Scaling effects in sodium zirconium silicate phosphate (Na1+xZr2SixP3-xO12) ion-conducting thin films

Ihlefeld, Jon F.; Gurniak, Emily; Jones, Brad H.; Wheeler, David R.; Rodriguez, Mark A.; McDaniel, Anthony H.

doi:10.1111/jace.14285

Title: Scaling effects in sodium zirconium silicate phosphate (Na₁₊_xZr₂Si_xP_3-_xO₁₂) ion-conducting thin films

Journal Article · Wed May 04 04:00:00 UTC 2016 · Journal of the American Ceramic Society

DOI: https://doi.org/10.1111/jace.14285 · OSTI ID:1262309

Ihlefeld, Jon F. ^[1]; Gurniak, Emily ^[1]; Jones, Brad H. ^[1]; Wheeler, David R. ^[1]; Rodriguez, Mark A. ^[1]; McDaniel, Anthony H. ^[2]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Preparation of sodium zirconium silicate phosphate (NaSICon), Na_1+xZr₂Si_xP_3–xO₁₂ (0.25 ≤ x ≤ 1.0), thin films has been investigated via a chemical solution approach on platinized silicon substrates. Increasing the silicon content resulted in a reduction in the crystallite size and a reduction in the measured ionic conductivity. Processing temperature was also found to affect microstructure and ionic conductivity with higher processing temperatures resulting in larger crystallite sizes and higher ionic conductivities. The highest room temperature sodium ion conductivity was measured for an x = 0.25 composition at 2.3 × 10^–5 S/cm. In conclusion, the decreasing ionic conductivity trends with increasing silicon content and decreasing processing temperature are consistent with grain boundary and defect scattering of conducting ions.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Sandia National Laboratories, Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1262309

Report Number(s):: SAND--2016-6422J; 643969

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (38)

