skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process

Abstract

In this paper, we demonstrate a novel process to convert TiO2 nanotubes into ferroelectric nanohoneycombs, comprised of vertically aligned PbTiO3 nanotubes. Tube bottom opening process enabled effective infiltration of lead acetate precursor into the nanotubes. Finally, nanohoneycombs, which were converted via additional lead supplement process, showed uniform conversion and well-defined ferroelectric properties with the effective piezoelectric coefficient of approximately 20 pm/V, which was measured by piezoresponse force microscopy.

Authors:
 [1];  [2];  [1];  [1]
  1. Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of). Dept. of Materials Science and Engineering
  2. Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of). Dept. of Materials Science and Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States); Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of)
Sponsoring Org.:
USDOE Office of Science (SC); National Research Foundation (NRF) of Korea (Korea, Republic of)
OSTI Identifier:
1352671
Grant/Contract Number:  
AC02-06CH11357; 2010-0015063
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Ceramic Society
Additional Journal Information:
Journal Volume: 99; Journal Issue: 7; Journal ID: ISSN 0002-7820
Publisher:
American Ceramic Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; nanohoneycomb; lead supplement process; ferroelectricity/ferroelectric materials; lead titanate; nanomaterials; piezoelectric materials/properties

Citation Formats

Kim, Bongsoo, Hong, Seungbum, Ahn, Gun, and No, Kwangsoo. Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process. United States: N. p., 2016. Web. https://doi.org/10.1111/jace.14307.
Kim, Bongsoo, Hong, Seungbum, Ahn, Gun, & No, Kwangsoo. Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process. United States. https://doi.org/10.1111/jace.14307
Kim, Bongsoo, Hong, Seungbum, Ahn, Gun, and No, Kwangsoo. Sat . "Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process". United States. https://doi.org/10.1111/jace.14307. https://www.osti.gov/servlets/purl/1352671.
@article{osti_1352671,
title = {Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process},
author = {Kim, Bongsoo and Hong, Seungbum and Ahn, Gun and No, Kwangsoo},
abstractNote = {In this paper, we demonstrate a novel process to convert TiO2 nanotubes into ferroelectric nanohoneycombs, comprised of vertically aligned PbTiO3 nanotubes. Tube bottom opening process enabled effective infiltration of lead acetate precursor into the nanotubes. Finally, nanohoneycombs, which were converted via additional lead supplement process, showed uniform conversion and well-defined ferroelectric properties with the effective piezoelectric coefficient of approximately 20 pm/V, which was measured by piezoresponse force microscopy.},
doi = {10.1111/jace.14307},
journal = {Journal of the American Ceramic Society},
number = 7,
volume = 99,
place = {United States},
year = {2016},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Effect of Epitaxial Strain on the Spontaneous Polarization of Thin Film Ferroelectrics
journal, December 2005


Electric field-induced polarization rotation and ultrahigh piezoelectricity in PbTiO 3
journal, March 2014

  • Ma, Wenhui; Hao, Aize
  • Journal of Applied Physics, Vol. 115, Issue 10
  • DOI: 10.1063/1.4868320

Phase stability, solubility and hydrothermal crystal growth of PbTiO3
journal, February 1999


Ferroelectric PbTiO3 thin films and their application
journal, January 1991


Facile Preparation of PbTiO3 Nanodot Arrays: Combining Nanohybridization with Vapor Phase Reaction Sputtering
journal, September 2011

  • Kim, Jiyoon; Hong, Jongin; Park, Moonkyu
  • Advanced Functional Materials, Vol. 21, Issue 22
  • DOI: 10.1002/adfm.201101033

High-Resolution Field Effect Sensing of Ferroelectric Charges
journal, April 2011

  • Ko, Hyoungsoo; Ryu, Kyunghee; Park, Hongsik
  • Nano Letters, Vol. 11, Issue 4, p. 1428-1433
  • DOI: 10.1021/nl103372a

Scanning resistive probe microscopy: Imaging ferroelectric domains
journal, March 2004

