Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000

Wang, Timothy C.; Vermeulen, Nicolaas A.; Kim, In Soo; Martinson, Alex B. F.; Stoddart, J. Fraser; Hupp, Joseph T.; Farha, Omar K.

doi:10.1038/nprot.2016.001

Title: Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000

Journal Article · 17 December 2015 · Nature Protocols

DOI: https://doi.org/10.1038/nprot.2016.001 · OSTI ID:1249523

^[1]; Vermeulen, Nicolaas A. ^[1]; Kim, In Soo ^[2]; Martinson, Alex B. F. ^[2]; Stoddart, J. Fraser ^[1]; Hupp, Joseph T. ^[1]; Farha, Omar K. ^[3]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry

The synthesis of NU-1000, a mesoporous metal-organic framework (MOF), can be conducted efficiently on a multigram scale from inexpensive starting materials. NU-1000 has been reported as an excellent candidate for gas separation and catalysis. In particular, it is ideal for the catalytic deactivation of nerve agents and shows great promise as a new generic platform for a wide range of applications. Multiple post-synthetic modification protocols have been developed using NU-1000 as the parent material, making it a potentially useful scaffold for several catalytic applications. The procedure for the preparation of NU-1000 can be scaled up reliably, and it is suitable for the production of 50 g of the tetracarboxylic acid containing organic linker and 200 mg–2.5 g of NU-1000. Lastly, the entire synthesis is performed without purification by column chromatography and can be completed within 10 d.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0012702

OSTI ID:: 1249523

Journal Information:: Nature Protocols, Vol. 11, Issue 1; ISSN 1754-2189

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 240 works

Citation information provided by
Web of Science

References (27)

Hybrid porous solids past, present, future Férey, Gérard Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214 https://doi.org/10.1039/B618320B	journal	January 2008
Soft porous crystals Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu Nature Chemistry, Vol. 1, Issue 9, p. 695-704 https://doi.org/10.1038/nchem.444	journal	November 2009
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials Farha, Omar K.; Hupp, Joseph T. Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175 https://doi.org/10.1021/ar1000617	journal	August 2010
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim Nature Chemistry, Vol. 2, Issue 11, p. 944-948 https://doi.org/10.1038/nchem.834	journal	September 2010
Hydrogen Storage in Metal–Organic Frameworks Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri Chemical Reviews, Vol. 112, Issue 2, p. 782-835 https://doi.org/10.1021/cr200274s	journal	September 2011
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021 https://doi.org/10.1021/ja3055639	journal	August 2012
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO₂ Adsorption Studies Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804 https://doi.org/10.1021/ja408959g	journal	October 2013
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Metal–organic framework materials for light-harvesting and energy transfer So, Monica C.; Wiederrecht, Gary P.; Mondloch, Joseph E. Chemical Communications, Vol. 51, Issue 17 https://doi.org/10.1039/C4CC09596K	journal	January 2015
Nanoscale Metal–Organic Frameworks for the Co-Delivery of Cisplatin and Pooled siRNAs to Enhance Therapeutic Efficacy in Drug-Resistant Ovarian Cancer Cells He, Chunbai; Lu, Kuangda; Liu, Demin Journal of the American Chemical Society, Vol. 136, Issue 14 https://doi.org/10.1021/ja4098862	journal	February 2014
Multirate delivery of multiple therapeutic agents from metal-organic frameworks McKinlay, Alistair C.; Allan, Phoebe K.; Renouf, Catherine L. APL Materials, Vol. 2, Issue 12 https://doi.org/10.1063/1.4903290	journal	December 2014
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828	journal	May 2013
MOF Functionalization via Solvent-Assisted Ligand Incorporation: Phosphonates vs Carboxylates Deria, Pravas; Bury, Wojciech; Hod, Idan Inorganic Chemistry, Vol. 54, Issue 5 https://doi.org/10.1021/ic502639v	journal	February 2015
The kagomé net: Band theoretical and topological aspects Johnston, Roy L.; Hoffmann, Roald Polyhedron, Vol. 9, Issue 15-16 https://doi.org/10.1016/S0277-5387(00)84002-4	journal	January 1990
Defining the Proton Topology of the Zr₆-Based Metal–Organic Framework NU-1000 Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723 https://doi.org/10.1021/jz501899j	journal	October 2014
Are Zr ₆ -based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse Mondloch, Joseph E.; Katz, Michael J.; Planas, Nora Chemical Communications, Vol. 50, Issue 64 https://doi.org/10.1039/C4CC02401J	journal	January 2014
A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO₂ Fixation and Regioselective and Enantioretentive Epoxide Activation Beyzavi, M. Hassan; Klet, Rachel C.; Tussupbayev, Samat Journal of the American Chemical Society, Vol. 136, Issue 45, p. 15861-15864 https://doi.org/10.1021/ja508626n	journal	October 2014
Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants Katz, Michael J.; Mondloch, Joseph E.; Totten, Ryan K. Angewandte Chemie International Edition, Vol. 53, Issue 2, p. 497-501 https://doi.org/10.1002/anie.201307520	journal	November 2013
Destruction of chemical warfare agents using metal–organic frameworks Mondloch, Joseph E.; Katz, Michael J.; Isley III, William C. Nature Materials, Vol. 14, Issue 5 https://doi.org/10.1038/nmat4238	journal	March 2015
Directed Growth of Electroactive Metal-Organic Framework Thin Films Using Electrophoretic Deposition Hod, Idan; Bury, Wojciech; Karlin, David M. Advanced Materials, Vol. 26, Issue 36 https://doi.org/10.1002/adma.201401940	journal	July 2014
A MOF platform for incorporation of complementary organic motifs for CO ₂ binding Deria, Pravas; Li, Song; Zhang, Hongda Chemical Communications, Vol. 51, Issue 62 https://doi.org/10.1039/C5CC04808G	journal	January 2015
Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound Hod, Idan; Bury, Wojciech; Gardner, Daniel M. The Journal of Physical Chemistry Letters, Vol. 6, Issue 4 https://doi.org/10.1021/acs.jpclett.5b00019	journal	February 2015
Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants Katz, Michael J.; Mondloch, Joseph E.; Totten, Ryan K. Angewandte Chemie, Vol. 126, Issue 2 https://doi.org/10.1002/ange.201307520	journal	November 2013

