Direct Evidence of Exciton–Exciton Annihilation in Single-Crystalline Organic Metal Halide Nanotube Assemblies

Ma, Ying -Zhong; Lin, Haoran; Du, Mao -Hua; Doughty, Benjamin L.; Ma, Biwu

doi:10.1021/acs.jpclett.8b00761

Title: Direct Evidence of Exciton–Exciton Annihilation in Single-Crystalline Organic Metal Halide Nanotube Assemblies

Journal Article · 11 April 2018 · Journal of Physical Chemistry Letters

DOI: https://doi.org/10.1021/acs.jpclett.8b00761 · OSTI ID:1436038

^[1]; Lin, Haoran ^[2];

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^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
FAMU-FSU College of Engineering, Tallahassee, FL (United States)
FAMU-FSU College of Engineering, Tallahassee, FL (United States); Florida State Univ., Tallahassee, FL (United States)

Excitons in low-dimensional organic–inorganic metal halide hybrid structures are commonly thought to undergo rapid self-trapping following creation due to strong quantum confinement and exciton–phonon interaction. Here we report an experimental study probing the dynamics of these self-trapped excitons in the single-crystalline bulk assemblies of 1D organic metal halide nanotubes, (C₆H₁₃N₄)₃Pb₂Br₇. Through time-resolved photoluminescence (PL) measurements at different excitation intensities, we observed a marked variation in the PL decay behavior that is manifested by an accelerated decay rate with increasing excitation fluence. Our results offer direct evidence of the occurrence of an exciton–exciton annihilation process, a nonlinear relaxation phenomenon that takes place only when some of the self-trapped excitons become mobile and can approach either each other or those trapped excitons. As a result, we further identify a fast and dominant PL decay component with a lifetime of ~2 ns with a nearly invariant relative area for all acquired PL kinetics, suggesting that this rapid relaxation process is intrinsic.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1436038

Journal Information:: Journal of Physical Chemistry Letters, Vol. 9, Issue 9; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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References (40)

