner, Dennis F.; Seaberg, Matthew D.
- Ultramicroscopy, Vol. 158
Nanoscale electrodynamics of strongly correlated quantum materials
journal, November 2016
- Liu, Mengkun; Sternbach, Aaron J.; Basov, D. N.
- Reports on Progress in Physics, Vol. 80, Issue 1
An approach to the Klein–Gordon equation for a dynamic study in ferroelectric materials
journal, April 2006
- Bandyopadhyay, A. K.; Ray, P. C.; Gopalan, Venkatraman
- Journal of Physics: Condensed Matter, Vol. 18, Issue 16
Tabletop nanometer extreme ultraviolet imaging in an extended reflection mode using coherent Fresnel ptychography
journal, January 2014
- Seaberg, Matthew D.; Zhang, Bosheng; Gardner, Dennis F.
- Optica, Vol. 1, Issue 1
Domain wall nanoelectronics
journal, February 2012
- Catalan, G.; Seidel, J.; Ramesh, R.
- Reviews of Modern Physics, Vol. 84, Issue 1
Dielectric Constant in Paraelectric Perovskites
journal, August 1964
- Rupprecht, G.; Bell, R. O.
- Physical Review, Vol. 135, Issue 3A
X-Ray Study of the Surface Layer on Barium Titanate Single Crystal
journal, January 1972
- Motegi, Hiroshi
- Journal of the Physical Society of Japan, Vol. 32, Issue 1
Ultrafast optical tuning of ferromagnetism via the carrier density
journal, April 2015
- Matsubara, Masakazu; Schroer, Alexander; Schmehl, Andreas
- Nature Communications, Vol. 6, Issue 1
Nanosecond Dynamics of Ferroelectric/Dielectric Superlattices
journal, July 2011
- Jo, Ji Young; Chen, Pice; Sichel, Rebecca J.
- Physical Review Letters, Vol. 107, Issue 5
Ultrafast Terahertz Gating of the Polarization and Giant Nonlinear Optical Response in BiFeO 3 Thin Films
journal, September 2015
- Chen, Frank; Goodfellow, John; Liu, Shi
- Advanced Materials, Vol. 27, Issue 41
Thermotropic phase boundaries in classic ferroelectrics
journal, January 2014
- Lummen, Tom T. A.; Gu, Yijia; Wang, Jianjun
- Nature Communications, Vol. 5, Issue 1
Optically enhanced coherent transport in YBa2Cu3O6.5 by ultrafast redistribution of interlayer coupling
text, January 2013
- Hu, W.; Kaiser, S.; Nicoletti, D.
- arXiv
Tabletop Nanometer Extreme Ultraviolet Imaging in an Extended Reflection Mode using Coherent Fresnel Ptychography
preprint, January 2013
- Seaberg, Matthew D.; Zhang, Bosheng; Gardner, Dennis F.
- arXiv
Mesoscopic structural phase progression in photo-excited VO2 revealed by time-resolved x-ray diffraction microscopy
text, January 2015
- Zhu, Yi; Cai, Zhonghou; Chen, Pice
- arXiv
Ultrafast terahertz-field-driven ionic response in ferroelectric BaTiO$_3$
text, January 2016
- Chen, F.; Zhu, Y.; Liu, S.
- arXiv
Aperiodic topological order in the domain configurations of functional materials
text, January 2017
- Huang, Fei-Ting; Cheong, Sang-Wook
- arXiv
Works referencing / citing this record:
Unexpected Giant Microwave Conductivity in a Nominally Silent BiFeO 3 Domain Wall
journal, January 2020
- Huang, Yen‐Lin; Zheng, Lu; Chen, Peng
- Advanced Materials, Vol. 32, Issue 9