A spongy nickel-organic CO2 reduction photocatalyst for nearly 100% selective CO production
Abstract
Solar-driven photocatalytic conversion of CO2 into fuels has attracted a lot of interest; however, developing active catalysts that can selectively convert CO2 to fuels with desirable reaction products remains a grand challenge. For instance, complete suppression of the competing H2 evolution during photocatalytic CO2-to-CO conversion has not been achieved before. We design and synthesize a spongy nickel-organic heterogeneous photocatalyst via a photochemical route. The catalyst has a crystalline network architecture with a high concentration of defects. It is highly active in converting CO2 to CO, with a production rate of ~1.6 × 104 μmol hour–1 g–1. No measurable H2 is generated during the reaction, leading to nearly 100% selective CO production over H2 evolution. When the spongy Ni-organic catalyst is enriched with Rh or Ag nanocrystals, the controlled photocatalytic CO2 reduction reactions generate formic acid and acetic acid. As a result, achieving such a spongy nickel-organic photocatalyst is a critical step toward practical production of high-value multicarbon fuels using solar energy.
- Authors:
-
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Nanyang Technological Univ. (Singapore); SinBeRISE (Singapore-Berkeley Research Initiative for Sustainable Energy) CREATE (Singapore)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of Science and Technology Beijing, Beijing (People's Republic of China)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Leiden Univ., Leiden (Netherlands)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1419436
- Alternate Identifier(s):
- OSTI ID: 1409644
- Report Number(s):
- BNL-114699-2017-JA
Journal ID: ISSN 2375-2548; ark:/13030/qt84194890
- Grant/Contract Number:
- AC02-05CH11231; SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 7; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; CO2 reduction photocatalyst; Center for Functional Nanomaterials
Citation Formats
Niu, Kaiyang, Xu, You, Wang, Haicheng, Ye, Rong, Xin, Huolin L., Lin, Feng, Tian, Chixia, Lum, Yanwei, Bustillo, Karen C., Doeff, Marca M., Koper, Marc T. M., Ager, Joel, Xu, Rong, and Zheng, Haimei. A spongy nickel-organic CO2 reduction photocatalyst for nearly 100% selective CO production. United States: N. p., 2017.
Web. doi:10.1126/sciadv.1700921.
Niu, Kaiyang, Xu, You, Wang, Haicheng, Ye, Rong, Xin, Huolin L., Lin, Feng, Tian, Chixia, Lum, Yanwei, Bustillo, Karen C., Doeff, Marca M., Koper, Marc T. M., Ager, Joel, Xu, Rong, & Zheng, Haimei. A spongy nickel-organic CO2 reduction photocatalyst for nearly 100% selective CO production. United States. https://doi.org/10.1126/sciadv.1700921
Niu, Kaiyang, Xu, You, Wang, Haicheng, Ye, Rong, Xin, Huolin L., Lin, Feng, Tian, Chixia, Lum, Yanwei, Bustillo, Karen C., Doeff, Marca M., Koper, Marc T. M., Ager, Joel, Xu, Rong, and Zheng, Haimei. Fri .
"A spongy nickel-organic CO2 reduction photocatalyst for nearly 100% selective CO production". United States. https://doi.org/10.1126/sciadv.1700921. https://www.osti.gov/servlets/purl/1419436.
