Bulk assembly of organic metal halide nanotubes
Abstract
The organic metal halide hybrids welcome a new member with a one-dimensional (1D) tubular structure. Herein we report the synthesis and characterization of a single crystalline bulk assembly of organic metal halide nanotubes, (C6H13N4)3Pb2Br7. In a metal halide nanotube, six face-sharing metal halide dimers (Pb2Br95–) connect at the corners to form rings that extend in one dimension, of which the inside and outside surfaces are coated with protonated hexamethylenetetramine (HMTA) cations (C6H13N4+). This unique 1D tubular structure possesses highly localized electronic states with strong quantum confinement, resulting in the formation of self-trapped excitons that give strongly Stokes shifted broadband yellowish-white emission with a photoluminescence quantum efficiency (PLQE) of ~7%. Finally, having realized single crystalline bulk assemblies of two-dimensional (2D) wells, 1D wires, and now 1D tubes using organic metal halide hybrids, our work significantly advances the research on bulk assemblies of quantum-confined materials.
- Authors:
-
[2];
[4];
[5];
[5];
[3]
- FAMU-FSU College of Engineering, Tallahassee, FL (United States)
- Florida State Univ., Tallahassee, FL (United States)
- FAMU-FSU College of Engineering, Tallahassee, FL (United States); Florida State Univ., Tallahassee, FL (United States)
- Univ. of Florida, Gainesville, FL (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1410201
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 12; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Lin, Haoran, Zhou, Chenkun, Tian, Yu, Besara, Tiglet, Neu, Jennifer, Siegrist, Theo, Zhou, Yan, Bullock, James, Schanze, Kirk S., Ming, Wenmei, Du, Mao -Hua, and Ma, Biwu. Bulk assembly of organic metal halide nanotubes. United States: N. p., 2017.
Web. doi:10.1039/c7sc03675b.
Lin, Haoran, Zhou, Chenkun, Tian, Yu, Besara, Tiglet, Neu, Jennifer, Siegrist, Theo, Zhou, Yan, Bullock, James, Schanze, Kirk S., Ming, Wenmei, Du, Mao -Hua, & Ma, Biwu. Bulk assembly of organic metal halide nanotubes. United States. https://doi.org/10.1039/c7sc03675b
Lin, Haoran, Zhou, Chenkun, Tian, Yu, Besara, Tiglet, Neu, Jennifer, Siegrist, Theo, Zhou, Yan, Bullock, James, Schanze, Kirk S., Ming, Wenmei, Du, Mao -Hua, and Ma, Biwu. Mon .
"Bulk assembly of organic metal halide nanotubes". United States. https://doi.org/10.1039/c7sc03675b. https://www.osti.gov/servlets/purl/1410201.
@article{osti_1410201,
title = {Bulk assembly of organic metal halide nanotubes},
author = {Lin, Haoran and Zhou, Chenkun and Tian, Yu and Besara, Tiglet and Neu, Jennifer and Siegrist, Theo and Zhou, Yan and Bullock, James and Schanze, Kirk S. and Ming, Wenmei and Du, Mao -Hua and Ma, Biwu},
abstractNote = {The organic metal halide hybrids welcome a new member with a one-dimensional (1D) tubular structure. Herein we report the synthesis and characterization of a single crystalline bulk assembly of organic metal halide nanotubes, (C6H13N4)3Pb2Br7. In a metal halide nanotube, six face-sharing metal halide dimers (Pb2Br95–) connect at the corners to form rings that extend in one dimension, of which the inside and outside surfaces are coated with protonated hexamethylenetetramine (HMTA) cations (C6H13N4+). This unique 1D tubular structure possesses highly localized electronic states with strong quantum confinement, resulting in the formation of self-trapped excitons that give strongly Stokes shifted broadband yellowish-white emission with a photoluminescence quantum efficiency (PLQE) of ~7%. Finally, having realized single crystalline bulk assemblies of two-dimensional (2D) wells, 1D wires, and now 1D tubes using organic metal halide hybrids, our work significantly advances the research on bulk assemblies of quantum-confined materials.},
