A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores (in German)
Abstract
Abstract Through topological rationalization, a zeotype mesoporous Zr‐containing metal–organic framework (MOF), namely PCN‐777, has been designed and synthesized. PCN‐777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm 3 g −1 among reported Zr‐MOFs. Moreover, PCN‐777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN‐777 and different guests can be varied to realize efficient immobilization.
- Authors:
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1367689
- Grant/Contract Number:
- DE‐AC02‐06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 127 Journal Issue: 1; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- German
Citation Formats
Feng, Dawei, Wang, Kecheng, Su, Jie, Liu, Tian‐Fu, Park, Jihye, Wei, Zhangwen, Bosch, Mathieu, Yakovenko, Andrey, Zou, Xiaodong, and Zhou, Hong‐Cai. A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores. Germany: N. p., 2014.
Web. doi:10.1002/ange.201409334.
Feng, Dawei, Wang, Kecheng, Su, Jie, Liu, Tian‐Fu, Park, Jihye, Wei, Zhangwen, Bosch, Mathieu, Yakovenko, Andrey, Zou, Xiaodong, & Zhou, Hong‐Cai. A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores. Germany. https://doi.org/10.1002/ange.201409334
Feng, Dawei, Wang, Kecheng, Su, Jie, Liu, Tian‐Fu, Park, Jihye, Wei, Zhangwen, Bosch, Mathieu, Yakovenko, Andrey, Zou, Xiaodong, and Zhou, Hong‐Cai. Mon .
"A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores". Germany. https://doi.org/10.1002/ange.201409334.
@article{osti_1367689,
title = {A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores},
author = {Feng, Dawei and Wang, Kecheng and Su, Jie and Liu, Tian‐Fu and Park, Jihye and Wei, Zhangwen and Bosch, Mathieu and Yakovenko, Andrey and Zou, Xiaodong and Zhou, Hong‐Cai},
abstractNote = {Abstract Through topological rationalization, a zeotype mesoporous Zr‐containing metal–organic framework (MOF), namely PCN‐777, has been designed and synthesized. PCN‐777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm 3 g −1 among reported Zr‐MOFs. Moreover, PCN‐777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN‐777 and different guests can be varied to realize efficient immobilization.},
doi = {10.1002/ange.201409334},
journal = {Angewandte Chemie},
number = 1,
volume = 127,
place = {Germany},
year = {Mon Nov 10 00:00:00 EST 2014},
month = {Mon Nov 10 00:00:00 EST 2014}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/ange.201409334
https://doi.org/10.1002/ange.201409334
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr)
journal, July 2013
- Vermoortele, Frederik; Bueken, Bart; Le Bars, Gaëlle
- Journal of the American Chemical Society, Vol. 135, Issue 31
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis
journal, August 2011
- Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E.
- Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454
Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks
journal, October 2012
- Kim, Min; Cahill, John F.; Fei, Honghan
- Journal of the American Chemical Society, Vol. 134, Issue 43
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013
- Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
- Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework
journal, October 2013
- Pullen, Sonja; Fei, Honghan; Orthaber, Andreas
- Journal of the American Chemical Society, Vol. 135, Issue 45
Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals
journal, May 2011
- Schaate, Andreas; Roy, Pascal; Godt, Adelheid
- Chemistry - A European Journal, Vol. 17, Issue 24
How Can Proteins Enter the Interior of a MOF? Investigation of Cytochrome c Translocation into a MOF Consisting of Mesoporous Cages with Microporous Windows
journal, August 2012
- Chen, Yao; Lykourinou, Vasiliki; Vetromile, Carissa
- Journal of the American Chemical Society, Vol. 134, Issue 32
A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal-Organic Frameworks
journal, August 2012
- Guillerm, V.; Ragon, F.; Dan-Hardi, M.
- Angewandte Chemie, Vol. 124, Issue 37
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012
- Morris, William; Volosskiy, Boris; Demir, Selcuk
- Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
Ionic Conductivity in the Metal-Organic Framework UiO-66 by Dehydration and Insertion of Lithium tert -Butoxide
journal, March 2013
- Ameloot, Rob; Aubrey, Michael; Wiers, Brian M.
- Chemistry - A European Journal, Vol. 19, Issue 18
Postsynthetic modification of metal–organic frameworks—a progress report
journal, January 2011
- Tanabe, Kristine K.; Cohen, Seth M.
- Chem. Soc. Rev., Vol. 40, Issue 2
Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation
journal, May 2008
- Hwang, Young Kyu; Hong, Do-Young; Chang, Jong-San
- Angewandte Chemie International Edition, Vol. 47, Issue 22, p. 4144-4148
Topological Analysis of Metal–Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity Principle
journal, November 2013
- Li, Mian; Li, Dan; O’Keeffe, Michael
- Chemical Reviews, Vol. 114, Issue 2
Synthesis and catalytic properties of MIL-100(Fe), an iron( iii ) carboxylate with large pores
journal, January 2007
- Horcajada, Patricia; Surblé, Suzy; Serre, Christian
- Chem. Commun., Issue 27
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
journal, October 2013
- Feng, Dawei; Chung, Wan-Chun; Wei, Zhangwen
- Journal of the American Chemical Society, Vol. 135, Issue 45
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014
- Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
- Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005
- Ferey, G.; Mellot-Draznieks, C.; Serre, C.
