Fast pyrolysis of tropical biomass species and influence of water pretreatment on product distributions
Abstract
The fast pyrolysis behaviour of pretreated banagrass was examined at four temperatures (between 400 and 600 C) and four residence times (between ~1.2 and 12 s). The pretreatment used water washing/leaching to reduce the inorganic content of the banagrass. Yields of bio-oil, permanent gases and char were determined at each reaction condition and compared to previously published results from untreated banagrass. Comparing the bio-oil yields from the untreated and pretreated banagrass shows that the yields were greater from the pretreated banagrass by 4 to 11 wt% (absolute) at all reaction conditions. The effect of pretreatment (i.e. reducing the amount of ash, and alkali and alkali earth metals) on pyrolysis products is: 1) to increase the dry bio-oil yield, 2) to decrease the amount of undetected material, 3) to produce a slight increase in CO yield or no change, 4) to slightly decrease CO 2 yield or no change, and 5) to produce a more stable bio-oil (less aging). Char yield and total gas yield were unaffected by feedstock pretreatment. Four other tropical biomass species were also pyrolyzed under one condition (450°C and 1.4 s residence time) for comparison to the banagrass results. The samples include two hardwoods: leucaena and eucalyptus,more »
- Authors:
-
- Univ. of Hawaii, Honolulu, HI (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- National Univ. of Ireland, Galway (Ireland)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1323898
- Alternate Identifier(s):
- OSTI ID: 1379115
- Report Number(s):
- SAND2016-8567J
Journal ID: ISSN 1932-6203; 647074
- Grant/Contract Number:
- AC04-94AL85000; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- PLoS ONE
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 3; Journal ID: ISSN 1932-6203
- Publisher:
- Public Library of Science
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS
Citation Formats
Morgan, Trevor James, Turn, Scott Q., Sun, Ning, George, Anthe, and Gupta, Vijai. Fast pyrolysis of tropical biomass species and influence of water pretreatment on product distributions. United States: N. p., 2016.
Web. doi:10.1371/journal.pone.0151368.
Morgan, Trevor James, Turn, Scott Q., Sun, Ning, George, Anthe, & Gupta, Vijai. Fast pyrolysis of tropical biomass species and influence of water pretreatment on product distributions. United States. https://doi.org/10.1371/journal.pone.0151368
Morgan, Trevor James, Turn, Scott Q., Sun, Ning, George, Anthe, and Gupta, Vijai. Tue .
"Fast pyrolysis of tropical biomass species and influence of water pretreatment on product distributions". United States. https://doi.org/10.1371/journal.pone.0151368. https://www.osti.gov/servlets/purl/1323898.
@article{osti_1323898,
title = {Fast pyrolysis of tropical biomass species and influence of water pretreatment on product distributions},
author = {Morgan, Trevor James and Turn, Scott Q. and Sun, Ning and George, Anthe and Gupta, Vijai},
abstractNote = {The fast pyrolysis behaviour of pretreated banagrass was examined at four temperatures (between 400 and 600 C) and four residence times (between ~1.2 and 12 s). The pretreatment used water washing/leaching to reduce the inorganic content of the banagrass. Yields of bio-oil, permanent gases and char were determined at each reaction condition and compared to previously published results from untreated banagrass. Comparing the bio-oil yields from the untreated and pretreated banagrass shows that the yields were greater from the pretreated banagrass by 4 to 11 wt% (absolute) at all reaction conditions. The effect of pretreatment (i.e. reducing the amount of ash, and alkali and alkali earth metals) on pyrolysis products is: 1) to increase the dry bio-oil yield, 2) to decrease the amount of undetected material, 3) to produce a slight increase in CO yield or no change, 4) to slightly decrease CO 2 yield or no change, and 5) to produce a more stable bio-oil (less aging). Char yield and total gas yield were unaffected by feedstock pretreatment. Four other tropical biomass species were also pyrolyzed under one condition (450°C and 1.4 s residence time) for comparison to the banagrass results. The samples include two hardwoods: leucaena and eucalyptus, and two grasses: sugarcane bagasse and energy-cane. A sample of pretreated energy-cane was also pyrolyzed. Of the materials tested, the best feedstocks for fast pyrolysis were sugarcane bagasse, pretreated energy cane and eucalyptus based on the yields of 'dry bio-oil', CO and CO 2 . On the same basis, the least productive feedstocks are untreated banagrass followed by pretreated banagrass and leucaena.},
doi = {10.1371/journal.pone.0151368},
journal = {PLoS ONE},
number = 3,
volume = 11,
place = {United States},
year = {Tue Mar 15 00:00:00 EDT 2016},
month = {Tue Mar 15 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Mallee wood fast pyrolysis: Effects of alkali and alkaline earth metallic species on the yield and composition of bio-oil
journal, September 2011
- Mourant, Daniel; Wang, Zhouhong; He, Min
- Fuel, Vol. 90, Issue 9
Ethanol technical potential in Hawaii based on sugarcane, banagrass, Eucalyptus, and Leucaena
journal, February 2009
- Keffer, V. I.; Turn, S. Q.; Kinoshita, C. M.
