Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]

Abstract

In this paper, the experimental results from long-term solubility experiments on micro crystalline neodymium hydroxide, Nd(OH)3(micro cr), in high ionic strength solutions at 298.15 K under well-constrained conditions are presented. The starting material was synthesized according to a well-established method in the literature. In contrast with the previous studies in which hydrogen ion concentrations in experiments were adjusted with addition of either an acid or a base, the hydrogen ion concentrations in our experiments are controlled by the dissolution of Nd(OH)3(micro cr), avoiding the possibility of phase change.

Authors:
 [1];  [1];  [1]
+ Show Author Affiliations
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Carlsbad Programs Group
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1324611
Report Number(s):
SAND2016-5527J
Journal ID: ISSN 1380-6165; 641757
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Aquatic Geochemistry
Additional Journal Information:
Journal Volume: 23; Journal Issue: 5-6; Journal ID: ISSN 1380-6165
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Xiong, Yongliang, Kirkes, Leslie Dawn, and Marrs, Cassandra. Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]. United States: N. p., 2017. Web. doi:10.1007/s10498-017-9326-6.
Copy to clipboard
Xiong, Yongliang, Kirkes, Leslie Dawn, & Marrs, Cassandra. Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]. United States. https://doi.org/10.1007/s10498-017-9326-6
Copy to clipboard
Xiong, Yongliang, Kirkes, Leslie Dawn, and Marrs, Cassandra. Fri . "Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]". United States. https://doi.org/10.1007/s10498-017-9326-6. https://www.osti.gov/servlets/purl/1324611.
Copy to clipboard
@article{osti_1324611,
title = {Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]},
author = {Xiong, Yongliang and Kirkes, Leslie Dawn and Marrs, Cassandra},
abstractNote = {In this paper, the experimental results from long-term solubility experiments on micro crystalline neodymium hydroxide, Nd(OH)3(micro cr), in high ionic strength solutions at 298.15 K under well-constrained conditions are presented. The starting material was synthesized according to a well-established method in the literature. In contrast with the previous studies in which hydrogen ion concentrations in experiments were adjusted with addition of either an acid or a base, the hydrogen ion concentrations in our experiments are controlled by the dissolution of Nd(OH)3(micro cr), avoiding the possibility of phase change.},
doi = {10.1007/s10498-017-9326-6},
journal = {Aquatic Geochemistry},
number = 5-6,
volume = 23,
place = {United States},
year = {2017},
month = {12}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1007/s10498-017-9326-6
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Interaction of Nd( iii ) and Cm( iii ) with borate in dilute to concentrated alkaline NaCl, MgCl 2 and CaCl 2 solutions: solubility and TRLFS studies
journal, January 2015

  • Hinz, Katja; Altmaier, Marcus; Gaona, Xavier
  • New Journal of Chemistry, Vol. 39, Issue 2
  • DOI: 10.1039/C4NJ01203H

Thermodynamics of trivalent actinides and neodymium in NaCl, MgCl2, and CaCl2 solutions: Solubility, hydrolysis, and ternary Ca-M(III)-OH complexes
journal, August 2009

  • Neck, Volker; Altmaier, Marcus; Rabung, Thomas
  • Pure and Applied Chemistry, Vol. 81, Issue 9
  • DOI: 10.1351/PAC-CON-08-09-05

The aqueous geochemistry of Zr and the solubility of some Zr-bearing minerals
journal, November 1995

New modification procedure of zinc powder in neodymium nitrate solution for improving the electrochemical properties of alkaline zinc electrodes
journal, January 2009

  • Zhu, Liqun; Zhang, Hui; Li, Weiping
  • Journal of Physics and Chemistry of Solids, Vol. 70, Issue 1
  • DOI: 10.1016/j.jpcs.2008.09.005

Actinide speciation in the environment
journal, June 2007

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Effects of lanthanum and neodymium hydroxides on secondary alkaline zinc electrode
journal, November 1997

Coupled modeling of cement/claystone interactions and radionuclide migration
journal, February 2004

Experimental determination of lead carbonate solubility at high ionic strengths: a Pitzer model description
journal, May 2015

Modeling of Near Field Actinide Concentrations in Radioactive Waste Repositories in Salt Formations: Effect of Buffer Materials
journal, January 2000

Neodymium conversion layers formed on zinc powder for improving electrochemical properties of zinc electrodes
journal, October 2008

Nd(III) Hydrolysis Constants and Solubilities of Nd(III) Hydroxide.
journal, January 1993

Geochemical and isotopic evidence for a genetic link between Canadian Shield brines, dolomitization in the Western Canada Sedimentary Basin, and Devonian calcium-chloridic seawater
journal, November 2005

  • Bottomley, Dennis J.; Clark, Ian D.; Battye, Nicholas
  • Canadian Journal of Earth Sciences, Vol. 42, Issue 11
  • DOI: 10.1139/e05-075

Effect of neodymium on microstructure and corrosion resistance of AZ91 magnesium alloy
journal, February 2007

    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: