Water electrolysis on La1-xSrxCoO3-δ perovskite electrocatalysts
Abstract
Perovskite oxides are attractive candidates as catalysts for the electrolysis of water in alkaline energy storage and conversion systems. However, the rational design of active catalysts has been hampered by the lack of understanding of the mechanism of water electrolysis on perovskite surfaces. Key parameters that have been overlooked include the role of oxygen vacancies, B–O bond covalency, and redox activity of lattice oxygen species. In this paper, we present a series of cobaltite perovskites where the covalency of the Co–O bond and the concentration of oxygen vacancies are controlled through Sr2+ substitution into La1-xSrxCoO3-δ. In addition, we attempt to rationalize the high activities of La1-xSrxCoO3-δ through the electronic structure and participation of lattice oxygen in the mechanism of water electrolysis as revealed through ab initio modelling. Using this approach, we report a material, SrCoO2.7, with a high, room temperature-specific activity and mass activity towards alkaline water electrolysis.
- Authors:
-
- Univ. of Texas at Austin, Austin, TX (United States)
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Skolkovo Institute of Science and Technology, Moscow (Russia); Univ. of Antwerp, Antwerp (Belgium)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Texas at Austin, Austin, TX (United States); Skolkovo Institute of Science and Technology, Moscow (Russia)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1261341
- Alternate Identifier(s):
- OSTI ID: 1324110
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 7; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Mefford, J. Tyler, Rong, Xi, Abakumov, Artem M., Hardin, William G., Dai, Sheng, Kolpak, Alexie, Johnston, Keith P., and Stevenson, Keith J. Water electrolysis on La1-xSrxCoO3-δ perovskite electrocatalysts. United States: N. p., 2016.
Web. doi:10.1038/ncomms11053.
Mefford, J. Tyler, Rong, Xi, Abakumov, Artem M., Hardin, William G., Dai, Sheng, Kolpak, Alexie, Johnston, Keith P., & Stevenson, Keith J. Water electrolysis on La1-xSrxCoO3-δ perovskite electrocatalysts. United States. https://doi.org/10.1038/ncomms11053
Mefford, J. Tyler, Rong, Xi, Abakumov, Artem M., Hardin, William G., Dai, Sheng, Kolpak, Alexie, Johnston, Keith P., and Stevenson, Keith J. Wed .
"Water electrolysis on La1-xSrxCoO3-δ perovskite electrocatalysts". United States. https://doi.org/10.1038/ncomms11053. https://www.osti.gov/servlets/purl/1261341.
@article{osti_1261341,
title = {Water electrolysis on La1-xSrxCoO3-δ perovskite electrocatalysts},
author = {Mefford, J. Tyler and Rong, Xi and Abakumov, Artem M. and Hardin, William G. and Dai, Sheng and Kolpak, Alexie and Johnston, Keith P. and Stevenson, Keith J.},
abstractNote = {Perovskite oxides are attractive candidates as catalysts for the electrolysis of water in alkaline energy storage and conversion systems. However, the rational design of active catalysts has been hampered by the lack of understanding of the mechanism of water electrolysis on perovskite surfaces. Key parameters that have been overlooked include the role of oxygen vacancies, B–O bond covalency, and redox activity of lattice oxygen species. In this paper, we present a series of cobaltite perovskites where the covalency of the Co–O bond and the concentration of oxygen vacancies are controlled through Sr2+ substitution into La1-xSrxCoO3-δ. In addition, we attempt to rationalize the high activities of La1-xSrxCoO3-δ through the electronic structure and participation of lattice oxygen in the mechanism of water electrolysis as revealed through ab initio modelling. Using this approach, we report a material, SrCoO2.7, with a high, room temperature-specific activity and mass activity towards alkaline water electrolysis.},
doi = {10.1038/ncomms11053},
journal = {Nature Communications},
number = ,
volume = 7,
place = {United States},
year = {Wed Mar 23 00:00:00 EDT 2016},
month = {Wed Mar 23 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013
- Sathiya, M.; Rousse, G.; Ramesha, K.
- Nature Materials, Vol. 12, Issue 9
Catalytically Active Oxygen Species in La 1 - x Sr x CoO 3 - δ Studied by XPS and XAFS Spectroscopy
journal, August 2000
- Imamura, M.; Matsubayashi, N.; Shimada, H.
- The Journal of Physical Chemistry B, Vol. 104, Issue 31
Time-Resolved in Situ Studies of Oxygen Intercalation into SrCoO2.5, Performed by Neutron Diffraction and X-ray Absorption Spectroscopy
journal, October 2006
- Le Toquin, Ronan; Paulus, Werner; Cousson, Alain
- Journal of the American Chemical Society, Vol. 128, Issue 40, p. 13161-13174
An electrochemical method for the determination of oxygen ion diffusion coefficients in La1−xSrxCoO3−y compounds
journal, March 1978
- Van Buren, F. R.; Broers, G. H. J.; Bouman, A. J.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 87, Issue 3
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation
journal, October 2010
- Gorlin, Yelena; Jaramillo, Thomas F.
- Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614
Reversible redox reactions in an epitaxially stabilized SrCoOx oxygen sponge
journal, August 2013
- Jeen, Hyoungjeen; Choi, Woo Seok; Biegalski, Michael D.
- Nature Materials, Vol. 12, Issue 11
Highly Active, Nonprecious Metal Perovskite Electrocatalysts for Bifunctional Metal–Air Battery Electrodes
journal, March 2013
- Hardin, William G.; Slanac, Daniel A.; Wang, Xiqing
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 8
Mechanism of oxygen evolution on perovskites
journal, July 1983
- Bockris, John O'M.; Otagawa, Takaaki
- The Journal of Physical Chemistry, Vol. 87, Issue 15
The Electrocatalysis of Oxygen Evolution on Perovskites
journal, January 1984
- Bockris, John O'M.
- Journal of The Electrochemical Society, Vol. 131, Issue 2
Effects of strain, d -band filling, and oxidation state on the surface electronic structure and reactivity of 3 d perovskite surfaces
journal, August 2012
- Akhade, Sneha A.; Kitchin, John R.
- The Journal of Chemical Physics, Vol. 137, Issue 8
Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution
journal, September 2013
- Grimaud, Alexis; May, Kevin J.; Carlton, Christopher E.