@article{osti_1419436,
title = {A spongy nickel-organic CO2 reduction photocatalyst for nearly 100% selective CO production},
author = {Niu, Kaiyang and Xu, You and Wang, Haicheng and Ye, Rong and Xin, Huolin L. and Lin, Feng and Tian, Chixia and Lum, Yanwei and Bustillo, Karen C. and Doeff, Marca M. and Koper, Marc T. M. and Ager, Joel and Xu, Rong and Zheng, Haimei},
abstractNote = {Solar-driven photocatalytic conversion of CO2 into fuels has attracted a lot of interest; however, developing active catalysts that can selectively convert CO2 to fuels with desirable reaction products remains a grand challenge. For instance, complete suppression of the competing H2 evolution during photocatalytic CO2-to-CO conversion has not been achieved before. We design and synthesize a spongy nickel-organic heterogeneous photocatalyst via a photochemical route. The catalyst has a crystalline network architecture with a high concentration of defects. It is highly active in converting CO2 to CO, with a production rate of ~1.6 × 104 μmol hour–1 g–1. No measurable H2 is generated during the reaction, leading to nearly 100% selective CO production over H2 evolution. When the spongy Ni-organic catalyst is enriched with Rh or Ag nanocrystals, the controlled photocatalytic CO2 reduction reactions generate formic acid and acetic acid. As a result, achieving such a spongy nickel-organic photocatalyst is a critical step toward practical production of high-value multicarbon fuels using solar energy.},
doi = {10.1126/sciadv.1700921},
journal = {Science Advances},
number = 7,
volume = 3,
place = {United States},
year = {Fri Jul 28 00:00:00 EDT 2017},
month = {Fri Jul 28 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Electrochemical Reduction of Carbon Dioxide at a Platinum Electrode in Acetonitrile-Water Mixtures
journal, January 2000
- Tomita, Y.; Teruya, S.; Koga, O.
- Journal of The Electrochemical Society, Vol. 147, Issue 11
CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012
- Li, Christina W.; Kanan, Matthew W.
- Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
Warming caused by cumulative carbon emissions towards the trillionth tonne
journal, April 2009
- Allen, Myles R.; Frame, David J.; Huntingford, Chris
- Nature, Vol. 458, Issue 7242
Co 3 O 4 Hexagonal Platelets with Controllable Facets Enabling Highly Efficient Visible-Light Photocatalytic Reduction of CO 2
journal, May 2016
- Gao, Chao; Meng, Qiangqiang; Zhao, Kun
- Advanced Materials, Vol. 28, Issue 30
Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006
- Lewis, N. S.; Nocera, D. G.
- Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
Conversion of CO 2 from Air into Methanol Using a Polyamine and a Homogeneous Ruthenium Catalyst
journal, January 2016
- Kothandaraman, Jotheeswari; Goeppert, Alain; Czaun, Miklos
- Journal of the American Chemical Society, Vol. 138, Issue 3
The climate response to five trillion tonnes of carbon
journal, May 2016
- Tokarska, Katarzyna B.; Gillett, Nathan P.; Weaver, Andrew J.
- Nature Climate Change, Vol. 6, Issue 9
Nature-Inspired, Highly Durable CO 2 Reduction System Consisting of a Binuclear Ruthenium(II) Complex and an Organic Semiconductor Using Visible Light
journal, April 2016
- Kuriki, Ryo; Matsunaga, Hironori; Nakashima, Takuya
- Journal of the American Chemical Society, Vol. 138, Issue 15
Catalytic Aspects of Light-Induced Hydrogen Generation in Water with TiO2 and Other Photocatalysts: A Simple and Practical Way Towards a Normalization?
journal, January 2010
- Maschmeyer, Thomas; Che, Michel
- Angewandte Chemie International Edition, Vol. 49, Issue 9
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
journal, April 2014
- Li, Christina W.; Ciston, Jim; Kanan, Matthew W.
- Nature, Vol. 508, Issue 7497
Photocatalytic Reduction of Carbon Dioxide over Ag Cocatalyst-Loaded ALa 4 Ti 4 O 15 (A = Ca, Sr, and Ba) Using Water as a Reducing Reagent
journal, December 2011
- Iizuka, Kosuke; Wato, Tomoaki; Miseki, Yugo
- Journal of the American Chemical Society, Vol. 133, Issue 51
Synthesis and Structure Characterization of Copper Terephthalate Metal-Organic Frameworks
journal, June 2009
- Carson, Cantwell G.; Hardcastle, Kenneth; Schwartz, Justin
- European Journal of Inorganic Chemistry, Vol. 2009, Issue 16
CO2 photoreduction at enzyme-modified metal oxide nanoparticles
journal, January 2011
- Woolerton, Thomas W.; Sheard, Sally; Pierce, Elizabeth
- Energy & Environmental Science, Vol. 4, Issue 7
Development of a Stable MnCo 2 O 4 Cocatalyst for Photocatalytic CO 2 Reduction with Visible Light
journal, February 2015
- Wang, Sibo; Hou, Yidong; Wang, Xinchen
- ACS Applied Materials & Interfaces, Vol. 7, Issue 7
Accelerating extinction risk from climate change
journal, April 2015
- Urban, M. C.