Fabrication of two-dimensional layered perovskite [NH3(CH2)12NH3]PbX4 thin films using a self-assembly method Matsui, Takashi; Yamaguchi, Akane; Takeoka, Yuko Chemical Communications, Issue 10 https://doi.org/10.1039/b200965j	journal	April 2002
Excitonic Many-Body Interactions in Two-Dimensional Lead Iodide Perovskite Quantum Wells Wu, Xiaoxi; Trinh, M. Tuan; Zhu, X. -Y. The Journal of Physical Chemistry C, Vol. 119, Issue 26 https://doi.org/10.1021/acs.jpcc.5b00148	journal	March 2015
Atomically thin two-dimensional organic-inorganic hybrid perovskites Dou, L.; Wong, A. B.; Yu, Y. Science, Vol. 349, Issue 6255 https://doi.org/10.1126/science.aac7660	journal	September 2015
One-dimensional organic lead halide perovskites with efficient bluish white-light emission Yuan, Zhao; Zhou, Chenkun; Tian, Yu Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14051	journal	January 2017
Low-Dimensional Organic Tin Bromide Perovskites and Their Photoinduced Structural Transformation Zhou, Chenkun; Tian, Yu; Wang, Mingchao Angewandte Chemie International Edition, Vol. 56, Issue 31 https://doi.org/10.1002/anie.201702825	journal	July 2017
A Zero-Dimensional Organic Seesaw-Shaped Tin Bromide with Highly Efficient Strongly Stokes-Shifted Deep-Red Emission Zhou, Chenkun; Lin, Haoran; Shi, Hongliang Angewandte Chemie International Edition, Vol. 57, Issue 4 https://doi.org/10.1002/anie.201710383	journal	December 2017
Low-Dimensional Organometal Halide Perovskites Lin, Haoran; Zhou, Chenkun; Tian, Yu ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b00926	journal	November 2017
Luminescent zero-dimensional organic metal halide hybrids with near-unity quantum efficiency Zhou, Chenkun; Lin, Haoran; Tian, Yu Chemical Science, Vol. 9, Issue 3 https://doi.org/10.1039/C7SC04539E	journal	January 2018
Bulk assembly of organic metal halide nanotubes Lin, Haoran; Zhou, Chenkun; Tian, Yu Chemical Science, Vol. 8, Issue 12 https://doi.org/10.1039/C7SC03675B	journal	January 2017
Self-Assembly of Broadband White-Light Emitters Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja411045r	journal	January 2014
Intrinsic White-Light Emission from Layered Hybrid Perovskites Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R. Journal of the American Chemical Society, Vol. 136, Issue 38 https://doi.org/10.1021/ja507086b	journal	September 2014
Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites Hu, Te; Smith, Matthew D.; Dohner, Emma R. The Journal of Physical Chemistry Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acs.jpclett.6b00793	journal	May 2016
Structural origins of broadband emission from layered Pb–Br hybrid perovskites Smith, Matthew D.; Jaffe, Adam; Dohner, Emma R. Chemical Science, Vol. 8, Issue 6 https://doi.org/10.1039/C7SC01590A	journal	January 2017
White-Light Emission from Layered Halide Perovskites Smith, Matthew D.; Karunadasa, Hemamala I. Accounts of Chemical Research, Vol. 51, Issue 3 https://doi.org/10.1021/acs.accounts.7b00433	journal	February 2018
Semiconductor Clusters, Nanocrystals, and Quantum Dots Alivisatos, A. P. Science, Vol. 271, Issue 5251, p. 933-937 https://doi.org/10.1126/science.271.5251.933	journal	February 1996
A DNA-based method for rationally assembling nanoparticles into macroscopic materials Mirkin, Chad A.; Letsinger, Robert L.; Mucic, Robert C. Nature, Vol. 382, Issue 6592, p. 607-609 https://doi.org/10.1038/382607a0	journal	August 1996
Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies Murray, C. B.; Kagan, C. R.; Bawendi, M. G. Annual Review of Materials Science, Vol. 30, Issue 1, p. 545-610 https://doi.org/10.1146/annurev.matsci.30.1.545	journal	August 2000
Band Gap Fluorescence from Individual Single-Walled Carbon Nanotubes O'Connell, Michael J.; Bachilo, Sergei M.; Huffman, Chad B. Science, Vol. 297, Issue 5581, p. 593-596 https://doi.org/10.1126/science.1072631	journal	July 2002
Sorting carbon nanotubes by electronic structure using density differentiation Arnold, Michael S.; Green, Alexander A.; Hulvat, James F. Nature Nanotechnology, Vol. 1, Issue 1, p. 60-65 https://doi.org/10.1038/nnano.2006.52	journal	October 2006
Energy Gaps in "Metallic" Single-Walled Carbon Nanotubes Ouyang, M. Science, Vol. 292, Issue 5517 https://doi.org/10.1126/science.1058853	journal	April 2001
Spectroscopy of zigzag single-walled carbon nanotubes: Comparing femtosecond transient absorption spectra with ab initio calculations Ma, Ying-Zhong; Spataru, Catalin D.; Valkunas, Leonas Physical Review B, Vol. 74, Issue 8 https://doi.org/10.1103/PhysRevB.74.085402	journal	August 2006
