DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High-Q, Low-Threshold Monolithic Perovskite Thin-Film Vertical-Cavity Lasers

Abstract

A vertical-cavity surface-emitting perovskite laser is achieved using a microcavity configuration where CH3NH3PbI3 thin solid films are embedded within a custom GaN-based high-quality (Q-factor) resonator. This single-mode perovskite laser reaches a low threshold (≈7.6 µJ cm-2) at room temperature and emits spatially coherent Gaussian laser beams. The devices allow direct access to the study of perovskite gain dynamics and material robustness.

Authors:
 [1];  [2];  [1];  [2];  [3]
  1. Brown Univ., Providence, RI (United States). School of Engineering
  2. Yale Univ., New Haven, CT (United States). Dept. of Electrical Engineering
  3. Brown Univ., Providence, RI (United States). School of Engineering. Dept. of Physics
Publication Date:
Research Org.:
Brown Univ., Providence, RI (United States); Yale Univ., New Haven, CT (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); Air Force Office of Scientific Research (AFOSR) (United States); National Science Foundation (NSF)
OSTI Identifier:
1533032
Alternate Identifier(s):
OSTI ID: 1401051
Grant/Contract Number:  
FG02-07ER46387; FA9550-12-1-0488; CMMI-1129964; DMR 1119826; DE‐FG02‐07ER46387
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 29; Journal Issue: 16; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; gain dynamics; nanoporous GaN; perovskites; quasi-steady state; vertical-cavities surface-emitting lasers

Citation Formats

Chen, Songtao, Zhang, Cheng, Lee, Joonhee, Han, Jung, and Nurmikko, Arto. High-Q, Low-Threshold Monolithic Perovskite Thin-Film Vertical-Cavity Lasers. United States: N. p., 2017. Web. doi:10.1002/adma.201604781.
Chen, Songtao, Zhang, Cheng, Lee, Joonhee, Han, Jung, & Nurmikko, Arto. High-Q, Low-Threshold Monolithic Perovskite Thin-Film Vertical-Cavity Lasers. United States. https://doi.org/10.1002/adma.201604781
Chen, Songtao, Zhang, Cheng, Lee, Joonhee, Han, Jung, and Nurmikko, Arto. Fri . "High-Q, Low-Threshold Monolithic Perovskite Thin-Film Vertical-Cavity Lasers". United States. https://doi.org/10.1002/adma.201604781. https://www.osti.gov/servlets/purl/1533032.
@article{osti_1533032,
title = {High-Q, Low-Threshold Monolithic Perovskite Thin-Film Vertical-Cavity Lasers},
author = {Chen, Songtao and Zhang, Cheng and Lee, Joonhee and Han, Jung and Nurmikko, Arto},
abstractNote = {A vertical-cavity surface-emitting perovskite laser is achieved using a microcavity configuration where CH3NH3PbI3 thin solid films are embedded within a custom GaN-based high-quality (Q-factor) resonator. This single-mode perovskite laser reaches a low threshold (≈7.6 µJ cm-2) at room temperature and emits spatially coherent Gaussian laser beams. The devices allow direct access to the study of perovskite gain dynamics and material robustness.},
doi = {10.1002/adma.201604781},
journal = {Advanced Materials},
number = 16,
volume = 29,
place = {United States},
year = {Fri Feb 17 00:00:00 EST 2017},
month = {Fri Feb 17 00:00:00 EST 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 102 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Metal-halide perovskites for photovoltaic and light-emitting devices
journal, May 2015

  • Stranks, Samuel D.; Snaith, Henry J.
  • Nature Nanotechnology, Vol. 10, Issue 5
  • DOI: 10.1038/nnano.2015.90

Continuous-wave biexciton lasing at room temperature using solution-processed quantum wells
journal, October 2014

  • Grim, Joel Q.; Christodoulou, Sotirios; Di Stasio, Francesco
  • Nature Nanotechnology, Vol. 9, Issue 11
  • DOI: 10.1038/nnano.2014.213

