Impact of lubricant additives on the physicochemical properties and activity of three-way catalysts
Abstract
As alternative lubricant anti-wear additives are sought to reduce friction and improve overall fuel economy, it is important that these additives are also compatible with current emissions control catalysts. In the present work, an oil-miscible phosphorous-containing ionic liquid (IL), trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate ([P66614][DEHP]), is evaluated for its impact on three-way catalysts (TWC) and benchmarked against the industry standard zinc-dialkyl-dithio-phosphate (ZDDP). The TWCs are aged in different scenarios: neat gasoline (no-additive, or NA), gasoline+ZDDP, and gasoline+IL. The aged samples, along with the as received TWC, are characterized through various analytical techniques including catalyst reactivity evaluation in a bench-flow reactor. The temperatures of 50% conversion (T50) for the ZDDP-aged TWCs increased by 30, 24, and 25 °C for NO, CO, and C3H6, respectively, compared to the no-additive case. Although the IL-aged TWC also increased in T50 for CO and C3H6, it was notably less than ZDDP, 7 and 9 °C, respectively. Additionally, the IL-aged samples had higher water-gas-shift reactivity and oxygen storage capacity than the ZDDP-aged TWC. Characterization of the aged samples indicated the predominant presence of CePO4 in the ZDDP-aged TWC aged by ZDDP, while its formation was retarded in the case of IL where higher levels of AlPO4 is observed.more »
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- General Motors, Inc., Warren, MI (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Tenneco, Inc., Grass Lake, MI (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1253249
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysts
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 4; Journal ID: ISSN 2073-4344
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 33 ADVANCED PROPULSION SYSTEMS; three way catalysts; phosphorus deactivation; ZDDP; ionic liquid; lubricant additive
Citation Formats
Toops, Todd J., Lance, Michael J., Qu, Jun, Viola, Michael B, Lewis, Samuel Arthur, Leonard, Donovan N., Edward W. Hagaman, and Xie, Chao. Impact of lubricant additives on the physicochemical properties and activity of three-way catalysts. United States: N. p., 2016.
Web. doi:10.3390/catal6040054.
Toops, Todd J., Lance, Michael J., Qu, Jun, Viola, Michael B, Lewis, Samuel Arthur, Leonard, Donovan N., Edward W. Hagaman, & Xie, Chao. Impact of lubricant additives on the physicochemical properties and activity of three-way catalysts. United States. https://doi.org/10.3390/catal6040054
Toops, Todd J., Lance, Michael J., Qu, Jun, Viola, Michael B, Lewis, Samuel Arthur, Leonard, Donovan N., Edward W. Hagaman, and Xie, Chao. Mon .
"Impact of lubricant additives on the physicochemical properties and activity of three-way catalysts". United States. https://doi.org/10.3390/catal6040054. https://www.osti.gov/servlets/purl/1253249.
