Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO 2 sequestration conditions: mineral precipitation and permeability evolution

Zhang, Liwei; Soong, Yee; Dilmore, Robert M.

doi:10.1002/ghg.1703

Title: Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO ₂ sequestration conditions: mineral precipitation and permeability evolution

Abstract

Abstract A numerical model was developed using CrunchFlow to simulate reactive transport and porosity and permeability changes of sandstone and carbonate rock samples taken from the Lower Tuscaloosa Formation and the Selma Chalk Formation, Jackson County, MS, USA. The model predicted a permeability decrease from 2190 mD to 2038 mD for the Lower Tuscaloosa Sandstone sample in a static batch reactor after 180 days of exposure to CO ₂ ‐saturated brine, which is consistent with measured permeability results. The model predicted a negligible permeability change from 2.00 mD to 2.08 mD for the Selma Chalk carbonate sample after 180 days of exposure to CO ₂ ‐saturated brine. Based on model prediction, key mineral dissolution and precipitation reactions in the Lower Tuscaloosa Sandstone sample include dissolution of quartz, chlorite, and feldspar, as well as precipitation of amorphous silica and kaolinite. For the Selma Chalk carbonate sample, key predicted reactions include dissolution of calcite, quartz and chlorite, and precipitation of kaolinite and amorphous silica. Initial porosity, initial feldspar content and the exponent n value (related to pore structure and tortuosity) used in permeability calculations were three important factors affecting permeability evolution of sandstone samples under CO ₂ sequestration conditions. The small permeabilitymore »« less

Authors:

^[1]; Soong, Yee ^[2]; Dilmore, Robert M. ^[2]

State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil Mechanics (IRSM) Chinese Academy of Sciences Wuhan, China, ORISE, NETL Pittsburgh PA USA
US Department of Energy NETL Pittsburgh PA USA

Publication Date:: Mon Jul 24 00:00:00 EDT 2017

Sponsoring Org.:: USDOE

OSTI Identifier:: 1401813

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Greenhouse Gases: Science and Technology

Additional Journal Information:: Journal Name: Greenhouse Gases: Science and Technology Journal Volume: 7 Journal Issue: 6; Journal ID: ISSN 2152-3878

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Zhang, Liwei, Soong, Yee, and Dilmore, Robert M. Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO 2 sequestration conditions: mineral precipitation and permeability evolution.  United Kingdom: N. p., 2017. 
Web.  doi:10.1002/ghg.1703.

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                    Zhang, Liwei, Soong, Yee, & Dilmore, Robert M. Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO 2 sequestration conditions: mineral precipitation and permeability evolution.  United Kingdom.  https://doi.org/10.1002/ghg.1703

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                    Zhang, Liwei, Soong, Yee, and Dilmore, Robert M. Mon .  
"Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO 2 sequestration conditions: mineral precipitation and permeability evolution".  United Kingdom.  https://doi.org/10.1002/ghg.1703.

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@article{osti_1401813,

  title        = {Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO 2 sequestration conditions: mineral precipitation and permeability evolution},

  author       = {Zhang, Liwei and Soong, Yee and Dilmore, Robert M.},

  abstractNote = {Abstract A numerical model was developed using CrunchFlow to simulate reactive transport and porosity and permeability changes of sandstone and carbonate rock samples taken from the Lower Tuscaloosa Formation and the Selma Chalk Formation, Jackson County, MS, USA. The model predicted a permeability decrease from 2190 mD to 2038 mD for the Lower Tuscaloosa Sandstone sample in a static batch reactor after 180 days of exposure to CO 2 ‐saturated brine, which is consistent with measured permeability results. The model predicted a negligible permeability change from 2.00 mD to 2.08 mD for the Selma Chalk carbonate sample after 180 days of exposure to CO 2 ‐saturated brine. Based on model prediction, key mineral dissolution and precipitation reactions in the Lower Tuscaloosa Sandstone sample include dissolution of quartz, chlorite, and feldspar, as well as precipitation of amorphous silica and kaolinite. For the Selma Chalk carbonate sample, key predicted reactions include dissolution of calcite, quartz and chlorite, and precipitation of kaolinite and amorphous silica. Initial porosity, initial feldspar content and the exponent n value (related to pore structure and tortuosity) used in permeability calculations were three important factors affecting permeability evolution of sandstone samples under CO 2 sequestration conditions. The small permeability change predicted for both the Lower Tuscaloosa Sandstone and the Selma Chalk caprock after exposure to CO 2 ‐saturated brine suggests that poro‐permeability changes during CO 2 injection into the Lower Tuscaloosa Formation are not likely to significantly affect reservoir and seal quality. © 2017 Society of Chemical Industry and John Wiley & Sons, Ltd.},

  doi          = {10.1002/ghg.1703},

  journal      = {Greenhouse Gases: Science and Technology},

  number       = 6,

  volume       = 7,

  place        = {United Kingdom},

  year         = {Mon Jul 24 00:00:00 EDT 2017},

  month        = {Mon Jul 24 00:00:00 EDT 2017}

}

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Title: Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO 2 sequestration conditions: mineral precipitation and permeability evolution