Nanolasers grown on silicon
journal, February 2011

  • Chen, Roger; Tran, Thai-Truong D.; Ng, Kar Wei
  • Nature Photonics, Vol. 5, Issue 3, p. 170-175
  • DOI: 10.1038/nphoton.2010.315

Perovskite Microdisk Microlasers Self-Assembled from Solution
journal, April 2015


Native‐oxide defined ring contact for low threshold vertical‐cavity lasers
journal, July 1994

  • Huffaker, D. L.; Deppe, D. G.; Kumar, K.
  • Applied Physics Letters, Vol. 65, Issue 1
  • DOI: 10.1063/1.113087

Photonic crystals and microdisk cavities based on GaInAsP-InP system
journal, June 1997

  • Baba, T.
  • IEEE Journal of Selected Topics in Quantum Electronics, Vol. 3, Issue 3
  • DOI: 10.1109/2944.640635

Temperature-Dependent Charge-Carrier Dynamics in CH 3 NH 3 PbI 3 Perovskite Thin Films
journal, September 2015

  • Milot, Rebecca L.; Eperon, Giles E.; Snaith, Henry J.
  • Advanced Functional Materials, Vol. 25, Issue 39
  • DOI: 10.1002/adfm.201502340

The emergence of perovskite solar cells
journal, July 2014

  • Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
  • Nature Photonics, Vol. 8, Issue 7, p. 506-514
  • DOI: 10.1038/nphoton.2014.134

Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
journal, January 2015


Diode-Pumped Organo-Lead Halide Perovskite Lasing in a Metal-Clad Distributed Feedback Resonator
journal, June 2016


Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites
journal, June 2015

  • Miyata, Atsuhiko; Mitioglu, Anatolie; Plochocka, Paulina
  • Nature Physics, Vol. 11, Issue 7
  • DOI: 10.1038/nphys3357

Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors
journal, April 2015

  • Zhu, Haiming; Fu, Yongping; Meng, Fei
  • Nature Materials, Vol. 14, Issue 6
  • DOI: 10.1038/nmat4271

Red, green and blue lasing enabled by single-exciton gain in colloidal quantum dot films
journal, April 2012

  • Dang, Cuong; Lee, Joonhee; Breen, Craig
  • Nature Nanotechnology, Vol. 7, Issue 5
  • DOI: 10.1038/nnano.2012.61

Excitons in a II-VI semiconductor microcavity in the strong-coupling regime
journal, August 1995


Electro-optics of perovskite solar cells
journal, December 2014

  • Lin, Qianqian; Armin, Ardalan; Nagiri, Ravi Chandra Raju
  • Nature Photonics, Vol. 9, Issue 2
  • DOI: 10.1038/nphoton.2014.284

The gain and carrier density in semiconductor lasers under steady-state and transient conditions
journal, June 1992

  • Zhao, B.; Chen, T. R.; Yariv, A.
  • IEEE Journal of Quantum Electronics, Vol. 28, Issue 6
  • DOI: 10.1109/3.135300

Lasing in robust cesium lead halide perovskite nanowires
journal, February 2016

  • Eaton, Samuel W.; Lai, Minliang; Gibson, Natalie A.
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 8
  • DOI: 10.1073/pnas.1600789113

Bright light-emitting diodes based on organometal halide perovskite
journal, August 2014

  • Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling
  • Nature Nanotechnology, Vol. 9, Issue 9
  • DOI: 10.1038/nnano.2014.149

Effective optical properties of non-absorbing nanoporous thin films
journal, February 2006


Nanowire Lasers of Formamidinium Lead Halide Perovskites and Their Stabilized Alloys with Improved Stability
journal, January 2016


Can Trihalide Lead Perovskites Support Continuous Wave Lasing?
journal, August 2015

  • Cadelano, Michele; Sarritzu, Valerio; Sestu, Nicola
  • Advanced Optical Materials, Vol. 3, Issue 11
  • DOI: 10.1002/adom.201500229

Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
journal, July 2013

  • Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
  • Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038
  • DOI: 10.1021/ic401215x

Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
journal, January 2015


A Photonic Crystal Laser from Solution Based Organo-Lead Iodide Perovskite Thin Films
journal, March 2016


Analysis of semiconductor microcavity lasers using rate equations
journal, January 1991

