The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)
Abstract
Herein we show that hydrazine intercalation into 2D titanium carbide (Ti3C2-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti3C2Tx layers pre-opening the structure and improving the accessability to active sites. Furthermore, the hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g–1 in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.
- Authors:
-
- Drexel Univ., Philadelphia, PA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- CEMHTI-CNRS, Univ. Orleans, Orleans (France)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1261319
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 17; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Mashtalir, O., Lukatskaya, Maria R., Kolesnikov, Alexander I., Raymundo-Pinero, E., Naguib, Michael, Barsoum, M. W., and Gogotsi, Yury G. The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene). United States: N. p., 2016.
Web. doi:10.1039/C6NR01462C.
Mashtalir, O., Lukatskaya, Maria R., Kolesnikov, Alexander I., Raymundo-Pinero, E., Naguib, Michael, Barsoum, M. W., & Gogotsi, Yury G. The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene). United States. https://doi.org/10.1039/C6NR01462C
Mashtalir, O., Lukatskaya, Maria R., Kolesnikov, Alexander I., Raymundo-Pinero, E., Naguib, Michael, Barsoum, M. W., and Gogotsi, Yury G. Fri .
"The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)". United States. https://doi.org/10.1039/C6NR01462C. https://www.osti.gov/servlets/purl/1261319.
@article{osti_1261319,
title = {The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)},
author = {Mashtalir, O. and Lukatskaya, Maria R. and Kolesnikov, Alexander I. and Raymundo-Pinero, E. and Naguib, Michael and Barsoum, M. W. and Gogotsi, Yury G.},
abstractNote = {Herein we show that hydrazine intercalation into 2D titanium carbide (Ti3C2-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti3C2Tx layers pre-opening the structure and improving the accessability to active sites. Furthermore, the hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g–1 in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.},
doi = {10.1039/C6NR01462C},
journal = {Nanoscale},
number = 17,
volume = 8,
place = {United States},
year = {Fri Mar 25 00:00:00 EDT 2016},
month = {Fri Mar 25 00:00:00 EDT 2016}
}
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