Ultrathin Co 3 O 4 Layers with Large Contact Area on Carbon Fibers as High‐Performance Electrode for Flexible Zinc–Air Battery Integrated with Flexible Display
Abstract
A facile and binder‐free method is developed for the in situ and horizontal growth of ultrathin mesoporous Co 3 O 4 layers on the surface of carbon fibers in the carbon cloth (ultrathin Co 3 O 4 /CC) as high‐performance air electrode for the flexible Zn–air battery. In particular, the ultrathin Co 3 O 4 layers have a maximum contact area on the conductive support, facilitating the rapid electron transport and preventing the aggregation of ultrathin layers. The ultrathin feature of Co 3 O 4 layers is characterized by the transmission electron microscopy, Raman spectra, and X‐ray absorption fine structure spectroscopy. Benefiting from the high utilization degree of active materials and rapid charge transport, the mass activity for oxygen reduction and evolution reactions of the ultrathin Co 3 O 4 /CC electrode is more than 10 times higher than that of the carbon cloth loaded with commercial Co 3 O 4 nanoparticles. Compared to the commercial Co 3 O 4 /CC electrode, the flexible Zn–air battery using ultrathin Co 3 O 4 /CC electrode exhibits excellent rechargeable performance and high mechanical stability. Furthermore, the flexible Zn–air battery is integrated with a flexible display unit. The whole integrated device can operatemore »
- Authors:
-
- State Key Laboratory of Metal Matrix Composites Department of Material Science and Engineering Shanghai Jiao Tong University Shanghai 200240 China
- Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education) School of Material Science and Engineering Tianjin University Tianjin 300072 China, Tianjin Key Laboratory of Composite and Functional Materials School of Material Science and Engineering Tianjin University Tianjin 300072 China
- Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education) School of Material Science and Engineering Tianjin University Tianjin 300072 China
- X‐ray Science Division Argonne National Laboratory Lemont IL USA
- Tianjin Key Laboratory of Composite and Functional Materials School of Material Science and Engineering Tianjin University Tianjin 300072 China
- Chemical Sciences and Engineering Division Argonne National Laboratory Lemont IL USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1393304
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Name: Advanced Energy Materials Journal Volume: 7 Journal Issue: 18; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Chen, Xu, Liu, Bin, Zhong, Cheng, Liu, Zhi, Liu, Jie, Ma, Lu, Deng, Yida, Han, Xiaopeng, Wu, Tianpin, Hu, Wenbin, and Lu, Jun. Ultrathin Co 3 O 4 Layers with Large Contact Area on Carbon Fibers as High‐Performance Electrode for Flexible Zinc–Air Battery Integrated with Flexible Display. Germany: N. p., 2017.
Web. doi:10.1002/aenm.201700779.
Chen, Xu, Liu, Bin, Zhong, Cheng, Liu, Zhi, Liu, Jie, Ma, Lu, Deng, Yida, Han, Xiaopeng, Wu, Tianpin, Hu, Wenbin, & Lu, Jun. Ultrathin Co 3 O 4 Layers with Large Contact Area on Carbon Fibers as High‐Performance Electrode for Flexible Zinc–Air Battery Integrated with Flexible Display. Germany. https://doi.org/10.1002/aenm.201700779
Chen, Xu, Liu, Bin, Zhong, Cheng, Liu, Zhi, Liu, Jie, Ma, Lu, Deng, Yida, Han, Xiaopeng, Wu, Tianpin, Hu, Wenbin, and Lu, Jun. Mon .
"Ultrathin Co 3 O 4 Layers with Large Contact Area on Carbon Fibers as High‐Performance Electrode for Flexible Zinc–Air Battery Integrated with Flexible Display". Germany. https://doi.org/10.1002/aenm.201700779.
@article{osti_1393304,
title = {Ultrathin Co 3 O 4 Layers with Large Contact Area on Carbon Fibers as High‐Performance Electrode for Flexible Zinc–Air Battery Integrated with Flexible Display},
author = {Chen, Xu and Liu, Bin and Zhong, Cheng and Liu, Zhi and Liu, Jie and Ma, Lu and Deng, Yida and Han, Xiaopeng and Wu, Tianpin and Hu, Wenbin and Lu, Jun},
abstractNote = {A facile and binder‐free method is developed for the in situ and horizontal growth of ultrathin mesoporous Co 3 O 4 layers on the surface of carbon fibers in the carbon cloth (ultrathin Co 3 O 4 /CC) as high‐performance air electrode for the flexible Zn–air battery. In particular, the ultrathin Co 3 O 4 layers have a maximum contact area on the conductive support, facilitating the rapid electron transport and preventing the aggregation of ultrathin layers. The ultrathin feature of Co 3 O 4 layers is characterized by the transmission electron microscopy, Raman spectra, and X‐ray absorption fine structure spectroscopy. Benefiting from the high utilization degree of active materials and rapid charge transport, the mass activity for oxygen reduction and evolution reactions of the ultrathin Co 3 O 4 /CC electrode is more than 10 times higher than that of the carbon cloth loaded with commercial Co 3 O 4 nanoparticles. Compared to the commercial Co 3 O 4 /CC electrode, the flexible Zn–air battery using ultrathin Co 3 O 4 /CC electrode exhibits excellent rechargeable performance and high mechanical stability. Furthermore, the flexible Zn–air battery is integrated with a flexible display unit. The whole integrated device can operate without obvious performance degradation under serious deformation and even during the cutting process, which makes it highly promising for wearable and roll‐up optoelectronics.},
doi = {10.1002/aenm.201700779},
journal = {Advanced Energy Materials},
number = 18,
volume = 7,
place = {Germany},
year = {Mon May 22 00:00:00 EDT 2017},
month = {Mon May 22 00:00:00 EDT 2017}
}
https://doi.org/10.1002/aenm.201700779
Web of Science
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