- Nature Communications, Vol. 4, Issue 1
Structural and Thermal Properties of La 1- x Sr x CoO 3- δ
journal, December 2006
- Mastin, Johann; Einarsrud, Mari-Ann; Grande, Tor
- Chemistry of Materials, Vol. 18, Issue 25
Highly Stable and Active Pt−Cu Oxygen Reduction Electrocatalysts Based on Mesoporous Graphitic Carbon Supports
journal, October 2009
- Gupta, Gaurav; Slanac, Daniel A.; Kumar, Pavan
- Chemistry of Materials, Vol. 21, Issue 19
Correlation between the structure and the spin state in ( , Pr, and Nd)
journal, October 2007
- Takami, T.; Zhou, J. -S.; Goodenough, J. B.
- Physical Review B, Vol. 76, Issue 14
Oxygen Evolution Activity and Stability of Ba 6 Mn 5 O 16 , Sr 4 Mn 2 CoO 9 , and Sr 6 Co 5 O 15 : The Influence of Transition Metal Coordination
journal, November 2013
- Grimaud, Alexis; Carlton, Christopher E.; Risch, Marcel
- The Journal of Physical Chemistry C, Vol. 117, Issue 49
Oxygen content determination in perovskite-type cobaltates
journal, February 2005
- Conder, K.; Pomjakushina, E.; Soldatov, A.
- Materials Research Bulletin, Vol. 40, Issue 2
The electrochemical determination of oxygen ion diffusion coefficients in La0.50Sr0.50CoO3−y
journal, April 1978
- Van Buren, F. R.; Broers, G. H. J.; Bouman, A. J.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 88, Issue 3
Covalency Criterion for Localized vs Collective Electrons in Oxides with the Perovskite Structure
journal, March 1966
- Goodenough, John B.
- Journal of Applied Physics, Vol. 37, Issue 3
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
journal, June 2010
- Dau, Holger; Limberg, Christian; Reier, Tobias
- ChemCatChem, Vol. 2, Issue 7
Oxygen mobility in LaCoO3 perovskites
journal, March 2006
- Royer, S.; Duprez, D.; Kaliaguine, S.
- Catalysis Today, Vol. 112, Issue 1-4
Ammonia-Treated Ordered Mesoporous Carbons as Catalytic Materials for Oxygen Reduction Reaction
journal, April 2010
- Wang, Xiqing; Lee, Je Seung; Zhu, Qing
- Chemistry of Materials, Vol. 22, Issue 7
The Synthesis and Properties of the Chemically Oxidized Perovskite, La1–xSrxCoO3−δ(0.5≤x≤0.9)
journal, September 1998
- Sunstrom, Joseph E.; Ramanujachary, K. V.; Greenblatt, Martha
- Journal of Solid State Chemistry, Vol. 139, Issue 2
Synthesis and characterization of Sr0.75Y0.25Co1−xMxO2.625+δ (M=Ga, 0.125⩽x⩽0.500 and M=Fe, 0.125⩽x⩽0.875)
journal, May 2006
- Lindberg, F.; Drozhzhin, O. A.; Istomin, S. Ya.
- Journal of Solid State Chemistry, Vol. 179, Issue 5
Evidence for orbital ordering in
journal, June 2003
- Maris, G.; Ren, Y.; Volotchaev, V.
- Physical Review B, Vol. 67, Issue 22
Atomic Ensemble and Electronic Effects in Ag-Rich AgPd Nanoalloy Catalysts for Oxygen Reduction in Alkaline Media
journal, May 2012
- Slanac, Daniel A.; Hardin, William G.; Johnston, Keith P.
- Journal of the American Chemical Society, Vol. 134, Issue 23
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles
journal, October 2011
- Suntivich, J.; May, K. J.; Gasteiger, H. A.
- Science, Vol. 334, Issue 6061
Orthorhombic superstructures within the rare earth strontium-doped cobaltate perovskites: Ln1−xSrxCoO3−δ (Ln=Y3+, Dy3+–Yb3+; 0.750⩽x⩽0.875)
journal, August 2007
- James, Michael; Avdeev, Maxim; Barnes, Paris
- Journal of Solid State Chemistry, Vol. 180, Issue 8
Topotactic Phase Transformation of the Brownmillerite SrCoO 2.5 to the Perovskite SrCoO 3- δ
journal, July 2013
- Jeen, H.; Choi, W. S.; Freeland, J. W.
- Advanced Materials, Vol. 25, Issue 27
Low-cost Oxygen Electrode Material
journal, May 1970
- Meadowcroft, D. B.
- Nature, Vol. 226, Issue 5248
Influence of the nature of the conduction band of transition metal oxides on catalytic activity for oxygen reduction
journal, October 1977
- Matsumoto, Y.; Yoneyama, H.; Tamura, H.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 83, Issue 2
A Potentiostatic Pulse Study of Oxygen Evolution on Teflon-Bonded Nickel-Cobalt Oxide Electrodes
journal, January 1979
- Jasem, S. M.
- Journal of The Electrochemical Society, Vol. 126, Issue 8
Chemical Structures and Performance of Perovskite Oxides
journal, July 2001
- Pena, M.; Fierro, J.
- Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
journal, March 2011
- Man, Isabela C.; Su, Hai‐Yan; Calle‐Vallejo, Federico
- ChemCatChem, Vol. 3, Issue 7
Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions
journal, May 2014
- Maiyalagan, Thandavarayan; Jarvis, Karalee A.; Therese, Soosairaj
- Nature Communications, Vol. 5, Issue 1
Tuning the Electrocatalytic Activity of Perovskites through Active Site Variation and Support Interactions
journal, June 2014
- Hardin, William G.; Mefford, J. Tyler; Slanac, Daniel A.
- Chemistry of Materials, Vol. 26, Issue 11
Phase relation and oxygen-non-stoichiometry of Perovskite-like Compound SrCoOx (2.29 < x > 2.80)
journal, September 1986
- Takeda, Y.; Kanno, R.; Takada, T.
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 540, Issue 9-10
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
The influence of the particle size distribution on the measurement of oxygen ion diffusion coefficients in La0.50Sr0.50CoO3−y
journal, August 1978
- Kobussen, A. G. C.; van Buren, F. R.; Broers, G. H. J.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 91, Issue 2
Dynamic potential–pH diagrams application to electrocatalysts for wateroxidation
journal, January 2012
- Minguzzi, Alessandro; Fan, Fu-Ren F.; Vertova, Alberto
- Chem. Sci., Vol. 3, Issue 1
Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals
journal, March 1999
- Hammer, B.; Hansen, L. B.; Nørskov, J. K.