Abstract

Citation Formats

An experimental study of CO2–brine–rock interaction at in situ pressure–temperature reservoir conditions journal, October 2012

Evaporite Caprock Integrity: An Experimental Study of Reactive Mineralogy and Pore-Scale Heterogeneity during Brine-CO 2 Exposure journal, August 2012

Kinetics of Water-Rock Interaction book, January 2008

CO 2 /brine/rock interactions in Lower Tuscaloosa formation journal, December 2016

Fluid-Rock Interaction: A Reactive Transport Approach journal, January 2009

Effects of physical and geochemical heterogeneities on mineral transformation and biomass accumulation during biostimulation experiments at Rifle, Colorado journal, March 2010

Preparation of muscovite with ultrahigh specific surface area by chemical cleavage journal, April 1992

Alterations of Fractures in Carbonate Rocks by CO 2 -Acidified Brines journal, August 2015

Microstructure and mechanical properties of β-hemihydrate produced gypsum: An insight from its hydration process journal, July 2011

Separation and Capture of CO 2 from Large Stationary Sources and Sequestration in Geological Formations—Coalbeds and Deep Saline Aquifers journal, June 2003

Dissolution and Precipitation of Clay Minerals under Geologic CO 2 Sequestration Conditions: CO 2 −Brine−Phlogopite Interactions journal, August 2010

Spatial patterns of diagenesis during geothermal circulation in carbonate platforms journal, October 2001

Dissolution of illite in saline–acidic solutions at 25°C journal, June 2011

Spatial characterization of the location of potentially leaky wells penetrating a deep saline aquifer in a mature sedimentary basin journal, June 2004

Coupled alkali-feldspar dissolution and secondary mineral precipitation in batch systems: 1. New experiments at 200 °C and 300 bars journal, January 2009

Gas-water-rock interactions in Frio Formation following CO2 injection: Implications for the storage of greenhouse gases in sedimentary basins journal, January 2006

Dissolution-Driven Permeability Reduction of a Fractured Carbonate Caprock journal, April 2013

Influence of reaction kinetics and mesh refinement on the numerical modelling of concrete/clay interactions journal, January 2009

A fresh approach to investigating CO 2 storage: Experimental CO 2 –water–rock interactions in a low-salinity reservoir system journal, April 2015

Experimental investigation of geochemical and mineralogical effects of CO2 sequestration on flow characteristics of reservoir rock in deep saline aquifers journal, January 2016

Geomechanical and geochemical effects on sandstones caused by the reaction with supercritical CO2: an experimental approach to in situ conditions in deep geological reservoirs journal, October 2012

Wormhole formation and compact dissolution in single- and two-phase CO 2 -brine injections journal, April 2015

An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar journal, February 2003

Mineral sequestration of carbon dioxide in a sandstone–shale system journal, April 2005

Reactivity of Mount Simon Sandstone and the Eau Claire Shale Under CO 2 Storage Conditions journal, August 2012

Numerical simulation of porosity and permeability evolution of Mount Simon sandstone under geological carbon sequestration conditions journal, May 2015

Kinetics of chlorite dissolution at elevated temperatures and CO2 conditions journal, June 2013

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Title: Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO ₂ sequestration conditions: mineral precipitation and permeability evolution

An experimental study of CO2–brine–rock interaction at in situ pressure–temperature reservoir conditions
journal, October 2012

Evaporite Caprock Integrity: An Experimental Study of Reactive Mineralogy and Pore-Scale Heterogeneity during Brine-CO ₂ Exposure
journal, August 2012

Kinetics of Water-Rock Interaction
book, January 2008

CO ₂ /brine/rock interactions in Lower Tuscaloosa formation
journal, December 2016

Fluid-Rock Interaction: A Reactive Transport Approach
journal, January 2009

Effects of physical and geochemical heterogeneities on mineral transformation and biomass accumulation during biostimulation experiments at Rifle, Colorado
journal, March 2010

Preparation of muscovite with ultrahigh specific surface area by chemical cleavage
journal, April 1992

Alterations of Fractures in Carbonate Rocks by CO ₂ -Acidified Brines
journal, August 2015

Microstructure and mechanical properties of β-hemihydrate produced gypsum: An insight from its hydration process
journal, July 2011

Separation and Capture of CO ₂ from Large Stationary Sources and Sequestration in Geological Formations—Coalbeds and Deep Saline Aquifers
journal, June 2003

Dissolution and Precipitation of Clay Minerals under Geologic CO ₂ Sequestration Conditions: CO ₂ −Brine−Phlogopite Interactions
journal, August 2010

Spatial patterns of diagenesis during geothermal circulation in carbonate platforms
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Wormhole formation and compact dissolution in single- and two-phase CO ₂ -brine injections
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An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar
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