Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction
Abstract
Conversion of carbon monoxide (CO), a major one-carbon product of carbon dioxide (CO2) reduction, into value-added multicarbon species is a challenge to addressing global energy demands and climate change. Here in this paper, we report a modular synthetic approach for aqueous electrochemical CO reduction to carbon-carbon coupled products via self-assembly of supramolecular cages at molecular-materials interfaces. Heterobimetallic cavities formed by face-to-face coordination of thiol-terminated metalloporphyrins to copper electrodes through varying organic struts convert CO to C2 products with high faradaic efficiency (FE = 83% total with 57% to ethanol) and current density (1.34 mA/cm2) at a potential of -0.40 V vs RHE. The cage-functionalized electrodes offer an order of magnitude improvement in both selectivity and activity for electrocatalytic carbon fixation compared to parent copper surfaces or copper functionalized with porphyrins in an edge-on orientation.
- Authors:
-
[2];
- Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, Shanxi 030001, China
- Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, Shanxi 030001, China, Synfuels China, Beijing, 100195, China
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Science Foundation (NSF)
- OSTI Identifier:
- 1389889
- Alternate Identifier(s):
- OSTI ID: 1416929
- Grant/Contract Number:
- 101528-002; AC02-05CH11231
- Resource Type:
- Published Article
- Journal Name:
- ACS Central Science
- Additional Journal Information:
- Journal Name: ACS Central Science Journal Volume: 3 Journal Issue: 9; Journal ID: ISSN 2374-7943
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Gong, Ming, Cao, Zhi, Liu, Wei, Nichols, Eva M., Smith, Peter T., Derrick, Jeffrey S., Liu, Yi-Sheng, Liu, Jinjia, Wen, Xiaodong, and Chang, Christopher J. Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction. United States: N. p., 2017.
Web. doi:10.1021/acscentsci.7b00316.
Gong, Ming, Cao, Zhi, Liu, Wei, Nichols, Eva M., Smith, Peter T., Derrick, Jeffrey S., Liu, Yi-Sheng, Liu, Jinjia, Wen, Xiaodong, & Chang, Christopher J. Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction. United States. https://doi.org/10.1021/acscentsci.7b00316
Gong, Ming, Cao, Zhi, Liu, Wei, Nichols, Eva M., Smith, Peter T., Derrick, Jeffrey S., Liu, Yi-Sheng, Liu, Jinjia, Wen, Xiaodong, and Chang, Christopher J. Wed .
"Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction". United States. https://doi.org/10.1021/acscentsci.7b00316.
@article{osti_1389889,
title = {Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction},
author = {Gong, Ming and Cao, Zhi and Liu, Wei and Nichols, Eva M. and Smith, Peter T. and Derrick, Jeffrey S. and Liu, Yi-Sheng and Liu, Jinjia and Wen, Xiaodong and Chang, Christopher J.},
abstractNote = {Conversion of carbon monoxide (CO), a major one-carbon product of carbon dioxide (CO2) reduction, into value-added multicarbon species is a challenge to addressing global energy demands and climate change. Here in this paper, we report a modular synthetic approach for aqueous electrochemical CO reduction to carbon-carbon coupled products via self-assembly of supramolecular cages at molecular-materials interfaces. Heterobimetallic cavities formed by face-to-face coordination of thiol-terminated metalloporphyrins to copper electrodes through varying organic struts convert CO to C2 products with high faradaic efficiency (FE = 83% total with 57% to ethanol) and current density (1.34 mA/cm2) at a potential of -0.40 V vs RHE. The cage-functionalized electrodes offer an order of magnitude improvement in both selectivity and activity for electrocatalytic carbon fixation compared to parent copper surfaces or copper functionalized with porphyrins in an edge-on orientation.},
doi = {10.1021/acscentsci.7b00316},
journal = {ACS Central Science},
number = 9,
volume = 3,
place = {United States},
year = {Wed Sep 13 00:00:00 EDT 2017},
month = {Wed Sep 13 00:00:00 EDT 2017}
}
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https://doi.org/10.1021/acscentsci.7b00316
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Works referenced in this record:
Mesostructure-Induced Selectivity in CO 2 Reduction Catalysis
journal, November 2015
- Hall, Anthony Shoji; Yoon, Youngmin; Wuttig, Anna
- Journal of the American Chemical Society, Vol. 137, Issue 47
Nickel N-heterocyclic carbene–pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water
journal, January 2011
- Thoi, V. Sara; Chang, Christopher J.
