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Title: Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries

Abstract

Polymer gel electrolyte using AlCl3 complexed acrylamide as functional monomer and ionic liquids based on acidic mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and AlCl3 as plasticizer has been successfully prepared for the first time by free radical polymerization. Aluminum deposition is successfully obtained with a polymer gel membrane contianing 80 wt% ionic liquid. As a result, the polymer gel membranes are also good candidates for rechargeable aluminum ion batteries.

Authors:
 [1];  [2];  [2];  [3];  [3];  [2]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  3. Osaka Univ., Suita (Japan)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1237640
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 52; Journal Issue: 2; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats

Sun, Xiao -Guang, Fang, Youxing, Jiang, Xueguang, Yoshii, Kazuki, Tsuda, Tetsuya, and Dai, Sheng. Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries. United States: N. p., 2015. Web. doi:10.1039/C5CC06643C.
Sun, Xiao -Guang, Fang, Youxing, Jiang, Xueguang, Yoshii, Kazuki, Tsuda, Tetsuya, & Dai, Sheng. Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries. United States. https://doi.org/10.1039/C5CC06643C
Sun, Xiao -Guang, Fang, Youxing, Jiang, Xueguang, Yoshii, Kazuki, Tsuda, Tetsuya, and Dai, Sheng. Thu . "Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries". United States. https://doi.org/10.1039/C5CC06643C. https://www.osti.gov/servlets/purl/1237640.
@article{osti_1237640,
title = {Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries},
author = {Sun, Xiao -Guang and Fang, Youxing and Jiang, Xueguang and Yoshii, Kazuki and Tsuda, Tetsuya and Dai, Sheng},
abstractNote = {Polymer gel electrolyte using AlCl3 complexed acrylamide as functional monomer and ionic liquids based on acidic mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and AlCl3 as plasticizer has been successfully prepared for the first time by free radical polymerization. Aluminum deposition is successfully obtained with a polymer gel membrane contianing 80 wt% ionic liquid. As a result, the polymer gel membranes are also good candidates for rechargeable aluminum ion batteries.},
doi = {10.1039/C5CC06643C},
journal = {ChemComm},
number = 2,
volume = 52,
place = {United States},
year = {Thu Oct 22 00:00:00 EDT 2015},
month = {Thu Oct 22 00:00:00 EDT 2015}
}

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Cited by: 80 works
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Works referenced in this record:

Update on alternatives for cadmium coatings on military electrical connectors
journal, March 2010


Preparation technique and alloying effect of aluminide coatings as tritium permeation barriers: A review
journal, March 2015


Different Cold Spray Deposition Strategies: Single- and Multi-layers to Repair Aluminium Alloy Components
journal, August 2014

  • Rech, Silvano; Trentin, Andrea; Vezzù, Simone
  • Journal of Thermal Spray Technology, Vol. 23, Issue 8
  • DOI: 10.1007/s11666-014-0141-y

Low temperature electrochemical deposition of highly active elements
journal, April 2015

  • Falola, Bamidele D.; Suni, Ian I.
  • Current Opinion in Solid State and Materials Science, Vol. 19, Issue 2
  • DOI: 10.1016/j.cossms.2014.11.006

Application of ionic liquids to the electrodeposition of metals
journal, January 2006

  • Abbott, Andrew P.; McKenzie, Katy J.
  • Physical Chemistry Chemical Physics, Vol. 8, Issue 37
  • DOI: 10.1039/b607329h

Electroplating Using Ionic Liquids
journal, July 2013


Electroplated bright aluminium coatings for anticorrosion and decorative purposes
journal, February 2010


Ionic Liquids: Promising Solvents for Electrochemistry
journal, February 2004


Electrodeposition of metals from non-aqueous solutions
journal, September 2009


Electrodeposition of aluminium from nonaqueous organic electrolytic systems and room temperature molten salts
journal, January 1997


Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009

  • Armand, Michel; Endres, Frank; MacFarlane, Douglas R.
  • Nature Materials, Vol. 8, Issue 8, p. 621-629
  • DOI: 10.1038/nmat2448

Lewis Acids:  From Conventional Homogeneous to Green Homogeneous and Heterogeneous Catalysis
journal, November 2003

  • Corma, Avelino; García, Hermenegildo
  • Chemical Reviews, Vol. 103, Issue 11
  • DOI: 10.1021/cr030680z

Electrochemical Reactivity in Room-Temperature Ionic Liquids
journal, July 2008

  • Hapiot, Philippe; Lagrost, Corinne
  • Chemical Reviews, Vol. 108, Issue 7
  • DOI: 10.1021/cr0680686

Electrodeposition of Aluminum from the Aluminum Chloride-1-Methyl-3-ethylimidazolium Chloride Room Temperature Molten Salt + Benzene
journal, January 1997