@article{osti_1253249,
title = {Impact of lubricant additives on the physicochemical properties and activity of three-way catalysts},
author = {Toops, Todd J. and Lance, Michael J. and Qu, Jun and Viola, Michael B and Lewis, Samuel Arthur and Leonard, Donovan N. and Edward W. Hagaman and Xie, Chao},
abstractNote = {As alternative lubricant anti-wear additives are sought to reduce friction and improve overall fuel economy, it is important that these additives are also compatible with current emissions control catalysts. In the present work, an oil-miscible phosphorous-containing ionic liquid (IL), trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate ([P66614][DEHP]), is evaluated for its impact on three-way catalysts (TWC) and benchmarked against the industry standard zinc-dialkyl-dithio-phosphate (ZDDP). The TWCs are aged in different scenarios: neat gasoline (no-additive, or NA), gasoline+ZDDP, and gasoline+IL. The aged samples, along with the as received TWC, are characterized through various analytical techniques including catalyst reactivity evaluation in a bench-flow reactor. The temperatures of 50% conversion (T50) for the ZDDP-aged TWCs increased by 30, 24, and 25 °C for NO, CO, and C3H6, respectively, compared to the no-additive case. Although the IL-aged TWC also increased in T50 for CO and C3H6, it was notably less than ZDDP, 7 and 9 °C, respectively. Additionally, the IL-aged samples had higher water-gas-shift reactivity and oxygen storage capacity than the ZDDP-aged TWC. Characterization of the aged samples indicated the predominant presence of CePO4 in the ZDDP-aged TWC aged by ZDDP, while its formation was retarded in the case of IL where higher levels of AlPO4 is observed. Furthermore, the results in this work indicate that the phosphonium-phosphate IL potentially has less adverse impact on TWC than ZDDP.},
doi = {10.3390/catal6040054},
journal = {Catalysts},
number = 4,
volume = 6,
place = {United States},
year = {Mon Apr 04 00:00:00 EDT 2016},
month = {Mon Apr 04 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Catalyst Deactivation Due to Glaze Formation from Oil-Derived Phosphorus and Zinc
conference, October 1984
- Williamson, W. B.; Perry, J.; Goss, R. L.
- 1984 SAE International Fall Fuels and Lubricants Meeting and Exhibition, SAE Technical Paper Series
The Impact of Passenger Car Motor Oil Phosphorus Levels on Engine Durability, Oil Degradation, and Exhaust Emissions in a Field Trial
conference, October 1995
- Culley, Scott A.; McDonnell, Thomas F.
- 1995 SAE International Fall Fuels and Lubricants Meeting and Exhibition, SAE Technical Paper Series
Effects of Oil-Derived Contaminants on Emissions from TWC-Equipped Vehicles
conference, June 2000
- Darr, S. T.; Choksi, R. A.; Hubbard, C. P.
- CEC/SAE Spring Fuels & Lubricants Meeting & Exposition, SAE Technical Paper Series
Characterization of phosphorus-poisoned automotive exhaust catalysts
journal, October 2001
- Rokosz, M. J.; Chen, A. E.; Lowe-Ma, C. K.
- Applied Catalysis B: Environmental, Vol. 33, Issue 3
Observation of cerium phosphate in aged automotive catalysts using Raman spectroscopy
journal, March 2003
- Uy, D.; O’Neill, A. E.; Xu, L.
- Applied Catalysis B: Environmental, Vol. 41, Issue 3
Deactivation of Diesel Oxidation Catalysts by Oil-Derived Phosphorus
conference, October 2006
- Eaton, Scott J.; Nguyen, Ke; Bunting, Bruce G.
- Powertrain & Fluid Systems Conference and Exhibition, SAE Technical Paper Series
Phosphorous Poisoning and Phosphorous Exhaust Chemistry with Diesel Oxidation Catalysts
conference, April 2005
- Bunting, Bruce G.; More, Karren; Lewis, Sam
- SAE 2005 World Congress & Exhibition, SAE Technical Paper Series
Development of an Engine-Based Catalytic Converter Poisoning Test to Assess the Impact of Volatile ZDDP Decomposition Products from Passenger Car Engine Oils
conference, October 2007
- Guinther, Gregory H.; Danner, Michael M.
- Powertrain & Fluid Systems Conference and Exhibition, SAE Technical Paper Series
Low Volatility ZDDP Technology: Part 2 - Exhaust Catalysts Performance in Field Applications
conference, October 2007
- Bardasz, Ewa A.; Schiferl, Elizabeth; Nahumck, William
- Powertrain & Fluid Systems Conference and Exhibition, SAE Technical Paper Series
Thermal and chemical aging of model three-way catalyst Pd/Al2O3 and its impact on the conversion of CNG vehicle exhaust
journal, April 2012
- Matam, Santhosh Kumar; Otal, E. H.; Aguirre, M. H.
