Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process

Kim, Bongsoo; Hong, Seungbum; Ahn, Gun; No, Kwangsoo

doi:10.1111/jace.14307

Title: Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process

Journal Article · Sat May 14 04:00:00 UTC 2016 · Journal of the American Ceramic Society

DOI: https://doi.org/10.1111/jace.14307 · OSTI ID:1352671

Kim, Bongsoo ^[1]; Hong, Seungbum ^[2]; Ahn, Gun ^[1]; No, Kwangsoo ^[1]

Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of). Dept. of Materials Science and Engineering
Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of). Dept. of Materials Science and Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division

In this paper, we demonstrate a novel process to convert TiO₂ nanotubes into ferroelectric nanohoneycombs, comprised of vertically aligned PbTiO₃ nanotubes. Tube bottom opening process enabled effective infiltration of lead acetate precursor into the nanotubes. Finally, nanohoneycombs, which were converted via additional lead supplement process, showed uniform conversion and well-defined ferroelectric properties with the effective piezoelectric coefficient of approximately 20 pm/V, which was measured by piezoresponse force microscopy.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States); Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of)

Sponsoring Organization:: USDOE Office of Science (SC); National Research Foundation (NRF) of Korea (Korea, Republic of)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1352671

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 7 Vol. 99; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (24)

Facile Preparation of PbTiO3 Nanodot Arrays: Combining Nanohybridization with Vapor Phase Reaction Sputtering Kim, Jiyoon; Hong, Jongin; Park, Moonkyu Advanced Functional Materials, Vol. 21, Issue 22 https://doi.org/10.1002/adfm.201101033	journal	September 2011
New Developments in Transmission Electron Microscopy for Nanotechnology Wang, Z. L. Advanced Materials, Vol. 15, Issue 18 https://doi.org/10.1002/adma.200300384	journal	September 2003
Inorganic Nanotubes Remškar, M. Advanced Materials, Vol. 16, Issue 17 https://doi.org/10.1002/adma.200306428	journal	September 2004
3D Electrodes for Dye-Sensitized Solar Cells: Synthesis of ITO Nanowire Arrays Inside the TiO ₂ Nanotubes Hung, Pei-Ling; Wen, Ming-Hsien; Hung, Kai-Hsiang Journal of the Chinese Chemical Society, Vol. 57, Issue 5B https://doi.org/10.1002/jccs.201000166	journal	October 2010
Ferroelectric PbTiO3 thin films and their application Okuyama, M.; Hamakawa, Y. International Journal of Engineering Science, Vol. 29, Issue 3 https://doi.org/10.1016/0020-7225(91)90159-Z	journal	January 1991
Phase stability, solubility and hydrothermal crystal growth of PbTiO3 Gelabert, M. C.; Laudise, R. A.; Riman, R. E. Journal of Crystal Growth, Vol. 197, Issue 1-2 https://doi.org/10.1016/S0022-0248(98)00914-2	journal	February 1999
Inorganic nanowires Rao, C. N. R.; Deepak, F. L.; Gundiah, Gautam Progress in Solid State Chemistry, Vol. 31, Issue 1-2 https://doi.org/10.1016/j.progsolidstchem.2003.08.001	journal	January 2003
Fabrication of a Vertically Aligned Ferroelectric Perovskite Nanowire Array on Conducting Substrate Im, Badro; Jun, Hwichan; Lee, Kyung Hee Chemistry of Materials, Vol. 22, Issue 16 https://doi.org/10.1021/cm101412d	journal	August 2010
High-Resolution Field Effect Sensing of Ferroelectric Charges Ko, Hyoungsoo; Ryu, Kyunghee; Park, Hongsik Nano Letters, Vol. 11, Issue 4, p. 1428-1433 https://doi.org/10.1021/nl103372a	journal	April 2011
Terahertz Emission from Tubular Pb(Zr,Ti)O ₃ Nanostructures Scott, J. F.; Fan, H. J.; Kawasaki, S. Nano Letters, Vol. 8, Issue 12 https://doi.org/10.1021/nl802277k	journal	December 2008
Nanotube composites Ajayan, Pulickel M.; Tour, James M. Nature, Vol. 447, Issue 7148 https://doi.org/10.1038/4471066a	journal	June 2007
