Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO 2 Reduction in Water

Authors:
 [1];  [2];  [1]; ORCiD logo [3];  [1]; ORCiD logo [4]; ORCiD logo [5]
+ Show Author Affiliations
  1. Department of Chemistry University of California, Berkeley Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720-1460 USA
  2. Center for Self-assembly and Complexity (CSC) Institute for Basic Science (IBS) Pohang 37673 Republic of Korea
  3. Department of Chemistry Pohang University of Science and Technology Pohang 37673 Republic of Korea
  4. Center for Self-assembly and Complexity (CSC) Institute for Basic Science (IBS) Pohang 37673 Republic of Korea, Department of Chemistry Pohang University of Science and Technology Pohang 37673 Republic of Korea
  5. Department of Chemistry University of California, Berkeley Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720-1460 USA, Department Molecular and Cell Biology and the Howard Hughes Medical Institute University of California, Berkeley Berkeley CA 94720-1460 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1459221
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 31; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Smith, Peter T., Benke, Bahiru Punja, Cao, Zhi, Kim, Younghoon, Nichols, Eva M., Kim, Kimoon, and Chang, Christopher J. Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO 2 Reduction in Water. Germany: N. p., 2018. Web. doi:10.1002/ange.201803873.
Copy to clipboard
Smith, Peter T., Benke, Bahiru Punja, Cao, Zhi, Kim, Younghoon, Nichols, Eva M., Kim, Kimoon, & Chang, Christopher J. Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO 2 Reduction in Water. Germany. https://doi.org/10.1002/ange.201803873
Copy to clipboard
Smith, Peter T., Benke, Bahiru Punja, Cao, Zhi, Kim, Younghoon, Nichols, Eva M., Kim, Kimoon, and Chang, Christopher J. Thu . "Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO 2 Reduction in Water". Germany. https://doi.org/10.1002/ange.201803873.
Copy to clipboard
@article{osti_1459221,
title = {Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO 2 Reduction in Water},
author = {Smith, Peter T. and Benke, Bahiru Punja and Cao, Zhi and Kim, Younghoon and Nichols, Eva M. and Kim, Kimoon and Chang, Christopher J.},
abstractNote = {},
doi = {10.1002/ange.201803873},
journal = {Angewandte Chemie},
number = 31,
volume = 130,
place = {Germany},
year = {2018},
month = {7}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1002/ange.201803873
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Porous organic cages: soluble, modular and molecular pores
journal, July 2016

Electrocatalytic CO 2 reduction with a membrane supported manganese catalyst in aqueous solution
journal, January 2014

  • Walsh, James J.; Neri, Gaia; Smith, Charlotte L.
  • Chem. Commun., Vol. 50, Issue 84
  • DOI: 10.1039/C4CC06404F

Enhanced Catalytic Activity of Cobalt Porphyrin in CO 2 Electroreduction upon Immobilization on Carbon Materials
journal, May 2017

  • Hu, Xin-Ming; Rønne, Magnus H.; Pedersen, Steen U.
  • Angewandte Chemie International Edition, Vol. 56, Issue 23
  • DOI: 10.1002/anie.201701104

Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons
journal, May 2017

  • Hahn, Christopher; Hatsukade, Toru; Kim, Youn-Geun
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 23
  • DOI: 10.1073/pnas.1618935114

Organic cage compounds – from shape-persistency to function
journal, January 2014

  • Zhang, Gang; Mastalerz, Michael
  • Chem. Soc. Rev., Vol. 43, Issue 6
  • DOI: 10.1039/C3CS60358J

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO 2 -to-CO Electrochemical Conversion
journal, December 2016

  • Azcarate, Iban; Costentin, Cyrille; Robert, Marc
  • Journal of the American Chemical Society, Vol. 138, Issue 51
  • DOI: 10.1021/jacs.6b07014

A Permanent Mesoporous Organic Cage with an Exceptionally High Surface Area
journal, January 2014

Separation of rare gases and chiral molecules by selective binding in porous organic cages
journal, July 2014

  • Chen, Linjiang; Reiss, Paul S.; Chong, Samantha Y.
  • Nature Materials, Vol. 13, Issue 10
  • DOI: 10.1038/nmat4035

Metal-driven self-assembly: the case of redox-active discrete architectures
journal, January 2015

  • Croué, V.; Goeb, S.; Sallé, M.
  • Chemical Communications, Vol. 51, Issue 34
  • DOI: 10.1039/C5CC00597C

Porphyrin Boxes: Rationally Designed Porous Organic Cages
journal, August 2015

  • Hong, Soonsang; Rohman, Md. Rumum; Jia, Jiangtao
  • Angewandte Chemie International Edition, Vol. 54, Issue 45
  • DOI: 10.1002/anie.201505531

