The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)

Mashtalir, O.; Lukatskaya, Maria R.; Kolesnikov, Alexander I.; Raymundo-Pinero, E.; Naguib, Michael; Barsoum, M. W.; Gogotsi, Yury G.

doi:10.1039/C6NR01462C

Title: The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)

Journal Article · Fri Mar 25 00:00:00 EDT 2016 · Nanoscale

DOI: https://doi.org/10.1039/C6NR01462C · OSTI ID:1261319

Mashtalir, O. ^[1]; Lukatskaya, Maria R. ^[1]; Kolesnikov, Alexander I. ^[2]; Raymundo-Pinero, E. ^[3]; Naguib, Michael ^[2]; Barsoum, M. W. ^[1]; Gogotsi, Yury G. ^[1]

Drexel Univ., Philadelphia, PA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
CEMHTI-CNRS, Univ. Orleans, Orleans (France)

Herein we show that hydrazine intercalation into 2D titanium carbide (Ti₃C₂-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti₃C₂T_x layers pre-opening the structure and improving the accessability to active sites. Furthermore, the hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g^–1 in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source; Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261319

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 17 Vol. 8; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Title: The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)

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