Nanoporous Metals with Structural Hierarchy: A Review
Abstract
Nanoporous (np) metals have generated much interest since they combine several desirable material characteristics, such as high surface area, mechanical size effects, and high conductivity. Most of the research has been focused on np Au due to its relatively straightforward synthesis, chemical stability, and many promising applications in the fields of catalysis and actuation. Other materials, such as np-Cu, Ag, and Pd have also been studied. Here, this review discusses recent advances in the field of np metals, focusing on new research areas that implement and leverage structural hierarchy while using np metals as their base structural constituents. First, we focus on single-element porous metals that are made of np metals at the fundamental level, but synthesized with additional levels of porosity. Second, we discuss the fabrication of composite structures, which use auxiliary materials to enhance the properties of np metals. Important applications of these hierarchical materials, especially in the fields of catalysis and electrochemistry, are also reviewed. Lastly, we conclude with a discussion about future opportunities for the advancement and application of np metals.
- Authors:
-
- Univ. of Southern California, Los Angeles, CA (United States). Dept. of Aerospace and Mechanical Engineering, Mork Family Dept. of Chemical Engineering and Materials Science
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Nanoscale Synthesis and Characterization Lab.
- Hamburg Univ. of Technology, Hamburg (Germany); Helmholtz-Zentrum Geesthacht, Geesthacht (Germany). Inst. of Materials Research, Materials Mechanics
- Publication Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); US Air Force Office of Scientific Research (AFOSR)
- OSTI Identifier:
- 1410018
- Report Number(s):
- LLNL-JRNL-733717
Journal ID: ISSN 1438-1656
- Grant/Contract Number:
- AC52-07NA27344; FA9550‐14‐1‐0352; SC0012573
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Engineering Materials
- Additional Journal Information:
- Journal Volume: 19; Journal Issue: 12; Journal ID: ISSN 1438-1656
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Juarez, Theresa, Biener, Juergen, Weissmüller, Jörg, and Hodge, Andrea M. Nanoporous Metals with Structural Hierarchy: A Review. United States: N. p., 2017.
Web. doi:10.1002/adem.201700389.
Juarez, Theresa, Biener, Juergen, Weissmüller, Jörg, & Hodge, Andrea M. Nanoporous Metals with Structural Hierarchy: A Review. United States. https://doi.org/10.1002/adem.201700389
Juarez, Theresa, Biener, Juergen, Weissmüller, Jörg, and Hodge, Andrea M. Wed .
"Nanoporous Metals with Structural Hierarchy: A Review". United States. https://doi.org/10.1002/adem.201700389. https://www.osti.gov/servlets/purl/1410018.
@article{osti_1410018,
title = {Nanoporous Metals with Structural Hierarchy: A Review},
author = {Juarez, Theresa and Biener, Juergen and Weissmüller, Jörg and Hodge, Andrea M.},
abstractNote = {Nanoporous (np) metals have generated much interest since they combine several desirable material characteristics, such as high surface area, mechanical size effects, and high conductivity. Most of the research has been focused on np Au due to its relatively straightforward synthesis, chemical stability, and many promising applications in the fields of catalysis and actuation. Other materials, such as np-Cu, Ag, and Pd have also been studied. Here, this review discusses recent advances in the field of np metals, focusing on new research areas that implement and leverage structural hierarchy while using np metals as their base structural constituents. First, we focus on single-element porous metals that are made of np metals at the fundamental level, but synthesized with additional levels of porosity. Second, we discuss the fabrication of composite structures, which use auxiliary materials to enhance the properties of np metals. Important applications of these hierarchical materials, especially in the fields of catalysis and electrochemistry, are also reviewed. Lastly, we conclude with a discussion about future opportunities for the advancement and application of np metals.},
doi = {10.1002/adem.201700389},
journal = {Advanced Engineering Materials},
number = 12,
volume = 19,
place = {United States},
year = {Wed Aug 09 00:00:00 EDT 2017},
month = {Wed Aug 09 00:00:00 EDT 2017}
}
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