Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000
Abstract
The synthesis of NU-1000, a mesoporous metal-organic framework (MOF), can be conducted efficiently on a multigram scale from inexpensive starting materials. NU-1000 has been reported as an excellent candidate for gas separation and catalysis. In particular, it is ideal for the catalytic deactivation of nerve agents and shows great promise as a new generic platform for a wide range of applications. Multiple post-synthetic modification protocols have been developed using NU-1000 as the parent material, making it a potentially useful scaffold for several catalytic applications. The procedure for the preparation of NU-1000 can be scaled up reliably, and it is suitable for the production of 50 g of the tetracarboxylic acid containing organic linker and 200 mg–2.5 g of NU-1000. Lastly, the entire synthesis is performed without purification by column chromatography and can be completed within 10 d.
- Authors:
-
[1];
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1249523
- Grant/Contract Number:
- AC02-06CH11357; SC0012702
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Protocols
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 1; Journal ID: ISSN 1754-2189
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Metal-organic framework; NU-1000; mesoporous
Citation Formats
Wang, Timothy C., Vermeulen, Nicolaas A., Kim, In Soo, Martinson, Alex B. F., Stoddart, J. Fraser, Hupp, Joseph T., and Farha, Omar K. Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000. United States: N. p., 2015.
Web. doi:10.1038/nprot.2016.001.
Wang, Timothy C., Vermeulen, Nicolaas A., Kim, In Soo, Martinson, Alex B. F., Stoddart, J. Fraser, Hupp, Joseph T., & Farha, Omar K. Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000. United States. https://doi.org/10.1038/nprot.2016.001
Wang, Timothy C., Vermeulen, Nicolaas A., Kim, In Soo, Martinson, Alex B. F., Stoddart, J. Fraser, Hupp, Joseph T., and Farha, Omar K. Thu .
"Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000". United States. https://doi.org/10.1038/nprot.2016.001. https://www.osti.gov/servlets/purl/1249523.
@article{osti_1249523,
title = {Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000},
author = {Wang, Timothy C. and Vermeulen, Nicolaas A. and Kim, In Soo and Martinson, Alex B. F. and Stoddart, J. Fraser and Hupp, Joseph T. and Farha, Omar K.},
abstractNote = {The synthesis of NU-1000, a mesoporous metal-organic framework (MOF), can be conducted efficiently on a multigram scale from inexpensive starting materials. NU-1000 has been reported as an excellent candidate for gas separation and catalysis. In particular, it is ideal for the catalytic deactivation of nerve agents and shows great promise as a new generic platform for a wide range of applications. Multiple post-synthetic modification protocols have been developed using NU-1000 as the parent material, making it a potentially useful scaffold for several catalytic applications. The procedure for the preparation of NU-1000 can be scaled up reliably, and it is suitable for the production of 50 g of the tetracarboxylic acid containing organic linker and 200 mg–2.5 g of NU-1000. Lastly, the entire synthesis is performed without purification by column chromatography and can be completed within 10 d.},
doi = {10.1038/nprot.2016.001},
journal = {Nature Protocols},
number = 1,
volume = 11,
place = {United States},
year = {Thu Dec 17 00:00:00 EST 2015},
month = {Thu Dec 17 00:00:00 EST 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 220 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Hybrid porous solids past, present, future
journal, January 2008
- Férey, Gérard
- Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
Soft porous crystals
journal, November 2009
- Horike, Satoshi; Shimomura, Satoru; Kitagawa, Susumu
- Nature Chemistry, Vol. 1, Issue 9, p. 695-704
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials
journal, August 2010
- Farha, Omar K.; Hupp, Joseph T.
- Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175
Hydrogen storage in metal–organic frameworks
journal, January 2009
- Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010
- Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
- Nature Chemistry, Vol. 2, Issue 11, p. 944-948
Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011
- Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
- Chemical Reviews, Vol. 112, Issue 2, p. 782-835
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
journal, August 2012
- Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon
- Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021
Metal–Organic Frameworks for Separations
journal, September 2011
- Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
- Chemical Reviews, Vol. 112, Issue 2, p. 869-932
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013
- Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
- Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
Metal–organic framework materials as catalysts
journal, January 2009
- Lee, JeongYong; Farha, Omar K.; Roberts, John
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Metal–organic framework materials for light-harvesting and energy transfer
journal, January 2015
- So, Monica C.; Wiederrecht, Gary P.; Mondloch, Joseph E.
- Chemical Communications, Vol. 51, Issue 17
Nanoscale Metal–Organic Frameworks for the Co-Delivery of Cisplatin and Pooled siRNAs to Enhance Therapeutic Efficacy in Drug-Resistant Ovarian Cancer Cells
journal, February 2014
- He, Chunbai; Lu, Kuangda; Liu, Demin
- Journal of the American Chemical Society, Vol. 136, Issue 14
Multirate delivery of multiple therapeutic agents from metal-organic frameworks
journal, December 2014
- McKinlay, Alistair C.; Allan, Phoebe K.; Renouf, Catherine L.