  • Bjork, G.; Yamamoto, Y.
  • IEEE Journal of Quantum Electronics, Vol. 27, Issue 11
  • DOI: 10.1109/3.100877

Perovskite Materials for Light-Emitting Diodes and Lasers
journal, May 2016

  • Veldhuis, Sjoerd A.; Boix, Pablo P.; Yantara, Natalia
  • Advanced Materials, Vol. 28, Issue 32
  • DOI: 10.1002/adma.201600669

Room Temperature Lasing at Blue Wavelengths in Gallium Nitride Microcavities
journal, September 1999


Low-temperature solution-processed wavelength-tunable perovskites for lasing
journal, March 2014

  • Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien
  • Nature Materials, Vol. 13, Issue 5
  • DOI: 10.1038/nmat3911

InGaN light emitting diodes with a nanopipe layer formed from the GaN epitaxial layer
journal, January 2016

  • Hsu, Wei-Ju; Chen, Kuei-Ting; Huang, Wan-Chun
  • Optics Express, Vol. 24, Issue 11
  • DOI: 10.1364/OE.24.011601

High Photoluminescence Efficiency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors
journal, March 2014

  • Deschler, Felix; Price, Michael; Pathak, Sandeep
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 8
  • DOI: 10.1021/jz5005285

Many-body interactions in photo-excited lead iodide perovskite
journal, January 2015

  • Trinh, M. Tuan; Wu, Xiaoxi; Niesner, Daniel
  • Journal of Materials Chemistry A, Vol. 3, Issue 17
  • DOI: 10.1039/C5TA01093D

Fluorene-based polymer gain media for solid-state laser emission across the full visible spectrum
journal, May 2003

  • Xia, Ruidong; Heliotis, George; Bradley, Donal D. C.
  • Applied Physics Letters, Vol. 82, Issue 21
  • DOI: 10.1063/1.1576906

Mesoporous GaN for Photonic Engineering—Highly Reflective GaN Mirrors as an Example
journal, June 2015


Surface-emitting laser-its birth and generation of new optoelectronics field
journal, November 2000

  • Iga, K.
  • IEEE Journal of Selected Topics in Quantum Electronics, Vol. 6, Issue 6
  • DOI: 10.1109/2944.902168

A conductivity-based selective etching for next generation GaN devices
journal, June 2010

  • Zhang, Yu; Ryu, Sang-Wan; Yerino, Chris
  • physica status solidi (b), Vol. 247, Issue 7, p. 1713-1716
  • DOI: 10.1002/pssb.200983650

Spectral dynamics of picosecond gain-switched pulses from nitride-based vertical-cavity surface-emitting lasers
journal, March 2014

  • Chen, Shaoqiang; Ito, Takashi; Asahara, Akifumi
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep04325

Random lasing in organo-lead halide perovskite microcrystal networks
journal, October 2014

  • Dhanker, R.; Brigeman, A. N.; Larsen, A. V.
  • Applied Physics Letters, Vol. 105, Issue 15
  • DOI: 10.1063/1.4898703

Correlated electron–hole plasma in organometal perovskites
journal, September 2014

  • Saba, Michele; Cadelano, Michele; Marongiu, Daniela
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6049

Measurement of spontaneous emission factor for vertical-cavity surface-emitting semiconductor lasers
journal, November 1995

  • Zhao, Y. -G.; McInerney, J. G.; Morgan, R. A.
  • IEEE Photonics Technology Letters, Vol. 7, Issue 11
  • DOI: 10.1109/68.473455

All-Inorganic Colloidal Perovskite Quantum Dots: A New Class of Lasing Materials with Favorable Characteristics
journal, October 2015


Room-Temperature Near-Infrared High-Q Perovskite Whispering-Gallery Planar Nanolasers
journal, September 2014

  • Zhang, Qing; Ha, Son Tung; Liu, Xinfeng
  • Nano Letters, Vol. 14, Issue 10
  • DOI: 10.1021/nl503057g

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013


Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites
journal, August 2015

  • Yakunin, Sergii; Protesescu, Loredana; Krieg, Franziska
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9056

