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Title: Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis

Abstract

Here, the facile pyrolysis of a bipyridyl metal-organic framework, MOF-253, produces N-doped porous carbons (Cz-MOF-253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen-containing MOF-derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz-MOF-253-supported Pd nanoparticles (Pd/Cz-MOF-253-800) show excellent performance in a one-pot sequential Knoevenagel condensation-hydrogenation reaction.

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [2];  [3];  [1];  [1]; ORCiD logo [1]
+ Show Author Affiliations
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
  2. Beijing Normal Univ., Beijing (People's Republic of China)
  3. Iowa State Univ., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1357787
Report Number(s):
IS-J-9273
Journal ID: ISSN 0947-6539
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Volume: 23; Journal Issue: 18; Journal ID: ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; Knoevenagel condensation; metal–organic frameworks; n-doped carbons; palladium; tandem catalysis

Citation Formats

Li, Xinle, Zhang, Biying, Fang, Yuhui, Sun, Weijun, Qi, Zhiyuan, Pei, Yuchen, Qi, Shuyan, Yuan, Pengyu, Luan, Xuechen, Goh, Tian Wei, and Huang, Wenyu. Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis. United States: N. p., 2017. Web. doi:10.1002/chem.201605852.
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Li, Xinle, Zhang, Biying, Fang, Yuhui, Sun, Weijun, Qi, Zhiyuan, Pei, Yuchen, Qi, Shuyan, Yuan, Pengyu, Luan, Xuechen, Goh, Tian Wei, & Huang, Wenyu. Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis. United States. https://doi.org/10.1002/chem.201605852
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Li, Xinle, Zhang, Biying, Fang, Yuhui, Sun, Weijun, Qi, Zhiyuan, Pei, Yuchen, Qi, Shuyan, Yuan, Pengyu, Luan, Xuechen, Goh, Tian Wei, and Huang, Wenyu. Sat . "Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis". United States. https://doi.org/10.1002/chem.201605852. https://www.osti.gov/servlets/purl/1357787.
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@article{osti_1357787,
title = {Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis},
author = {Li, Xinle and Zhang, Biying and Fang, Yuhui and Sun, Weijun and Qi, Zhiyuan and Pei, Yuchen and Qi, Shuyan and Yuan, Pengyu and Luan, Xuechen and Goh, Tian Wei and Huang, Wenyu},
abstractNote = {Here, the facile pyrolysis of a bipyridyl metal-organic framework, MOF-253, produces N-doped porous carbons (Cz-MOF-253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen-containing MOF-derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz-MOF-253-supported Pd nanoparticles (Pd/Cz-MOF-253-800) show excellent performance in a one-pot sequential Knoevenagel condensation-hydrogenation reaction.},
doi = {10.1002/chem.201605852},
journal = {Chemistry - A European Journal},
number = 18,
volume = 23,
place = {United States},
year = {Sat Feb 11 00:00:00 EST 2017},
month = {Sat Feb 11 00:00:00 EST 2017}
}
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https://doi.org/10.1002/chem.201605852
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Works referenced in this record:

Palladium-loaded magnetic core–shell porous carbon nanospheres derived from a metal–organic framework as a recyclable catalyst
journal, January 2015

  • Bao, Chao; Zhou, Lincheng; Shao, Yanming
  • RSC Advances, Vol. 5, Issue 101
  • DOI: 10.1039/C5RA17971H

Nanocarbons for the Development of Advanced Catalysts
journal, May 2013

  • Su, Dang Sheng; Perathoner, Siglinda; Centi, Gabriele
  • Chemical Reviews, Vol. 113, Issue 8
  • DOI: 10.1021/cr300367d

Core–Shell Palladium Nanoparticle@Metal–Organic Frameworks as Multifunctional Catalysts for Cascade Reactions
journal, January 2014

  • Zhao, Meiting; Deng, Ke; He, Liangcan
  • Journal of the American Chemical Society, Vol. 136, Issue 5
  • DOI: 10.1021/ja411468e

Solid base catalysts for the synthesis of fine chemicals
journal, May 2003

Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
journal, October 2010

  • Bloch, Eric D.; Britt, David; Lee, Chain
  • Journal of the American Chemical Society, Vol. 132, Issue 41, p. 14382-14384
  • DOI: 10.1021/ja106935d

One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation
journal, January 2015

