Progress in High‐Voltage Cathode Materials for Rechargeable Sodium‐Ion Batteries
Abstract
Abstract Room‐temperature rechargeable sodium‐ion batteries are considered as a promising alternative technology for grid and other storage applications due to their competitive cost benefit and sustainable resource supply, triumphing other battery systems on the market. To facilitate the practical realization of the sodium‐ion technology, the energy density of sodium‐ion batteries needs to be boosted to the level of current commercial Li‐ion batteries. An effective approach would be to elevate the operating voltage of the battery, which requires the use of electrochemically stable cathode materials with high voltage versus Na + /Na. This review summarizes the recent progress with the emerging high‐voltage cathode materials for room‐temperature sodium‐ion batteries, which include layered transitional‐metal oxides, Na‐rich materials, and polyanion compounds. The key challenges and corresponding strategies for these materials are also discussed, with an emphasis placed on the intrinsic structural properties, Na storage electrochemistry, and the voltage variation tendency with respect to the redox reactions. The insights presented in this article can serve as a guide for improving the energy densities of room‐temperature Na‐ion batteries.
- Authors:
-
- Materials Science and Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1392184
- Grant/Contract Number:
- DE‐SC0005397
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Name: Advanced Energy Materials Journal Volume: 8 Journal Issue: 2; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
You, Ya, and Manthiram, Arumugam. Progress in High‐Voltage Cathode Materials for Rechargeable Sodium‐Ion Batteries. Germany: N. p., 2017.
Web. doi:10.1002/aenm.201701785.
You, Ya, & Manthiram, Arumugam. Progress in High‐Voltage Cathode Materials for Rechargeable Sodium‐Ion Batteries. Germany. https://doi.org/10.1002/aenm.201701785
You, Ya, and Manthiram, Arumugam. Mon .
"Progress in High‐Voltage Cathode Materials for Rechargeable Sodium‐Ion Batteries". Germany. https://doi.org/10.1002/aenm.201701785.
@article{osti_1392184,
title = {Progress in High‐Voltage Cathode Materials for Rechargeable Sodium‐Ion Batteries},
author = {You, Ya and Manthiram, Arumugam},
abstractNote = {Abstract Room‐temperature rechargeable sodium‐ion batteries are considered as a promising alternative technology for grid and other storage applications due to their competitive cost benefit and sustainable resource supply, triumphing other battery systems on the market. To facilitate the practical realization of the sodium‐ion technology, the energy density of sodium‐ion batteries needs to be boosted to the level of current commercial Li‐ion batteries. An effective approach would be to elevate the operating voltage of the battery, which requires the use of electrochemically stable cathode materials with high voltage versus Na + /Na. This review summarizes the recent progress with the emerging high‐voltage cathode materials for room‐temperature sodium‐ion batteries, which include layered transitional‐metal oxides, Na‐rich materials, and polyanion compounds. The key challenges and corresponding strategies for these materials are also discussed, with an emphasis placed on the intrinsic structural properties, Na storage electrochemistry, and the voltage variation tendency with respect to the redox reactions. The insights presented in this article can serve as a guide for improving the energy densities of room‐temperature Na‐ion batteries.},
doi = {10.1002/aenm.201701785},
journal = {Advanced Energy Materials},
number = 2,
volume = 8,
place = {Germany},
year = {Mon Sep 18 00:00:00 EDT 2017},
month = {Mon Sep 18 00:00:00 EDT 2017}
}
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