Using Perovskite Nanoparticles as Halide Reservoirs in Catalysis and as Spectrochemical Probes of Ions in Solution
Abstract
The ability of cesium lead halide (CsPbX3; X = Cl–, Br–, I–) perovskite nanoparticles (P-NPs) to participate in halide exchange reactions, to catalyze Finkelstein organohalide substitution reactions, and to colorimetrically monitor chemical reactions and detect anions in real time is described. With the use of tetraoctylammonium halide salts as a starting point, halide exchange with the P-NPs was performed to calibrate reactivity, stability, and extent of ion exchange. Also, the exchange of CsPbI3 with Cl– or Br– causes a significant blue-shift in absorption and photoluminescence, whereas reacting I– with CsPbBr3 causes a red-shift of similar magnitudes. With the high local halide concentrations and the facile nature of halide exchange in mind, we then explored the ability of P-NPs to catalyze organohalide exchange in Finkelstein like reactions. Results indicate that the P-NPs serve as excellent halide reservoirs for substitution of organohalides in nonpolar media, leading to not only different organohalide products, but also a complementary color change over the course of the reaction, which can be used to monitor kinetics in a precise manner. Finally, the merits of using P-NP as spectrochemical probes for real time assaying is then expanded to other anions which can react with, or result in unique,more »
- Authors:
-
- Syracuse Univ., NY (United States). Department of Chemistry
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1336037
- Report Number(s):
- BNL-112191-2016-JA
Journal ID: ISSN 1936-0851; KC0403020
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 6; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; anion exchange; chemical assay; colorimetric; CsPbX3; Finkelstein; lead halide; nano; perovskite; spectrochemical
Citation Formats
Doane, Tennyson L., Ryan, Kayla L., Pathade, Laxmikant, Cruz, Kevin J., Zang, Huidong, Cotlet, Mircea, and Maye, Mathew M. Using Perovskite Nanoparticles as Halide Reservoirs in Catalysis and as Spectrochemical Probes of Ions in Solution. United States: N. p., 2016.
Web. doi:10.1021/acsnano.6b00806.
Doane, Tennyson L., Ryan, Kayla L., Pathade, Laxmikant, Cruz, Kevin J., Zang, Huidong, Cotlet, Mircea, & Maye, Mathew M. Using Perovskite Nanoparticles as Halide Reservoirs in Catalysis and as Spectrochemical Probes of Ions in Solution. United States. https://doi.org/10.1021/acsnano.6b00806
Doane, Tennyson L., Ryan, Kayla L., Pathade, Laxmikant, Cruz, Kevin J., Zang, Huidong, Cotlet, Mircea, and Maye, Mathew M. Thu .
"Using Perovskite Nanoparticles as Halide Reservoirs in Catalysis and as Spectrochemical Probes of Ions in Solution". United States. https://doi.org/10.1021/acsnano.6b00806. https://www.osti.gov/servlets/purl/1336037.
@article{osti_1336037,
title = {Using Perovskite Nanoparticles as Halide Reservoirs in Catalysis and as Spectrochemical Probes of Ions in Solution},
author = {Doane, Tennyson L. and Ryan, Kayla L. and Pathade, Laxmikant and Cruz, Kevin J. and Zang, Huidong and Cotlet, Mircea and Maye, Mathew M.},
abstractNote = {The ability of cesium lead halide (CsPbX3; X = Cl–, Br–, I–) perovskite nanoparticles (P-NPs) to participate in halide exchange reactions, to catalyze Finkelstein organohalide substitution reactions, and to colorimetrically monitor chemical reactions and detect anions in real time is described. With the use of tetraoctylammonium halide salts as a starting point, halide exchange with the P-NPs was performed to calibrate reactivity, stability, and extent of ion exchange. Also, the exchange of CsPbI3 with Cl– or Br– causes a significant blue-shift in absorption and photoluminescence, whereas reacting I– with CsPbBr3 causes a red-shift of similar magnitudes. With the high local halide concentrations and the facile nature of halide exchange in mind, we then explored the ability of P-NPs to catalyze organohalide exchange in Finkelstein like reactions. Results indicate that the P-NPs serve as excellent halide reservoirs for substitution of organohalides in nonpolar media, leading to not only different organohalide products, but also a complementary color change over the course of the reaction, which can be used to monitor kinetics in a precise manner. Finally, the merits of using P-NP as spectrochemical probes for real time assaying is then expanded to other anions which can react with, or result in unique, classes of perovskites.},
doi = {10.1021/acsnano.6b00806},
journal = {ACS Nano},
number = 6,
volume = 10,
place = {United States},
year = {Thu May 05 00:00:00 EDT 2016},
month = {Thu May 05 00:00:00 EDT 2016}
}
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