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Title: A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores.

Abstract

Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8nm and the highest pore volume of 2.8cm(3)g(-1) among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN-777 and different guests can be varied to realize efficient immobilization

Authors:
; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); US Department of the Navy, Office of Naval Research (ONR)
OSTI Identifier:
1239628
DOE Contract Number:
AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Angewandte Chemie (International Edition); Journal Volume: 54; Journal Issue: 1
Country of Publication:
United States
Language:
English
Subject:
mesoporous materials; zirconium; carboxylate ligands; host-guest systems; metal-organic frameworks

Citation Formats

Feng, Dawei, Wang, Kecheng, Su, Jie, Liu, Tian-Fu, Park, Jihye, Wei, Zhangwen, Bosch, Mathieu, Yakovenko, Andrey, Zou, Xiaodong, and Zhou, Hong-Cai. A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores.. United States: N. p., 2015. Web. doi:10.1002/anie.201409334.
Feng, Dawei, Wang, Kecheng, Su, Jie, Liu, Tian-Fu, Park, Jihye, Wei, Zhangwen, Bosch, Mathieu, Yakovenko, Andrey, Zou, Xiaodong, & Zhou, Hong-Cai. A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores.. United States. doi:10.1002/anie.201409334.
Feng, Dawei, Wang, Kecheng, Su, Jie, Liu, Tian-Fu, Park, Jihye, Wei, Zhangwen, Bosch, Mathieu, Yakovenko, Andrey, Zou, Xiaodong, and Zhou, Hong-Cai. Fri . "A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores.". United States. doi:10.1002/anie.201409334.
@article{osti_1239628,
title = {A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores.},
author = {Feng, Dawei and Wang, Kecheng and Su, Jie and Liu, Tian-Fu and Park, Jihye and Wei, Zhangwen and Bosch, Mathieu and Yakovenko, Andrey and Zou, Xiaodong and Zhou, Hong-Cai},
abstractNote = {Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8nm and the highest pore volume of 2.8cm(3)g(-1) among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN-777 and different guests can be varied to realize efficient immobilization},
doi = {10.1002/anie.201409334},
journal = {Angewandte Chemie (International Edition)},
number = 1,
volume = 54,
place = {United States},
year = {Fri Jan 02 00:00:00 EST 2015},
month = {Fri Jan 02 00:00:00 EST 2015}
}