Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process
Abstract
In this paper, we demonstrate a novel process to convert TiO2 nanotubes into ferroelectric nanohoneycombs, comprised of vertically aligned PbTiO3 nanotubes. Tube bottom opening process enabled effective infiltration of lead acetate precursor into the nanotubes. Finally, nanohoneycombs, which were converted via additional lead supplement process, showed uniform conversion and well-defined ferroelectric properties with the effective piezoelectric coefficient of approximately 20 pm/V, which was measured by piezoresponse force microscopy.
- Authors:
-
- Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of). Dept. of Materials Science and Engineering
- Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of). Dept. of Materials Science and Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Research Foundation (NRF) of Korea (Korea, Republic of)
- OSTI Identifier:
- 1352671
- Grant/Contract Number:
- AC02-06CH11357; 2010-0015063
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Ceramic Society
- Additional Journal Information:
- Journal Volume: 99; Journal Issue: 7; Journal ID: ISSN 0002-7820
- Publisher:
- American Ceramic Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; nanohoneycomb; lead supplement process; ferroelectricity/ferroelectric materials; lead titanate; nanomaterials; piezoelectric materials/properties
Citation Formats
Kim, Bongsoo, Hong, Seungbum, Ahn, Gun, and No, Kwangsoo. Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process. United States: N. p., 2016.
Web. doi:10.1111/jace.14307.
Kim, Bongsoo, Hong, Seungbum, Ahn, Gun, & No, Kwangsoo. Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process. United States. https://doi.org/10.1111/jace.14307
Kim, Bongsoo, Hong, Seungbum, Ahn, Gun, and No, Kwangsoo. Sat .
"Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process". United States. https://doi.org/10.1111/jace.14307. https://www.osti.gov/servlets/purl/1352671.
@article{osti_1352671,
title = {Synthesis of Ferroelectric Lead Titanate Nanohoneycomb Arrays via Lead Supplement Process},
author = {Kim, Bongsoo and Hong, Seungbum and Ahn, Gun and No, Kwangsoo},
abstractNote = {In this paper, we demonstrate a novel process to convert TiO2 nanotubes into ferroelectric nanohoneycombs, comprised of vertically aligned PbTiO3 nanotubes. Tube bottom opening process enabled effective infiltration of lead acetate precursor into the nanotubes. Finally, nanohoneycombs, which were converted via additional lead supplement process, showed uniform conversion and well-defined ferroelectric properties with the effective piezoelectric coefficient of approximately 20 pm/V, which was measured by piezoresponse force microscopy.},
doi = {10.1111/jace.14307},
journal = {Journal of the American Ceramic Society},
number = 7,
volume = 99,
place = {United States},
year = {Sat May 14 00:00:00 EDT 2016},
month = {Sat May 14 00:00:00 EDT 2016}
}
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Works referenced in this record:
Effect of Epitaxial Strain on the Spontaneous Polarization of Thin Film Ferroelectrics
journal, December 2005
- Ederer, Claude; Spaldin, Nicola A.
- Physical Review Letters, Vol. 95, Issue 25
Electric field-induced polarization rotation and ultrahigh piezoelectricity in PbTiO 3
journal, March 2014
- Ma, Wenhui; Hao, Aize
- Journal of Applied Physics, Vol. 115, Issue 10
Phase stability, solubility and hydrothermal crystal growth of PbTiO3
journal, February 1999
- Gelabert, M. C.; Laudise, R. A.; Riman, R. E.
- Journal of Crystal Growth, Vol. 197, Issue 1-2
Ferroelectric PbTiO3 thin films and their application
journal, January 1991
- Okuyama, M.; Hamakawa, Y.
- International Journal of Engineering Science, Vol. 29, Issue 3
Facile Preparation of PbTiO3 Nanodot Arrays: Combining Nanohybridization with Vapor Phase Reaction Sputtering
journal, September 2011
- Kim, Jiyoon; Hong, Jongin; Park, Moonkyu
- Advanced Functional Materials, Vol. 21, Issue 22
High-Resolution Field Effect Sensing of Ferroelectric Charges
journal, April 2011
- Ko, Hyoungsoo; Ryu, Kyunghee; Park, Hongsik
- Nano Letters, Vol. 11, Issue 4, p. 1428-1433
Scanning resistive probe microscopy: Imaging ferroelectric domains
journal, March 2004
- Park, Hongsik; Jung, Juhwan; Min, Dong-Ki
- Applied Physics Letters, Vol. 84, Issue 10
Terahertz Emission from Tubular Pb(Zr,Ti)O 3 Nanostructures
journal, December 2008
- Scott, J. F.; Fan, H. J.; Kawasaki, S.