- Science, Vol. 348, Issue 6234
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
journal, August 2014
- Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R.
- Journal of the American Chemical Society, Vol. 136, Issue 40
Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K
journal, February 2017
- Cheng, Tao; Xiao, Hai; Goddard, William A.
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 8
The teraton challenge. A review of fixation and transformation of carbon dioxide
journal, January 2010
- Mikkelsen, Mette; Jørgensen, Mikkel; Krebs, Frederik C.
- Energy Environ. Sci., Vol. 3, Issue 1
Characterizing loss and damage from climate change
journal, October 2014
- James, Rachel; Otto, Friederike; Parker, Hannah
- Nature Climate Change, Vol. 4, Issue 11
Climate Change Impacts on Global Food Security
journal, August 2013
- Wheeler, T.; von Braun, J.
- Science, Vol. 341, Issue 6145
Visible-Light-Driven CO 2 Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts
journal, January 2015
- Kuriki, Ryo; Sekizawa, Keita; Ishitani, Osamu
- Angewandte Chemie International Edition, Vol. 54, Issue 8
Tuning the structure and function of metal–organic frameworks via linker design
journal, January 2014
- Lu, Weigang; Wei, Zhangwen; Gu, Zhi-Yuan
- Chem. Soc. Rev., Vol. 43, Issue 16
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
journal, August 2008
- Kanan, M. W.; Nocera, D. G.
- Science, Vol. 321, Issue 5892, p. 1072-1075
Impact of Anthropogenic CO2 on the CaCO3 System in the Oceans
journal, July 2004
- Feely, R. A.
- Science, Vol. 305, Issue 5682
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015
- Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao
- Science, Vol. 349, Issue 6253
Thermodynamic and achievable efficiencies for solar-driven electrochemical reduction of carbon dioxide to transportation fuels
journal, October 2015
- Singh, Meenesh R.; Clark, Ezra L.; Bell, Alexis T.
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 45
Photocatalytic CO 2 Reduction Using Cu(I) Photosensitizers with a Fe(II) Catalyst
journal, March 2016
- Takeda, Hiroyuki; Ohashi, Kenji; Sekine, Akiko
- Journal of the American Chemical Society, Vol. 138, Issue 13
Why Capture CO2 from the Atmosphere?
journal, September 2009
- Keith, D. W.
- Science, Vol. 325, Issue 5948
Photocatalytic CO 2 reduction by CdS promoted with a zeolitic imidazolate framework
journal, January 2015
- Wang, Sibo; Wang, Xinchen
- Applied Catalysis B: Environmental, Vol. 162
Visible-Light-Induced Selective CO 2 Reduction Utilizing a Ruthenium Complex Electrocatalyst Linked to a p-Type Nitrogen-Doped Ta 2 O 5 Semiconductor
journal, June 2010
- Sato, Shunsuke; Morikawa, Takeshi; Saeki, Shu
- Angewandte Chemie International Edition, Vol. 49, Issue 30
Inhibited proton transfer enhances Au-catalyzed CO 2 -to-fuels selectivity
journal, July 2016
- Wuttig, Anna; Yaguchi, Momo; Motobayashi, Kenta
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 32
Studies of the pH dependence of carbon-13 shifts and carbon-carbon coupling constants of [U-13C]aspartic and -glutamic acids
journal, June 1978
- London, Robert E.; Walker, Thomas E.; Kollman, Victor H.