- Biomass and Bioenergy, Vol. 33, Issue 2
Banagrass vs Eucalyptus Wood as Feedstocks for Metallurgical Biocarbon Production †
journal, December 2008
- Yoshida, Takuya; Turn, Scott Q.; Yost, Russell S.
- Industrial & Engineering Chemistry Research, Vol. 47, Issue 24
Effect of process conditions on product yield and composition of fast pyrolysis of Eucalyptus grandis in fluidized bed reactor
journal, July 2014
- Heidari, Aghdas; Stahl, Ralph; Younesi, Habibollah
- Journal of Industrial and Engineering Chemistry, Vol. 20, Issue 4
Evaluation of the production potential of bio-oil from Vietnamese biomass resources by fast pyrolysis
journal, March 2014
- Phan, Binh M. Q.; Duong, Long T.; Nguyen, Viet D.
- Biomass and Bioenergy, Vol. 62
Optimizing biofuel production: An economic analysis for selected biofuel feedstock production in Hawaii
journal, May 2011
- Tran, Nghia; Illukpitiya, Prabodh; Yanagida, John F.
- Biomass and Bioenergy, Vol. 35, Issue 5
The fate of inorganic constituents of biomass in fluidized bed gasification
journal, February 1998
- Turn, S.
- Fuel, Vol. 77, Issue 3
An overview of the organic and inorganic phase composition of biomass
journal, April 2012
- Vassilev, Stanislav V.; Baxter, David; Andersen, Lars K.
- Fuel, Vol. 94
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
journal, May 2006
- Mohan, Dinesh; Pittman,, Charles U.; Steele, Philip H.
- Energy & Fuels, Vol. 20, Issue 3, p. 848-889
A Kinetic Model for the Production of Liquids from the Flash Pyrolysis of Biomass
journal, March 1988
- Liden, A. G.; Berruti, F.; Scott, D. S.
- Chemical Engineering Communications, Vol. 65, Issue 1
Bench-Scale Fluidized-Bed Pyrolysis of Switchgrass for Bio-Oil Production †
journal, March 2007
- Boateng, Akwasi A.; Daugaard, Daren E.; Goldberg, Neil M.
- Industrial & Engineering Chemistry Research, Vol. 46, Issue 7
A statistical analysis of the auto thermal fast pyrolysis of elephant grass in fluidized bed reactor based on produced charcoal
journal, April 2014
- Mesa-Pérez, Juan M.; Cortez, Luis A. B.; Marín-Mesa, Henry R.
- Applied Thermal Engineering, Vol. 65, Issue 1-2
Thermochemical Conversion of Sugarcane Bagasse into Bio-Crude Oils by Fluidized-Bed Pyrolysis Technology
journal, January 2010
- Islam, Mohammad Rofiqul; Haniu, Hiroyuki; Islam, Mohammad Nurul
- Journal of Thermal Science and Technology, Vol. 5, Issue 1
Bio-oil production from Colombian bagasse by fast pyrolysis in a fluidized bed: An experimental study
journal, March 2015
- Montoya, J. I.; Valdés, C.; Chejne, F.