doi = {10.1039/c7sc03675b},
journal = {Chemical Science},
number = 12,
volume = 8,
place = {United States},
year = {Mon Oct 16 00:00:00 EDT 2017},
month = {Mon Oct 16 00:00:00 EDT 2017}
}
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Figures / Tables:
Fig. 1: (a) View of the structure of (HMTA)3Pb2Br7 (red: lead atoms; green: bromine atoms; blue: nitrogen atoms; gray: carbon atoms; purple polyhedra: PbBr6 octahedra and Pb2Br9 dimers; hydrogen atoms are hidden for clarity). (b) Side view of an individual lead bromide nanotube. (c) Side view of an individual leadmore »
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Works referenced in this record:
A Metal−Organic Nanotube Exhibiting Reversible Adsorption of (H 2 O) 12 Cluster
journal, October 2008
- Dai, Fangna; He, Haiyan; Sun, Daofeng
- Journal of the American Chemical Society, Vol. 130, Issue 43
Intriguing Optoelectronic Properties of Metal Halide Perovskites
journal, June 2016
- Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V.
- Chemical Reviews, Vol. 116, Issue 21
One-dimensional organic lead halide perovskites with efficient bluish white-light emission
journal, January 2017
- Yuan, Zhao; Zhou, Chenkun; Tian, Yu
- Nature Communications, Vol. 8, Issue 1
Energy transport and scintillation of cerium-doped elpasolite Cs LiYCl : Hybrid density functional calculations
journal, July 2012
- Biswas, Koushik; Du, Mao-Hua
- Physical Review B, Vol. 86, Issue 1
Low-temperature solution-processed wavelength-tunable perovskites for lasing
journal, March 2014
- Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien
- Nature Materials, Vol. 13, Issue 5
Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites
journal, May 2016
- Hu, Te; Smith, Matthew D.; Dohner, Emma R.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 12
Helical microtubules of graphitic carbon
journal, November 1991
- Iijima, Sumio
- Nature, Vol. 354, Issue 6348
Excitonic and Polaronic Properties of 2D Hybrid Organic–Inorganic Perovskites
journal, January 2017
- Yin, Jun; Li, Hong; Cortecchia, Daniele
- ACS Energy Letters, Vol. 2, Issue 2
Alkali halide crystals containing impurity ions with the ns2 ground-state electronic configuration†
journal, January 1991
- Jacobs, P. W. M.
- Journal of Physics and Chemistry of Solids, Vol. 52, Issue 1
Low-Dimensional Organic Tin Bromide Perovskites and Their Photoinduced Structural Transformation
journal, July 2017
- Zhou, Chenkun; Tian, Yu; Wang, Mingchao
- Angewandte Chemie International Edition, Vol. 56, Issue 31
Synthesis and Characterization of [NH2C(I):NH2]3MI5 (M = Sn, Pb): Stereochemical Activity in Divalent Tin and Lead Halides Containing Single .ltbbrac.110.rtbbrac. Perovskite Sheets
journal, May 1995
- Wang, Shumin; Mitzi, David B.; Feild, Chris A.
- Journal of the American Chemical Society, Vol. 117, Issue 19
A Microscale Perovskite as Single Component Broadband Phosphor for Downconversion White-Light-Emitting Devices
journal, September 2016
- Yuan, Zhao; Zhou, Chenkun; Messier, Joshua
- Advanced Optical Materials, Vol. 4, Issue 12
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009
- Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
- Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
Intrinsic White-Light Emission from Layered Hybrid Perovskites
journal, September 2014
- Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R.
- Journal of the American Chemical Society, Vol. 136, Issue 38
A Prototypical Zeolitic Lanthanide−Organic Framework with Nanotubular Structure
journal, January 2008
- Huang, You-Gui; Jiang, Fei-Long; Yuan, Da-Qiang
- Crystal Growth & Design, Vol. 8, Issue 1
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
journal, March 2016
- Saparov, Bayrammurad; Mitzi, David B.