  • Park, Hongsik; Jung, Juhwan; Min, Dong-Ki
  • Applied Physics Letters, Vol. 84, Issue 10
  • DOI: 10.1063/1.1667266

Terahertz Emission from Tubular Pb(Zr,Ti)O 3 Nanostructures
journal, December 2008

  • Scott, J. F.; Fan, H. J.; Kawasaki, S.
  • Nano Letters, Vol. 8, Issue 12
  • DOI: 10.1021/nl802277k

Inorganic Nanotubes
journal, September 2004


Inorganic nanowires
journal, January 2003


New Developments in Transmission Electron Microscopy for Nanotechnology
journal, September 2003


Nanorod-Superconductor Composites: A Pathway to Materials with High Critical Current Densities
journal, September 1996


Nanotube composites
journal, June 2007

  • Ajayan, Pulickel M.; Tour, James M.
  • Nature, Vol. 447, Issue 7148
  • DOI: 10.1038/4471066a

Fabrication of a Vertically Aligned Ferroelectric Perovskite Nanowire Array on Conducting Substrate
journal, August 2010

  • Im, Badro; Jun, Hwichan; Lee, Kyung Hee
  • Chemistry of Materials, Vol. 22, Issue 16
  • DOI: 10.1021/cm101412d

Synthesis and Growth Mechanism of Lead Titanate Nanotube Arrays by Hydrothermal Method
journal, October 2008


Ferroelectric PbTiO3 nanotube arrays synthesized by hydrothermal method
journal, March 2008

  • Yang, Yang; Wang, Xiaohui; Zhong, Caifu
  • Applied Physics Letters, Vol. 92, Issue 12
  • DOI: 10.1063/1.2903497

Fabrication and Characterization of Nanoscale Ferroelectric Honeycombs
journal, April 2013

  • Kim, Bongsoo; Hong, Seungbum; Choi, Hyunwoo
  • Journal of the American Ceramic Society, Vol. 96, Issue 5
  • DOI: 10.1111/jace.12352

Fabrication of open-ended high aspect-ratio anodic TiO2 nanotube films for photocatalytic and photoelectrocatalytic applications
journal, January 2008

  • Lin, Chin-Jung; Yu, Wen-Yueh; Lu, Yen-Tien
  • Chemical Communications, Issue 45
  • DOI: 10.1039/b813937g

3D Electrodes for Dye-Sensitized Solar Cells: Synthesis of ITO Nanowire Arrays Inside the TiO 2 Nanotubes
journal, October 2010

  • Hung, Pei-Ling; Wen, Ming-Hsien; Hung, Kai-Hsiang
  • Journal of the Chinese Chemical Society, Vol. 57, Issue 5B
  • DOI: 10.1002/jccs.201000166

Large scale free-standing open-ended TiO2 nanotube arrays: stress-induced self-detachment and in situ pore opening
journal, January 2013

  • Ouyang, Hao Miao; Fei, Guang Tao; Zhang, Yao
  • Journal of Materials Chemistry C, Vol. 1, Issue 45
  • DOI: 10.1039/c3tc31642d

Principle of ferroelectric domain imaging using atomic force microscope
journal, January 2001

  • Hong, Seungbum; Woo, Jungwon; Shin, Hyunjung
  • Journal of Applied Physics, Vol. 89, Issue 2, p. 1377-1386
  • DOI: 10.1063/1.1331654

Self-Assembled TiO 2 Nanotube Arrays with U-Shaped Profile by Controlling Anodization Temperature
journal, January 2010

  • Chen, Jingfei; Lin, Jia; Chen, Xianfeng
  • Journal of Nanomaterials, Vol. 2010
  • DOI: 10.1155/2010/753253

Piezoresponse force microscopy studies of PbTiO3 thin films grown via layer-by-layer gas phase reaction
journal, March 2009

  • Park, Moonkyu; Hong, Seungbum; Kim, Jiyoon
  • Applied Physics Letters, Vol. 94, Issue 9
  • DOI: 10.1063/1.3081120

    Works referencing / citing this record:

    Effects of NH4F and distilled water on structure of pores in TiO2 nanotube arrays
    journal, August 2018