- Science, Vol. 309, Issue 5743, p. 2040-2042
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie, Vol. 124, Issue 41, p. 10453-10456
Three-dimensional rotation electron diffraction: software RED for automated data collection and data processing
journal, November 2013
- Wan, Wei; Sun, Junliang; Su, Jie
- Journal of Applied Crystallography, Vol. 46, Issue 6
Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal–Organic Frameworks
journal, August 2012
- Jiang, Hai-Long; Feng, Dawei; Liu, Tian-Fu
- Journal of the American Chemical Society, Vol. 134, Issue 36
A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
journal, August 2004
- Férey, Gérard; Serre, Christian; Mellot-Draznieks, Caroline
- Angewandte Chemie International Edition, Vol. 43, Issue 46
Discovery, development, and functionalization of Zr( iv )-based metal–organic frameworks
journal, January 2012
- Kim, Min; Cohen, Seth M.
- CrystEngComm, Vol. 14, Issue 12
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008
- Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
- Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
Introduction to Metal–Organic Frameworks
journal, September 2011
- Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 673-674
Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66
journal, July 2014
- Shearer, Greig C.; Chavan, Sachin; Ethiraj, Jayashree
- Chemistry of Materials, Vol. 26, Issue 14
A new isoreticular class of metal-organic-frameworks with the MIL-88 topology
journal, January 2006
- Surblé, Suzy; Serre, Christian; Mellot-Draznieks, Caroline
- Chemical Communications, Vol. 0, Issue 3, p. 284-286
Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption
journal, May 2013
- Wu, Hui; Chua, Yong Shen; Krungleviciute, Vaiva
- Journal of the American Chemical Society, Vol. 135, Issue 28
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
journal, August 2012
- Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon
- Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021
High valence 3p and transition metal based MOFs
journal, January 2014
- Devic, Thomas; Serre, Christian
- Chem. Soc. Rev., Vol. 43, Issue 16
A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal-Organic Frameworks
journal, August 2012
- Guillerm, V.; Ragon, F.; Dan-Hardi, M.
- Angewandte Chemie International Edition, Vol. 51, Issue 37
In Situ Infrared Spectroscopic and Gravimetric Characterisation of the Solvent Removal and Dehydroxylation of the Metal Organic Frameworks UiO-66 and UiO-67
journal, May 2013
- Shearer, Greig C.; Forselv, Stian; Chavan, Sachin
- Topics in Catalysis, Vol. 56, Issue 9-10
MIL-100(V) – A mesoporous vanadium metal organic framework with accessible metal sites
journal, July 2012
- Lieb, Alexandra; Leclerc, Hervé; Devic, Thomas
- Microporous and Mesoporous Materials, Vol. 157
Elucidating Molecular Iridium Water Oxidation Catalysts Using Metal–Organic Frameworks: A Comprehensive Structural, Catalytic, Spectroscopic, and Kinetic Study
journal, November 2012
- Wang, Cheng; Wang, Jin-Liang; Lin, Wenbin
- Journal of the American Chemical Society, Vol. 134, Issue 48
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
- Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
- Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation
journal, May 2008
- Hwang, Young Kyu; Hong, Do-Young; Chang, Jong-San
- Angewandte Chemie, Vol. 120, Issue 22
A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
journal, August 2004
- Férey, Gérard; Serre, Christian; Mellot-Draznieks, Caroline
- Angewandte Chemie, Vol. 116, Issue 46, p. 6456-6461
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012
- Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
- Angewandte Chemie International Edition, Vol. 51, Issue 41
Collecting 3D electron diffraction data by the rotation method
journal, January 2010
- Zhang, Daliang; Oleynikov, Peter; Hovmöller, Sven
- Zeitschrift für Kristallographie, Vol. 225, Issue 2-3
Stepwise Ligand Exchange for the Preparation of a Family of Mesoporous MOFs
journal, May 2013
- Li, Tao; Kozlowski, Mark T.; Doud, Evan A.
- Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11688-11691
Metal–organic framework composites
journal, January 2014
- Zhu, Qi-Long; Xu, Qiang
- Chem. Soc. Rev., Vol. 43, Issue 16
A robust, catalytic metal–organic framework with open 2,2′-bipyridine sites
journal, January 2014
- Fei, Honghan; Cohen, Seth M.
- Chem. Commun., Vol. 50, Issue 37
Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012
- Deng, H.; Grunder, S.; Cordova, K. E.
- Science, Vol. 336, Issue 6084, p. 1018-1023
Synthesis, Single-Crystal X-ray Microdiffraction, and NMR Characterizations of the Giant Pore Metal-Organic Framework Aluminum Trimesate MIL-100
journal, December 2009
- Volkringer, Christophe; Popov, Dimitry; Loiseau, Thierry
- Chemistry of Materials, Vol. 21, Issue 24