Cited By (24)

The Chemistry of Reticular Framework Nanoparticles: MOF, ZIF, and COF Materials Ploetz, Evelyn; Engelke, Hanna; Lächelt, Ulrich Advanced Functional Materials, Vol. 30, Issue 41 https://doi.org/10.1002/adfm.201909062	journal	February 2020
Heterogeneous Catalysis in Zeolites, Mesoporous Silica, and Metal-Organic Frameworks Liang, Jie; Liang, Zibin; Zou, Ruqiang Advanced Materials, Vol. 29, Issue 30 https://doi.org/10.1002/adma.201701139	journal	June 2017
Stable Metal-Organic Frameworks: Design, Synthesis, and Applications Yuan, Shuai; Feng, Liang; Wang, Kecheng Advanced Materials, Vol. 30, Issue 37 https://doi.org/10.1002/adma.201704303	journal	February 2018
Pore-Environment Engineering with Multiple Metal Sites in Rare-Earth Porphyrinic Metal-Organic Frameworks Zhang, Liangliang; Yuan, Shuai; Feng, Liang Angewandte Chemie, Vol. 130, Issue 18 https://doi.org/10.1002/ange.201802661	journal	March 2018
A Reusable MOF‐Supported Single‐Site Zinc(II) Catalyst for Efficient Intramolecular Hydroamination of o ‐Alkynylanilines Li, Beibei; Ju, Zhanfeng; Zhou, Mi Angewandte Chemie, Vol. 131, Issue 23 https://doi.org/10.1002/ange.201902171	journal	May 2019
A Reusable MOF-Supported Single-Site Zinc(II) Catalyst for Efficient Intramolecular Hydroamination of o -Alkynylanilines Li, Beibei; Ju, Zhanfeng; Zhou, Mi Angewandte Chemie International Edition, Vol. 58, Issue 23 https://doi.org/10.1002/anie.201902171	journal	May 2019
Metal–Organic Gels Derived from Iron(III) and Pyridine Ligands: Morphology, Self‐Healing and Catalysis for Ethylene Selective Dimerization Li, Botian; Zhou, Xue; Liu, Xiangyun Chemistry – An Asian Journal, Vol. 14, Issue 9 https://doi.org/10.1002/asia.201900131	journal	March 2019
Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard Howarth, Ashlee J.; Buru, Cassandra T.; Liu, Yangyang Chemistry - A European Journal, Vol. 23, Issue 1 https://doi.org/10.1002/chem.201604972	journal	November 2016
Metal–Organic Framework (MOF)‐Based Materials as Heterogeneous Catalysts for C−H Bond Activation Liu, Mengjia; Wu, Jie; Hou, Hongwei Chemistry – A European Journal https://doi.org/10.1002/chem.201804149	journal	December 2018
Disappearing Polymorphs in Metal–Organic Framework Chemistry: Unexpected Stabilization of a Layered Polymorph over an Interpenetrated Three‐Dimensional Structure in Mercury Imidazolate Speight, Isaiah R.; Huskić, Igor; Arhangelskis, Mihails Chemistry – A European Journal, Vol. 26, Issue 8 https://doi.org/10.1002/chem.201905280	journal	November 2019
Mesoporous Metal-Organic Frameworks: Synthetic Strategies and Emerging Applications Liu, Dingxin; Zou, Dianting; Zhu, Haolin Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201801454	journal	August 2018
Alkylated Meso-Macroporous Metal-Organic Framework Hollow Tubes as Nanocontainers of Octadecane for Energy Storage and Thermal Regulation Tang, Jia; Chen, Xingyu; Zhang, Liguo Small, Vol. 14, Issue 35 https://doi.org/10.1002/smll.201801970	journal	August 2018
Three coordination polymers constructed from succinic acid and 1,4-bis(1H-imidazol-4-yl)benzene: synthesis, crystal structures, and properties Wang, Li-Na; Zhang, Yan-Hong; Wang, Zuo-Peng Transition Metal Chemistry, Vol. 43, Issue 6 https://doi.org/10.1007/s11243-018-0235-3	journal	April 2018
Wheat flour-derived N-doped mesoporous carbon extrudate as superior metal-free catalysts for acetylene hydrochlorination Lan, Guojun; Wang, Yan; Qiu, Yiyang Chemical Communications, Vol. 54, Issue 6 https://doi.org/10.1039/c7cc09370e	journal	January 2018