  • Yang, Qihao; Chen, Yu-Zhen; Wang, Zhiyong U.
  • Chemical Communications, Vol. 51, Issue 52
  • DOI: 10.1039/C5CC03102H

Development of MOF-Derived Carbon-Based Nanomaterials for Efficient Catalysis
journal, August 2016

Knoevenagel Condensation Reactions Catalysed by Metal-Organic Frameworks
journal, March 2013

Nitrogen-doped porous carbon materials: promising catalysts or catalyst supports for heterogeneous hydrogenation and oxidation
journal, January 2016

  • Li, Mingming; Xu, Fan; Li, Haoran
  • Catalysis Science & Technology, Vol. 6, Issue 11
  • DOI: 10.1039/C6CY00544F

Pd Nanocubes@ZIF-8: Integration of Plasmon-Driven Photothermal Conversion with a Metal-Organic Framework for Efficient and Selective Catalysis
journal, January 2016

  • Yang, Qihao; Xu, Qiang; Yu, Shu-Hong
  • Angewandte Chemie International Edition, Vol. 55, Issue 11
  • DOI: 10.1002/anie.201510655

Supercapacitors Prepared from Melamine-Based Carbon
journal, March 2005

  • Hulicova, Denisa; Yamashita, Junya; Soneda, Yasushi
  • Chemistry of Materials, Vol. 17, Issue 5
  • DOI: 10.1021/cm049337g

Synthesis of Monodisperse Palladium Nanoclusters Using Metal-Organic Frameworks as Sacrificial Templates
journal, June 2016

Mono-functionalization of porous aromatic frameworks to use as compatible heterogeneous catalysts in one-pot cascade reactions
journal, January 2014

Nitrogen-rich porous carbon derived from biomass as a high performance anode material for lithium ion batteries
journal, January 2015

  • Ou, Junke; Zhang, Yongzhi; Chen, Li
  • Journal of Materials Chemistry A, Vol. 3, Issue 12
  • DOI: 10.1039/C4TA06614F

Synthesis and Characterization of an Amino Functionalized MIL-101(Al): Separation and Catalytic Properties
journal, May 2011

  • Serra-Crespo, Pablo; Ramos-Fernandez, Enrique V.; Gascon, Jorge
  • Chemistry of Materials, Vol. 23, Issue 10
  • DOI: 10.1021/cm103644b

Heterogeneous Catalysis for Tandem Reactions
journal, January 2014

  • Climent, Maria J.; Corma, Avelino; Iborra, Sara
  • ACS Catalysis, Vol. 4, Issue 3
  • DOI: 10.1021/cs401052k

Rapid Synthesis of Nitrogen-Doped Porous Carbon Monolith for CO 2 Capture
journal, February 2010

CO2 cycloaddition of styrene oxide over MOF catalysts
journal, February 2013

Synthesis, structure, luminescence and catalytic properties of cadmium(ii) coordination polymers with 9H-carbazole-2,7-dicarboxylic acid
journal, January 2014

  • Yi, Xiu-Chun; Huang, Meng-Xuan; Qi, Yan
  • Dalton Transactions, Vol. 43, Issue 9
  • DOI: 10.1039/c3dt53109k

Pd(0)@UiO-68-AP: chelation-directed bifunctional heterogeneous catalyst for stepwise organic transformations
journal, January 2016

  • Li, Yan-An; Yang, Song; Liu, Qi-Kui
  • Chemical Communications, Vol. 52, Issue 39
  • DOI: 10.1039/C6CC01194B

Au@Cu(II)-MOF: Highly Efficient Bifunctional Heterogeneous Catalyst for Successive Oxidation–Condensation Reactions
journal, June 2016

Multimetal-MOF-derived transition metal alloy NPs embedded in an N-doped carbon matrix: highly active catalysts for hydrogenation reactions
journal, January 2016

  • Long, Jilan; Shen, Kui; Chen, Liang
  • Journal of Materials Chemistry A, Vol. 4, Issue 26
  • DOI: 10.1039/C6TA00157B

MOF-253-Pd(OAc) 2 : a recyclable MOF for transition-metal catalysis in water
journal, January 2016

  • Van Zeeland, Ryan; Li, Xinle; Huang, Wenyu
  • RSC Advances, Vol. 6, Issue 61
  • DOI: 10.1039/C6RA12746K

Template-Free One-Pot Synthesis of Porous Binary and Ternary Metal Nitride@N-Doped Carbon Composites from Ionic Liquids
journal, February 2012

  • Fechler, Nina; Fellinger, Tim-Patrick; Antonietti, Markus
  • Chemistry of Materials, Vol. 24, Issue 4
  • DOI: 10.1021/cm203667g

Synthesis of Structured Porous Polymers with Acid and Basic Sites and Their Catalytic Application in Cascade-Type Reactions
journal, March 2013

  • Merino, Estíbaliz; Verde-Sesto, Ester; Maya, Eva M.
  • Chemistry of Materials, Vol. 25, Issue 6, p. 981-988
  • DOI: 10.1021/cm400123d

Impact of Linker Engineering on the Catalytic Activity of Metal–Organic Frameworks Containing Pd(II)–Bipyridine Complexes
journal, August 2016

Mesoporous nitrogen-rich carbons derived from protein for ultra-high capacity battery anodes and supercapacitors
journal, January 2013

  • Li, Zhi; Xu, Zhanwei; Tan, Xuehai
  • Energy & Environmental Science, Vol. 6, Issue 3
  • DOI: 10.1039/c2ee23599d

From Bimetallic Metal-Organic Framework to Porous Carbon: High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis
journal, July 2015

  • Chen, Yu-Zhen; Wang, Chengming; Wu, Zhen-Yu
  • Advanced Materials, Vol. 27, Issue 34
  • DOI: 10.1002/adma.201502315

Tandem Catalysis by Palladium Nanoclusters Encapsulated in Metal–Organic Frameworks
journal, September 2014

  • Li, Xinle; Guo, Zhiyong; Xiao, Chaoxian
  • ACS Catalysis, Vol. 4, Issue 10
  • DOI: 10.1021/cs5006635

Postfunctionalized Porous Polymeric Aromatic Frameworks with an Organocatalyst and a Transition Metal Catalyst for Tandem Condensation–Hydrogenation Reactions
journal, December 2015

  • Verde-Sesto, Ester; Merino, Estíbaliz; Rangel-Rangel, Elizabeth
  • ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 3
  • DOI: 10.1021/acssuschemeng.5b01147

ZIF-Derived Nitrogen-Doped Porous Carbons for Xe Adsorption and Separation
journal, February 2016

  • Zhong, Shan; Wang, Qian; Cao, Dapeng
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep21295
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    Works referencing / citing this record:

    Insight into the epitaxial encapsulation of Pd catalysts in an oriented metalloporphyrin network thin film for tandem catalysis
    journal, January 2017

    • Vohra, M. Ismail; Li, De-Jing; Gu, Zhi-Gang
    • Nanoscale, Vol. 9, Issue 23
    • DOI: 10.1039/c7nr02284k

    Tandem catalysis induced by hollow PdO: highly efficient H 2 generation coupled with organic dye degradation via sodium formate reforming
    journal, January 2018

    • Zhu, Xiaohui; Du, Leilei; Guo, Ziwei
    • Catalysis Science & Technology, Vol. 8, Issue 23
    • DOI: 10.1039/c8cy01551a

    Amino-functionalized MOFs with high physicochemical stability for efficient gas storage/separation, dye adsorption and catalytic performance
    journal, January 2018

    • Fan, Weidong; Wang, Xia; Xu, Ben
    • Journal of Materials Chemistry A, Vol. 6, Issue 47
    • DOI: 10.1039/c8ta07839d

    Palladium NPs supported on sulfonic acid functionalized metal–organic frameworks as catalysts for biomass cascade reactions
    journal, January 2019

    • Zhang, Xibo; Chen, Luning; Li, Yongjian
    • Dalton Transactions, Vol. 48, Issue 17
    • DOI: 10.1039/c9dt00348g

    Al-based metal organic framework derived self-assembled carbon nanosheets as innovative anodes for Li- and Na-ion batteries
    journal, January 2020

    New and Advanced Porous Carbon Materials in Fine Chemical Synthesis. Emerging Precursors of Porous Carbons
    journal, February 2019

    • Pérez-Mayoral, Elena; Matos, Inês; Bernardo, Maria
    • Catalysts, Vol. 9, Issue 2
    • DOI: 10.3390/catal9020133

    Modification Effects of B2O3 on The Structure and Catalytic Activity of WO3-UiO-66 Catalyst
    journal, September 2018

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