- Journal of the American Chemical Society, Vol. 100, Issue 12
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
journal, September 2014
- Luo, J.; Im, J. -H.; Mayer, M. T.
- Science, Vol. 345, Issue 6204
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Hydrogen Generation by Visible Light Irradiation of Aqueous Solutions of Metal Complexes. An approach to the photochemical conversion and storage of solar energy
journal, June 1979
- Kirch, Michele; Lehn, Jean-Marie; Sauvage, Jean-Pierre
- Helvetica Chimica Acta, Vol. 62, Issue 4
A stable ZnCo 2 O 4 cocatalyst for photocatalytic CO 2 reduction
journal, January 2015
- Wang, Sibo; Ding, Zhengxin; Wang, Xinchen
- Chemical Communications, Vol. 51, Issue 8
Tuning Complex Transition Metal Hydroxide Nanostructures as Active Catalysts for Water Oxidation by a Laser–Chemical Route
journal, March 2015
- Niu, Kai-Yang; Lin, Feng; Jung, Suho
- Nano Letters, Vol. 15, Issue 4
Photocatalytic Reduction of CO 2 on TiO 2 and Other Semiconductors
journal, June 2013
- Habisreutinger, Severin N.; Schmidt-Mende, Lukas; Stolarczyk, Jacek K.
- Angewandte Chemie International Edition, Vol. 52, Issue 29
The velocity of climate change
journal, December 2009
- Loarie, Scott R.; Duffy, Philip B.; Hamilton, Healy
- Nature, Vol. 462, Issue 7276
Tailoring Copper Nanocrystals towards C 2 Products in Electrochemical CO 2 Reduction
journal, April 2016
- Loiudice, Anna; Lobaccaro, Peter; Kamali, Esmail A.
- Angewandte Chemie International Edition, Vol. 55, Issue 19
Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin
journal, September 2015
- Shen, Jing; Kortlever, Ruud; Kas, Recep
- Nature Communications, Vol. 6, Issue 1
Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO 2 under Mild Reaction Conditions
journal, December 2013
- Wang, Sibo; Yao, Wangshu; Lin, Jinliang
- Angewandte Chemie International Edition, Vol. 53, Issue 4
Low-temperature oxidation of CO catalysed by Co3O4 nanorods
journal, April 2009
- Xie, Xiaowei; Li, Yong; Liu, Zhi-Quan
- Nature, Vol. 458, Issue 7239, p. 746-749
Future temperature in southwest Asia projected to exceed a threshold for human adaptability
journal, October 2015
- Pal, Jeremy S.; Eltahir, Elfatih A. B.
- Nature Climate Change, Vol. 6, Issue 2
Electrochemical CO 2 Reduction to Formic Acid at Low Overpotential and with High Faradaic Efficiency on Carbon-Supported Bimetallic Pd–Pt Nanoparticles
journal, June 2015
- Kortlever, Ruud; Peters, Ines; Koper, Sander
- ACS Catalysis, Vol. 5, Issue 7
Light-Driven Hydrogen Generation: Efficient Iron-Based Water Reduction Catalysts
journal, December 2009
- Gärtner, Felix; Sundararaju, Basker; Surkus, Annette-Enrica
- Angewandte Chemie International Edition, Vol. 48, Issue 52
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
journal, August 2015
- White, James L.; Baruch, Maor F.; Pander, James E.
- Chemical Reviews, Vol. 115, Issue 23
Future CO 2 Emissions and Climate Change from Existing Energy Infrastructure
journal, September 2010
- Davis, Steven J.; Caldeira, Ken; Matthews, H. Damon
- Science, Vol. 329, Issue 5997
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012
- Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
- Energy & Environmental Science, Vol. 5, Issue 5
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Importance of trivalency and the eg1 configuration in the photocatalytic oxidation of water by Mn and Co oxides
journal, July 2013
- Maitra, U.; Naidu, B. S.; Govindaraj, A.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 29
Research opportunities to advance solar energy utilization
journal, January 2016
- Lewis, N. S.