- APL Materials, Vol. 2, Issue 12
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
- Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
- Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation
journal, January 2014
- Deria, Pravas; Bury, Wojciech; Hupp, Joseph T.
- Chemical Communications, Vol. 50, Issue 16, p. 1965-1968
MOF Functionalization via Solvent-Assisted Ligand Incorporation: Phosphonates vs Carboxylates
journal, February 2015
- Deria, Pravas; Bury, Wojciech; Hod, Idan
- Inorganic Chemistry, Vol. 54, Issue 5
The kagomé net: Band theoretical and topological aspects
journal, January 1990
- Johnston, Roy L.; Hoffmann, Roald
- Polyhedron, Vol. 9, Issue 15-16
Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
journal, October 2014
- Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
Are Zr 6 -based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse
journal, January 2014
- Mondloch, Joseph E.; Katz, Michael J.; Planas, Nora
- Chemical Communications, Vol. 50, Issue 64
A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
journal, October 2014
- Beyzavi, M. Hassan; Klet, Rachel C.; Tussupbayev, Samat
- Journal of the American Chemical Society, Vol. 136, Issue 45, p. 15861-15864
Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
journal, November 2013
- Katz, Michael J.; Mondloch, Joseph E.; Totten, Ryan K.
- Angewandte Chemie International Edition, Vol. 53, Issue 2, p. 497-501
Destruction of chemical warfare agents using metal–organic frameworks
journal, March 2015
- Mondloch, Joseph E.; Katz, Michael J.; Isley III, William C.
- Nature Materials, Vol. 14, Issue 5
Directed Growth of Electroactive Metal-Organic Framework Thin Films Using Electrophoretic Deposition
journal, July 2014
- Hod, Idan; Bury, Wojciech; Karlin, David M.
- Advanced Materials, Vol. 26, Issue 36
A MOF platform for incorporation of complementary organic motifs for CO 2 binding
journal, January 2015
- Deria, Pravas; Li, Song; Zhang, Hongda
- Chemical Communications, Vol. 51, Issue 62
Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound
journal, February 2015
- Hod, Idan; Bury, Wojciech; Gardner, Daniel M.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 4
Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
journal, November 2013
- Katz, Michael J.; Mondloch, Joseph E.; Totten, Ryan K.
- Angewandte Chemie, Vol. 126, Issue 2
Works referencing / citing this record:
The Chemistry of Reticular Framework Nanoparticles: MOF, ZIF, and COF Materials
journal, February 2020
- Ploetz, Evelyn; Engelke, Hanna; Lächelt, Ulrich
- Advanced Functional Materials, Vol. 30, Issue 41
Heterogeneous Catalysis in Zeolites, Mesoporous Silica, and Metal-Organic Frameworks
journal, June 2017
- Liang, Jie; Liang, Zibin; Zou, Ruqiang
- Advanced Materials, Vol. 29, Issue 30
Stable Metal-Organic Frameworks: Design, Synthesis, and Applications
journal, February 2018
- Yuan, Shuai; Feng, Liang; Wang, Kecheng
- Advanced Materials, Vol. 30, Issue 37
Pore-Environment Engineering with Multiple Metal Sites in Rare-Earth Porphyrinic Metal-Organic Frameworks
journal, March 2018
- Zhang, Liangliang; Yuan, Shuai; Feng, Liang
- Angewandte Chemie, Vol. 130, Issue 18
A Reusable MOF‐Supported Single‐Site Zinc(II) Catalyst for Efficient Intramolecular Hydroamination of o ‐Alkynylanilines
journal, May 2019
- Li, Beibei; Ju, Zhanfeng; Zhou, Mi
- Angewandte Chemie, Vol. 131, Issue 23
A Reusable MOF-Supported Single-Site Zinc(II) Catalyst for Efficient Intramolecular Hydroamination of o -Alkynylanilines
journal, May 2019
- Li, Beibei; Ju, Zhanfeng; Zhou, Mi
- Angewandte Chemie International Edition, Vol. 58, Issue 23
Metal–Organic Gels Derived from Iron(III) and Pyridine Ligands: Morphology, Self‐Healing and Catalysis for Ethylene Selective Dimerization
journal, March 2019
- Li, Botian; Zhou, Xue; Liu, Xiangyun
- Chemistry – An Asian Journal, Vol. 14, Issue 9
Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard
journal, November 2016
- Howarth, Ashlee J.; Buru, Cassandra T.; Liu, Yangyang
- Chemistry - A European Journal, Vol. 23, Issue 1
Metal–Organic Framework (MOF)‐Based Materials as Heterogeneous Catalysts for C−H Bond Activation
journal, December 2018
- Liu, Mengjia; Wu, Jie; Hou, Hongwei
- Chemistry – A European Journal
