Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]
Abstract
In this paper, the experimental results from long-term solubility experiments on micro crystalline neodymium hydroxide, Nd(OH)3(micro cr), in high ionic strength solutions at 298.15 K under well-constrained conditions are presented. The starting material was synthesized according to a well-established method in the literature. In contrast with the previous studies in which hydrogen ion concentrations in experiments were adjusted with addition of either an acid or a base, the hydrogen ion concentrations in our experiments are controlled by the dissolution of Nd(OH)3(micro cr), avoiding the possibility of phase change.
- Authors:
-
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Carlsbad Programs Group
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1324611
- Report Number(s):
- SAND2016-5527J
Journal ID: ISSN 1380-6165; 641757
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Aquatic Geochemistry
- Additional Journal Information:
- Journal Volume: 23; Journal Issue: 5-6; Journal ID: ISSN 1380-6165
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Xiong, Yongliang, Kirkes, Leslie Dawn, and Marrs, Cassandra. Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]. United States: N. p., 2017.
Web. doi:10.1007/s10498-017-9326-6.
Xiong, Yongliang, Kirkes, Leslie Dawn, & Marrs, Cassandra. Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]. United States. https://doi.org/10.1007/s10498-017-9326-6
Xiong, Yongliang, Kirkes, Leslie Dawn, and Marrs, Cassandra. Fri .
"Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]". United States. https://doi.org/10.1007/s10498-017-9326-6. https://www.osti.gov/servlets/purl/1324611.
@article{osti_1324611,
title = {Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]},
author = {Xiong, Yongliang and Kirkes, Leslie Dawn and Marrs, Cassandra},
abstractNote = {In this paper, the experimental results from long-term solubility experiments on micro crystalline neodymium hydroxide, Nd(OH)3(micro cr), in high ionic strength solutions at 298.15 K under well-constrained conditions are presented. The starting material was synthesized according to a well-established method in the literature. In contrast with the previous studies in which hydrogen ion concentrations in experiments were adjusted with addition of either an acid or a base, the hydrogen ion concentrations in our experiments are controlled by the dissolution of Nd(OH)3(micro cr), avoiding the possibility of phase change.},
doi = {10.1007/s10498-017-9326-6},
journal = {Aquatic Geochemistry},
number = 5-6,
volume = 23,
place = {United States},
year = {Fri Dec 01 00:00:00 EST 2017},
month = {Fri Dec 01 00:00:00 EST 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 3 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Interaction of Nd( iii ) and Cm( iii ) with borate in dilute to concentrated alkaline NaCl, MgCl 2 and CaCl 2 solutions: solubility and TRLFS studies
journal, January 2015
- Hinz, Katja; Altmaier, Marcus; Gaona, Xavier
- New Journal of Chemistry, Vol. 39, Issue 2
Thermodynamics of trivalent actinides and neodymium in NaCl, MgCl2, and CaCl2 solutions: Solubility, hydrolysis, and ternary Ca-M(III)-OH complexes
journal, August 2009
- Neck, Volker; Altmaier, Marcus; Rabung, Thomas
- Pure and Applied Chemistry, Vol. 81, Issue 9
An Aqueous Thermodynamic Model for the Solubility of Potassium Ferrate in Alkaline Solutions to High Ionic Strengths from 283.15 to 333.15 K
journal, July 2013
- Xiong, Yongliang
- Journal of Solution Chemistry, Vol. 42, Issue 7
The aqueous geochemistry of Zr and the solubility of some Zr-bearing minerals
journal, November 1995
- Aja, Stephen U.; Wood, Scott A.; Williams-Jones, Anthony E.
- Applied Geochemistry, Vol. 10, Issue 6
Solubilities and Speciation of Selected Transuranium Ions. A Comparison of a Non-Complexing Solution with a Groundwater from the Nevada Tuff Site
journal, January 1985
- Nitsche, Heino; Edelstein, Norman M.