- Physical Review B, Vol. 59, Issue 11
Electrochemical topotactic oxidation of nonstoichiometric perovskites at ambient temperature
journal, April 2002
- Nemudry, A.; Goldberg, E. L.; Aguirre, M.
- Solid State Sciences, Vol. 4, Issue 5
Redox activity of surface oxygen anions in oxygen-deficient perovskite oxides during electrochemical reactions
journal, January 2015
- Mueller, David N.; Machala, Michael L.; Bluhm, Hendrik
- Nature Communications, Vol. 6, Issue 1
Properties ofSrMO 3-?(M=Fe, Co) as oxygen electrodes in alkaline solution
journal, May 1982
- Takeda, Y.; Kanno, R.; Kondo, T.
- Journal of Applied Electrochemistry, Vol. 12, Issue 3
Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis
journal, June 2013
- Cui, Chunhua; Gan, Lin; Heggen, Marc
- Nature Materials, Vol. 12, Issue 8
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013
- McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 135, Issue 45
Topotactic Electrochemical Redox Reactions of the Defect Perovskite SrCoO2.5+x
September 1996
- Nemudry, A.; Rudolf, P.; Schollhorn, R.
- Chemistry of Materials, Vol. 8, Issue 9, p. 2232-2238
Electrochemical Behavior of the Perovskite-Type Nd[sub 1−x]Sr[sub x]CoO[sub 3] in an Aqueous Alkaline Solution
journal, January 1975
- Kudo, Tetsuichi
- Journal of The Electrochemical Society, Vol. 122, Issue 2
Electrocatalytic properties of transition metal oxides for oxygen evolution reaction
journal, May 1986
- Matsumoto, Y.; Sato, E.
- Materials Chemistry and Physics, Vol. 14, Issue 5, p. 397-426
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
journal, January 2015
- Hong, Wesley T.; Risch, Marcel; Stoerzinger, Kelsey A.
- Energy & Environmental Science, Vol. 8, Issue 5
Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries
journal, June 2011
- Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki
- Nature Chemistry, Vol. 3, Issue 7, p. 546-550
Ab initio energetics of ( , Fe, Co, and Ni) for solid oxide fuel cell cathodes
journal, December 2009
- Lee, Yueh-Lin; Kleis, Jesper; Rossmeisl, Jan
- Physical Review B, Vol. 80, Issue 22
Correlation between the Structural Distortions and Thermoelectric Characteristics in La 1− x A x CoO 3 (A = Ca and Sr)
journal, April 2010
- Wang, Yang; Sui, Yu; Ren, Peng
- Inorganic Chemistry, Vol. 49, Issue 7
Atomic ordering in the doped rare earth cobaltates Ln0.33Sr0.67CoO3−δ (Ln=Y3+, Ho3+ and Dy3+)
journal, August 2003
- Withers, R. L.; James, M.; Goossens, D. J.
- Journal of Solid State Chemistry, Vol. 174, Issue 1
Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodes
journal, June 2014
- Mefford, J. Tyler; Hardin, William G.; Dai, Sheng
- Nature Materials, Vol. 13, Issue 7
A Fundamental Relationship between Reaction Mechanism and Stability in Metal Oxide Catalysts for Oxygen Evolution
journal, January 2016
- Rong, Xi; Parolin, Jules; Kolpak, Alexie M.
- ACS Catalysis, Vol. 6, Issue 2
Electrolytic Oxygen Evolution in Alkaline Medium on La[sub 1−x]Sr[sub x]FeO[sub 3−y] Perovskite-Related Ferrites
journal, January 1987
- Wattiaux, A.
- Journal of The Electrochemical Society, Vol. 134, Issue 7
Probing oxygen vacancy concentration and homogeneity in solid-oxide fuel-cell cathode materials on the subunit-cell level
journal, August 2012
- Kim, Young-Min; He, Jun; Biegalski, Michael D.
- Nature Materials, Vol. 11, Issue 10
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020
- Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna
- Scientific Reports, Vol. 10, Issue 1
Highly Active, Nonprecious Metal Perovskite Electrocatalysts for Bifunctional Metal-Air Battery Electrodes
journal, October 2013
- Stevenson, Keith J.; Hardin, William G.; Mefford, J. Tyler
- ECS Meeting Abstracts, Vol. MA2013-02, Issue 4, p. 233-233
Topotactic Phase Transformation of the Brownmillerite SrCoO 2.5 to the Perovskite SrCoO 3- δ
journal, July 2013
- Jeen, H.; Choi, W. S.; Freeland, J. W.
- Advanced Materials, Vol. 25, Issue 27
A Fundamental Relationship between Reaction Mechanism and Stability in Metal Oxide Catalysts for Oxygen Evolution
journal, January 2016
- Rong, Xi; Parolin, Jules; Kolpak, Alexie M.
- ACS Catalysis, Vol. 6, Issue 2
Chemical Structures and Performance of Perovskite Oxides
journal, July 2001
- Pena, M.; Fierro, J.
- Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018
Correlation between the Structural Distortions and Thermoelectric Characteristics in La 1− x A x CoO 3 (A = Ca and Sr)
journal, April 2010
- Wang, Yang; Sui, Yu; Ren, Peng
- Inorganic Chemistry, Vol. 49, Issue 7
Mechanism of oxygen evolution on perovskites
journal, July 1983
- Bockris, John O'M.; Otagawa, Takaaki
- The Journal of Physical Chemistry, Vol. 87, Issue 15
Time-Resolved in Situ Studies of Oxygen Intercalation into SrCoO2.5, Performed by Neutron Diffraction and X-ray Absorption Spectroscopy
journal, October 2006
- Le Toquin, Ronan; Paulus, Werner; Cousson, Alain
- Journal of the American Chemical Society, Vol. 128, Issue 40, p. 13161-13174
Atomic Ensemble and Electronic Effects in Ag-Rich AgPd Nanoalloy Catalysts for Oxygen Reduction in Alkaline Media
journal, May 2012
- Slanac, Daniel A.; Hardin, William G.; Johnston, Keith P.
- Journal of the American Chemical Society, Vol. 134, Issue 23
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013
- McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 135, Issue 45
Highly Active, Nonprecious Metal Perovskite Electrocatalysts for Bifunctional Metal–Air Battery Electrodes
journal, March 2013
- Hardin, William G.; Slanac, Daniel A.; Wang, Xiqing
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 8
Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries
journal, June 2011
- Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki
- Nature Chemistry, Vol. 3, Issue 7, p. 546-550
Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions
journal, May 2014
- Maiyalagan, Thandavarayan; Jarvis, Karalee A.; Therese, Soosairaj
- Nature Communications, Vol. 5, Issue 1
Probing oxygen vacancy concentration and homogeneity in solid-oxide fuel-cell cathode materials on the subunit-cell level
journal, August 2012
- Kim, Young-Min; He, Jun; Biegalski, Michael D.
- Nature Materials, Vol. 11, Issue 10
Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis
journal, June 2013
- Cui, Chunhua; Gan, Lin; Heggen, Marc
- Nature Materials, Vol. 12, Issue 8
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013
- Sathiya, M.; Rousse, G.; Ramesha, K.
- Nature Materials, Vol. 12, Issue 9
Effects of strain, d -band filling, and oxidation state on the surface electronic structure and reactivity of 3 d perovskite surfaces
journal, August 2012
- Akhade, Sneha A.; Kitchin, John R.
- The Journal of Chemical Physics, Vol. 137, Issue 8
Crystallographic Computing System JANA2006: General features
journal, January 2014
- Petříček, Václav; Dušek, Michal; Palatinus, Lukáš
- Zeitschrift für Kristallographie - Crystalline Materials, Vol. 229, Issue 5
Reversible redox reactions in an epitaxially stabilized SrCoOx oxygen sponge
text, January 2013
- Jeen, Hyoungjeen; Choi, Woo Seok; Biegalski, Michael D.
- arXiv
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journal, September 2017
- An, Li; Li, Yuxuan; Luo, Mingchuan
- Advanced Functional Materials, Vol. 27, Issue 42
Improving the Activity for Oxygen Evolution Reaction by Tailoring Oxygen Defects in Double Perovskite Oxides
journal, June 2019
- Zhu, Yunmin; Zhang, Lei; Zhao, Bote
- Advanced Functional Materials, Vol. 29, Issue 34
Enhanced Electrocatalytic Oxygen Evolution Activity by Tuning Both the Oxygen Vacancy and Orbital Occupancy of B‐Site Metal Cation in NdNiO 3
journal, June 2019
- Hu, Chang; Wang, Xianjie; Yao, Tai
- Advanced Functional Materials, Vol. 29, Issue 30
Efficient Optimization of Electron/Oxygen Pathway by Constructing Ceria/Hydroxide Interface for Highly Active Oxygen Evolution Reaction
journal, December 2019
- Xia, Jiale; Zhao, Hongyang; Huang, Bolong
- Advanced Functional Materials, Vol. 30, Issue 9
Amorphous Cobalt Phyllosilicate with Layered Crystalline Motifs as Water Oxidation Catalyst
journal, March 2017
- Kim, Ju Seong; Park, Inchul; Jeong, Eun-Suk
- Advanced Materials, Vol. 29, Issue 21
Enlarged CoO Covalency in Octahedral Sites Leading to Highly Efficient Spinel Oxides for Oxygen Evolution Reaction
journal, June 2018
- Zhou, Ye; Sun, Shengnan; Song, Jiajia
- Advanced Materials, Vol. 30, Issue 32
Nanoscale Topotactic Phase Transformation in SrFeO x Epitaxial Thin Films for High‐Density Resistive Switching Memory
journal, October 2019
- Tian, Junjiang; Wu, Haijun; Fan, Zhen
- Advanced Materials, Vol. 31, Issue 49
Photoinduced Defect Engineering: Enhanced Photothermal Catalytic Performance of 2D Black In 2 O 3− x Nanosheets with Bifunctional Oxygen Vacancies
journal, December 2019
- Qi, Yuhang; Song, Lizhu; Ouyang, Shuxin
- Advanced Materials, Vol. 32, Issue 6
Earth-Abundant Silicon for Facilitating Water Oxidation over Iron-Based Perovskite Electrocatalyst
journal, February 2018
- Xu, Xiaomin; Chen, Yubo; Zhou, Wei
- Advanced Materials Interfaces, Vol. 5, Issue 11
An Efficient Family of Misfit‐Layered Calcium Cobalt Oxide Catalyst for Oxygen Evolution Reaction
journal, August 2018
- Lin, Xiao; Bao, Hongliang; Zheng, Dehua
- Advanced Materials Interfaces, Vol. 5, Issue 23
Uncovering the Effect of Lattice Strain and Oxygen Deficiency on Electrocatalytic Activity of Perovskite Cobaltite Thin Films
journal, January 2019
- Liu, Xi; Zhang, Lei; Zheng, Yun
- Advanced Science, Vol. 6, Issue 6
Janus Co/CoP Nanoparticles as Efficient Mott-Schottky Electrocatalysts for Overall Water Splitting in Wide pH Range
journal, February 2017
- Xue, Zhong-Hua; Su, Hui; Yu, Qiu-Ying
- Advanced Energy Materials, Vol. 7, Issue 12
Highly Defective Layered Double Perovskite Oxide for Efficient Energy Storage via Reversible Pseudocapacitive Oxygen-Anion Intercalation
journal, January 2018
- Liu, Yu; Wang, Zhenbin; Veder, Jean-Pierre Marcel
- Advanced Energy Materials, Vol. 8, Issue 11
Symmetry-Broken Atom Configurations at Grain Boundaries and Oxygen Evolution Electrocatalysis in Perovskite Oxides
journal, October 2018
- Heo, Yoon; Choi, Seungkyu; Bak, Jumi
- Advanced Energy Materials, Vol. 8, Issue 34
Shifting Oxygen Charge Towards Octahedral Metal: A Way to Promote Water Oxidation on Cobalt Spinel Oxides
journal, April 2019
- Sun, Shengnan; Sun, Yuanmiao; Zhou, Ye
- Angewandte Chemie, Vol. 131, Issue 18
A Porous Pyrochlore Y 2 [Ru 1.6 Y 0.4 ]O 7– δ Electrocatalyst for Enhanced Performance towards the Oxygen Evolution Reaction in Acidic Media
journal, October 2018
- Kim, Jaemin; Shih, Pei‐Chieh; Qin, Yao
- Angewandte Chemie International Edition, Vol. 57, Issue 42
A Dissolution/Precipitation Equilibrium on the Surface of Iridium‐Based Perovskites Controls Their Activity as Oxygen Evolution Reaction Catalysts in Acidic Media
journal, February 2019
- Zhang, Ronghuan; Dubouis, Nicolas; Ben Osman, Manel
- Angewandte Chemie International Edition, Vol. 58, Issue 14
B-Site Cation Ordered Double Perovskites as Efficient and Stable Electrocatalysts for Oxygen Evolution Reaction
journal, March 2017
- Sun, Hainan; Chen, Gao; Zhu, Yinlong
- Chemistry - A European Journal, Vol. 23, Issue 24
Amorphous Cobalt Iron Borate Grown on Carbon Paper as a Precatalyst for Water Oxidation
journal, July 2019
- Liu, Huibing; Yang, Liu; Qiao, Kangwei
- ChemSusChem