- Journal of Analytical and Applied Pyrolysis, Vol. 112
Pyrolysis of napier grass in an induction-heating reactor
journal, July 2010
- Lee, Mei-Kuei; Tsai, Wen-Tien; Tsai, Yi-Lin
- Journal of Analytical and Applied Pyrolysis, Vol. 88, Issue 2
Pyrolysis of Coals and Biomass: Analysis of Thermal Breakdown and Its Products
journal, October 2013
- Morgan, Trevor J.; Kandiyoti, Rafael
- Chemical Reviews, Vol. 114, Issue 3
Bio-oil production by flash pyrolysis of sugarcane residues and post treatments of the aqueous phase
journal, May 2011
- Xu, R.; Ferrante, L.; Briens, C.
- Journal of Analytical and Applied Pyrolysis, Vol. 91, Issue 1
Secondary reactions of flash pyrolysis tars measured in a fluidized bed pyrolysis reactor with some novel design features
journal, March 1989
- Stiles, H.; Kandiyoti, R.
- Fuel, Vol. 68, Issue 3
Thermal conversion of elephant grass (Pennisetum Purpureum Schum) to bio-gas, bio-oil and charcoal
journal, November 2008
- Strezov, Vladimir; Evans, Tim J.; Hayman, Chris
- Bioresource Technology, Vol. 99, Issue 17
A comparative study of straw, perennial grasses and hardwoods in terms of fast pyrolysis products
journal, June 2013
- Greenhalf, C. E.; Nowakowski, D. J.; Harms, A. B.
- Fuel, Vol. 108
Pyrolytic Reactions of Lignin within Naturally Occurring Plant Matrices: Challenges in Biomass Pyrolysis Modeling Due to Synergistic Effects
journal, October 2014
- George, Anthe; Morgan, Trevor J.; Kandiyoti, Rafael
- Energy & Fuels, Vol. 28, Issue 11
Comparison of physicochemical features of biooils and biochars produced from various woody biomasses by fast pyrolysis
journal, February 2013
- Kim, Kwang Ho; Kim, Tae-Seung; Lee, Soo-Min
- Renewable Energy, Vol. 50
Inherent process variations between fast pyrolysis technologies: A case study on Eucalyptus grandis
journal, March 2015
- Joubert, Jan-Erns; Carrier, Marion; Dahmen, Nicolaus
- Fuel Processing Technology, Vol. 131
Quantitative X-ray Fluorescence Analysis of Biomass: Objective Evaluation of a Typical Commercial Multi-Element Method on a WD-XRF Spectrometer
journal, November 2013
- Andersen, Lars Klembt; Morgan, Trevor J.; Boulamanti, Aikaterini K.
- Energy & Fuels, Vol. 27, Issue 12
Structural and Chemical Characterization of Hardwood from Tree Species with Applications as Bioenergy Feedstocks
journal, December 2012
- Çetinkol, Özgül Persil; Smith-Moritz, Andreia M.; Cheng, Gang
- PLoS ONE, Vol. 7, Issue 12
Comparison of pyrolytic products produced from inorganic-rich and demineralized rice straw (Oryza sativa L.) by fluidized bed pyrolyzer for future biorefinery approach
journal, January 2013
- Eom, In-Yong; Kim, Jae-Young; Lee, Soo-Min
- Bioresource Technology, Vol. 128
Quantitative X-ray Fluorescence Analysis of Biomass (Switchgrass, Corn Stover, Eucalyptus, Beech, and Pine Wood) with a Typical Commercial Multi-Element Method on a WD-XRF Spectrometer
journal, March 2015
- Morgan, Trevor J.; George, Anthe; Boulamanti, Aikaterini K.
- Energy & Fuels, Vol. 29, Issue 3
The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability
journal, June 2008
- Fahmi, R.; Bridgwater, A. V.; Donnison, I.
- Fuel, Vol. 87, Issue 7
Fast Pyrolysis Bio-Oils from Wood and Agricultural Residues
journal, February 2010
- Oasmaa, Anja; Solantausta, Yrjö; Arpiainen, Vesa
- Energy & Fuels, Vol. 24, Issue 2
Characterization of bioresidues for biooil production through pyrolysis
journal, June 2013
- Mythili, R.; Venkatachalam, P.; Subramanian, P.