Surface-emitting red, green, and blue colloidal quantum dot distributed feedback lasers
journal, January 2014

  • Roh, Kwangdong; Dang, Cuong; Lee, Joonhee
  • Optics Express, Vol. 22, Issue 15
  • DOI: 10.1364/OE.22.018800

Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications
journal, January 2013

  • Baikie, Tom; Fang, Yanan; Kadro, Jeannette M.
  • Journal of Materials Chemistry A, Vol. 1, Issue 18
  • DOI: 10.1039/c3ta10518k

Two-dimensional photonic crystal bandedge laser with hybrid perovskite thin film for optical gain
journal, May 2016

  • Cha, Hyungrae; Bae, Seunghwan; Lee, Myungjae
  • Applied Physics Letters, Vol. 108, Issue 18
  • DOI: 10.1063/1.4948681

Nanopores in GaN by electrochemical anodization in hydrofluoric acid: Formation and mechanism
journal, September 2012

  • Chen, Danti; Xiao, Hongdi; Han, Jung
  • Journal of Applied Physics, Vol. 112, Issue 6, Article No. 064303
  • DOI: 10.1063/1.4752259

Conformal Organohalide Perovskites Enable Lasing on Spherical Resonators
journal, October 2014

  • Sutherland, Brandon R.; Hoogland, Sjoerd; Adachi, Michael M.
  • ACS Nano, Vol. 8, Issue 10
  • DOI: 10.1021/nn504856g

Vapor Phase Synthesis of Organometal Halide Perovskite Nanowires for Tunable Room-Temperature Nanolasers
journal, June 2015


High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites
journal, December 2013

  • Wehrenfennig, Christian; Eperon, Giles E.; Johnston, Michael B.
  • Advanced Materials, Vol. 26, Issue 10
  • DOI: 10.1002/adma.201305172

Blue and Near-Ultraviolet Vertical-Cavity Surface-Emitting Lasers
journal, July 2002


Optically pumped room-temperature GaAs nanowire lasers
journal, November 2013


Enhanced Amplified Spontaneous Emission in Perovskites Using a Flexible Cholesteric Liquid Crystal Reflector
journal, July 2015


Exciton-polariton dynamics in a transparent organic semiconductor microcavity
journal, June 2004


Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites
text, January 2015

  • Miyata, A.; Mitioglu, A.; Plochocka, P.
  • Apollo - University of Cambridge Repository
  • DOI: 10.17863/cam.38431

Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites
text, January 2015


Nanolasers grown on silicon
text, January 2011


Works referencing / citing this record:

Enhanced Exciton and Photon Confinement in Ruddlesden-Popper Perovskite Microplatelets for Highly Stable Low-Threshold Polarized Lasing
journal, April 2018


Semiconductor Quantum Dots: An Emerging Candidate for CO 2 Photoreduction
journal, June 2019

  • Wu, Hao‐Lin; Li, Xu‐Bing; Tung, Chen‐Ho
  • Advanced Materials, Vol. 31, Issue 36
  • DOI: 10.1002/adma.201900709

Lasing from Mechanically Exfoliated 2D Homologous Ruddlesden–Popper Perovskite Engineered by Inorganic Layer Thickness
journal, August 2019


Lasing Characteristics of CH 3 NH 3 PbCl 3 Single-Crystal Microcavities under Multiphoton Excitation
journal, December 2017


Recent Advances in Perovskite Micro- and Nanolasers
journal, June 2018

  • Wang, Kaiyang; Wang, Shuai; Xiao, Shumin
  • Advanced Optical Materials, Vol. 6, Issue 18
  • DOI: 10.1002/adom.201800278

Optical Energy Losses in Organic-Inorganic Hybrid Perovskite Light-Emitting Diodes
journal, July 2018

  • Shi, Xiao-Bo; Liu, Yuan; Yuan, Zhongcheng
  • Advanced Optical Materials, Vol. 6, Issue 17
  • DOI: 10.1002/adom.201800667

Advances in Functional Solution Processed Planar 1D Photonic Crystals
journal, August 2018

