A high performance hybrid battery based on aluminum anode and LiFePO4 cathode
Abstract
A unique battery hybrid utilizes an aluminum anode, a LiFePO4 cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl 3) (EMImCl-AlCl 3, 1-1.1 in molar ratio) with or without LiAlCl4 is proposed. This hybrid ion battery delivers an initial high capacity of 160 mAh g-1 at a current rate of C/5. It also shows good rate capability and cycling performance.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1237159
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 52; Journal Issue: 8; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Sun, Xiao-Guang, Bi, Zhonghe, Liu, Hansan, Bridges, Craig A., Paranthaman, Mariappan Parans, Dai, Sheng, and Brown, Gilbert M. A high performance hybrid battery based on aluminum anode and LiFePO4 cathode. United States: N. p., 2015.
Web. doi:10.1039/C5CC09019A.
Sun, Xiao-Guang, Bi, Zhonghe, Liu, Hansan, Bridges, Craig A., Paranthaman, Mariappan Parans, Dai, Sheng, & Brown, Gilbert M. A high performance hybrid battery based on aluminum anode and LiFePO4 cathode. United States. https://doi.org/10.1039/C5CC09019A
Sun, Xiao-Guang, Bi, Zhonghe, Liu, Hansan, Bridges, Craig A., Paranthaman, Mariappan Parans, Dai, Sheng, and Brown, Gilbert M. Mon .
"A high performance hybrid battery based on aluminum anode and LiFePO4 cathode". United States. https://doi.org/10.1039/C5CC09019A. https://www.osti.gov/servlets/purl/1237159.
@article{osti_1237159,
title = {A high performance hybrid battery based on aluminum anode and LiFePO4 cathode},
author = {Sun, Xiao-Guang and Bi, Zhonghe and Liu, Hansan and Bridges, Craig A. and Paranthaman, Mariappan Parans and Dai, Sheng and Brown, Gilbert M.},
abstractNote = {A unique battery hybrid utilizes an aluminum anode, a LiFePO4 cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl 3) (EMImCl-AlCl 3, 1-1.1 in molar ratio) with or without LiAlCl4 is proposed. This hybrid ion battery delivers an initial high capacity of 160 mAh g-1 at a current rate of C/5. It also shows good rate capability and cycling performance.},
doi = {10.1039/C5CC09019A},
journal = {ChemComm},
number = 8,
volume = 52,
place = {United States},
year = {Mon Dec 07 00:00:00 EST 2015},
month = {Mon Dec 07 00:00:00 EST 2015}
}
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Works referenced in this record:
Electrochemical Energy Storage for Green Grid
journal, May 2011
- Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
- Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
Sodium and sodium-ion energy storage batteries
journal, August 2012
- Ellis, Brian L.; Nazar, Linda F.
- Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Rechargeable magnesium battery: Current status and key challenges for the future
journal, October 2014
- Saha, Partha; Datta, Moni Kanchan; Velikokhatnyi, Oleg I.
- Progress in Materials Science, Vol. 66
Magnesium batteries: Current state of the art, issues and future perspectives
journal, January 2014
- Mohtadi, Rana; Mizuno, Fuminori
- Beilstein Journal of Nanotechnology, Vol. 5
Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond
journal, October 2014
- Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas
- Chemical Reviews, Vol. 114, Issue 23
Mg rechargeable batteries: an on-going challenge
journal, January 2013
- Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef
- Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279
An ultrafast rechargeable aluminium-ion battery
journal, April 2015
- Lin, Meng-Chang; Gong, Ming; Lu, Bingan
- Nature, Vol. 520, Issue 7547
Aluminum as anode for energy storage and conversion: a review
journal, July 2002
- Li, Qingfeng; Bjerrum, Niels J.