Interfacial Charge-Carrier Trapping in CH ₃ NH ₃ PbI ₃ -Based Heterolayered Structures Revealed by Time-Resolved Photoluminescence Spectroscopy Yamada, Yasuhiro; Yamada, Takumi; Shimazaki, Ai The Journal of Physical Chemistry Letters, Vol. 7, Issue 11 https://doi.org/10.1021/acs.jpclett.6b00653	journal	May 2016
Photosynthetic Excitons van Amerongen, Herbert; van Grondelle, Rienk; Valkunas, Leonas World Scientific https://doi.org/10.1142/3609	book	January 2000
Exciton–Exciton Annihilation in Copper-phthalocyanine Single-Crystal Nanowires Ma, Ying-Zhong; Xiao, Kai; Shaw, Robert W. The Journal of Physical Chemistry C, Vol. 116, Issue 40 https://doi.org/10.1021/jp3057543	journal	September 2012
Ultrafast Excitation Relaxation in Colloidal Particles of Chloroaluminum Phthalocyanine: One-Dimensional Exciton-Exciton Annihilation Gulbinas, V.; Chachisvilis, M.; Persson, A. The Journal of Physical Chemistry, Vol. 98, Issue 33 https://doi.org/10.1021/j100084a032	journal	August 1994
Excited State Dynamics of Phthalocyanine Films Gulbinas, V.; Chachisvilis, M.; Valkunas, L. The Journal of Physical Chemistry, Vol. 100, Issue 6 https://doi.org/10.1021/jp951910j	journal	January 1996
Ultrafast carrier dynamics in single-walled carbon nanotubes probed by femtosecond spectroscopy Ma, Ying-Zhong; Stenger, Jens; Zimmermann, Jörg The Journal of Chemical Physics, Vol. 120, Issue 7 https://doi.org/10.1063/1.1640339	journal	February 2004
Femtosecond Spectroscopy of Optical Excitations in Single-Walled Carbon Nanotubes: Evidence for Exciton-Exciton Annihilation Ma, Ying-Zhong; Valkunas, Leonas; Dexheimer, Susan L. Physical Review Letters, Vol. 94, Issue 15 https://doi.org/10.1103/PhysRevLett.94.157402	journal	April 2005
Exciton-exciton annihilation in single-walled carbon nanotubes Valkunas, Leonas; Ma, Ying-Zhong; Fleming, Graham R. Physical Review B, Vol. 73, Issue 11 https://doi.org/10.1103/PhysRevB.73.115432	journal	March 2006
Ultrafast Exciton Dephasing in Semiconducting Single-Walled Carbon Nanotubes Ma, Ying-Zhong; Graham, Matthew W.; Fleming, Graham R. Physical Review Letters, Vol. 101, Issue 21 https://doi.org/10.1103/PhysRevLett.101.217402	journal	November 2008
The self-trapped exciton Williams, R. T.; Song, K. S. Journal of Physics and Chemistry of Solids, Vol. 51, Issue 7 https://doi.org/10.1016/0022-3697(90)90144-5	journal	January 1990
Exciton self-trapping processes Georgiev, Mladen; Mihailov, L.; Singh, J. Pure and Applied Chemistry, Vol. 67, Issue 3 https://doi.org/10.1351/pac199567030447	journal	January 1995
Self-trapping dynamics of excitons on a one-dimensional lattice Ishida, Kunio Zeitschrift für Physik B Condensed Matter, Vol. 102, Issue 4 https://doi.org/10.1007/s002570050316	journal	December 1997
Trap States in Lead Iodide Perovskites Wu, Xiaoxi; Trinh, M. Tuan; Niesner, Daniel Journal of the American Chemical Society, Vol. 137, Issue 5 https://doi.org/10.1021/ja512833n	journal	January 2015
Singlet–Singlet Annihilation Kinetics in Aggregates and Trimers of LHCII Barzda, V.; Gulbinas, V.; Kananavicius, R. Biophysical Journal, Vol. 80, Issue 5 https://doi.org/10.1016/S0006-3495(01)76210-8	journal	May 2001
Exciton–exciton annihilation and biexciton stimulated emission in graphene nanoribbons Soavi, Giancarlo; Dal Conte, Stefano; Manzoni, Cristian Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11010	journal	March 2016
One-Dimensional Exciton Diffusion in Perylene Bisimide Aggregates Marciniak, Henning; Li, Xue-Qing; Würthner, Frank The Journal of Physical Chemistry A, Vol. 115, Issue 5 https://doi.org/10.1021/jp107407p	journal	February 2011
Theory and Ab Initio Calculation of Radiative Lifetime of Excitons in Semiconducting Carbon Nanotubes Spataru, Catalin D.; Ismail-Beigi, Sohrab; Capaz, Rodrigo B. Physical Review Letters, Vol. 95, Issue 24 https://doi.org/10.1103/PhysRevLett.95.247402	journal	December 2005
Electron-Electron Interaction Effects on the Optical Excitations of Semiconducting Single-Walled Carbon Nanotubes Zhao, Hongbo; Mazumdar, Sumit Physical Review Letters, Vol. 93, Issue 15 https://doi.org/10.1103/PhysRevLett.93.157402	journal	October 2004
Excited-State Dynamics of Water-Soluble Polythiophene Derivatives: Temperature and Side-Chain Length Effects Ma, Ying-Zhong; Shaw, Robert W.; Yu, Xiang The Journal of Physical Chemistry B, Vol. 116, Issue 49 https://doi.org/10.1021/jp304526h	journal	November 2012

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