Smart Control of Composition for Double Perovskite Electrocatalysts toward Enhanced Oxygen Evolution Reaction
journal, October 2019
- Sun, Hainan; Xu, Xiaomin; Chen, Gao
- ChemSusChem, Vol. 12, Issue 23
Nanoscopic Combination of Edge and Flat Planes in the Active Site for Oxygen Reduction and Evolution: Nanoscopic Combination of Edge and Flat Planes in the Active Site for Oxygen Reduction and Evolution
journal, October 2019
- Maruyama, Jun; Maruyama, Shohei; Fukuhara, Tomoko
- European Journal of Inorganic Chemistry, Vol. 2019, Issue 38
Recent Studies on Bifunctional Perovskite Electrocatalysts in Oxygen Evolution, Oxygen Reduction, and Hydrogen Evolution Reactions under Alkaline Electrolyte
journal, May 2019
- Ramakrishnan, Prakash; Im, Hyunsik; Baek, Seong‐Ho
- Israel Journal of Chemistry, Vol. 59, Issue 8
Sol‐Gel Preparation of Perovskite Oxides Using Ethylene Glycol and Alcohol Mixture as Complexant and Its Catalytic Performances for CO Oxidation
journal, November 2018
- Wang, Shan; Zhang, Yibo; Zhu, Junjiang
- ChemistrySelect, Vol. 3, Issue 43
First-Row Transition Metal Based Catalysts for the Oxygen Evolution Reaction under Alkaline Conditions: Basic Principles and Recent Advances
journal, September 2017
- Lu, Fei; Zhou, Min; Zhou, Yuxue
- Small, Vol. 13, Issue 45
Nickel@Nitrogen-Doped Carbon@MoS 2 Nanosheets: An Efficient Electrocatalyst for Hydrogen Evolution Reaction
journal, January 2019
- Shah, Sayyar Ali; Shen, Xiaoping; Xie, Minghua
- Small, Vol. 15, Issue 9
Super‐Exchange Interaction Induced Overall Optimization in Ferromagnetic Perovskite Oxides Enables Ultrafast Water Oxidation
journal, August 2019
- Dai, Jie; Zhu, Yinlong; Yin, Yichun
- Small, Vol. 15, Issue 39
Recent Advances in Novel Nanostructuring Methods of Perovskite Electrocatalysts for Energy-Related Applications
journal, May 2018
- Xu, Xiaomin; Wang, Wei; Zhou, Wei
- Small Methods, Vol. 2, Issue 7
A New Defect-Rich CoGa Layered Double Hydroxide as Efficient and Stable Oxygen Evolution Electrocatalyst
journal, September 2018
- Zhang, Jie; Dong, Chaoqun; Wang, Zhenbin
- Small Methods, Vol. 3, Issue 2
Speciation and Electronic Structure of La1−xSrxCoO3−δ During Oxygen Electrolysis
journal, October 2018
- Stoerzinger, Kelsey A.; Renshaw Wang, Xiao; Hwang, Jonathan
- Topics in Catalysis, Vol. 61, Issue 20
Transition metal oxides for water oxidation: All about oxyhydroxides?
journal, September 2019
- Xu, Zhichuan J.
- Science China Materials, Vol. 63, Issue 1
A tailored double perovskite nanofiber catalyst enables ultrafast oxygen evolution
journal, February 2017
- Zhao, Bote; Zhang, Lei; Zhen, Dongxing
- Nature Communications, Vol. 8, Issue 1
Dynamic surface self-reconstruction is the key of highly active perovskite nano-electrocatalysts for water splitting
journal, July 2017
- Fabbri, Emiliana; Nachtegaal, Maarten; Binninger, Tobias
- Nature Materials, Vol. 16, Issue 9
Regulating p-block metals in perovskite nanodots for efficient electrocatalytic water oxidation
journal, October 2017
- Li, Bo-Quan; Xia, Zi-Jing; Zhang, Bingsen
- Nature Communications, Vol. 8, Issue 1
Exceptionally active iridium evolved from a pseudo-cubic perovskite for oxygen evolution in acid
journal, February 2019
- Chen, Yubo; Li, Haiyan; Wang, Jingxian
- Nature Communications, Vol. 10, Issue 1
Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
journal, June 2019
- Bak, Jumi; Bin Bae, Hyung; Chung, Sung-Yoon
- Nature Communications, Vol. 10, Issue 1
Electronic-reconstruction-enhanced hydrogen evolution catalysis in oxide polymorphs
journal, July 2019
- Li, Yangyang; Yu, Zhi Gen; Wang, Ling
- Nature Communications, Vol. 10, Issue 1
Iron-facilitated dynamic active-site generation on spinel CoAl2O4 with self-termination of surface reconstruction for water oxidation
journal, August 2019
- Wu, Tianze; Sun, Shengnan; Song, Jiajia
- Nature Catalysis, Vol. 2, Issue 9
Crystal structure and surface characteristics of Sr-doped GdBaCo 2 O 6−δ double perovskites: oxygen evolution reaction and conductivity
journal, January 2018
- Pramana, Stevin S.; Cavallaro, Andrea; Li, Cheng
- Journal of Materials Chemistry A, Vol. 6, Issue 13
Transition metal oxide-based oxygen reduction reaction electrocatalysts for energy conversion systems with aqueous electrolytes
journal, January 2018
- Xue, Yejian; Sun, Shanshan; Wang, Qin
- Journal of Materials Chemistry A, Vol. 6, Issue 23
Ferromagnetic ligand holes in cobalt perovskite electrocatalysts as an essential factor for high activity towards oxygen evolution
journal, January 2019
- Zhang, Ling; Cheruvathur, Ajin; Biz, Chiara
- Physical Chemistry Chemical Physics, Vol. 21, Issue 6
Monitoring surface transformations of metal carbodiimide water oxidation catalysts by operando XAS and Raman spectroscopy
journal, January 2018
- Müller, Rafael J.; Lan, Jinggang; Lienau, Karla
- Dalton Transactions, Vol. 47, Issue 31
Optimization of iron-doped Ni 3 S 2 nanosheets by disorder engineering for oxygen evolution reaction
journal, January 2019
- Zhu, Yan; Yang, Haidong; Lan, Kai
- Nanoscale, Vol. 11, Issue 5
A metal-vacancy-solid-solution NiAlP nanowall array bifunctional electrocatalyst for exceptional all-pH overall water splitting
journal, January 2018
- Cheng, Weiren; Zhang, Hui; Zhao, Xu
- Journal of Materials Chemistry A, Vol. 6, Issue 20