Disappearing Polymorphs in Metal–Organic Framework Chemistry: Unexpected Stabilization of a Layered Polymorph over an Interpenetrated Three‐Dimensional Structure in Mercury Imidazolate
journal, November 2019
- Speight, Isaiah R.; Huskić, Igor; Arhangelskis, Mihails
- Chemistry – A European Journal, Vol. 26, Issue 8
Mesoporous Metal-Organic Frameworks: Synthetic Strategies and Emerging Applications
journal, August 2018
- Liu, Dingxin; Zou, Dianting; Zhu, Haolin
- Small, Vol. 14, Issue 37
Alkylated Meso-Macroporous Metal-Organic Framework Hollow Tubes as Nanocontainers of Octadecane for Energy Storage and Thermal Regulation
journal, August 2018
- Tang, Jia; Chen, Xingyu; Zhang, Liguo
- Small, Vol. 14, Issue 35
Three coordination polymers constructed from succinic acid and 1,4-bis(1H-imidazol-4-yl)benzene: synthesis, crystal structures, and properties
journal, April 2018
- Wang, Li-Na; Zhang, Yan-Hong; Wang, Zuo-Peng
- Transition Metal Chemistry, Vol. 43, Issue 6
Wheat flour-derived N-doped mesoporous carbon extrudate as superior metal-free catalysts for acetylene hydrochlorination
journal, January 2018
- Lan, Guojun; Wang, Yan; Qiu, Yiyang
- Chemical Communications, Vol. 54, Issue 6
MOFs vs. zeolites: carbonyl activation with M( iv ) catalytic sites
journal, January 2017
- Cirujano, Francisco G.
- Catalysis Science & Technology, Vol. 7, Issue 23
Tuning the properties of metal–organic framework nodes as supports of single-site iridium catalysts: node modification by atomic layer deposition of aluminium
journal, January 2017
- Yang, Dong; Momeni, Mohammad R.; Demir, Hakan
- Faraday Discussions, Vol. 201
Assembly of dicobalt and cobalt–aluminum oxide clusters on metal–organic framework and nanocast silica supports
journal, January 2017
- Desai, Sai Puneet; Malonzo, Camille D.; Webber, Thomas
- Faraday Discussions, Vol. 201
Effect of asphaltene precipitation on CO 2 -flooding performance in low-permeability sandstones: a nuclear magnetic resonance study
journal, January 2017
- Wang, Chen; Li, Tiantai; Gao, Hui
- RSC Advances, Vol. 7, Issue 61
Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework
journal, January 2018
- Islamoglu, Timur; Otake, Ken-ichi; Li, Peng
- CrystEngComm, Vol. 20, Issue 39
Highly stable and porous porphyrin-based zirconium and hafnium phosphonates – electron crystallography as an important tool for structure elucidation
journal, January 2018
- Rhauderwiek, Timo; Zhao, Haishuang; Hirschle, Patrick
- Chemical Science, Vol. 9, Issue 24
Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects
journal, January 2018
- Buru, Cassandra T.; Platero-Prats, Ana. E.; Chica, Daniel G.
- Journal of Materials Chemistry A, Vol. 6, Issue 17
Structure–property relationship of metal–organic frameworks for alcohol-based adsorption-driven heat pumps via high-throughput computational screening
journal, January 2019
- Li, Wei; Xia, Xiaoxiao; Cao, Meng
- Journal of Materials Chemistry A, Vol. 7, Issue 13
An effective strategy for creating asymmetric MOFs for chirality induction: a chiral Zr-based MOF for enantioselective epoxidation
journal, January 2019
- Berijani, Kayhaneh; Morsali, Ali; Hupp, Joseph T.
- Catalysis Science & Technology, Vol. 9, Issue 13
Insights into the water adsorption mechanism in the chemically stable zirconium-based MOF DUT-67 – a prospective material for adsorption-driven heat transformations
journal, January 2019
- Bon, Volodymyr; Senkovska, Irena; Evans, Jack D.
- Journal of Materials Chemistry A, Vol. 7, Issue 20
Unusual Fluorescence Behavior of Pyrene-Amine Containing Dendrimers
journal, November 2019
- Ruiu, Andrea; Vonlanthen, Mireille; Rojas-Montoya, Sandra M.
- Molecules, Vol. 24, Issue 22
Towards Generalized Noise-Level Dependent Crystallographic Symmetry Classifications of More or Less Periodic Crystal Patterns
journal, April 2018
- Moeck, Peter
- Symmetry, Vol. 10, Issue 5
Pore-Environment Engineering with Multiple Metal Sites in Rare-Earth Porphyrinic Metal-Organic Frameworks
journal, March 2018
- Zhang, Liangliang; Yuan, Shuai; Feng, Liang
- Angewandte Chemie International Edition, Vol. 57, Issue 18
Oxidative Dehydrogenation of Propane in the Realm of Metal–Organic Frameworks
journal, January 2017
- Korzyński, Maciej Damian; Dincă, Mircea
- ACS Central Science, Vol. 3, Issue 1