- Bioresource Technology, Vol. 138
Pyrolysis kinetics of elephant grass pretreated biomasses
journal, June 2014
- Braga, Renata M.; Costa, Tiago R.; Freitas, Julio C. O.
- Journal of Thermal Analysis and Calorimetry, Vol. 117, Issue 3
Prediction of Klason lignin and lignin thermal degradation products by Py–GC/MS in a collection of Lolium and Festuca grasses
journal, August 2007
- Fahmi, R.; Bridgwater, A. V.; Thain, S. C.
- Journal of Analytical and Applied Pyrolysis, Vol. 80, Issue 1
Characterization of biomass pyrolysis tars produced in the relative absence of extraparticle secondary reactions
journal, July 1991
- Fraga, Ana-Rita; Gaines, Alec F.; Kandiyoti, Rafael
- Fuel, Vol. 70, Issue 7
Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor
journal, August 2015
- Morgan, Trevor James; Turn, Scott Q.; George, Anthe
- PLOS ONE, Vol. 10, Issue 8
Pyrolysis kinetics of elephant grass pretreated biomasses
journal, June 2014
- Braga, Renata M.; Costa, Tiago R.; Freitas, Julio C. O.
- Journal of Thermal Analysis and Calorimetry, Vol. 117, Issue 3
Secondary reactions of flash pyrolysis tars measured in a fluidized bed pyrolysis reactor with some novel design features
journal, March 1989
- Stiles, H.; Kandiyoti, R.
- Fuel, Vol. 68, Issue 3
A statistical analysis of the auto thermal fast pyrolysis of elephant grass in fluidized bed reactor based on produced charcoal
journal, April 2014
- Mesa-Pérez, Juan M.; Cortez, Luis A. B.; Marín-Mesa, Henry R.
- Applied Thermal Engineering, Vol. 65, Issue 1-2
Optimizing biofuel production: An economic analysis for selected biofuel feedstock production in Hawaii
journal, May 2011
- Tran, Nghia; Illukpitiya, Prabodh; Yanagida, John F.
- Biomass and Bioenergy, Vol. 35, Issue 5
Evaluation of the production potential of bio-oil from Vietnamese biomass resources by fast pyrolysis
journal, March 2014
- Phan, Binh M. Q.; Duong, Long T.; Nguyen, Viet D.
- Biomass and Bioenergy, Vol. 62
Thermal conversion of elephant grass (Pennisetum Purpureum Schum) to bio-gas, bio-oil and charcoal
journal, November 2008
- Strezov, Vladimir; Evans, Tim J.; Hayman, Chris
- Bioresource Technology, Vol. 99, Issue 17
Comparison of pyrolytic products produced from inorganic-rich and demineralized rice straw (Oryza sativa L.) by fluidized bed pyrolyzer for future biorefinery approach
journal, January 2013
- Eom, In-Yong; Kim, Jae-Young; Lee, Soo-Min
- Bioresource Technology, Vol. 128
Characterization of bioresidues for biooil production through pyrolysis
journal, June 2013
- Mythili, R.; Venkatachalam, P.; Subramanian, P.
- Bioresource Technology, Vol. 138
The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability
journal, June 2008
- Fahmi, R.; Bridgwater, A. V.; Donnison, I.
- Fuel, Vol. 87, Issue 7
Mallee wood fast pyrolysis: Effects of alkali and alkaline earth metallic species on the yield and composition of bio-oil
journal, September 2011
- Mourant, Daniel; Wang, Zhouhong; He, Min
- Fuel, Vol. 90, Issue 9
A comparative study of straw, perennial grasses and hardwoods in terms of fast pyrolysis products
journal, June 2013
- Greenhalf, C. E.; Nowakowski, D. J.; Harms, A. B.