Ultrahigh-performance tungsten-doped perovskites for the oxygen evolution reaction
journal, January 2018
- Chen, Gao; Hu, Zhiwei; Zhu, Yanping
- Journal of Materials Chemistry A, Vol. 6, Issue 21
Anionic defect engineering of transition metal oxides for oxygen reduction and evolution reactions
journal, January 2019
- Zhu, Yunmin; Liu, Xi; Jin, Shiguang
- Journal of Materials Chemistry A, Vol. 7, Issue 11
Tunable pH-dependent oxygen evolution activity of strontium cobaltite thin films for electrochemical water splitting
journal, January 2019
- Shi, Yanuo; Xie, Renjie; Liu, Xuetao
- Physical Chemistry Chemical Physics, Vol. 21, Issue 29
Enhancing oxygen and hydrogen evolution activities of perovskite oxide LaCoO 3 via effective doping of platinum
journal, January 2019
- Wang, Caiyun; Zeng, Lirong; Guo, Wei
- RSC Advances, Vol. 9, Issue 61
Nanoporous gold supported chromium-doped NiFe oxyhydroxides as high-performance catalysts for the oxygen evolution reaction
journal, January 2019
- Sun, Jie-Song; Zhou, Yi-Tong; Yao, Rui-Qi
- Journal of Materials Chemistry A, Vol. 7, Issue 16
Boosting the oxygen evolution reaction activity of a perovskite through introducing multi-element synergy and building an ordered structure
journal, January 2019
- Sun, Hainan; Xu, Xiaomin; Hu, Zhiwei
- Journal of Materials Chemistry A, Vol. 7, Issue 16
Bismuth ferrite: an abnormal perovskite with electrochemical extraction of ions from A site
journal, January 2019
- Ma, Chao-Jie; Chen, Ya; Zhu, Cheng
- Journal of Materials Chemistry A, Vol. 7, Issue 19
Morphology, crystal structure and electronic state one-step co-tuning strategy towards developing superior perovskite electrocatalysts for water oxidation
journal, January 2019
- Zhang, Haijuan; Guan, Daqin; Gao, Xuechao
- Journal of Materials Chemistry A, Vol. 7, Issue 33
Interfacial coupling-induced distinct magnetic structure in La 1/2 Sr 1/2 CoO 2.5+δ /La 2/3 Sr 1/3 MnO 3 / La 1/2 Sr 1/2 CoO 2.5+δ heterostructure
journal, March 2019
- Zhang, Jine; Wang, Wei; Zhang, Jing
- AIP Advances, Vol. 9, Issue 3
Short O–O separation in layered oxide Na 0.67 CoO 2 enables an ultrafast oxygen evolution reaction
journal, November 2019
- Wang, Hao; Wu, Jinpeng; Dolocan, Andrei
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 47
Topotactic transition between perovskite and brownmillerite phases for epitaxial LaCoO 3− δ films and effects thus resulted
journal, February 2020
- Huang, Hailin; Zhang, Jine; Zhang, Hui
- Journal of Physics D: Applied Physics, Vol. 53, Issue 15
Epitaxial catalysts for oxygen evolution reaction: model systems and beyond
journal, July 2019
- Weber, Moritz L.; Gunkel, Felix
- Journal of Physics: Energy, Vol. 1, Issue 3
Perpendicular magnetic anisotropy in trilayers
journal, September 2019
- Zhang, Jine; Han, Furong; Wang, Wei
- Physical Review B, Vol. 100, Issue 9
Perovskites in catalysis and electrocatalysis
journal, November 2017
- Hwang, Jonathan; Rao, Reshma R.; Giordano, Livia
- Science, Vol. 358, Issue 6364
Factors Controlling the Redox Activity of Oxygen in Perovskites: From Theory to Application for Catalytic Reactions
journal, May 2017
- Yang, Chunzhen; Grimaud, Alexis
- Catalysts, Vol. 7, Issue 5
Oxygen Evolution at Manganite Perovskite Ruddlesden-Popper Type Particles: Trends of Activity on Structure, Valence and Covalence
journal, November 2016
- Ebrahimizadeh Abrishami, Majid; Risch, Marcel; Scholz, Julius
- Materials, Vol. 9, Issue 11
Recent Advances in Oxygen Electrocatalysts Based on Perovskite Oxides
journal, August 2019
- Xu, Jun; Chen, Chan; Han, Zhifei
- Nanomaterials, Vol. 9, Issue 8
Physically Adsorbed Metal Ions in Porous Supports as Electrocatalysts for Oxygen Evolution Reaction
journal, February 2020
- Yang, Liu; Liu, Huibing; Shen, Hangjia
- Advanced Functional Materials, Vol. 30, Issue 12
Bifunctional Oxygen Reaction Catalysis of Quadruple Manganese Perovskites
journal, November 2016
- Yamada, Ikuya; Fujii, Hiroshi; Takamatsu, Akihiko
- Advanced Materials, Vol. 29, Issue 4
Cations in Octahedral Sites: A Descriptor for Oxygen Electrocatalysis on Transition-Metal Spinels
journal, April 2017
- Wei, Chao; Feng, Zhenxing; Scherer, Günther G.
- Advanced Materials, Vol. 29, Issue 23
Electron Correlations Engineer Catalytic Activity of Pyrochlore Iridates for Acidic Water Oxidation
journal, December 2018
- Shang, Chunyan; Cao, Cong; Yu, Dayou
- Advanced Materials
Boosting Oxygen Evolution Reaction by Creating Both Metal Ion and Lattice‐Oxygen Active Sites in a Complex Oxide
journal, November 2019
- Zhu, Yinlong; Tahini, Hassan A.; Hu, Zhiwei
- Advanced Materials, Vol. 32, Issue 1
A Perovskite Nanorod as Bifunctional Electrocatalyst for Overall Water Splitting
journal, December 2016
- Zhu, Yinlong; Zhou, Wei; Zhong, Yijun
- Advanced Energy Materials, Vol. 7, Issue 8
Enhanced Stability and Thickness‐Independent Oxygen Evolution Electrocatalysis of Heterostructured Anodes with Buried Epitaxial Bilayers
journal, June 2019
- Baniecki, John D.; Yamaguchi, Hideshi; Harnagea, Catalin
- Advanced Energy Materials, Vol. 9, Issue 28
Facile CO Oxidation on Oxygen‐functionalized MXenes via the Mars‐van Krevelen Mechanism
journal, December 2019
- Tahini, Hassan A.; Tan, Xin; Smith, Sean C.