Chemically Homogeneous Complex Oxide Thin Films Via Improved Substrate Metallization Shelton, Christopher T.; Kotula, Paul G.; Brennecka, Geoff L. Advanced Functional Materials, Vol. 22, Issue 11 https://doi.org/10.1002/adfm.201103077	journal	March 2012
Electroceramics: Characterization by Impedance Spectroscopy Irvine, John T. S.; Sinclair, Derek C.; West, Anthony R. Advanced Materials, Vol. 2, Issue 3 https://doi.org/10.1002/adma.19900020304	journal	March 1990
Fast Lithium-Ion Conducting Thin-Film Electrolytes Integrated Directly on Flexible Substrates for High-Power Solid-State Batteries Ihlefeld, Jon F.; Clem, Paul G.; Doyle, Barney L. Advanced Materials, Vol. 23, Issue 47, p. 5663-5667 https://doi.org/10.1002/adma.201102980	journal	November 2011
Comparison of different synthesis methods for nasicon ceramics Gasmi, N.; Gharbi, N.; Zarrouk, H. Journal of Sol-Gel Science and Technology, Vol. 4, Issue 3 https://doi.org/10.1007/BF00488378	journal	January 1995
Grain-boundary ionic conductivity in nominal Li1+x M x Ti2?x (PO4)3 (M=Sc3+ or Y3+) and their zirconium analogues Saito, Y.; Ado, K.; Asai, T. Journal of Materials Science Letters, Vol. 11, Issue 12 https://doi.org/10.1007/BF00730497	journal	January 1992
Crystal structures and crystal chemistry in the system Na1+xZr2SixP3−xO12 Hong, H. Y-P. Materials Research Bulletin, Vol. 11, Issue 2 https://doi.org/10.1016/0025-5408(76)90073-8	journal	February 1976
Fast Na+-ion transport in skeleton structures Goodenough, J. B.; Hong, H. Y-P.; Kafalas, J. A. Materials Research Bulletin, Vol. 11, Issue 2 https://doi.org/10.1016/0025-5408(76)90077-5	journal	February 1976
NASICON solid electrolytes part III: Sodium conductivity enhancement along domain and grain boundaries Kreuer, K. D.; Kohler, H.; Warhus, U. Materials Research Bulletin, Vol. 21, Issue 2 https://doi.org/10.1016/0025-5408(86)90201-1	journal	February 1986
Preparation of NASICON thin films by dip-coating on Si/SiO2 wafers and corresponding C-V measurements Huang, Yuan Long; Caneiro, Alberto; Attari, Mokhtar Thin Solid Films, Vol. 196, Issue 2 https://doi.org/10.1016/0040-6090(91)90372-5	journal	February 1991
Compositional dependence of the electrochemical and structural parameters in the Nasicon system (Na1+xSixZr2P3−xO12) Vonalpen, U.; Bell, M.; Hofer, H. Solid State Ionics, Vol. 3-4 https://doi.org/10.1016/0167-2738(81)90085-0	journal	August 1981
Note on the parameterization of the constant-phase admittance element Rossmacdonald, J. Solid State Ionics, Vol. 13, Issue 2 https://doi.org/10.1016/0167-2738(84)90049-3	journal	May 1984
Conductivity measurements in the Nasicon system Nicholas, V.; Johnson, P.; Kingon, A. Solid State Ionics, Vol. 17, Issue 4 https://doi.org/10.1016/0167-2738(85)90081-5	journal	November 1985
Sputtered silicate-limit NASICON thin films for electrochemical sensors☆ Ivanov, D.; Currie, J.; Bouchard, H. Solid State Ionics, Vol. 67, Issue 3-4 https://doi.org/10.1016/0167-2738(94)90020-5	journal	January 1994
Ion conductivity of Nasicon ceramics:effects of texture and doping with B2O3 and Al2O3 Høj, J. W.; Engell, J. Materials Science and Engineering: B, Vol. 19, Issue 3 https://doi.org/10.1016/0921-5107(93)90191-O	journal	June 1993
A complex impedance analysis of the ionic conductivity of Na1+xZr2SixP3−xO12 ceramics Bayard, M. L.; Barna, G. G. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 91, Issue 2 https://doi.org/10.1016/S0022-0728(78)80100-4	journal	August 1978
Sol–gel processing of NASICON thin film using aqueous complex precursor Shimizu, Y. Solid State Ionics, Vol. 132, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00703-7	journal	July 2000
Influence of microstructure on the electrical properties of NASICON materials Fuentes, R. Solid State Ionics, Vol. 140, Issue 1-2 https://doi.org/10.1016/S0167-2738(01)00701-9	journal	March 2001
Electrical and interfacial properties of a Li3Fe2(PO4)3 single crystal with silver electrodes Ivanov-Schitz, A. Solid State Ionics, Vol. 91, Issue 1-2 https://doi.org/10.1016/S0167-2738(96)00415-8	journal	October 1996
Ionic conductivity of the NaZr2(PO4)3 single crystals Ivanov-Schitz, A. Solid State Ionics, Vol. 100, Issue 1-2 https://doi.org/10.1016/S0167-2738(97)00267-1	journal	September 1997
Conductivity measurements on nasicon and nasicon-modified materials Bohnke, O. Solid State Ionics, Vol. 122, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00062-4	journal	July 1999
Sol–gel preparation of Li+ ion conductive thin film Takada, Kazunori; Fujimoto, Kenjiro; Inada, Taro Applied Surface Science, Vol. 189, Issue 3-4 https://doi.org/10.1016/S0169-4332(01)01007-8	journal	April 2002
NMR and XRD study of the influence of the P precursor in sol-gel synthesis of NASICON powders and films Martucci, A.; Sartori, S.; Guglielmi, M. Journal of the European Ceramic Society, Vol. 22, Issue 12 https://doi.org/10.1016/S0955-2219(01)00536-2	journal	November 2002
Grain boundary resistance of fast lithium ion conductors: Comparison between a lithium-ion conductive Li–Al–Ti–P–O-type glass ceramic and a Li1.5Al0.5Ge1.5P3O12 ceramic Mariappan, Chinnasamy R.; Gellert, Michael; Yada, Chihiro Electrochemistry Communications, Vol. 14, Issue 1 https://doi.org/10.1016/j.elecom.2011.10.022	journal	January 2012
High conductivity of dense tetragonal Li₇La₃Zr₂O₁₂ Wolfenstine, Jeff; Rangasamy, Ezhiyl; Allen, Jan L. Journal of Power Sources, Vol. 208, p. 193-196 https://doi.org/10.1016/j.jpowsour.2012.02.031	journal	June 2012
A review of lithium and non-lithium based solid state batteries Kim, Joo Gon; Son, Byungrak; Mukherjee, Santanu Journal of Power Sources, Vol. 282 https://doi.org/10.1016/j.jpowsour.2015.02.054	journal	May 2015
Physical and electrochemical characterization of amorphous lithium lanthanum titanate solid electrolyte thin-film fabricated by e-beam evaporation Li, Chi-Lin; Zhang, Bin; Fu, Zheng-Wen Thin Solid Films, Vol. 515, Issue 4 https://doi.org/10.1016/j.tsf.2006.07.026	journal	December 2006
Mechanical characterization of LiPON films using nanoindentation Herbert, E. G.; Tenhaeff, W. E.; Dudney, N. J. Thin Solid Films, Vol. 520, Issue 1 https://doi.org/10.1016/j.tsf.2011.07.068	journal	October 2011
Extrinsic scaling effects on the dielectric response of ferroelectric thin films Ihlefeld, Jon F.; Vodnick, Aaron M.; Baker, Shefford P. Journal of Applied Physics, Vol. 103, Issue 7 https://doi.org/10.1063/1.2903211	journal	April 2008
Crystal coherence length effects on the infrared optical response of MgO thin films Ihlefeld, J. F.; Ginn, J. C.; Shelton, D. J. Applied Physics Letters, Vol. 97, Issue 19, Article No. 191913 https://doi.org/10.1063/1.3515901	journal	November 2010
Simultaneous structure and size–strain refinement by the Rietveld method Lutterotti, L.; Scardi, P. Journal of Applied Crystallography, Vol. 23, Issue 4 https://doi.org/10.1107/S0021889890002382	journal	August 1990
Ionic Conductivity in the System NaZr2(PO4)3-Na3Y2(PO4)3 Nagai, Masayuki; Fujitsu, Satoru; Kanazawa, Takafumi Journal of the American Ceramic Society, Vol. 63, Issue 7-8 https://doi.org/10.1111/j.1151-2916.1980.tb10216.x	journal	July 1980
Grain-Size Effects in YSZ Thin-Film Electrolytes Peters, Christoph; Weber, André; Butz, Benjamin Journal of the American Ceramic Society, Vol. 92, Issue 9 https://doi.org/10.1111/j.1551-2916.2009.03157.x	journal	September 2009
The Influences of Excess Sodium on Low-Temperature NaSICON Synthesis Bell, Nelson S.; Edney, Cynthia; Wheeler, Jill S. Journal of the American Ceramic Society, Vol. 97, Issue 12 https://doi.org/10.1111/jace.13167	journal	August 2014
A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride Yu, Xiaohua; Bates, J. B.; Jellison, G. E. Journal of The Electrochemical Society, Vol. 144, Issue 2, p. 524-532 https://doi.org/10.1149/1.1837443	journal	January 1997
Pulsed Laser Deposition of NASICON Thin Films for the Fabrication of Ion Selective Membranes Izquierdo, R. Journal of The Electrochemical Society, Vol. 144, Issue 12 https://doi.org/10.1149/1.1838147	journal	January 1997
Preparation and Processing Temperature Effects on Ion Conductivity in Solution Derived Sodium Zirconium Phosphate (NaZr ₂ P ₃ O ₁₂ ) Thin Films Meier, William; Apblett, Christopher; Ingersoll, David Journal of The Electrochemical Society, Vol. 161, Issue 3 https://doi.org/10.1149/2.068403jes	journal	December 2013
The structure of NaZnPO ₄ Elammari, Lahcen; Durand, Jean; Cot, Louis Zeitschrift für Kristallographie, Vol. 180, Issue 1-4 https://doi.org/10.1524/zkri.1987.180.1-4.137	journal	January 1987
Metallization schemes for dielectric thin film capacitors Al-Shareef, H. N.; Dimos, D.; Tuttle, B. A. Journal of Materials Research, Vol. 12, Issue 2 https://doi.org/10.1557/JMR.1997.0050	journal	February 1997