Fabrication of open-ended high aspect-ratio anodic TiO2 nanotube films for photocatalytic and photoelectrocatalytic applications Lin, Chin-Jung; Yu, Wen-Yueh; Lu, Yen-Tien Chemical Communications, Issue 45 https://doi.org/10.1039/b813937g	journal	January 2008
Large scale free-standing open-ended TiO2 nanotube arrays: stress-induced self-detachment and in situ pore opening Ouyang, Hao Miao; Fei, Guang Tao; Zhang, Yao Journal of Materials Chemistry C, Vol. 1, Issue 45 https://doi.org/10.1039/c3tc31642d	journal	January 2013
Principle of ferroelectric domain imaging using atomic force microscope Hong, Seungbum; Woo, Jungwon; Shin, Hyunjung Journal of Applied Physics, Vol. 89, Issue 2, p. 1377-1386 https://doi.org/10.1063/1.1331654	journal	January 2001
Scanning resistive probe microscopy: Imaging ferroelectric domains Park, Hongsik; Jung, Juhwan; Min, Dong-Ki Applied Physics Letters, Vol. 84, Issue 10 https://doi.org/10.1063/1.1667266	journal	March 2004
Ferroelectric PbTiO3 nanotube arrays synthesized by hydrothermal method Yang, Yang; Wang, Xiaohui; Zhong, Caifu Applied Physics Letters, Vol. 92, Issue 12 https://doi.org/10.1063/1.2903497	journal	March 2008
Piezoresponse force microscopy studies of PbTiO3 thin films grown via layer-by-layer gas phase reaction Park, Moonkyu; Hong, Seungbum; Kim, Jiyoon Applied Physics Letters, Vol. 94, Issue 9 https://doi.org/10.1063/1.3081120	journal	March 2009
Effect of deposition temperature of TiO2 on the piezoelectric property of PbTiO3 film grown by PbO gas phase reaction sputtering Bühlmann, Simon Journal of Applied Physics, Vol. 107, Issue 10 https://doi.org/10.1063/1.3406148	journal	May 2010
Electric field-induced polarization rotation and ultrahigh piezoelectricity in PbTiO ₃ Ma, Wenhui; Hao, Aize Journal of Applied Physics, Vol. 115, Issue 10 https://doi.org/10.1063/1.4868320	journal	March 2014
Effect of Epitaxial Strain on the Spontaneous Polarization of Thin Film Ferroelectrics Ederer, Claude; Spaldin, Nicola A. Physical Review Letters, Vol. 95, Issue 25 https://doi.org/10.1103/PhysRevLett.95.257601	journal	December 2005
Synthesis and Growth Mechanism of Lead Titanate Nanotube Arrays by Hydrothermal Method Yang, Yang; Wang, Xiaohui; Zhong, Caifu Journal of the American Ceramic Society, Vol. 91, Issue 10 https://doi.org/10.1111/j.1551-2916.2008.02535.x	journal	October 2008
Fabrication and Characterization of Nanoscale Ferroelectric Honeycombs Kim, Bongsoo; Hong, Seungbum; Choi, Hyunwoo Journal of the American Ceramic Society, Vol. 96, Issue 5 https://doi.org/10.1111/jace.12352	journal	April 2013
Nanorod-Superconductor Composites: A Pathway to Materials with High Critical Current Densities Yang, P.; Lieber, C. M. Science, Vol. 273, Issue 5283 https://doi.org/10.1126/science.273.5283.1836	journal	September 1996
Self-Assembled TiO ₂ Nanotube Arrays with U-Shaped Profile by Controlling Anodization Temperature Chen, Jingfei; Lin, Jia; Chen, Xianfeng Journal of Nanomaterials, Vol. 2010 https://doi.org/10.1155/2010/753253	journal	January 2010

Cited By (3)

Enhanced electrocaloric analysis and energy-storage performance of lanthanum modified lead titanate ceramics for potential solid-state refrigeration applications Zhang, Tian-Fu; Huang, Xian-Xiong; Tang, Xin-Gui Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-017-18810-z	journal	January 2018
Effects of NH4F and distilled water on structure of pores in TiO2 nanotube arrays Kim, Jaegyu; Kim, Bongsoo; Oh, Chungik Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-30668-3	journal	August 2018
Effects of NH4F and distilled water on structure of pores in TiO2 nanotube arrays Kim, Jaegyu; Kim, Bongsoo; Oh, Chungik Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-30668-3	journal	August 2018

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36 MATERIALS SCIENCE
ferroelectricity/ferroelectric materials
lead supplement process
lead titanate
nanohoneycomb
nanomaterials
piezoelectric materials/properties

Title: Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process

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