A Highly C 70 Selective Shape-Persistent Rectangular Prism Constructed through One-Step Alkyne Metathesis
journal, December 2011

  • Zhang, Chenxi; Wang, Qi; Long, Hai
  • Journal of the American Chemical Society, Vol. 133, Issue 51
  • DOI: 10.1021/ja210418t

A Perspective on the Synthesis, Purification, and Characterization of Porous Organic Cages
journal, September 2016

Active and Selective Conversion of CO 2 to CO on Ultrathin Au Nanowires
journal, November 2014

  • Zhu, Wenlei; Zhang, Yin-Jia; Zhang, Hongyi
  • Journal of the American Chemical Society, Vol. 136, Issue 46
  • DOI: 10.1021/ja5095099

Enantiopure Water-Soluble [Fe 4 L 6 ] Cages: Host-Guest Chemistry and Catalytic Activity
journal, June 2013

  • Bolliger, Jeanne L.; Belenguer, Ana M.; Nitschke, Jonathan R.
  • Angewandte Chemie International Edition, Vol. 52, Issue 31
  • DOI: 10.1002/anie.201302136

Reversible water uptake by a stable imine-based porous organic cage
journal, January 2012

  • Hasell, Tom; Schmidtmann, Marc; Stone, Corinne A.
  • Chemical Communications, Vol. 48, Issue 39
  • DOI: 10.1039/c2cc31212c

Permanent Porous Materials from Discrete Organic Molecules-Towards Ultra-High Surface Areas
journal, July 2012

A supramolecular microenvironment strategy for transition metal catalysis
journal, December 2015

Transforming a chemically labile [2+3] imine cage into a robust carbamate cage
journal, January 2017

  • Hu, Xin-Yue; Zhang, Wen-Shan; Rominger, Frank
  • Chemical Communications, Vol. 53, Issue 61
  • DOI: 10.1039/C7CC03677A

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis
journal, June 2012

  • Costentin, Cyrille; Drouet, Samuel; Robert, Marc
  • Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242
  • DOI: 10.1021/ja303560c

Simultaneous Reduction of CO 2 and Splitting of H 2 O by a Single Immobilized Cobalt Phthalocyanine Electrocatalyst
journal, April 2016

  • Morlanés, Natalia; Takanabe, Kazuhiro; Rodionov, Valentin
  • ACS Catalysis, Vol. 6, Issue 5
  • DOI: 10.1021/acscatal.6b00543

Electrochemical Reduction of CO2 to CO Catalyzed by a Bimetallic Palladium Complex
journal, July 2006

  • Raebiger, James W.; Turner, Jeffrey W.; Noll, Bruce C.
  • Organometallics, Vol. 25, Issue 14, p. 3345-3351
  • DOI: 10.1021/om060228g

Enhanced Catalytic Activity of Cobalt Porphyrin in CO 2 Electroreduction upon Immobilization on Carbon Materials
journal, May 2017

  • Hu, Xin-Ming; Rønne, Magnus H.; Pedersen, Steen U.
  • Angewandte Chemie, Vol. 129, Issue 23
  • DOI: 10.1002/ange.201701104

Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination
journal, March 2015

  • Cook, Timothy R.; Stang, Peter J.
  • Chemical Reviews, Vol. 115, Issue 15
  • DOI: 10.1021/cr5005666

Polymer coordination promotes selective CO 2 reduction by cobalt phthalocyanine
journal, January 2016

  • Kramer, W. W.; McCrory, C. C. L.
  • Chemical Science, Vol. 7, Issue 4
  • DOI: 10.1039/C5SC04015A

Enantiomerenreine wasserlösliche [Fe 4 L 6 ]-Käfigverbindungen: Wirt-Gast-Chemie und katalytische Aktivität
journal, June 2013

  • Bolliger, Jeanne L.; Belenguer, Ana M.; Nitschke, Jonathan R.
  • Angewandte Chemie, Vol. 125, Issue 31
  • DOI: 10.1002/ange.201302136

A Self-Assembled Cofacial Cobalt Porphyrin Prism for Oxygen Reduction Catalysis
journal, January 2017

  • Oldacre, Amanda N.; Friedman, Alan E.; Cook, Timothy R.
  • Journal of the American Chemical Society, Vol. 139, Issue 4
  • DOI: 10.1021/jacs.6b12404

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015

Reticular Electronic Tuning of Porphyrin Active Sites in Covalent Organic Frameworks for Electrocatalytic Carbon Dioxide Reduction
journal, January 2018

  • Diercks, Christian S.; Lin, Song; Kornienko, Nikolay
  • Journal of the American Chemical Society, Vol. 140, Issue 3
  • DOI: 10.1021/jacs.7b11940

Template Synthesis of Gold Nanoparticles with an Organic Molecular Cage
journal, January 2014

