Probing Structural Evolution and Charge Storage Mechanism of NiO 2 H x Electrode Materials using In Operando Resonance Raman Spectroscopy

Chen, Dongchang; Xiong, Xunhui; Zhao, Bote; Mahmoud, Mahmoud A.; El‐Sayed, Mostafa A.; Liu, Meilin

doi:10.1002/advs.201500433

Title: Probing Structural Evolution and Charge Storage Mechanism of NiO ₂ H _x Electrode Materials using In Operando Resonance Raman Spectroscopy

Abstract

The demand for clean, affordable, and reliable energy storage devices has greatly inspired extensive global research on advanced battery/capacitor technologies.

Authors:

Chen, Dongchang ^[1]; Xiong, Xunhui ^[2]; Zhao, Bote ^[2]; Mahmoud, Mahmoud A. ^[3]; El‐Sayed, Mostafa A. ^[3]; Liu, Meilin ^[2]

School of Materials Science and Engineering Center for Innovative Fuel Cell and Battery Technologies Georgia Institute of Technology 771 Ferst Drive Atlanta GA 30332‐0245 USA, Laser Dynamics Laboratory School of Chemistry and Biochemistry Georgia Institute of Technology 901 Atlantic Drive Atlanta GA 30332‐0400 USA
School of Materials Science and Engineering Center for Innovative Fuel Cell and Battery Technologies Georgia Institute of Technology 771 Ferst Drive Atlanta GA 30332‐0245 USA
Laser Dynamics Laboratory School of Chemistry and Biochemistry Georgia Institute of Technology 901 Atlantic Drive Atlanta GA 30332‐0400 USA

Publication Date:: Tue Feb 23 00:00:00 EST 2016

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Heterogeneous Functional Materials Center (HeteroFoaM); Univ. of South Carolina, Columbia, SC (United States). South Carolina Research Foundation

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1341088

Alternate Identifier(s):: OSTI ID: 1306109; OSTI ID: 1341089

Grant/Contract Number:: SC0001061

Resource Type:: Published Article

Journal Name:: Advanced Science

Additional Journal Information:: Journal Name: Advanced Science Journal Volume: 3 Journal Issue: 6; Journal ID: ISSN 2198-3844

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Chen, Dongchang, Xiong, Xunhui, Zhao, Bote, Mahmoud, Mahmoud A., El‐Sayed, Mostafa A., and Liu, Meilin. Probing Structural Evolution and Charge Storage Mechanism of NiO 2 H x Electrode Materials using In Operando Resonance Raman Spectroscopy.  Germany: N. p., 2016. 
Web.  doi:10.1002/advs.201500433.

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                    Chen, Dongchang, Xiong, Xunhui, Zhao, Bote, Mahmoud, Mahmoud A., El‐Sayed, Mostafa A., & Liu, Meilin. Probing Structural Evolution and Charge Storage Mechanism of NiO 2 H x Electrode Materials using In Operando Resonance Raman Spectroscopy.  Germany.  https://doi.org/10.1002/advs.201500433

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                    Chen, Dongchang, Xiong, Xunhui, Zhao, Bote, Mahmoud, Mahmoud A., El‐Sayed, Mostafa A., and Liu, Meilin. Tue .  
"Probing Structural Evolution and Charge Storage Mechanism of NiO 2 H x Electrode Materials using In Operando Resonance Raman Spectroscopy".  Germany.  https://doi.org/10.1002/advs.201500433.

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@article{osti_1341088,

  title        = {Probing Structural Evolution and Charge Storage Mechanism of NiO 2 H x Electrode Materials using In Operando Resonance Raman Spectroscopy},

  author       = {Chen, Dongchang and Xiong, Xunhui and Zhao, Bote and Mahmoud, Mahmoud A. and El‐Sayed, Mostafa A. and Liu, Meilin},

  abstractNote = {The demand for clean, affordable, and reliable energy storage devices has greatly inspired extensive global research on advanced battery/capacitor technologies.},

  doi          = {10.1002/advs.201500433},

  journal      = {Advanced Science},

  number       = 6,

  volume       = 3,

  place        = {Germany},

  year         = {Tue Feb 23 00:00:00 EST 2016},

  month        = {Tue Feb 23 00:00:00 EST 2016}

}

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Title: Probing Structural Evolution and Charge Storage Mechanism of NiO 2 H x Electrode Materials using In Operando Resonance Raman Spectroscopy

Abstract

Citation Formats

Probing the Charge Storage Mechanism of a Pseudocapacitive MnO 2 Electrode Using in Operando Raman Spectroscopy journal, September 2015

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Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides journal, January 1982