- ChemCatChem, Vol. 12, Issue 4
Homogeneously Distributed NiFe Alloy Nanoparticles on 3D Carbon Fiber Network as a Bifunctional Electrocatalyst for Overall Water Splitting
journal, March 2019
- Lv, Yanlong; Batool, Aisha; Wei, Yuxuan
- ChemElectroChem, Vol. 6, Issue 9
Silica‐Free Synthesis of Mesoporous Co 3 O 4 /CoO x P y as a Highly Active Oxygen Evolution Reaction Catalyst
journal, August 2019
- Sun, Tian; Liu, Piao; Yang, Daihui
- ChemNanoMat, Vol. 5, Issue 11
On the Role of Ferromagnetic Interactions in Highly Active Mo-Based Catalysts for Ammonia Synthesis
journal, September 2018
- Munarriz, Julen; Polo, Victor; Gracia, Jose
- ChemPhysChem, Vol. 19, Issue 21
Cooperative Co 0 /Co II Sites Stabilized by a Perovskite Matrix Enable Selective C−O and C−C bond Hydrogenolysis of Oxygenated Arenes
journal, April 2019
- Shetty, Manish; Zanchet, Daniela; Green, William H.
- ChemSusChem, Vol. 12, Issue 10
A review of transition metal‐based bifunctional oxygen electrocatalysts
journal, April 2019
- Ibrahim, Kassa B.; Tsai, Meng‐Che; Chala, Soressa A.
- Journal of the Chinese Chemical Society, Vol. 66, Issue 8
Noble Metal-Free Nanocatalysts with Vacancies for Electrochemical Water Splitting
journal, January 2018
- Yang, Min-Quan; Wang, Jing; Wu, Hao
- Small, Vol. 14, Issue 15
Ultrafine Metallic Nickel Domains and Reduced Molybdenum States Improve Oxygen Evolution Reaction of NiFeMo Electrocatalysts
journal, March 2019
- Moon, Byeong Cheul; Choi, Won Ho; Kim, Keon‐Han
- Small, Vol. 15, Issue 19
Humidity sensing effect in Bi25FeO39 sillenite-like compound
journal, August 2016
- Ramirez, F. E. N.; Espinosa, E. E.; Pedroza, Luana S.
- Journal of Materials Science, Vol. 51, Issue 24
H2O2 decomposition catalyzed by strontium cobaltites and their application in Rhodamine B degradation in aqueous medium
journal, March 2019
- Xu, Wen; Cao, Bo; Lin, Hechun
- Journal of Materials Science, Vol. 54, Issue 11
Molten-salt synthesis of porous La0.6Sr0.4Co0.2Fe0.8O2.9 perovskite as an efficient electrocatalyst for oxygen evolution
journal, April 2018
- Song, Sanzhao; Zhou, Jing; Zhang, Shuo
- Nano Research, Vol. 11, Issue 9
Exceptional electrocatalytic oxygen evolution via tunable charge transfer interactions in La0.5Sr1.5Ni1−xFexO4±δ Ruddlesden-Popper oxides
journal, August 2018
- Forslund, Robin P.; Hardin, William G.; Rong, Xi
- Nature Communications, Vol. 9, Issue 1
Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts
journal, March 2019
- Huang, Zhen-Feng; Song, Jiajia; Du, Yonghua
- Nature Energy, Vol. 4, Issue 4
Plasma engraved Bi0.1(Ba0.5Sr0.5)0.9Co0.8Fe0.2O3−δ perovskite for highly active and durable oxygen evolution
journal, March 2019
- Sun, Juan; Zhang, Zonghuai; Gong, Yansheng
- Scientific Reports, Vol. 9, Issue 1
Highly active and durable nitrogen doped-reduced graphene oxide/double perovskite bifunctional hybrid catalysts
journal, January 2017
- Kim, Nam-In; Afzal, Rana Arslan; Choi, Sung Ryul
- Journal of Materials Chemistry A, Vol. 5, Issue 25
Decoupling the roles of carbon and metal oxides on the electrocatalytic reduction of oxygen on La 1−x Sr x CoO 3−δ perovskite composite electrodes
journal, January 2019
- Mefford, J. Tyler; Kurilovich, Aleksandr A.; Saunders, Jennette
- Physical Chemistry Chemical Physics, Vol. 21, Issue 6
Understanding the crucial role of local crystal order in the electrocatalytic activity of crystalline manganese oxide
journal, January 2018
- Lee, Jang Mee; Patil, Sharad B.; Kang, Bohyun
- Journal of Materials Chemistry A, Vol. 6, Issue 26
Modulated transition metal–oxygen covalency in the octahedral sites of CoFe layered double hydroxides with vanadium doping leading to highly efficient electrocatalysts
journal, January 2019
- Yang, Yibin; Ou, Yingqing; Yang, Yang
- Nanoscale, Vol. 11, Issue 48
Exceptional oxygen evolution reactivities on CaCoO 3 and SrCoO 3
journal, August 2019
- Li, Xiang; Wang, Hao; Cui, Zhiming
- Science Advances, Vol. 5, Issue 8
Impact of Strontium-Substitution on Oxygen Evolution Reaction of Lanthanum Nickelates in Alkaline Solution
journal, January 2018
- Sankannavar, Ravi; Sandeep, K. C.; Kamath, Sachin
- Journal of The Electrochemical Society, Vol. 165, Issue 15
All-In-One Perovskite Catalyst: Smart Controls of Architecture and Composition toward Enhanced Oxygen/Hydrogen Evolution Reactions
journal, July 2017
- Hua, Bin; Li, Meng; Zhang, Ya-Qian
- Advanced Energy Materials, Vol. 7, Issue 20
A Porous Pyrochlore Y 2 [Ru 1.6 Y 0.4 ]O 7– δ Electrocatalyst for Enhanced Performance towards the Oxygen Evolution Reaction in Acidic Media
journal, September 2018
- Kim, Jaemin; Shih, Pei‐Chieh; Qin, Yao
- Angewandte Chemie, Vol. 130, Issue 42
Chemical Recognition of Active Oxygen Species on the Surface of Oxygen Evolution Reaction Electrocatalysts
journal, June 2017
- Yang, Chunzhen; Fontaine, Olivier; Tarascon, Jean-Marie
- Angewandte Chemie International Edition, Vol. 56, Issue 30
Engineering surface atomic structure of single-crystal cobalt (II) oxide nanorods for superior electrocatalysis