  • McCaffrey, Ryan; Long, Hai; Jin, Yinghua
  • Journal of the American Chemical Society, Vol. 136, Issue 5
  • DOI: 10.1021/ja412606t

Nanoporous Organic Polymer/Cage Composite Membranes
journal, December 2012

  • Bushell, Alexandra F.; Budd, Peter M.; Attfield, Martin P.
  • Angewandte Chemie International Edition, Vol. 52, Issue 4
  • DOI: 10.1002/anie.201206339

Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures
journal, March 2017

  • Zhang, Xing; Wu, Zishan; Zhang, Xiao
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14675

Acid- and Base-Stable Porous Organic Cages: Shape Persistence and pH Stability via Post-synthetic “Tying” of a Flexible Amine Cage
journal, May 2014

  • Liu, Ming; Little, Marc A.; Jelfs, Kim E.
  • Journal of the American Chemical Society, Vol. 136, Issue 21
  • DOI: 10.1021/ja503223j

Selective increase in CO 2 electroreduction activity at grain-boundary surface terminations
journal, November 2017

Noncovalent Immobilization of a Molecular Iron-Based Electrocatalyst on Carbon Electrodes for Selective, Efficient CO 2 -to-CO Conversion in Water
journal, February 2016

  • Maurin, Antoine; Robert, Marc
  • Journal of the American Chemical Society, Vol. 138, Issue 8
  • DOI: 10.1021/jacs.5b12652

Catalytic CO 2 -to-CO conversion in water by covalently functionalized carbon nanotubes with a molecular iron catalyst
journal, January 2016

  • Maurin, Antoine; Robert, Marc
  • Chemical Communications, Vol. 52, Issue 81
  • DOI: 10.1039/C6CC05430G

Radical Polymerization of Vinyl Monomers in Porous Organic Cages
journal, March 2016

  • Uemura, Takashi; Nakanishi, Ryo; Mochizuki, Shuto
  • Angewandte Chemie, Vol. 128, Issue 22
  • DOI: 10.1002/ange.201601587

Manganese Electrocatalysts with Bulky Bipyridine Ligands: Utilizing Lewis Acids To Promote Carbon Dioxide Reduction at Low Overpotentials
journal, January 2016

  • Sampson, Matthew D.; Kubiak, Clifford P.
  • Journal of the American Chemical Society, Vol. 138, Issue 4
  • DOI: 10.1021/jacs.5b12215

Polyimine Container Molecules and Nanocapsules
journal, July 2011

  • Rue, Nicholas M.; Sun, Junling; Warmuth, Ralf
  • Israel Journal of Chemistry, Vol. 51, Issue 7
  • DOI: 10.1002/ijch.201100064

Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions
journal, January 2016

  • Wang, Qi-Qiang; Gonell, Sergio; Leenders, Stefan H. A. M.
  • Nature Chemistry, Vol. 8, Issue 3
  • DOI: 10.1038/nchem.2425

Porous Organic Cage Compounds as Highly Potent Affinity Materials for Sensing by Quartz Crystal Microbalances
journal, September 2012

  • Brutschy, Malte; Schneider, Markus W.; Mastalerz, Michael
  • Advanced Materials, Vol. 24, Issue 45
  • DOI: 10.1002/adma.201202786

Iodide-Selective Synthetic Ion Channels Based on Shape-Persistent Organic Cages
journal, May 2017

  • Benke, Bahiru Punja; Aich, Pulakesh; Kim, Younghoon
  • Journal of the American Chemical Society, Vol. 139, Issue 22
  • DOI: 10.1021/jacs.7b02708

Efficient and selective molecular catalyst for the CO 2 -to-CO electrochemical conversion in water
journal, May 2015

  • Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 22
  • DOI: 10.1073/pnas.1507063112

Understanding gas capacity, guest selectivity, and diffusion in porous liquids
journal, January 2017

  • Greenaway, Rebecca L.; Holden, Daniel; Eden, Edward G. B.
  • Chemical Science, Vol. 8, Issue 4
  • DOI: 10.1039/C6SC05196K

Surface Immobilization of Molecular Electrocatalysts for Energy Conversion
journal, March 2017

  • Bullock, R. Morris; Das, Atanu K.; Appel, Aaron M.
  • Chemistry - A European Journal, Vol. 23, Issue 32
  • DOI: 10.1002/chem.201605066

Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO 2 Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry
journal, March 2018

  • Cao, Zhi; Derrick, Jeffrey S.; Xu, Jun
  • Angewandte Chemie International Edition, Vol. 57, Issue 18
  • DOI: 10.1002/anie.201800367

Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin
journal, September 2015

  • Shen, Jing; Kortlever, Ruud; Kas, Recep
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9177