- Catalysis Today, Vol. 184, Issue 1
Time resolved operando spectroscopic study of the origin of phosphorus induced chemical aging of model three-way catalysts Pd/Al2O3
journal, April 2013
- Matam, Santhosh Kumar; Newton, Mark A.; Weidenkaff, A.
- Catalysis Today, Vol. 205
Antiwear Performance and Mechanism of an Oil-Miscible Ionic Liquid as a Lubricant Additive
journal, February 2012
- Qu, Jun; Bansal, Dinesh G.; Yu, Bo
- ACS Applied Materials & Interfaces, Vol. 4, Issue 2, p. 997-1002
Comparison of an oil-miscible ionic liquid and ZDDP as a lubricant anti-wear additive
journal, March 2014
- Qu, Jun; Luo, Huimin; Chi, Miaofang
- Tribology International, Vol. 71, p. 88-97
Phosphonium-Organophosphate Ionic Liquids as Lubricant Additives: Effects of Cation Structure on Physicochemical and Tribological Characteristics
journal, December 2014
- Barnhill, William C.; Qu, Jun; Luo, Huimin
- ACS Applied Materials & Interfaces, Vol. 6, Issue 24
Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives
journal, July 2015
- Qu, Jun; Barnhill, William C.; Luo, Huimin
- Advanced Materials, Vol. 27, Issue 32
Tribological Bench and Engine Dynamometer Tests of a Low Viscosity SAE 0W-16 Engine Oil Using a Combination of Ionic Liquid and ZDDP as Anti-Wear Additives
journal, September 2015
- Barnhill, William C.; Gao, Hong; Kheireddin, Bassem
- Frontiers in Mechanical Engineering, Vol. 1
Lubricating Oil Consumption on the Standard Road Cycle
conference, April 2013
- West, Brian; Sluder, C. Scott
- SAE 2013 World Congress & Exhibition, SAE Technical Paper Series
Impact of sulfation and desulfation on NO reduction using Cu-chabazite SCR catalysts
journal, December 2015
- Brookshear, D. William; Nam, Jeong-gil; Nguyen, Ke
- Catalysis Today, Vol. 258
CHARACTERIZATION OF POLYMORPHIC CERIUM PHOSPHATES AS STUDIED BY SOLID-STATE HIGH-RESOLUTION <SUP>31</SUP>P NMR
journal, January 1998
- Nakayama, Hirokazu; Hayashi, Aki; Tsuhako, Mitsutomo
- Phosphorus Research Bulletin, Vol. 8, Issue 0
Deactivation of real three way catalysts by CePO4 formation
journal, February 2003
- Larese, C.
- Applied Catalysis B: Environmental, Vol. 40, Issue 4
Role of P-containing species in phosphated CeO2 in the deterioration of its oxygen storage and release properties
journal, April 2006
- Lopezgranados, M.; Galisteo, F.; Lambrou, P.
- Journal of Catalysis, Vol. 239, Issue 2
Works referencing / citing this record:
Impact of Lubricant Oil Additives on the Performance of Pd-Based Three-Way Catalysts
journal, September 2019
- Kim, Daekun; Toops, Todd J.; Nguyen, Ke
- Emission Control Science and Technology, Vol. 6, Issue 2
Combination of a protic ionic liquid-like surfactant and biocompatible solvents to generate environmentally friendly anionic reverse micelles
journal, January 2019
- Dib, Nahir; Silber, Juana J.; Correa, N. Mariano
- New Journal of Chemistry, Vol. 43, Issue 26
Non-halogenated Ionic Liquid Dramatically Enhances Tribological Performance of Biodegradable Oils
journal, February 2019
- Rohlmann, Patrick; Munavirov, Bulat; Furó, István
- Frontiers in Chemistry, Vol. 7
Understanding Tribofilm Formation Mechanisms in Ionic Liquid Lubrication
journal, August 2017
- Zhou, Yan; Leonard, Donovan N.; Guo, Wei
- Scientific Reports, Vol. 7, Issue 1