Effect of asphaltene precipitation on CO ₂ -flooding performance in low-permeability sandstones: a nuclear magnetic resonance study Wang, Chen; Li, Tiantai; Gao, Hui RSC Advances, Vol. 7, Issue 61 https://doi.org/10.1039/c7ra06392j	journal	January 2017
Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework Islamoglu, Timur; Otake, Ken-ichi; Li, Peng CrystEngComm, Vol. 20, Issue 39 https://doi.org/10.1039/c8ce00455b	journal	January 2018
Highly stable and porous porphyrin-based zirconium and hafnium phosphonates – electron crystallography as an important tool for structure elucidation Rhauderwiek, Timo; Zhao, Haishuang; Hirschle, Patrick Chemical Science, Vol. 9, Issue 24 https://doi.org/10.1039/c8sc01533c	journal	January 2018
Structure–property relationship of metal–organic frameworks for alcohol-based adsorption-driven heat pumps via high-throughput computational screening Li, Wei; Xia, Xiaoxiao; Cao, Meng Journal of Materials Chemistry A, Vol. 7, Issue 13 https://doi.org/10.1039/c8ta07909a	journal	January 2019
An effective strategy for creating asymmetric MOFs for chirality induction: a chiral Zr-based MOF for enantioselective epoxidation Berijani, Kayhaneh; Morsali, Ali; Hupp, Joseph T. Catalysis Science & Technology, Vol. 9, Issue 13 https://doi.org/10.1039/c9cy00565j	journal	January 2019
Insights into the water adsorption mechanism in the chemically stable zirconium-based MOF DUT-67 – a prospective material for adsorption-driven heat transformations Bon, Volodymyr; Senkovska, Irena; Evans, Jack D. Journal of Materials Chemistry A, Vol. 7, Issue 20 https://doi.org/10.1039/c9ta00825j	journal	January 2019
Unusual Fluorescence Behavior of Pyrene-Amine Containing Dendrimers Ruiu, Andrea; Vonlanthen, Mireille; Rojas-Montoya, Sandra M. Molecules, Vol. 24, Issue 22 https://doi.org/10.3390/molecules24224083	journal	November 2019
Towards Generalized Noise-Level Dependent Crystallographic Symmetry Classifications of More or Less Periodic Crystal Patterns Moeck, Peter Symmetry, Vol. 10, Issue 5 https://doi.org/10.3390/sym10050133	journal	April 2018
Pore-Environment Engineering with Multiple Metal Sites in Rare-Earth Porphyrinic Metal-Organic Frameworks Zhang, Liangliang; Yuan, Shuai; Feng, Liang Angewandte Chemie International Edition, Vol. 57, Issue 18 https://doi.org/10.1002/anie.201802661	journal	March 2018
Oxidative Dehydrogenation of Propane in the Realm of Metal–Organic Frameworks Korzyński, Maciej Damian; Dincă, Mircea ACS Central Science, Vol. 3, Issue 1 https://doi.org/10.1021/acscentsci.7b00013	journal	January 2017

Similar Records

Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000

Journal Article · 2015 · Nature Protocols · OSTI ID:1387253

Wang, Timothy C.; Vermeulen, Nicolaas A.; Kim, In Soo; +4 more

Role of a Modulator in the Synthesis of Phase-Pure NU-1000

Journal Article · 2017 · ACS Applied Materials and Interfaces · OSTI ID:1470050

Webber, Thomas E.; Liu, Wei-Guang; Desai, Sai Puneet; +3 more

Isomer of linker for NU-1000 yields a new she-type, catalytic, and hierarchically porous, Zr-based metal–organic framework

Journal Article · 2021 · ChemComm · OSTI ID:1778900

Lu, Zhiyong; Wang, Rui; Liao, Yijun; +7 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Metal-organic framework
NU-1000
mesoporous

Title: Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000

Citation Formats

References (27)

Cited By (24)

Similar Records

Related Subjects