Cited By (4)

Zirconium‐Based Materials for Electrochemical Energy Storage Wang, Jianda; Xiao, Xiao; Lu, Yao ChemElectroChem, Vol. 6, Issue 7 https://doi.org/10.1002/celc.201801586	journal	February 2019
First Principle Material Genome Approach for All Solid‐State Batteries Xu, Hongjie; Yu, Yuran; Wang, Zhuo ENERGY & ENVIRONMENTAL MATERIALS, Vol. 2, Issue 4 https://doi.org/10.1002/eem2.12053	journal	September 2019
Enhanced alkaline stability in a hafnium-substituted NaSICON ion conductor Small, Leo J.; Wheeler, Jill S.; Ihlefeld, Jon F. Journal of Materials Chemistry A, Vol. 6, Issue 20 https://doi.org/10.1039/c7ta09924j	journal	January 2018
Theoretical formulation of Na ₃ AO ₄ X (A = S/Se, X = F/Cl) as high-performance solid electrolytes for all-solid-state sodium batteries Yu, Yuran; Wang, Zhuo; Shao, Guosheng Journal of Materials Chemistry A, Vol. 7, Issue 38 https://doi.org/10.1039/c9ta08584j	journal	January 2019

Similar Records

Pore-Filling Induced Solid Electrolyte Failure of Ti-Doped Na₃Zr₂Si₂PO₁₂ Characterized by Operando Synchrotron X-Ray Tomography

Journal Article · Tue Aug 13 04:00:00 UTC 2024 · Batteries & Supercaps · OSTI ID:2438855

Li, Mengya; Dixit, Marm; Shevchenko, Pavel; +3 more

Molecular Dynamics Modeling of the Structure and Na⁺-Ion Transport in Na₂S + SiS₂ Glassy Electrolytes

Journal Article · Wed Jun 20 04:00:00 UTC 2018 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1480490

Dive, A.; Benmore, C.; Wilding, M.; +3 more

Thermodynamics of NASICON (Na/sub 1+x/Zr/sub 2/Si/sub x/P/sub 3-x/O/sub 12/)

Journal Article · Fri Jan 01 04:00:00 UTC 1988 · J. Solid State Chem.; (United States) · OSTI ID:7201613

Warhus, U; Maier, J; Rabenau, A

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY

Title: Scaling effects in sodium zirconium silicate phosphate (Na1+xZr2SixP3-xO12) ion-conducting thin films

Citation Formats

References (38)

Cited By (4)

Similar Records

Related Subjects

Title: Scaling effects in sodium zirconium silicate phosphate (Na₁₊_xZr₂Si_xP_3-_xO₁₂) ion-conducting thin films