- Science, Vol. 351, Issue 6271
Photocatalytic CO 2 reduction using a Mn complex as a catalyst
journal, January 2014
- Takeda, Hiroyuki; Koizumi, Hiroki; Okamoto, Kouhei
- Chem. Commun., Vol. 50, Issue 12
A Langmuir-like desorption model for reflecting the inhomogeneous pore structure of coal and its experimental verification
journal, January 2015
- Jiang, Haina; Cheng, Yuanping; Yuan, Liang
- RSC Advances, Vol. 5, Issue 4
Visible-Light-Induced Selective CO 2 Reduction Utilizing a Ruthenium Complex Electrocatalyst Linked to a p-Type Nitrogen-Doped Ta 2 O 5 Semiconductor
journal, June 2010
- Sato, Shunsuke; Morikawa, Takeshi; Saeki, Shu
- Angewandte Chemie, Vol. 122, Issue 30
Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO 2 under Mild Reaction Conditions
journal, December 2013
- Wang, Sibo; Yao, Wangshu; Lin, Jinliang
- Angewandte Chemie, Vol. 126, Issue 4
Visible-Light-Driven CO 2 Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts
journal, January 2015
- Kuriki, Ryo; Sekizawa, Keita; Ishitani, Osamu
- Angewandte Chemie, Vol. 127, Issue 8
Tailoring Copper Nanocrystals towards C 2 Products in Electrochemical CO 2 Reduction
journal, April 2016
- Loiudice, Anna; Lobaccaro, Peter; Kamali, Esmail A.
- Angewandte Chemie, Vol. 128, Issue 19
Works referencing / citing this record:
Rational Design of Catalytic Centers in Crystalline Frameworks
journal, June 2018
- Tu, Wenguang; Xu, You; Yin, Shengming
- Advanced Materials, Vol. 30, Issue 33
Structural‐Phase Catalytic Redox Reactions in Energy and Environmental Applications
journal, January 2020
- Uddin, Nasir; Zhang, Huayang; Du, Yaping
- Advanced Materials, Vol. 32, Issue 9
A Review of Metal- and Metal-Oxide-Based Heterogeneous Catalysts for Electroreduction of Carbon Dioxide
journal, May 2018
- Liu, Guanyu; Tran-Phu, Thanh; Chen, Hongjun
- Advanced Sustainable Systems, Vol. 2, Issue 8-9
MOFs-Based Heterogeneous Catalysts: New Opportunities for Energy-Related CO 2 Conversion
journal, October 2018
- Lei, Zhendong; Xue, Yuancheng; Chen, Wenqian
- Advanced Energy Materials, Vol. 8, Issue 32
Rational Design of Novel Catalysts with Atomic Layer Deposition for the Reduction of Carbon Dioxide
journal, August 2019
- Chen, Zhangsen; Zhang, Gaixia; Prakash, Jai
- Advanced Energy Materials, Vol. 9, Issue 37
Nickel Metal–Organic Framework Monolayers for Photoreduction of Diluted CO 2 : Metal‐Node‐Dependent Activity and Selectivity
journal, December 2018
- Han, Bin; Ou, Xinwen; Deng, Ziqi
- Angewandte Chemie, Vol. 130, Issue 51
Highly Selective Photoreduction of CO 2 with Suppressing H 2 Evolution over Monolayer Layered Double Hydroxide under Irradiation above 600 nm
journal, July 2019
- Tan, Ling; Xu, Si‐Min; Wang, Zelin
- Angewandte Chemie, Vol. 131, Issue 34
Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO 2 Reduction
journal, November 2019
- Wang, Yan; Wang, Sibo; Lou, Xiong Wen (David)
- Angewandte Chemie, Vol. 131, Issue 48
Nickel Metal–Organic Framework Monolayers for Photoreduction of Diluted CO 2 : Metal‐Node‐Dependent Activity and Selectivity
journal, December 2018
- Han, Bin; Ou, Xinwen; Deng, Ziqi