- Chemical Communications, Vol. 47, Issue 23
Atomistic Mechanisms Underlying Selectivities in C 1 and C 2 Products from Electrochemical Reduction of CO on Cu(111)
journal, December 2016
- Xiao, Hai; Cheng, Tao; Goddard, William A.
- Journal of the American Chemical Society, Vol. 139, Issue 1
Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO
journal, January 2012
- Schneider, Jacob; Jia, Hongfei; Kobiro, Kazuya
- Energy & Environmental Science, Vol. 5, Issue 11
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
journal, October 2015
- Kornienko, Nikolay; Zhao, Yingbo; Kley, Christopher S.
- Journal of the American Chemical Society, Vol. 137, Issue 44
Light-Harvesting Metal–Organic Frameworks (MOFs) Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs
journal, October 2011
- Lee, Chang Yeon; Farha, Omar K.; Hong, Bong Jin
- Journal of the American Chemical Society, Vol. 133, Issue 40, p. 15858-15861
Facet Dependence of CO 2 Reduction Paths on Cu Electrodes
journal, December 2015
- Luo, Wenjia; Nie, Xiaowa; Janik, Michael J.
- ACS Catalysis, Vol. 6, Issue 1
Fe-Porphyrin-Based Metal–Organic Framework Films as High-Surface Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO 2
journal, September 2015
- Hod, Idan; Sampson, Matthew D.; Deria, Pravas
- ACS Catalysis, Vol. 5, Issue 11
Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006
- Lewis, N. S.; Nocera, D. G.
- Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
journal, April 2014
- Li, Christina W.; Ciston, Jim; Kanan, Matthew W.
- Nature, Vol. 508, Issue 7497
Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen-Evolution Reaction
journal, March 2016
- Han, Yongzhen; Fang, Huayi; Jing, Huize
- Angewandte Chemie International Edition, Vol. 55, Issue 18
Life on carbon monoxide: X-ray structure of Rhodospirillum rubrum Ni-Fe-S carbon monoxide dehydrogenase
journal, October 2001
- Drennan, C. L.; Heo, J.; Sintchak, M. D.
- Proceedings of the National Academy of Sciences, Vol. 98, Issue 21
Ultraefficient homogeneous catalyst for the CO 2 -to-CO electrochemical conversion
journal, October 2014
- Costentin, Cyrille; Passard, Guillaume; Robert, Marc
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 42
Porous Molecular Solids and Liquids
journal, May 2017
- Cooper, Andrew I.
- ACS Central Science, Vol. 3, Issue 6
Underpotential Deposition of Lead on Copper(111): A Study Using a Single-Crystal Rotating Ring Disk Electrode and ex Situ Low-Energy Electron Diffraction and Scanning tunneling Microscopy
journal, June 1995
- Brisard, Gessie M.; Zenati, Entissar; Gasteiger, Hubert A.
- Langmuir, Vol. 11, Issue 6
Colloidal Covalent Organic Frameworks
journal, January 2017
- Smith, Brian J.; Parent, Lucas R.; Overholts, Anna C.
- ACS Central Science, Vol. 3, Issue 1
Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO 2 -to-CO Electrochemical Conversion
journal, December 2016
- Azcarate, Iban; Costentin, Cyrille; Robert, Marc
- Journal of the American Chemical Society, Vol. 138, Issue 51
Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins
journal, October 2014
- Bediako, D. Kwabena; Solis, Brian H.; Dogutan, Dilek K.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 42
Surface reconstruction of pure-Cu single-crystal electrodes under CO-reduction potentials in alkaline solutions: A study by seriatim ECSTM-DEMS
journal, November 2016
- Kim, Youn-Geun; Javier, Alnald; Baricuatro, Jack H.
