B-Site Metal Cation Exchange in Halide Perovskites
Abstract
e demonstrate exchange of the B-site metal cation in hybrid organic-inorganic halide perovskite thin films. We exchange tin in formamidinium tin triiodide (CH- (NH2)2SnI3, or FASnI3) with lead at controllable levels, forming CH(NH2)2SnxPb1-xI3 alloys with partial substitution and fully converting the film to CH(NH2)2PbI3 with a large excess of Pb2+. We observe no evidence for phase segregation or bilayered films, indicating that conversion is uniform throughout the film. This facile technique provides a new way to control composition independently from the crystallization processes, allowing formation of the black phase of CH(NH2)2PbI3 at much lower temperatures than those previously reported while also opening the door to new morphology-composition combinations. The surprising observation that the B-site metal cations are mobile may also provide insight into the nature of transient processes in these materials, suggesting that they may be involved in ionic conduction, and will be a critical consideration for long-term stability.
- Authors:
-
- Univ. of Washington, Seattle, WA (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Univ. of Washington, Seattle, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Washington Research Foundation, Seattle, WA (United States); National Science Foundation (NSF); National Institutes of Health (NIH)
- OSTI Identifier:
- 1361564
- Alternate Identifier(s):
- OSTI ID: 1425734; OSTI ID: 1508256
- Grant/Contract Number:
- SC0013957; ECC-1542101
- Resource Type:
- Published Article
- Journal Name:
- ACS Energy Letters
- Additional Journal Information:
- Journal Name: ACS Energy Letters Journal Volume: 2 Journal Issue: 5; Journal ID: ISSN 2380-8195
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Eperon, Giles E., and Ginger, David S. B-Site Metal Cation Exchange in Halide Perovskites. United States: N. p., 2017.
Web. doi:10.1021/acsenergylett.7b00290.
Eperon, Giles E., & Ginger, David S. B-Site Metal Cation Exchange in Halide Perovskites. United States. https://doi.org/10.1021/acsenergylett.7b00290
Eperon, Giles E., and Ginger, David S. Tue .
"B-Site Metal Cation Exchange in Halide Perovskites". United States. https://doi.org/10.1021/acsenergylett.7b00290.
@article{osti_1361564,
title = {B-Site Metal Cation Exchange in Halide Perovskites},
author = {Eperon, Giles E. and Ginger, David S.},
abstractNote = {e demonstrate exchange of the B-site metal cation in hybrid organic-inorganic halide perovskite thin films. We exchange tin in formamidinium tin triiodide (CH- (NH2)2SnI3, or FASnI3) with lead at controllable levels, forming CH(NH2)2SnxPb1-xI3 alloys with partial substitution and fully converting the film to CH(NH2)2PbI3 with a large excess of Pb2+. We observe no evidence for phase segregation or bilayered films, indicating that conversion is uniform throughout the film. This facile technique provides a new way to control composition independently from the crystallization processes, allowing formation of the black phase of CH(NH2)2PbI3 at much lower temperatures than those previously reported while also opening the door to new morphology-composition combinations. The surprising observation that the B-site metal cations are mobile may also provide insight into the nature of transient processes in these materials, suggesting that they may be involved in ionic conduction, and will be a critical consideration for long-term stability.},
doi = {10.1021/acsenergylett.7b00290},
journal = {ACS Energy Letters},
number = 5,
volume = 2,
place = {United States},
year = {Tue May 02 00:00:00 EDT 2017},
month = {Tue May 02 00:00:00 EDT 2017}
}
https://doi.org/10.1021/acsenergylett.7b00290
Web of Science
Figures / Tables:
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