Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks

Barkholtz, Heather M.; Liu, Di -Jia

doi:10.1039/c6mh00344c

Title: Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks

Journal Article · Sun Nov 13 19:00:00 EST 2016 · Materials Horizons

DOI: https://doi.org/10.1039/c6mh00344c · OSTI ID:1373936

Barkholtz, Heather M. ^[1]; Liu, Di -Jia ^[2]

Argonne National Lab. (ANL), Lemont, IL (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Over the past several years, metal-organic framework (MOF)-derived platinum group metal free (PGM-free) electrocatalysts have gained considerable attention due to their high efficiency and low cost as potential replacement for platinum in catalyzing oxygen reduction reaction (ORR). In this review, we summarize the recent advancements in design, synthesis and characterization of MOF-derived ORR catalysts and their performances in acidic and alkaline media. As a result, we also discuss the key challenges such as durability and activity enhancement critical in moving forward this emerging electrocatalyst science.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Fuel Cell Technologies Office (EE-3F); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1373936

Journal Information:: Materials Horizons, Journal Name: Materials Horizons Journal Issue: 1 Vol. 4; ISSN 2051-6347; ISSN MHAOAL

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Metal–organic frameworks based on tetraphenylpyrazine-derived tetracarboxylic acid for electrocatalytic hydrogen evolution reaction and NAC sensing Wang, Tao; Huang, Kun; Peng, Mengni CrystEngComm, Vol. 21, Issue 3 https://doi.org/10.1039/c8ce01868e	journal	January 2019
Hierarchically porous Fe–N–C nanospindles derived from a porphyrinic coordination network for oxygen reduction reaction Hua, Xing; Luo, Jin; Shen, Chencheng Catalysis Science & Technology, Vol. 8, Issue 7 https://doi.org/10.1039/c8cy00168e	journal	January 2018
Electrochemically in situ controllable assembly of hierarchically-ordered and integrated inorganic–carbon hybrids for efficient hydrogen evolution Wang, Zhong-Li; Sun, Keju; Henzie, Joel Materials Horizons, Vol. 5, Issue 6 https://doi.org/10.1039/c8mh00773j	journal	January 2018
From a Au-rich core/PtNi-rich shell to a Ni-rich core/PtAu-rich shell: an effective thermochemical pathway to nanoengineering catalysts for fuel cells Lu, Aolin; Wu, Zhi-Peng; Chen, Binghui Journal of Materials Chemistry A, Vol. 6, Issue 12 https://doi.org/10.1039/c8ta00025e	journal	January 2018
Apically Co-nanoparticles-wrapped nitrogen-doped carbon nanotubes from a single-source MOF for efficient oxygen reduction Ma, Lin; Wang, Rui; Li, Ya-Hui Journal of Materials Chemistry A, Vol. 6, Issue 47 https://doi.org/10.1039/c8ta08668k	journal	January 2018
High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites Zhang, Hanguang; Chung, Hoon T.; Cullen, David A. Energy & Environmental Science, Vol. 12, Issue 8 https://doi.org/10.1039/c9ee00877b	journal	January 2019
An active oxygen reduction electrocatalyst derived from bio-inspired tannic acid-Fe assembly Chen, Chan; Zhang, Zhijia; Yin, Yaqing Materials Research Express, Vol. 5, Issue 9 https://doi.org/10.1088/2053-1591/aad601	journal	August 2018
PGM-Free ORR Catalysts Designed by Templating PANI-Type Polymers Containing Functional Groups with High Affinity to Iron Yin, Xi; Chung, Hoon T.; Martinez, Ulises Journal of The Electrochemical Society, Vol. 166, Issue 7 https://doi.org/10.1149/2.0301907jes	journal	January 2019
Transition Metal–Nitrogen–Carbon (M–N–C) Catalysts for Oxygen Reduction Reaction. Insights on Synthesis and Performance in Polymer Electrolyte Fuel Cells Osmieri, Luigi ChemEngineering, Vol. 3, Issue 1 https://doi.org/10.3390/chemengineering3010016	journal	February 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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