- Journal of Electroanalytical Chemistry, Vol. 780
Porphyrin Boxes: Rationally Designed Porous Organic Cages
journal, August 2015
- Hong, Soonsang; Rohman, Md. Rumum; Jia, Jiangtao
- Angewandte Chemie International Edition, Vol. 54, Issue 45
Gold Nanoparticles Coated with Manganese–Porphyrin That Effectively Shorten the Longitudinal Relaxation Time of Water Molecules Depending on the Particle Size
journal, December 2014
- Hitomi, Yutaka; Aoki, Kazuki; Miyachi, Ryosuke
- Chemistry Letters, Vol. 43, Issue 12
Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K
journal, February 2017
- Cheng, Tao; Xiao, Hai; Goddard, William A.
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 8
Catalysis of the electrochemical reduction of carbon dioxide
journal, January 2013
- Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel
- Chem. Soc. Rev., Vol. 42, Issue 6
Active and Selective Conversion of CO 2 to CO on Ultrathin Au Nanowires
journal, November 2014
- Zhu, Wenlei; Zhang, Yin-Jia; Zhang, Hongyi
- Journal of the American Chemical Society, Vol. 136, Issue 46
Visible-Light-Driven Photocatalytic CO 2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production
journal, May 2017
- Hong, Dachao; Tsukakoshi, Yuto; Kotani, Hiroaki
- Journal of the American Chemical Society, Vol. 139, Issue 19
PRODUCTION OF CO AND CH 4 IN ELECTROCHEMICAL REDUCTION OF CO 2 AT METAL ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION
journal, November 1985
- Hori, Yoshio; Kikuchi, Katsuhei; Suzuki, Shin
- Chemistry Letters, Vol. 14, Issue 11
Photochemical and Photoelectrochemical Reduction of CO 2
journal, May 2012
- Kumar, Bhupendra; Llorente, Mark; Froehlich, Jesse
- Annual Review of Physical Chemistry, Vol. 63, Issue 1
Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin
journal, September 2012
- Liu, W.; Huang, X.; Cheng, M. -J.
- Science, Vol. 337, Issue 6100
Electronic effects of peripheral substituents in porphyrins: x-ray photoelectron spectroscopy and ab initio self-consistent field calculations
journal, December 1992
- Gassman, Paul G.; Ghosh, Abhik; Almlof, Jan
- Journal of the American Chemical Society, Vol. 114, Issue 25
Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide-Derived Copper
journal, December 2015
- Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide
- Angewandte Chemie International Edition, Vol. 55, Issue 4
Catalysis at a dinuclear [CuSMo(O)OH] cluster in a CO dehydrogenase resolved at 1.1-A resolution
journal, December 2002
- Dobbek, H.; Gremer, L.; Kiefersauer, R.
- Proceedings of the National Academy of Sciences, Vol. 99, Issue 25
Powering the planet with solar fuel
journal, April 2009
- Gray, Harry B.
- Nature Chemistry, Vol. 1, Issue 1
A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts
journal, April 2009
- Shultz, Abraham M.; Farha, Omar K.; Hupp, Joseph T.
- Journal of the American Chemical Society, Vol. 131, Issue 12, p. 4204-4205
Underpotential Deposition at Single Crystal Surfaces of Au, Pt, Ag and Other Materials
journal, July 2001
- Herrero, Enrique; Buller, Lisa J.; Abruña, Héctor D.
- Chemical Reviews, Vol. 101, Issue 7
Synthesis of a cyclic porphyrin trimer with a semi-rigid cavity
journal, January 1989
- Anderson, Harry L.; Sanders, Jeremy K. M.
- Journal of the Chemical Society, Chemical Communications, Issue 22
Enzymes as Working or Inspirational Electrocatalysts for Fuel Cells and Electrolysis
journal, July 2008
- Cracknell, James A.; Vincent, Kylie A.; Armstrong, Fraser A.
- Chemical Reviews, Vol. 108, Issue 7
Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
journal, July 2015
- Verdaguer-Casadevall, Arnau; Li, Christina W.; Johansson, Tobias P.