- Angewandte Chemie International Edition, Vol. 57, Issue 51
Highly Selective Photoreduction of CO 2 with Suppressing H 2 Evolution over Monolayer Layered Double Hydroxide under Irradiation above 600 nm
journal, July 2019
- Tan, Ling; Xu, Si-Min; Wang, Zelin
- Angewandte Chemie International Edition, Vol. 58, Issue 34
Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO 2 Reduction
journal, November 2019
- Wang, Yan; Wang, Sibo; Lou, Xiong Wen (David)
- Angewandte Chemie International Edition, Vol. 58, Issue 48
Spinel‐Type Mixed Metal Sulfide NiCo 2 S 4 for Efficient Photocatalytic Reduction of CO 2 with Visible Light
journal, October 2019
- Xiong, Zhuang; Huang, Lijuan; Peng, Junwen
- ChemCatChem, Vol. 11, Issue 22
An Exceptionally Efficient Co−Co 2 P@N, P-Codoped Carbon Hybrid Catalyst for Visible Light-Driven CO 2 -to-CO Conversion
journal, June 2018
- Xu, Yong; Mo, Jiang; Fu, Zi-Cheng
- Chemistry - A European Journal, Vol. 24, Issue 34
Direct conversion of CO and H2O into liquid fuels under mild conditions
journal, March 2019
- Xu, Yao; Li, Jing; Li, Wenjing
- Nature Communications, Vol. 10, Issue 1
Plasmonic photosynthesis of C1–C3 hydrocarbons from carbon dioxide assisted by an ionic liquid
journal, May 2019
- Yu, Sungju; Jain, Prashant K.
- Nature Communications, Vol. 10, Issue 1
Two-dimensional-related catalytic materials for solar-driven conversion of CO x into valuable chemical feedstocks
journal, January 2019
- Zhao, Yufei; Waterhouse, Geoffrey I. N.; Chen, Guangbo
- Chemical Society Reviews, Vol. 48, Issue 7
A donor-chromophore-catalyst assembly for solar CO 2 reduction
journal, January 2019
- Wang, Degao; Wang, Ying; Brady, Matthew D.
- Chemical Science, Vol. 10, Issue 16
Activity and selectivity regulation through varying the size of cobalt active sites in photocatalytic CO 2 reduction
journal, January 2018
- Mu, Qiaoqiao; Zhu, Wei; Yan, Gangbin
- Journal of Materials Chemistry A, Vol. 6, Issue 42
MOF-derived Co 1.11 Te 2 with half-metallic character for efficient photochemical conversion of CO 2 under visible-light irradiation
journal, January 2019
- Xu, Yong; Mo, Jiang; Xie, Guanqun
- Chemical Communications, Vol. 55, Issue 48
Organic–inorganic hybrids for CO 2 sensing, separation and conversion
journal, January 2020
- Rebber, Matthias; Willa, Christoph; Koziej, Dorota
- Nanoscale Horizons, Vol. 5, Issue 3
Branch-like ZnS–DETA/CdS hierarchical heterostructures as an efficient photocatalyst for visible light CO 2 reduction
journal, January 2019
- Su, Bo; Huang, Lijuan; Xiong, Zhuang
- Journal of Materials Chemistry A, Vol. 7, Issue 47
An artificial photosynthesis system comprising a covalent triazine framework as an electron relay facilitator for photochemical carbon dioxide reduction
journal, January 2020
- Zhang, Siquan; Wang, Shengyao; Guo, Liping
- Journal of Materials Chemistry C, Vol. 8, Issue 1
Ordered colloidal clusters constructed by nanocrystals with valence for efficient CO 2 photoreduction
journal, December 2019
- Nai, Jianwei; Wang, Sibo; Lou, Xiong Wen (David)
- Science Advances, Vol. 5, Issue 12