- Chemical Reviews, Vol. 116, Issue 7
High-Performance Flexible Broadband Photodetector Based on Organolead Halide Perovskite
journal, September 2014
- Hu, Xin; Zhang, Xiaodong; Liang, Lin
- Advanced Functional Materials, Vol. 24, Issue 46
Connecting Thermoelectric Performance and Topological-Insulator Behavior: and from First Principles
journal, January 2015
- Shi, Hongliang; Parker, David; Du, Mao-Hua
- Physical Review Applied, Vol. 3, Issue 1
Self-Assembly of Broadband White-Light Emitters
journal, January 2014
- Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I.
- Journal of the American Chemical Society, Vol. 136, Issue 5
Atomically thin two-dimensional organic-inorganic hybrid perovskites
journal, September 2015
- Dou, L.; Wong, A. B.; Yu, Y.
- Science, Vol. 349, Issue 6255
Using DFT Methods to Study Activators in Optical Materials
journal, August 2015
- Du, Mao-Hua
- ECS Journal of Solid State Science and Technology, Vol. 5, Issue 1
Self-assembled arrays of polyoxometalate-based metal–organic nanotubes for proton conduction and magnetism
journal, January 2015
- Jiao, Yan-Qing; Zang, Hong-Ying; Wang, Xin-Long
- Chemical Communications, Vol. 51, Issue 56
Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets
journal, March 1995
- Mitzi, D. B.; Wang, S.; Feild, C. A.
- Science, Vol. 267, Issue 5203, p. 1473-1476
Bright light-emitting diodes based on organometal halide perovskite
journal, August 2014
- Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling
- Nature Nanotechnology, Vol. 9, Issue 9
Two-Dimensional Metal Halide Perovskites: Theory, Synthesis, and Optoelectronics
journal, January 2017
- Huo, Chengxue; Cai, Bo; Yuan, Zhao
- Small Methods, Vol. 1, Issue 3
Self-Assembled Arrays of Single-Walled Metal-Organic Nanotubes
journal, November 2009
- Luo, Tzuoo-Tsair; Wu, Huang-Chun; Jao, Yu-Chen
- Angewandte Chemie International Edition, Vol. 48, Issue 50
Carrier Self-trapping and Luminescence in Intrinsically Activated Scintillator: Cesium Hafnium Chloride (Cs 2 HfCl 6 )
journal, May 2016
- Kang, By.; Biswas, Koushik
- The Journal of Physical Chemistry C, Vol. 120, Issue 22
Crystal structure and mechanism of a calcium-gated potassium channel
journal, May 2002
- Jiang, Youxing; Lee, Alice; Chen, Jiayun
- Nature, Vol. 417, Issue 6888
Recent developments in single-crystal inorganic nanotubes synthesised from removable templates
journal, January 2007
- Shen, Guozhen; Bando, Yoshio; Golberg, Dmitri
- International Journal of Nanotechnology, Vol. 4, Issue 6
Templating and structural engineering in organic–inorganic perovskites
journal, January 2001
- Mitzi, David B.
- Journal of the Chemical Society, Dalton Transactions, Issue 1
White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites
journal, March 2017
- Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C.
- Journal of the American Chemical Society, Vol. 139, Issue 14
A journey in search of single-walled metal–organic nanotubes
journal, January 2011
- Thanasekaran, Pounraj; Luo, Tzuoo-Tsair; Lee, Cheng-Hua
- Journal of Materials Chemistry, Vol. 21, Issue 35
Broadband Emission in Two-Dimensional Hybrid Perovskites: The Role of Structural Deformation
journal, December 2016
- Cortecchia, Daniele; Neutzner, Stefanie; Srimath Kandada, Ajay Ram
- Journal of the American Chemical Society, Vol. 139, Issue 1
Alkylammonium lead halides. Part 1. Isolated PbI 6 4− ions in (CH 3 NH 3 ) 4 PbI 6 •2H 2 O
journal, May 1987
- Vincent, Beverly R.; Robertson, Katherine N.; Cameron, T. Stanley
- Canadian Journal of Chemistry, Vol. 65, Issue 5
Optical Investigation of Broadband White-Light Emission in Self-Assembled Organic–Inorganic Perovskite (C 6 H 11 NH 3 ) 2 PbBr 4
journal, October 2015
- Yangui, A.; Garrot, D.; Lauret, J. S.