journal, September 2016
- Ling, Tao; Yan, Dong-Yang; Jiao, Yan
- Nature Communications, Vol. 7, Issue 1
Pulsed reactivity on LaCoO 3 -based perovskites: a comprehensive approach to elucidate the CO oxidation mechanism and the effect of dopants
journal, January 2019
- Pinto, Donato; Glisenti, Antonella
- Catalysis Science & Technology, Vol. 9, Issue 11
High-pressure synthesis of highly oxidized Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3−δ cubic perovskite
journal, January 2019
- Yamada, Ikuya; Odake, Takao; Asai, Kaisei
- Materials Chemistry Frontiers, Vol. 3, Issue 6
Amorphous Cobalt Phyllosilicate with Layered Crystalline Motifs As Water Oxidation Catalyst
journal, April 2018
- Kang, Kisuk; Kim, Ju Seong; Park, Inchul
- ECS Meeting Abstracts, Vol. MA2018-01, Issue 29, p. 1682-1682
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction
journal, January 2018
- Kim, Ju Seong; Kim, Byunghoon; Kim, Hyunah
- Advanced Energy Materials, Vol. 8, Issue 11
Shifting Oxygen Charge Towards Octahedral Metal: A Way to Promote Water Oxidation on Cobalt Spinel Oxides
journal, April 2019
- Sun, Shengnan; Sun, Yuanmiao; Zhou, Ye
- Angewandte Chemie International Edition, Vol. 58, Issue 18
Perovskite/Carbon Composites: Applications in Oxygen Electrocatalysis
journal, February 2017
- Zhu, Yinlong; Zhou, Wei; Shao, Zongping
- Small, Vol. 13, Issue 12
Amorphous Catalysts and Electrochemical Water Splitting: An Untold Story of Harmony
journal, December 2019
- Anantharaj, Sengeni; Noda, Suguru
- Small, Vol. 16, Issue 2
In-situ local phase-transitioned MoSe2 in La0.5Sr0.5CoO3-δ heterostructure and stable overall water electrolysis over 1000 hours
journal, April 2019
- Oh, Nam Khen; Kim, Changmin; Lee, Junghyun
- Nature Communications, Vol. 10, Issue 1
Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction
journal, March 2020
- Chung, Dong Young; Lopes, Pietro P.; Farinazzo Bergamo Dias Martins, Pedro
- Nature Energy, Vol. 5, Issue 3
The role of oxygen vacancies in water oxidation for perovskite cobalt oxide electrocatalysts: are more better?
journal, January 2019
- Miao, Xianbing; Wu, Liang; Lin, Yue
- Chemical Communications, Vol. 55, Issue 10
Tuning the Electronic Structure of LaNiO 3 through Alloying with Strontium to Enhance Oxygen Evolution Activity
journal, August 2019
- Liu, Jishan; Jia, Endong; Wang, Le
- Advanced Science, Vol. 6, Issue 19
A Dissolution/Precipitation Equilibrium on the Surface of Iridium‐Based Perovskites Controls Their Activity as Oxygen Evolution Reaction Catalysts in Acidic Media
journal, February 2019
- Zhang, Ronghuan; Dubouis, Nicolas; Ben Osman, Manel
- Angewandte Chemie, Vol. 131, Issue 14
The stability number as a metric for electrocatalyst stability benchmarking
journal, June 2018
- Geiger, Simon; Kasian, Olga; Ledendecker, Marc
- Nature Catalysis, Vol. 1, Issue 7
Uncovering the Effect of Lattice Strain and Oxygen Deficiency on Electrocatalytic Activity of Perovskite Cobaltite Thin Films
journal, January 2019
- Liu, Xi; Zhang, Lei; Zheng, Yun
- Advanced Science, Vol. 6, Issue 6
Engineering surface atomic structure of single-crystal cobalt (II) oxide nanorods for superior electrocatalysis
journal, September 2016
- Ling, Tao; Yan, Dong-Yang; Jiao, Yan
- Nature Communications, Vol. 7, Issue 1
Regulating p-block metals in perovskite nanodots for efficient electrocatalytic water oxidation
journal, October 2017
- Li, Bo-Quan; Xia, Zi-Jing; Zhang, Bingsen
- Nature Communications, Vol. 8, Issue 1
Exceptional electrocatalytic oxygen evolution via tunable charge transfer interactions in La0.5Sr1.5Ni1−xFexO4±δ Ruddlesden-Popper oxides
journal, August 2018
- Forslund, Robin P.; Hardin, William G.; Rong, Xi
- Nature Communications, Vol. 9, Issue 1
In-situ local phase-transitioned MoSe2 in La0.5Sr0.5CoO3-δ heterostructure and stable overall water electrolysis over 1000 hours
journal, April 2019
- Oh, Nam Khen; Kim, Changmin; Lee, Junghyun
- Nature Communications, Vol. 10, Issue 1
Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
journal, June 2019
- Bak, Jumi; Bin Bae, Hyung; Chung, Sung-Yoon
- Nature Communications, Vol. 10, Issue 1
Electronic-reconstruction-enhanced hydrogen evolution catalysis in oxide polymorphs
journal, July 2019
- Li, Yangyang; Yu, Zhi Gen; Wang, Ling
- Nature Communications, Vol. 10, Issue 1
Cation insertion to break the activity/stability relationship for highly active oxygen evolution reaction catalyst
journal, March 2020
- Yang, Chunzhen; Rousse, Gwenaëlle; Louise Svane, Katrine
- Nature Communications, Vol. 11, Issue 1
Sr, Fe Co-doped Perovskite Oxides With High Performance for Oxygen Evolution Reaction
journal, April 2019
- Guo, Qiang; Li, Xiang; Wei, Haifei
- Frontiers in Chemistry, Vol. 7
Oxygen Evolution at Manganite Perovskite Ruddlesden-Popper Type Particles: Trends of Activity on Structure, Valence and Covalence
journal, November 2016
- Ebrahimizadeh Abrishami, Majid; Risch, Marcel; Scholz, Julius
- Materials, Vol. 9, Issue 11