- Journal of Power Sources, Vol. 110, Issue 1, p. 1-10
A concept of dual-salt polyvalent-metal storage battery
journal, January 2014
- Yagi, Shunsuke; Ichitsubo, Tetsu; Shirai, Yoshimasa
- J. Mater. Chem. A, Vol. 2, Issue 4
Electrodeposition of Aluminum from the Aluminum Chloride-1-Methyl-3-ethylimidazolium Chloride Room Temperature Molten Salt + Benzene
journal, January 1997
- Liao, Qing
- Journal of The Electrochemical Society, Vol. 144, Issue 3
Electrodeposition of aluminium from nonaqueous organic electrolytic systems and room temperature molten salts
journal, January 1997
- Zhao, Yuguang; VanderNoot, T. J.
- Electrochimica Acta, Vol. 42, Issue 1
The Roles of V 2 O 5 and Stainless Steel in Rechargeable Al–Ion Batteries
journal, January 2013
- Reed, Luke D.; Menke, Erik
- Journal of The Electrochemical Society, Vol. 160, Issue 6
Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+ AlCl4− and comparison with imidazolium based systems
journal, January 2011
- Abood, Hadi M. A.; Abbott, Andrew P.; Ballantyne, Andrew D.
- Chemical Communications, Vol. 47, Issue 12
Ionic Liquids: Solvents for the Electrodeposition of Metals and Semiconductors
journal, February 2002
- Endres, Frank
- ChemPhysChem, Vol. 3, Issue 2
Electrodeposition of Metals and Semiconductors in Air- and Water-Stable Ionic Liquids
journal, January 2006
- Zein El Abedin, Sherif; Endres, Frank
- ChemPhysChem, Vol. 7, Issue 1
Aluminium electrodeposition under ambient conditions
journal, January 2014
- Abbott, Andrew P.; Harris, Robert C.; Hsieh, Yi-Ting
- Phys. Chem. Chem. Phys., Vol. 16, Issue 28
Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides
journal, October 2013
- Coleman, Fergal; Srinivasan, Geetha; Swadźba-Kwaśny, Małgorzata
- Angewandte Chemie International Edition, Vol. 52, Issue 48
New ionic liquids based on the complexation of dipropyl sulfide and AlCl 3 for electrodeposition of aluminum
journal, January 2015
- Fang, Youxing; Jiang, Xueguang; Sun, Xiao-Guang
- Chemical Communications, Vol. 51, Issue 68
An AlCl3 based ionic liquid with a neutral substituted pyridine ligand for electrochemical deposition of aluminum
journal, April 2015
- Fang, Youxing; Yoshii, Kazuki; Jiang, Xueguang
- Electrochimica Acta, Vol. 160
Sulfone-based electrolytes for aluminium rechargeable batteries
journal, January 2015
- Nakayama, Yuri; Senda, Yui; Kawasaki, Hideki
- Physical Chemistry Chemical Physics, Vol. 17, Issue 8
Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries
journal, January 2016
- Sun, Xiao-Guang; Fang, Youxing; Jiang, Xueguang
- Chemical Communications, Vol. 52, Issue 2, p. 292-295
The rechargeable aluminum-ion battery
journal, January 2011
- Jayaprakash, N.; Das, S. K.; Archer, L. A.
- Chemical Communications, Vol. 47, Issue 47
Fluorinated Natural Graphite Cathode for Rechargeable Ionic Liquid Based Aluminum–Ion Battery
journal, January 2013
- Rani, J. Vatsala; Kanakaiah, V.; Dadmal, Tulshiram
- Journal of The Electrochemical Society, Vol. 160, Issue 10
Chloroaluminate-Doped Conducting Polymers as Positive Electrodes in Rechargeable Aluminum Batteries
journal, March 2014
- Hudak, Nicholas S.