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Spherical α-Ni(OH)2 nanoarchitecture grown on graphene as advanced electrochemical pseudocapacitor materials journal, January 2012

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Electrochemical and In Situ Raman Spectroscopic Characterization of Nickel Hydroxide Electrodes journal, January 1997

A Study of the Electrochemical Redox Behavior of Electrochemically Precipitated Nickel Hydroxides Using Electrochemical Quartz Crystal Microbalance journal, January 1997

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Three-dimensional ultrathin Ni(OH)2 nanosheets grown on nickel foam for high-performance supercapacitors journal, January 2015

Interwoven Three-Dimensional Architecture of Cobalt Oxide Nanobrush-Graphene@Ni x Co 2 x (OH) 6 x for High-Performance Supercapacitors journal, February 2015

Determination of the “NiOOH” charge and discharge mechanisms at ideal activity journal, March 2014

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Large-scale synthesis of coaxial carbon nanotube/Ni(OH)2 composites for asymmetric supercapacitor application journal, January 2015

To Be or Not To Be Pseudocapacitive? journal, January 2015

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Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials journal, May 2013

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Title: Probing Structural Evolution and Charge Storage Mechanism of NiO ₂ H _x Electrode Materials using In Operando Resonance Raman Spectroscopy

Probing the Charge Storage Mechanism of a Pseudocapacitive MnO ₂ Electrode Using in Operando Raman Spectroscopy
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journal, April 2012

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journal, October 2010

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Characteristics and Effects of γ-NiOOH on Cell Performance and a Method to Quantify It in Nickel Electrodes
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In situ crystallographic investigations of charge storage mechanisms in MnO2-based electrochemical capacitors
journal, May 2012

Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies
journal, July 2011

Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides
journal, January 1982

Structural models for nickel electrode active mass
journal, March 1988

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journal, January 2012

Raman Microspectrometry Applied to the Study of Electrode Materials for Lithium Batteries
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journal, January 1997

A Study of the Electrochemical Redox Behavior of Electrochemically Precipitated Nickel Hydroxides Using Electrochemical Quartz Crystal Microbalance
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Transport of alkaline cation and neutral species through the α-Ni(OH)2/γ-NiOOH film electrode
journal, June 2001

Zur kenntnis der nickelhydroxidelektrode—IV. Kristallstrukturuntersuchung des hochoxidierten γ1-Nickelhydroxids
journal, May 1971

Three-dimensional ultrathin Ni(OH)2 nanosheets grown on nickel foam for high-performance supercapacitors
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journal, February 2015

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journal, March 2014

Intercalation/deintercalation characteristics of electrodeposited and anodized nickel thin film on ITO electrode in aqueous and nonaqueous electrolytes
journal, September 2001

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journal, January 1992

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journal, January 2015

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journal, August 1966

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journal, May 1997

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011

Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes
journal, March 2011

Electrochemical and Spectroscopic Evidence on the Participation of Quadrivalent Nickel in the Nickel Hydroxide Redox Reaction
journal, January 1989

Electrochemistry and Structural Chemistry of LiNiO[sub 2] (R3m) for 4 Volt Secondary Lithium Cells
journal, January 1993

Valuing Reversible Energy Storage
journal, March 2012

Synergistic Effect of Hierarchical Nanostructured MoO ₂ /Co(OH) ₂ with Largely Enhanced Pseudocapacitor Cyclability
journal, October 2013

Raman spectroscopy as a versatile tool for studying the properties of graphene
journal, April 2013

Phase evolution of an alpha MnO 2 -based electrode for pseudo-capacitors probed by in operando Raman spectroscopy
journal, October 2014

Applications of in Situ Raman Spectroscopy for Identifying Nickel Hydroxide Materials and Surface Layers during Chemical Aging
journal, February 2014

Raman Spectrum of Graphene and Graphene Layers
journal, October 2006

Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials
journal, May 2013

Nickel–Cobalt Hydroxide Nanosheets Coated on NiCo ₂ O ₄ Nanowires Grown on Carbon Fiber Paper for High-Performance Pseudocapacitors
journal, June 2013

Die Struktur höherer Nickelhydroxyde
journal, February 1950

Zur Kenntnis der Nickelhydroxidelektrode. II. �ber die Oxydationsprodukte von Nickel(II)-hydroxiden
journal, April 1969

In Situ Laser Raman Spectroscopic Study of Anodic Corrosion Films on Nickel and Cobalt
journal, January 1984

Characterization of Redox States of Nickel Hydroxide Film Electrodes by In Situ Surface Raman Spectroscopy
journal, January 1988

Raman study of layered rock-salt LiCoO2 and its electrochemical lithium deintercalation
journal, August 1997