  • Lova, Paola; Manfredi, Giovanni; Comoretto, Davide
  • Advanced Optical Materials, Vol. 6, Issue 24
  • DOI: 10.1002/adom.201800730

Tunable Halide Perovskites for Miniaturized Solid‐State Laser Applications
journal, March 2019


Optically Pumped Lasing from Hybrid Perovskite Light‐Emitting Diodes
journal, November 2019

  • Kim, Hoyeon; Roh, Kwangdong; Murphy, John P.
  • Advanced Optical Materials, Vol. 8, Issue 1
  • DOI: 10.1002/adom.201901297

Improved air-stability of an organic–inorganic perovskite with anhydrously transferred graphene
journal, January 2018

  • Shen, Xinpeng; Wang, Mengye; Zhou, Feichi
  • Journal of Materials Chemistry C, Vol. 6, Issue 32
  • DOI: 10.1039/c8tc01507d

Low threshold lasing from novel thulium-incorporated C(NH 2 ) 3 PbI 3 perovskite thin films in Fabry–Pérot resonator
journal, January 2018

  • Arumugam, Gowri Manohari; Xu, Chunxiang; Karunakaran, Santhosh Kumar
  • Journal of Materials Chemistry C, Vol. 6, Issue 46
  • DOI: 10.1039/c8tc04697b

Low-threshold room-temperature continuous-wave optical lasing of single-crystalline perovskite in a distributed reflector microcavity
journal, January 2019

  • Tian, Cheng; Tong guo, Tong guo; Zhao, Shiqi
  • RSC Advances, Vol. 9, Issue 62
  • DOI: 10.1039/c9ra07442b

Whispering gallery mode lasing in lead halide perovskite crystals grown in microcapillary
journal, July 2018

  • Kurahashi, Naho; Nguyen, Van-Cao; Sasaki, Fumio
  • Applied Physics Letters, Vol. 113, Issue 1
  • DOI: 10.1063/1.5037243

Optically pumped lasing of segregated quasi-2D perovskite microcrystals in vertical microcavity at room temperature
journal, April 2019

  • Zhai, Wenhao; Tian, Cheng; Yuan, Kai
  • Applied Physics Letters, Vol. 114, Issue 13
  • DOI: 10.1063/1.5090569

Inkjet-printed perovskite distributed feedback lasers
journal, January 2018

  • Mathies, Florian; Brenner, Philipp; Hernandez-Sosa, Gerardo
  • Optics Express, Vol. 26, Issue 2
  • DOI: 10.1364/oe.26.00a144

Continuous-wave optically pumped green perovskite vertical-cavity surface-emitter
journal, January 2017

  • Alias, Mohd Sharizal; Liu, Zhixiong; Al-atawi, Abdullah
  • Optics Letters, Vol. 42, Issue 18
  • DOI: 10.1364/ol.42.003618

Continuous-wave operation in directly patterned perovskite distributed feedback light source at room temperature
journal, January 2018

  • Gharajeh, Abouzar; Haroldson, Ross; Li, Zhitong
  • Optics Letters, Vol. 43, Issue 3
  • DOI: 10.1364/ol.43.000611

Triple cation mixed-halide perovskites for tunable lasers
journal, January 2017

  • Brenner, Philipp; Glöckler, Tim; Rueda-Delgado, Diana
  • Optical Materials Express, Vol. 7, Issue 11
  • DOI: 10.1364/ome.7.004082

Excitonic gain and laser emission from mixed-cation halide perovskite thin films
journal, January 2018


Amplified Spontaneous Emission and Lasing in Lead Halide Perovskites: State of the Art and Perspectives
journal, October 2019

  • De Giorgi, Maria Luisa; Anni, Marco
  • Applied Sciences, Vol. 9, Issue 21
  • DOI: 10.3390/app9214591

Triple cation mixed-halide perovskites for tunable lasers
text, January 2017


Triple cation mixed-halide perovskites for tunable lasers
text, January 2017

  • Brenner, Philipp; Glöckler, Tim; Rueda-Delgado, Diana
  • The Optical Society of America (OSA)
  • DOI: 10.5445/ir/1000076190