- Nano Letters, Vol. 8, Issue 12
Inorganic nanowires
journal, January 2003
- Rao, C. N. R.; Deepak, F. L.; Gundiah, Gautam
- Progress in Solid State Chemistry, Vol. 31, Issue 1-2
New Developments in Transmission Electron Microscopy for Nanotechnology
journal, September 2003
- Wang, Z. L.
- Advanced Materials, Vol. 15, Issue 18
Nanorod-Superconductor Composites: A Pathway to Materials with High Critical Current Densities
journal, September 1996
- Yang, P.; Lieber, C. M.
- Science, Vol. 273, Issue 5283
Nanotube composites
journal, June 2007
- Ajayan, Pulickel M.; Tour, James M.
- Nature, Vol. 447, Issue 7148
Fabrication of a Vertically Aligned Ferroelectric Perovskite Nanowire Array on Conducting Substrate
journal, August 2010
- Im, Badro; Jun, Hwichan; Lee, Kyung Hee
- Chemistry of Materials, Vol. 22, Issue 16
Synthesis and Growth Mechanism of Lead Titanate Nanotube Arrays by Hydrothermal Method
journal, October 2008
- Yang, Yang; Wang, Xiaohui; Zhong, Caifu
- Journal of the American Ceramic Society, Vol. 91, Issue 10
Ferroelectric PbTiO3 nanotube arrays synthesized by hydrothermal method
journal, March 2008
- Yang, Yang; Wang, Xiaohui; Zhong, Caifu
- Applied Physics Letters, Vol. 92, Issue 12
Fabrication and Characterization of Nanoscale Ferroelectric Honeycombs
journal, April 2013
- Kim, Bongsoo; Hong, Seungbum; Choi, Hyunwoo
- Journal of the American Ceramic Society, Vol. 96, Issue 5
Fabrication of open-ended high aspect-ratio anodic TiO2 nanotube films for photocatalytic and photoelectrocatalytic applications
journal, January 2008
- Lin, Chin-Jung; Yu, Wen-Yueh; Lu, Yen-Tien
- Chemical Communications, Issue 45
3D Electrodes for Dye-Sensitized Solar Cells: Synthesis of ITO Nanowire Arrays Inside the TiO 2 Nanotubes
journal, October 2010
- Hung, Pei-Ling; Wen, Ming-Hsien; Hung, Kai-Hsiang
- Journal of the Chinese Chemical Society, Vol. 57, Issue 5B
Large scale free-standing open-ended TiO2 nanotube arrays: stress-induced self-detachment and in situ pore opening
journal, January 2013
- Ouyang, Hao Miao; Fei, Guang Tao; Zhang, Yao
- Journal of Materials Chemistry C, Vol. 1, Issue 45
Effect of deposition temperature of TiO2 on the piezoelectric property of PbTiO3 film grown by PbO gas phase reaction sputtering
journal, May 2010
- Bühlmann, Simon
- Journal of Applied Physics, Vol. 107, Issue 10
Principle of ferroelectric domain imaging using atomic force microscope
journal, January 2001
- Hong, Seungbum; Woo, Jungwon; Shin, Hyunjung
- Journal of Applied Physics, Vol. 89, Issue 2, p. 1377-1386
Self-Assembled TiO 2 Nanotube Arrays with U-Shaped Profile by Controlling Anodization Temperature
journal, January 2010
- Chen, Jingfei; Lin, Jia; Chen, Xianfeng
- Journal of Nanomaterials, Vol. 2010
Piezoresponse force microscopy studies of PbTiO3 thin films grown via layer-by-layer gas phase reaction
journal, March 2009
- Park, Moonkyu; Hong, Seungbum; Kim, Jiyoon
- Applied Physics Letters, Vol. 94, Issue 9
Works referencing / citing this record:
Effects of NH4F and distilled water on structure of pores in TiO2 nanotube arrays
journal, August 2018
- Kim, Jaegyu; Kim, Bongsoo; Oh, Chungik
- Scientific Reports, Vol. 8, Issue 1
Enhanced electrocaloric analysis and energy-storage performance of lanthanum modified lead titanate ceramics for potential solid-state refrigeration applications
journal, January 2018
- Zhang, Tian-Fu; Huang, Xian-Xiong; Tang, Xin-Gui
- Scientific Reports, Vol. 8, Issue 1
Effects of NH4F and distilled water on structure of pores in TiO2 nanotube arrays
journal, August 2018
- Kim, Jaegyu; Kim, Bongsoo; Oh, Chungik
- Scientific Reports, Vol. 8, Issue 1