Scaling effects in sodium zirconium silicate phosphate (Na1+xZr2SixP3-xO12) ion-conducting thin films
Abstract
Preparation of sodium zirconium silicate phosphate (Na SIC on), Na 1+ x Z r 2 Si x P 3− x O 12 (0.25 ≤ x ≤ 1.0), thin films has been investigated via a chemical solution approach on platinized silicon substrates. Increasing the silicon content resulted in a reduction in the crystallite size and a reduction in the measured ionic conductivity. Processing temperature was also found to affect microstructure and ionic conductivity with higher processing temperatures resulting in larger crystallite sizes and higher ionic conductivities. The highest room temperature sodium ion conductivity was measured for an x = 0.25 composition at 2.3 × 10 −5 S/cm. The decreasing ionic conductivity trends with increasing silicon content and decreasing processing temperature are consistent with grain boundary and defect scattering of conducting ions.
- Authors:
-
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1262309
- Alternate Identifier(s):
- OSTI ID: 1401430
- Report Number(s):
- SAND-2016-6422J
Journal ID: ISSN 0002-7820; 643969
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Ceramic Society
- Additional Journal Information:
- Journal Name: Journal of the American Ceramic Society; Journal ID: ISSN 0002-7820
- Publisher:
- American Ceramic Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Ihlefeld, Jon F., Gurniak, Emily, Jones, Brad H., Wheeler, David R., Rodriguez, Mark A., and McDaniel, Anthony H. Scaling effects in sodium zirconium silicate phosphate (Na1+xZr2SixP3-xO12) ion-conducting thin films. United States: N. p., 2016.
Web. doi:10.1111/jace.14285.
Ihlefeld, Jon F., Gurniak, Emily, Jones, Brad H., Wheeler, David R., Rodriguez, Mark A., & McDaniel, Anthony H. Scaling effects in sodium zirconium silicate phosphate (Na1+xZr2SixP3-xO12) ion-conducting thin films. United States. https://doi.org/10.1111/jace.14285
Ihlefeld, Jon F., Gurniak, Emily, Jones, Brad H., Wheeler, David R., Rodriguez, Mark A., and McDaniel, Anthony H. Wed .
"Scaling effects in sodium zirconium silicate phosphate (Na1+xZr2SixP3-xO12) ion-conducting thin films". United States. https://doi.org/10.1111/jace.14285. https://www.osti.gov/servlets/purl/1262309.
@article{osti_1262309,
title = {Scaling effects in sodium zirconium silicate phosphate (Na1+xZr2SixP3-xO12) ion-conducting thin films},
author = {Ihlefeld, Jon F. and Gurniak, Emily and Jones, Brad H. and Wheeler, David R. and Rodriguez, Mark A. and McDaniel, Anthony H.},
abstractNote = {Preparation of sodium zirconium silicate phosphate (Na SIC on), Na 1+ x Z r 2 Si x P 3− x O 12 (0.25 ≤ x ≤ 1.0), thin films has been investigated via a chemical solution approach on platinized silicon substrates. Increasing the silicon content resulted in a reduction in the crystallite size and a reduction in the measured ionic conductivity. Processing temperature was also found to affect microstructure and ionic conductivity with higher processing temperatures resulting in larger crystallite sizes and higher ionic conductivities. The highest room temperature sodium ion conductivity was measured for an x = 0.25 composition at 2.3 × 10 −5 S/cm. The decreasing ionic conductivity trends with increasing silicon content and decreasing processing temperature are consistent with grain boundary and defect scattering of conducting ions.},
doi = {10.1111/jace.14285},
journal = {Journal of the American Ceramic Society},
number = ,
volume = ,
place = {United States},
year = {Wed May 04 00:00:00 EDT 2016},
month = {Wed May 04 00:00:00 EDT 2016}
}
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