- Journal of the American Chemical Society, Vol. 137, Issue 31
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015
- Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
- Angewandte Chemie International Edition, Vol. 54, Issue 17
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015
- Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao
- Science, Vol. 349, Issue 6253
A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
journal, March 2016
- Feng, Xiaofeng; Jiang, Kaili; Fan, Shoushan
- ACS Central Science, Vol. 2, Issue 3
Amine-Template-Directed Synthesis of Cyclic Porphyrin Oligomers
journal, December 1990
- Anderson, Harry L.; Sanders, Jeremy K. M.
- Angewandte Chemie International Edition in English, Vol. 29, Issue 12
Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process
journal, November 1986
- Beley, Marc.; Collin, Jean Paul.; Ruppert, Romain.
- Journal of the American Chemical Society, Vol. 108, Issue 24
Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes
journal, June 2012
- Schouten, Klaas Jan P.; Qin, Zisheng; Pérez Gallent, Elena
- Journal of the American Chemical Society, Vol. 134, Issue 24
Electroreduction of carbon monoxide to methane and ethylene at a copper electrode in aqueous solutions at ambient temperature and pressure
journal, August 1987
- Hori, Yoshio; Murata, Akira; Takahashi, Ryutaro
- Journal of the American Chemical Society, Vol. 109, Issue 16
Size Controlled Synthesis of Gold Nanoparticles by Porphyrin with Four Sulfur Atoms
journal, April 2009
- Ohyama, Junya; Hitomi, Yutaka; Higuchi, Yasuhiro
- Topics in Catalysis, Vol. 52, Issue 6-7
Spectroscopic Observation of a Hydrogenated CO Dimer Intermediate During CO Reduction on Cu(100) Electrodes
journal, February 2017
- Pérez-Gallent, Elena; Figueiredo, Marta C.; Calle-Vallejo, Federico
- Angewandte Chemie, Vol. 129, Issue 13
Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials
journal, September 2011
- Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.
- Science, Vol. 334, Issue 6056, p. 643-644
Manganese as a Substitute for Rhenium in CO 2 Reduction Catalysts: The Importance of Acids
journal, February 2013
- Smieja, Jonathan M.; Sampson, Matthew D.; Grice, Kyle A.
- Inorganic Chemistry, Vol. 52, Issue 5
Homogeneous catalysis using iron complexes: recent developments in selective reductions
journal, January 2011
- Junge, Kathrin; Schröder, Kristin; Beller, Matthias
- Chemical Communications, Vol. 47, Issue 17
Hydrogen Evolution from Neutral Water under Aerobic Conditions Catalyzed by Cobalt Microperoxidase-11
journal, December 2013
- Kleingardner, Jesse G.; Kandemir, Banu; Bren, Kara L.
- Journal of the American Chemical Society, Vol. 136, Issue 1
Molecular polypyridine-based metal complexes as catalysts for the reduction of CO 2
journal, January 2017
- Elgrishi, Noémie; Chambers, Matthew B.; Wang, Xia
- Chemical Society Reviews, Vol. 46, Issue 3
Advances in the Development of Novel Cobalt Fischer−Tropsch Catalysts for Synthesis of Long-Chain Hydrocarbons and Clean Fuels
journal, May 2007
- Khodakov, Andrei Y.; Chu, Wei; Fongarland, Pascal
- Chemical Reviews, Vol. 107, Issue 5
Iodide-Selective Synthetic Ion Channels Based on Shape-Persistent Organic Cages
journal, May 2017
- Benke, Bahiru Punja; Aich, Pulakesh; Kim, Younghoon
- Journal of the American Chemical Society, Vol. 139, Issue 22
A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst
journal, October 2012
- Costentin, Cyrille; Drouet, Samuel; Robert, Marc
- Science, Vol. 338, Issue 6103
Dioxygen Binding in Iron and Cobalt Picnic Basket Porphyrins
journal, July 1994
- Collman, James P.; Zhang, Xumu; Wong, Kelvin
- Journal of the American Chemical Society, Vol. 116, Issue 14
Structure-Sensitive CO 2 Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires
journal, January 2017
- Li, Yifan; Cui, Fan; Ross, Michael B.