Nanoporous Organic Polymer/Cage Composite Membranes
journal, December 2012

  • Bushell, Alexandra F.; Budd, Peter M.; Attfield, Martin P.
  • Angewandte Chemie, Vol. 125, Issue 4
  • DOI: 10.1002/ange.201206339

Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N -Heterocyclic Carbene–Isoquinoline Complex
journal, September 2013

  • Thoi, V. Sara; Kornienko, Nikolay; Margarit, Charles G.
  • Journal of the American Chemical Society, Vol. 135, Issue 38
  • DOI: 10.1021/ja4074003

Permeable Self-Assembled Molecular Containers for Catalyst Isolation Enabling Two-Step Cascade Reactions
journal, April 2017

  • Ueda, Yoshihiro; Ito, Hiroaki; Fujita, Daishi
  • Journal of the American Chemical Society, Vol. 139, Issue 17
  • DOI: 10.1021/jacs.7b02745

Electrochemically Driven Clathration/Declathration of Ferrocene and Its Derivatives by a Nanometer-Sized Coordination Cage
journal, October 2002

  • Sun, Wei-Yin; Kusukawa, Takahiro; Fujita, Makoto
  • Journal of the American Chemical Society, Vol. 124, Issue 39
  • DOI: 10.1021/ja0206285

Radical Polymerization of Vinyl Monomers in Porous Organic Cages
journal, March 2016

  • Uemura, Takashi; Nakanishi, Ryo; Mochizuki, Shuto
  • Angewandte Chemie International Edition, Vol. 55, Issue 22
  • DOI: 10.1002/anie.201601587

Liquids with permanent porosity
journal, November 2015

  • Giri, Nicola; Del Pópolo, Mario G.; Melaugh, Gavin
  • Nature, Vol. 527, Issue 7577
  • DOI: 10.1038/nature16072

Chemistry and Catalysis in Functional Cavitands
journal, March 2009

Tuning Product Selectivity for Aqueous CO 2 Reduction with a Mn(bipyridine)-pyrene Catalyst Immobilized on a Carbon Nanotube Electrode
journal, October 2017

  • Reuillard, Bertrand; Ly, Khoa H.; Rosser, Timothy E.
  • Journal of the American Chemical Society, Vol. 139, Issue 41
  • DOI: 10.1021/jacs.7b06269

A Metal−Organic Framework with a Covalently Prefabricated Porous Organic Linker
journal, September 2010

  • Swamy, Shashikala I.; Bacsa, John; Jones, James T. A.
  • Journal of the American Chemical Society, Vol. 132, Issue 37
  • DOI: 10.1021/ja104083y

Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles
journal, September 2014

  • Kim, Dohyung; Resasco, Joaquin; Yu, Yi
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5948

Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction
journal, September 2017

Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines
journal, January 1989

  • Furuya, Nagakazu; Matsui, Kuniyasu
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 271, Issue 1-2
  • DOI: 10.1016/0022-0728(89)80074-9

Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels
journal, January 2009

  • Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J.
  • Chem. Soc. Rev., Vol. 38, Issue 1
  • DOI: 10.1039/B804323J

Toward Homogenization of Heterogeneous Metal Nanoparticle Catalysts with Enhanced Catalytic Performance: Soluble Porous Organic Cage as a Stabilizer and Homogenizer
journal, June 2015

  • Sun, Jian-Ke; Zhan, Wen-Wen; Akita, Tomoki
  • Journal of the American Chemical Society, Vol. 137, Issue 22
  • DOI: 10.1021/jacs.5b04029

Nickel(II)-cyclam: an extremely selective electrocatalyst for reduction of CO2 in water
journal, January 1984

  • Beley, Marc; Collin, Jean-Paul; Ruppert, Romain
  • Journal of the Chemical Society, Chemical Communications, Issue 19
  • DOI: 10.1039/c39840001315

Porphyrin Boxes: Rationally Designed Porous Organic Cages
journal, August 2015

  • Hong, Soonsang; Rohman, Md. Rumum; Jia, Jiangtao
  • Angewandte Chemie, Vol. 127, Issue 45
  • DOI: 10.1002/ange.201505531

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
journal, June 2013

  • Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.
  • Chemical Reviews, Vol. 113, Issue 8
  • DOI: 10.1021/cr300463y

A Permanent Mesoporous Organic Cage with an Exceptionally High Surface Area
journal, January 2014

  • Zhang, Gang; Presly, Oliver; White, Fraser
  • Angewandte Chemie International Edition, Vol. 53, Issue 6
  • DOI: 10.1002/anie.201308924

Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation
journal, December 2008

  • Lee, Suk Joong; Cho, So-Hye; Mulfort, Karen L.
  • Journal of the American Chemical Society, Vol. 130, Issue 50
  • DOI: 10.1021/ja804014y
    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: