Oxidation of alloys for energy applications in supercritical CO2 and H2O
Abstract
To facilitate development of supercritical CO2 (sCO2) power plants, a comparison of the oxidation behavior of austenitic stainless steels and Ni-base alloys in sH2O and sCO2 were made. Experiments were conducted at 730 °C/207 bar (sCO2) and 726 °C/208 bar (sH2O). Ni-base alloys in sCO2 did not exhibit much change with pressure. Ni-base alloys in sH2O had an increase in corrosion rate and the log of the parabolic rate constant was proportional to pressure. Lastly, fine-grain austenitic stainless steels in sCO2 and sH2O were both less protective with pressure as the dense protective chromia scale was replaced with faster growing Fe-oxide rich scales.
- Authors:
-
- National Energy Technology Lab. (NETL), Albany, OR (United States)
- National Energy Technology Lab. (NETL), Albany, OR (United States); AECOM, Albany, OR (United States)
- Publication Date:
- Research Org.:
- National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1247687
- Report Number(s):
- NETL-PUB-20231
Journal ID: ISSN 0010-938X; PII: S0010938X16301184
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Corrosion Science
- Additional Journal Information:
- Journal Volume: 109; Journal Issue: C; Journal ID: ISSN 0010-938X
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Supercritical CO2, Supercritical H2O, austenitic stainless steel, Ni-base superalloys, oxidation
Citation Formats
Holcomb, Gordon R., Carney, Casey, and Doğan, Ömer N. Oxidation of alloys for energy applications in supercritical CO2 and H2O. United States: N. p., 2016.
Web. doi:10.1016/j.corsci.2016.03.018.
Holcomb, Gordon R., Carney, Casey, & Doğan, Ömer N. Oxidation of alloys for energy applications in supercritical CO2 and H2O. United States. https://doi.org/10.1016/j.corsci.2016.03.018
Holcomb, Gordon R., Carney, Casey, and Doğan, Ömer N. Sat .
"Oxidation of alloys for energy applications in supercritical CO2 and H2O". United States. https://doi.org/10.1016/j.corsci.2016.03.018. https://www.osti.gov/servlets/purl/1247687.
@article{osti_1247687,
title = {Oxidation of alloys for energy applications in supercritical CO2 and H2O},
author = {Holcomb, Gordon R. and Carney, Casey and Doğan, Ömer N.},
abstractNote = {To facilitate development of supercritical CO2 (sCO2) power plants, a comparison of the oxidation behavior of austenitic stainless steels and Ni-base alloys in sH2O and sCO2 were made. Experiments were conducted at 730 °C/207 bar (sCO2) and 726 °C/208 bar (sH2O). Ni-base alloys in sCO2 did not exhibit much change with pressure. Ni-base alloys in sH2O had an increase in corrosion rate and the log of the parabolic rate constant was proportional to pressure. Lastly, fine-grain austenitic stainless steels in sCO2 and sH2O were both less protective with pressure as the dense protective chromia scale was replaced with faster growing Fe-oxide rich scales.},
doi = {10.1016/j.corsci.2016.03.018},
journal = {Corrosion Science},
number = C,
volume = 109,
place = {United States},
year = {Sat Mar 19 00:00:00 EDT 2016},
month = {Sat Mar 19 00:00:00 EDT 2016}
}
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Works referencing / citing this record:
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