- Fuel, Vol. 108
Inherent process variations between fast pyrolysis technologies: A case study on Eucalyptus grandis
journal, March 2015
- Joubert, Jan-Erns; Carrier, Marion; Dahmen, Nicolaus
- Fuel Processing Technology, Vol. 131
Mechanical dewatering and water leaching pretreatment of fresh banagrass, guinea grass, energy cane, and sugar cane: Characterization of fuel properties and byproduct streams
journal, November 2015
- Cui, Hong; Turn, Scott Q.; Tran, Thai
- Fuel Processing Technology, Vol. 139
Prediction of Klason lignin and lignin thermal degradation products by Py–GC/MS in a collection of Lolium and Festuca grasses
journal, August 2007
- Fahmi, R.; Bridgwater, A. V.; Thain, S. C.
- Journal of Analytical and Applied Pyrolysis, Vol. 80, Issue 1
Bio-oil production from Colombian bagasse by fast pyrolysis in a fluidized bed: An experimental study
journal, March 2015
- Montoya, J. I.; Valdés, C.; Chejne, F.
- Journal of Analytical and Applied Pyrolysis, Vol. 112
Effect of process conditions on product yield and composition of fast pyrolysis of Eucalyptus grandis in fluidized bed reactor
journal, July 2014
- Heidari, Aghdas; Stahl, Ralph; Younesi, Habibollah
- Journal of Industrial and Engineering Chemistry, Vol. 20, Issue 4
Comparison of physicochemical features of biooils and biochars produced from various woody biomasses by fast pyrolysis
journal, February 2013
- Kim, Kwang Ho; Kim, Tae-Seung; Lee, Soo-Min
- Renewable Energy, Vol. 50
Pyrolysis of Coals and Biomass: Analysis of Thermal Breakdown and Its Products
journal, October 2013
- Morgan, Trevor J.; Kandiyoti, Rafael
- Chemical Reviews, Vol. 114, Issue 3
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
journal, May 2006
- Mohan, Dinesh; Pittman,, Charles U.; Steele, Philip H.
- Energy & Fuels, Vol. 20, Issue 3, p. 848-889
Pyrolytic Reactions of Lignin within Naturally Occurring Plant Matrices: Challenges in Biomass Pyrolysis Modeling Due to Synergistic Effects
journal, October 2014
- George, Anthe; Morgan, Trevor J.; Kandiyoti, Rafael
- Energy & Fuels, Vol. 28, Issue 11
Quantitative X-ray Fluorescence Analysis of Biomass (Switchgrass, Corn Stover, Eucalyptus, Beech, and Pine Wood) with a Typical Commercial Multi-Element Method on a WD-XRF Spectrometer
journal, March 2015
- Morgan, Trevor J.; George, Anthe; Boulamanti, Aikaterini K.
- Energy & Fuels, Vol. 29, Issue 3
Fast Pyrolysis Bio-Oils from Wood and Agricultural Residues
journal, February 2010
- Oasmaa, Anja; Solantausta, Yrjö; Arpiainen, Vesa
- Energy & Fuels, Vol. 24, Issue 2
Bench-Scale Fluidized-Bed Pyrolysis of Switchgrass for Bio-Oil Production †
journal, March 2007
- Boateng, Akwasi A.; Daugaard, Daren E.; Goldberg, Neil M.
- Industrial & Engineering Chemistry Research, Vol. 46, Issue 7
A Kinetic Model for the Production of Liquids from the Flash Pyrolysis of Biomass
journal, March 1988
- Liden, A. G.; Berruti, F.; Scott, D. S.
- Chemical Engineering Communications, Vol. 65, Issue 1
Thermochemical Conversion of Sugarcane Bagasse into Bio-Crude Oils by Fluidized-Bed Pyrolysis Technology
journal, January 2010
- Islam, Mohammad Rofiqul; Haniu, Hiroyuki; Islam, Mohammad Nurul
- Journal of Thermal Science and Technology, Vol. 5, Issue 1
Structural and Chemical Characterization of Hardwood from Tree Species with Applications as Bioenergy Feedstocks
journal, December 2012
- Çetinkol, Özgül Persil; Smith-Moritz, Andreia M.; Cheng, Gang
- PLoS ONE, Vol. 7, Issue 12
Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor
journal, August 2015
- Morgan, Trevor James; Turn, Scott Q.; George, Anthe
- PLOS ONE, Vol. 10, Issue 8