- Radiochimica Acta, Vol. 39, Issue 1
New modification procedure of zinc powder in neodymium nitrate solution for improving the electrochemical properties of alkaline zinc electrodes
journal, January 2009
- Zhu, Liqun; Zhang, Hui; Li, Weiping
- Journal of Physics and Chemistry of Solids, Vol. 70, Issue 1
Actinide speciation in the environment
journal, June 2007
- Choppin, G. R.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 273, Issue 3
Experimental determination of solubilities of sodium tetraborate (borax) in NaCl solutions, and a thermodynamic model for the Na-B(OH)3-Cl-SO4 system to high-ionic strengths at 25 C
journal, November 2013
- Xiong, Y.; Kirkes, L.; Westfall, T.
- American Mineralogist, Vol. 98, Issue 11-12
A thermodynamic model for silica and aluminum in alkaline solutions with high ionic strength at elevated temperatures up to 100 C: Applications to zeolites
journal, December 2012
- Xiong, Y.
- American Mineralogist, Vol. 98, Issue 1
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Effects of lanthanum and neodymium hydroxides on secondary alkaline zinc electrode
journal, November 1997
- Ji-Iing Zhu,
- Journal of Power Sources, Vol. 69, Issue 1-2
Coupled modeling of cement/claystone interactions and radionuclide migration
journal, February 2004
- De Windt, L.; Pellegrini, D.; van der Lee, J.
- Journal of Contaminant Hydrology, Vol. 68, Issue 3-4
Experimental determination of lead carbonate solubility at high ionic strengths: a Pitzer model description
journal, May 2015
- Xiong, Yongliang
- Monatshefte für Chemie - Chemical Monthly, Vol. 146, Issue 9
Modeling of Near Field Actinide Concentrations in Radioactive Waste Repositories in Salt Formations: Effect of Buffer Materials
journal, January 2000
- Schuessler, W.; Kienzler, B.; Wilhelm, S.
- MRS Proceedings, Vol. 663
Experimental determination of the solubility constant for magnesium chloride hydroxide hydrate (Mg3Cl(OH)5·4H2O, phase 5) at room temperature, and its importance to nuclear waste isolation in geological repositories in salt formations
journal, August 2010
- Xiong, Yongliang; Deng, Haoran; Nemer, Martin
- Geochimica et Cosmochimica Acta, Vol. 74, Issue 16
Neodymium conversion layers formed on zinc powder for improving electrochemical properties of zinc electrodes
journal, October 2008
- Zhu, Liqun; Zhang, Hui; Li, Weiping
- Materials Chemistry and Physics, Vol. 111, Issue 2-3
Nd(III) Hydrolysis Constants and Solubilities of Nd(III) Hydroxide.
journal, January 1993
- Makino, Hitoshi; Yajima, Tatsuya; Yoshikawa, Hideki
- NIPPON KAGAKU KAISHI, Issue 5
Thermodynamic Properties of Brucite Determined by Solubility Studies and Their Significance to Nuclear Waste Isolation
journal, July 2008
- Xiong, Yongliang
- Aquatic Geochemistry, Vol. 14, Issue 3
Experimental determination of solubilities of lead oxalate (PbC2O4(cr)) in a NaCl medium to high ionic strengths, and the importance of lead oxalate in low temperature environments
journal, March 2013
- Xiong, Yongliang; Kirkes, Leslie; Westfall, Terry
- Chemical Geology, Vol. 342
A Pitzer model for the Na–Al(OH)4–Cl–OH system and solubility of boehmite (AlOOH) to high ionic strength and to 250°C
journal, May 2014
- Xiong, Yongliang
- Chemical Geology, Vol. 373
Geochemical and isotopic evidence for a genetic link between Canadian Shield brines, dolomitization in the Western Canada Sedimentary Basin, and Devonian calcium-chloridic seawater
journal, November 2005
- Bottomley, Dennis J.; Clark, Ian D.; Battye, Nicholas
- Canadian Journal of Earth Sciences, Vol. 42, Issue 11
Experimental investigations of the reaction path in the MgO–CO2–H2O system in solutions with various ionic strengths, and their applications to nuclear waste isolation
journal, June 2008
- Xiong, Yongliang; Lord, Anna Snider
- Applied Geochemistry, Vol. 23, Issue 6
Effect of neodymium on microstructure and corrosion resistance of AZ91 magnesium alloy
journal, February 2007
- Song, Y. L.; Liu, Yao Hui; Yu, S. R.
- Journal of Materials Science, Vol. 42, Issue 12