- The Journal of Physical Chemistry C, Vol. 119, Issue 41
Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges
journal, July 2015
- Berry, Joseph; Buonassisi, Tonio; Egger, David A.
- Advanced Materials, Vol. 27, Issue 35
Self-Assembled Arrays of Single-Walled Metal-Organic Nanotubes
journal, November 2009
- Luo, Tzuoo-Tsair; Wu, Huang-Chun; Jao, Yu-Chen
- Angewandte Chemie, Vol. 121, Issue 50
Low-Dimensional Organic Tin Bromide Perovskites and Their Photoinduced Structural Transformation
journal, July 2017
- Zhou, Chenkun; Tian, Yu; Wang, Mingchao
- Angewandte Chemie, Vol. 129, Issue 31
Works referencing / citing this record:
Microwave Absorption of Organic Metal Halide Nanotubes
journal, December 2019
- Lin, Haoran; Green, Michael; Xu, Liang‐Jin
- Advanced Materials Interfaces, Vol. 7, Issue 3
Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission
journal, December 2018
- Lin, Haoran; Zhou, Chenkun; Neu, Jennifer
- Advanced Optical Materials, Vol. 7, Issue 6
Spintronics of Hybrid Organic–Inorganic Perovskites: Miraculous Basis of Integrated Optoelectronic Devices
journal, June 2019
- Liao, Kun; Hu, Xiaoyong; Cheng, Yinke
- Advanced Optical Materials, Vol. 7, Issue 15
Negative Thermal Quenching of Efficient White‐Light Emission in a 1D Ladder‐Like Organic/Inorganic Hybrid Material
journal, July 2019
- Barkaoui, Hamdi; Abid, Haitham; Zelewski, Szymon
- Advanced Optical Materials, Vol. 7, Issue 20
Intrinsic White‐Light‐Emitting Metal–Organic Frameworks with Structurally Deformable Secondary Building Units
journal, April 2019
- Peng, Chengdong; Song, Xueling; Yin, Jinlin
- Angewandte Chemie, Vol. 131, Issue 23
Intrinsic White-Light-Emitting Metal-Organic Frameworks with Structurally Deformable Secondary Building Units
journal, April 2019
- Peng, Chengdong; Song, Xueling; Yin, Jinlin
- Angewandte Chemie International Edition, Vol. 58, Issue 23
Semiconducting crystalline inorganic–organic hybrid metal halide nanochains
journal, January 2020
- Wang, Guan-E; Sun, Cai; Wang, Ming-Sheng
- Nanoscale, Vol. 12, Issue 8
Direct emission from quartet excited states triggered by upconversion phenomena in solid-phase synthesized fluorescent lead-free organic–inorganic hybrid compounds
journal, January 2019
- Jana, Atanu; Zhumagali, Shynggys; Ba, Qiankai
- Journal of Materials Chemistry A, Vol. 7, Issue 46
White light emission in low-dimensional perovskites
journal, January 2019
- Cortecchia, Daniele; Yin, Jun; Petrozza, Annamaria
- Journal of Materials Chemistry C, Vol. 7, Issue 17
A three-dimensional cuprous lead bromide framework with highly efficient and stable thermochromic luminescence properties
journal, January 2020
- Jing, Chang-Qing; Wu, Jia-Hang; Cao, Yao-Yao
- Chemical Communications
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