- Nano Letters, Vol. 17, Issue 2
Covalent Organic Frameworks with High Charge Carrier Mobility
journal, September 2011
- Wan, Shun; Gándara, Felipe; Asano, Atsushi
- Chemistry of Materials, Vol. 23, Issue 18, p. 4094-4097
Cobalt(I) porphyrin catalysts of hydrogen production from water
journal, July 1985
- Kellett, Richard M.; Spiro, Thomas G.
- Inorganic Chemistry, Vol. 24, Issue 15
Efficient and Clean Photoreduction of CO 2 to CO by Enzyme-Modified TiO 2 Nanoparticles Using Visible Light
journal, February 2010
- Woolerton, Thomas W.; Sheard, Sally; Reisner, Erwin
- Journal of the American Chemical Society, Vol. 132, Issue 7
Tailoring Copper Nanocrystals towards C 2 Products in Electrochemical CO 2 Reduction
journal, April 2016
- Loiudice, Anna; Lobaccaro, Peter; Kamali, Esmail A.
- Angewandte Chemie International Edition, Vol. 55, Issue 19
Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex
journal, September 2013
- Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G.
- Journal of the American Chemical Society, Vol. 135, Issue 38
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
journal, August 2016
- Liu, Min; Pang, Yuanjie; Zhang, Bo
- Nature, Vol. 537, Issue 7620
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO
journal, October 2013
- Zhu, Wenlei; Michalsky, Ronald; Metin, Önder
- Journal of the American Chemical Society, Vol. 135, Issue 45
A Molecular Surface Functionalization Approach to Tuning Nanoparticle Electrocatalysts for Carbon Dioxide Reduction
journal, June 2016
- Cao, Zhi; Kim, Dohyung; Hong, Dachao
- Journal of the American Chemical Society, Vol. 138, Issue 26
Selectivity on Etching: Creation of High-Energy Facets on Copper Nanocrystals for CO 2 Electrochemical Reduction
journal, March 2016
- Wang, Zhenni; Yang, Guang; Zhang, Zhaorui
- ACS Nano, Vol. 10, Issue 4
Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles
journal, September 2014
- Kim, Dohyung; Resasco, Joaquin; Yu, Yi
- Nature Communications, Vol. 5, Issue 1
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
journal, September 1980
- Fisher, Barbara J.; Eisenberg, Richard
- Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363
Dendritic Growth and Morphology Selection in Copper Electrodeposition from Acidic Sulfate Solutions Containing Chlorides
journal, May 2009
- Shao, Wenbo; Zangari, Giovanni
- The Journal of Physical Chemistry C, Vol. 113, Issue 23
Self-assembled monolayers of n-alkanethiolates on copper are barrier films that protect the metal against oxidation by air
journal, November 1992
- Laibinis, Paul E.; Whitesides, George M.
- Journal of the American Chemical Society, Vol. 114, Issue 23
Reversible interconversion of carbon dioxide and formate by an electroactive enzyme
journal, July 2008
- Reda, T.; Plugge, C. M.; Abram, N. J.
- Proceedings of the National Academy of Sciences, Vol. 105, Issue 31, p. 10654-10658
A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes
journal, January 2011
- Schouten, K. J. P.; Kwon, Y.; van der Ham, C. J. M.
- Chemical Science, Vol. 2, Issue 10
Nature and Strength of M−S Bonds (M = Au, Ag, and Cu) in Binary Alloy Gold Clusters
journal, September 2010
- Pakiari, A. H.; Jamshidi, Z.
- The Journal of Physical Chemistry A, Vol. 114, Issue 34
Conformational adaptation of 2H-Tetraphenylporphyrin at Fe/Si(100) interface during metalation
journal, January 2014
- Lal, Chhagan; Caputo, Marco; Goldoni, Andrea
- Journal of Materials Research and Technology, Vol. 3, Issue 1
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
journal, June 2013
- Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.
- Chemical Reviews, Vol. 113, Issue 8
Azurin as a Protein Scaffold for a Low-coordinate Nonheme Iron Site with a Small-molecule Binding Pocket
journal, November 2012
- McLaughlin, Matthew P.; Retegan, Marius; Bill, Eckhard
- Journal of the American Chemical Society, Vol. 134, Issue 48