Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage
Abstract
Aqueous electrochemical energy storage devices have attracted significant attention owing to their high safety, low cost and environmental friendliness. However, their applications have been limited by a narrow potential window (1/41.23 V), beyond which the hydrogen and oxygen evolution reactions occur. Here we report the formation of layered Mn 5 O 8 pseudocapacitor electrode material with a well-ordered hydroxylated interphase. A symmetric full cell using such electrodes demonstrates a stable potential window of 3.0 V in an aqueous electrolyte, as well as high energy and power performance, nearly 100% coulombic efficiency and 85% energy efficiency after 25,000 charge-discharge cycles. The interplay between hydroxylated interphase on the surface and the unique bivalence structure of Mn 5 O 8 suppresses the gas evolution reactions, offers a two-electron charge transfer via Mn 2+ /Mn 4+ redox couple, and provides facile pathway for Na-ion transport via intra-/inter-layer defects of Mn 5 O 8.
- Authors:
-
[3];
[5];
[1]
- Univ. of New Hampshire, Durham, NH (United States)
- Univ. of Pittsburgh, PA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Univ. of New Hampshire, Durham, NH (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1594578
- Alternate Identifier(s):
- OSTI ID: 1328373; OSTI ID: 1337640; OSTI ID: 1377589
- Report Number(s):
- BNL-112679-2016-JA; BNL-113277-2016-JA
Journal ID: ISSN 2041-1723
- Grant/Contract Number:
- SC0010286; SC00112704; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Mn5O8; aqueous sodium-ion storage; Center for Functional Nanomaterials; 29 ENERGY PLANNING, POLICY, AND ECONOMY; Mn5O8
Citation Formats
Shan, Xiaoqiang, Charles, Daniel S., Lei, Yinkai, Qiao, Ruimin, Wang, Guofeng, Yang, Wanli, Feygenson, Mikhail, Su, Dong, and Teng, Xiaowei. Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage. United States: N. p., 2016.
Web. doi:10.1038/ncomms13370.
Shan, Xiaoqiang, Charles, Daniel S., Lei, Yinkai, Qiao, Ruimin, Wang, Guofeng, Yang, Wanli, Feygenson, Mikhail, Su, Dong, & Teng, Xiaowei. Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage. United States. https://doi.org/10.1038/ncomms13370
Shan, Xiaoqiang, Charles, Daniel S., Lei, Yinkai, Qiao, Ruimin, Wang, Guofeng, Yang, Wanli, Feygenson, Mikhail, Su, Dong, and Teng, Xiaowei. Tue .
"Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage". United States. https://doi.org/10.1038/ncomms13370. https://www.osti.gov/servlets/purl/1594578.
@article{osti_1594578,
title = {Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage},
author = {Shan, Xiaoqiang and Charles, Daniel S. and Lei, Yinkai and Qiao, Ruimin and Wang, Guofeng and Yang, Wanli and Feygenson, Mikhail and Su, Dong and Teng, Xiaowei},
abstractNote = {Aqueous electrochemical energy storage devices have attracted significant attention owing to their high safety, low cost and environmental friendliness. However, their applications have been limited by a narrow potential window (1/41.23 V), beyond which the hydrogen and oxygen evolution reactions occur. Here we report the formation of layered Mn 5 O 8 pseudocapacitor electrode material with a well-ordered hydroxylated interphase. A symmetric full cell using such electrodes demonstrates a stable potential window of 3.0 V in an aqueous electrolyte, as well as high energy and power performance, nearly 100% coulombic efficiency and 85% energy efficiency after 25,000 charge-discharge cycles. The interplay between hydroxylated interphase on the surface and the unique bivalence structure of Mn 5 O 8 suppresses the gas evolution reactions, offers a two-electron charge transfer via Mn 2+ /Mn 4+ redox couple, and provides facile pathway for Na-ion transport via intra-/inter-layer defects of Mn 5 O 8.},
doi = {10.1038/ncomms13370},
journal = {Nature Communications},
number = 1,
volume = 7,
place = {United States},
year = {Tue Nov 15 00:00:00 EST 2016},
month = {Tue Nov 15 00:00:00 EST 2016}
}
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