  • Liao, Qing
  • Journal of The Electrochemical Society, Vol. 144, Issue 3
  • DOI: 10.1149/1.1837510

Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+ AlCl4− and comparison with imidazolium based systems
journal, January 2011

  • Abood, Hadi M. A.; Abbott, Andrew P.; Ballantyne, Andrew D.
  • Chemical Communications, Vol. 47, Issue 12
  • DOI: 10.1039/c0cc04989a

Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides
journal, October 2013

  • Coleman, Fergal; Srinivasan, Geetha; Swadźba-Kwaśny, Małgorzata
  • Angewandte Chemie International Edition, Vol. 52, Issue 48
  • DOI: 10.1002/anie.201306267

An AlCl3 based ionic liquid with a neutral substituted pyridine ligand for electrochemical deposition of aluminum
journal, April 2015


New ionic liquids based on the complexation of dipropyl sulfide and AlCl 3 for electrodeposition of aluminum
journal, January 2015

  • Fang, Youxing; Jiang, Xueguang; Sun, Xiao-Guang
  • Chemical Communications, Vol. 51, Issue 68
  • DOI: 10.1039/C5CC05233E

Liquid coordination complexes: a new class of Lewis acids as safer alternatives to BF 3 in synthesis of polyalphaolefins
journal, January 2015

  • Hogg, James M.; Coleman, Fergal; Ferrer-Ugalde, Albert
  • Green Chemistry, Vol. 17, Issue 3
  • DOI: 10.1039/C4GC02080D

Aluminium electrodeposition under ambient conditions
journal, January 2014

  • Abbott, Andrew P.; Harris, Robert C.; Hsieh, Yi-Ting
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 28
  • DOI: 10.1039/C4CP01508H

Electrodeposition of Metals and Semiconductors in Air- and Water-Stable Ionic Liquids
journal, January 2006


Review of gel-type polymer electrolytes for lithium-ion batteries
journal, February 1999


Review on gel polymer electrolytes for lithium batteries
journal, January 2006


An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte
journal, January 1988

  • Gifford, P. R.; Palmisano, J. B.
  • Journal of The Electrochemical Society, Vol. 135, Issue 3, p. 650-654
  • DOI: 10.1149/1.2095685

Secondary aluminium-iron (III) chloride batteries with a low temperature molten salt electrolyte
journal, March 1992

  • Donahue, F. M.; Mancini, S. E.; Simonsen, L.
  • Journal of Applied Electrochemistry, Vol. 22, Issue 3
  • DOI: 10.1007/BF01030182

Chloroaluminate-Doped Conducting Polymers as Positive Electrodes in Rechargeable Aluminum Batteries
journal, March 2014

  • Hudak, Nicholas S.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 10
  • DOI: 10.1021/jp500593d

The rechargeable aluminum-ion battery
journal, January 2011

  • Jayaprakash, N.; Das, S. K.; Archer, L. A.
  • Chemical Communications, Vol. 47, Issue 47
  • DOI: 10.1039/c1cc15779e

Fluorinated Natural Graphite Cathode for Rechargeable Ionic Liquid Based Aluminum–Ion Battery
journal, January 2013

  • Rani, J. Vatsala; Kanakaiah, V.; Dadmal, Tulshiram
  • Journal of The Electrochemical Society, Vol. 160, Issue 10
  • DOI: 10.1149/2.072310jes

The Roles of V 2 O 5 and Stainless Steel in Rechargeable Al–Ion Batteries
journal, January 2013

  • Reed, Luke D.; Menke, Erik
  • Journal of The Electrochemical Society, Vol. 160, Issue 6
  • DOI: 10.1149/2.114306jes

An ultrafast rechargeable aluminium-ion battery
journal, April 2015

  • Lin, Meng-Chang; Gong, Ming; Lu, Bingan
  • Nature, Vol. 520, Issue 7547
  • DOI: 10.1038/nature14340

Dialkylimidazolium chloroaluminate melts: a new class of room-temperature ionic liquids for electrochemistry, spectroscopy and synthesis
journal, March 1982

  • Wilkes, John S.; Levisky, Joseph A.; Wilson, Robert A.
  • Inorganic Chemistry, Vol. 21, Issue 3
  • DOI: 10.1021/ic00133a078

Aluminum-27 and carbon-13 NMR studies of aluminum chloride-dialkylimidazolium chloride molten salts
journal, December 1983

  • Wilkes, John S.; Frye, James S.; Reynolds, G. Fredric
  • Inorganic Chemistry, Vol. 22, Issue 26
  • DOI: 10.1021/ic00168a011

Spectroscopic investigations of complexes between acetonitrile and aluminum trichloride. 1. Aluminum chloride-acetonitrile solutions
journal, March 1982

  • Dalibart, M.; Derouault, J.; Granger, P.
  • Inorganic Chemistry, Vol. 21, Issue 3
  • DOI: 10.1021/ic00133a034

Vibrational spectra, assignments and normal coordinate calculation of acrylamide
journal, April 2001


Works referencing / citing this record:

Flexible Stable Solid-State Al-Ion Batteries
journal, November 2018

  • Yu, Zhijing; Jiao, Shuqiang; Li, Shijie
  • Advanced Functional Materials, Vol. 29, Issue 1
  • DOI: 10.1002/adfm.201806799

An Overview and Future Perspectives of Aluminum Batteries
journal, June 2016

  • Elia, Giuseppe Antonio; Marquardt, Krystan; Hoeppner, Katrin
  • Advanced Materials, Vol. 28, Issue 35
  • DOI: 10.1002/adma.201601357

An Innovative Freeze-Dried Reduced Graphene Oxide Supported SnS 2 Cathode Active Material for Aluminum-Ion Batteries
journal, March 2017


Emerging Nonaqueous Aluminum-Ion Batteries: Challenges, Status, and Perspectives
journal, June 2018


Halogenid‐basierte Materialien und Chemie für wiederaufladbare Batterien
journal, January 2020

  • Zhao, Xiangyu; Zhao‐Karger, Zhirong; Fichtner, Maximilian
  • Angewandte Chemie, Vol. 132, Issue 15
  • DOI: 10.1002/ange.201902842

Halide‐Based Materials and Chemistry for Rechargeable Batteries
journal, January 2020

  • Zhao, Xiangyu; Zhao‐Karger, Zhirong; Fichtner, Maximilian
  • Angewandte Chemie International Edition, Vol. 59, Issue 15
  • DOI: 10.1002/anie.201902842

Stability of Metallic Current Collectors in Acidic Ionic Liquid for Rechargeable Aluminum-Ion Batteries
journal, August 2018


Synthesis and Characterization of Bromoaluminate Ionic Liquids
journal, June 2017

  • Hog, Michael; Schneider, Marius; Krossing, Ingo
  • Chemistry - A European Journal, Vol. 23, Issue 41
  • DOI: 10.1002/chem.201700105

Recent Progress and Future Trends of Aluminum Batteries
journal, December 2018


Single-step synthesis of novel chloroaluminate ionic liquid for green Friedel–Crafts alkylation reaction
journal, October 2019

  • Sakhalkar, Mangesh; Aduri, Pavankumar; Lande, Sharad
  • Clean Technologies and Environmental Policy, Vol. 22, Issue 1
  • DOI: 10.1007/s10098-019-01769-y

Designing solid-state electrolytes for safe, energy-dense batteries
journal, February 2020


A nitrogen–sulfur co-doped porous graphene matrix as a sulfur immobilizer for high performance lithium–sulfur batteries
journal, January 2016

  • Xu, Jing; Su, Dawei; Zhang, Wenxue
  • Journal of Materials Chemistry A, Vol. 4, Issue 44
  • DOI: 10.1039/c6ta05878g

Recent progress in flexible non-lithium based rechargeable batteries
journal, January 2019

  • Liu, Yang; Sun, Zehang; Tan, Ke
  • Journal of Materials Chemistry A, Vol. 7, Issue 9
  • DOI: 10.1039/c8ta10258a

Rod-shaped Cu 1.81 Te as a novel cathode material for aluminum-ion batteries
journal, January 2020

  • Wu, Junnan; Wu, Dongzheng; Zhao, Min
  • Dalton Transactions, Vol. 49, Issue 3
  • DOI: 10.1039/c9dt04157e

Different positive electrode materials in organic and aqueous systems for aluminium ion batteries
journal, January 2019

  • Ru, Yue; Zheng, Shasha; Xue, Huaiguo
  • Journal of Materials Chemistry A, Vol. 7, Issue 24
  • DOI: 10.1039/c9ta01550g

High Coulombic efficiency aluminum-ion battery using an AlCl 3 -urea ionic liquid analog electrolyte
journal, January 2017

  • Angell, Michael; Pan, Chun-Jern; Rong, Youmin
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 5
  • DOI: 10.1073/pnas.1619795114

Printed Transparent Thin Film Zn-MnO 2 Battery
journal, January 2017

  • Lao-atiman, Woranunt; Julaphatachote, Thanatham; Boonmongkolras, Passarut
  • Journal of The Electrochemical Society, Vol. 164, Issue 4
  • DOI: 10.1149/2.1511704jes

Stability of Metallic Current Collectors in Acidic Ionic Liquid for Rechargeable Aluminum-Ion Batteries
journal, October 2018