- The Journal of Physical Chemistry C, Vol. 118, Issue 10
Binder-Free V 2 O 5 Cathode for Greener Rechargeable Aluminum Battery
journal, December 2014
- Wang, Huali; Bai, Ying; Chen, Shi
- ACS Applied Materials & Interfaces, Vol. 7, Issue 1
Reversible Electrochemical Intercalation of Aluminum in Mo 6 S 8
journal, July 2015
- Geng, Linxiao; Lv, Guocheng; Xing, Xuebing
- Chemistry of Materials, Vol. 27, Issue 14
A new aluminium-ion battery with high voltage, high safety and low cost
journal, January 2015
- Sun, Haobo; Wang, Wei; Yu, Zhijing
- Chemical Communications, Vol. 51, Issue 59
Reversible Aluminum-Ion Intercalation in Prussian Blue Analogs and Demonstration of a High-Power Aluminum-Ion Asymmetric Capacitor
journal, November 2014
- Li, Zheng; Xiang, Kai; Xing, Wenting
- Advanced Energy Materials, Vol. 5, Issue 5
Cyclic chronopotentiometric studies of the LiAl anode in methyl acetate
journal, March 1989
- Fung, Y. S.; Lai, H. C.
- Journal of Applied Electrochemistry, Vol. 19, Issue 2
High performance batteries based on hybrid magnesium and lithium chemistry
journal, January 2014
- Cheng, Yingwen; Shao, Yuyan; Zhang, Ji-Guang
- Chem. Commun., Vol. 50, Issue 68
Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009
- Armand, Michel; Endres, Frank; MacFarlane, Douglas R.
- Nature Materials, Vol. 8, Issue 8, p. 621-629
Electrochemical investigations of ionic liquids with vinylene carbonate for applications in rechargeable lithium ion batteries
journal, June 2010
- Sun, Xiao-Guang; Dai, Sheng
- Electrochimica Acta, Vol. 55, Issue 15, p. 4618-4626
Bicyclic imidazolium ionic liquids as potential electrolytes for rechargeable lithium ion batteries
journal, September 2013
- Sun, Xiao-Guang; Liao, Chen; Shao, Nan
- Journal of Power Sources, Vol. 237
Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides
journal, October 2013
- Coleman, Fergal; Srinivasan, Geetha; Swadźba-Kwaśny, Małgorzata
- Angewandte Chemie, Vol. 125, Issue 48
Works referencing / citing this record:
Emerging Nonaqueous Aluminum-Ion Batteries: Challenges, Status, and Perspectives
journal, June 2018
- Zhang, Yu; Liu, Shiqi; Ji, Yongjun
- Advanced Materials, Vol. 30, Issue 38
Paving the Path toward Reliable Cathode Materials for Aluminum-Ion Batteries
journal, February 2019
- Wu, Feng; Yang, Haoyi; Bai, Ying
- Advanced Materials, Vol. 31, Issue 16
Trends in Aluminium-Based Intercalation Batteries
journal, March 2017
- Ambroz, Filip; Macdonald, Thomas J.; Nann, Thomas
- Advanced Energy Materials, Vol. 7, Issue 15
Die wiederaufladbare Aluminiumbatterie: Möglichkeiten und Herausforderungen
journal, June 2019
- Yang, Huicong; Li, Hucheng; Li, Juan
- Angewandte Chemie, Vol. 131, Issue 35
The Rechargeable Aluminum Battery: Opportunities and Challenges
journal, August 2019
- Yang, Huicong; Li, Hucheng; Li, Juan
- Angewandte Chemie International Edition, Vol. 58, Issue 35
Stable Performance of Aluminum-Metal Battery by Incorporating Lithium-Ion Chemistry
journal, May 2017
- Yoo, Dong-Joo; Kim, Joo-Seong; Shin, Jaeho
- ChemElectroChem, Vol. 4, Issue 9
Synthesis and Characterization of Bromoaluminate Ionic Liquids
journal, June 2017
- Hog, Michael; Schneider, Marius; Krossing, Ingo
- Chemistry - A European Journal, Vol. 23, Issue 41
Critical Role of pH Evolution of Electrolyte in the Reaction Mechanism for Rechargeable Zinc Batteries
journal, September 2016
- Lee, Boeun; Seo, Hyo Ree; Lee, Hae Ri
- ChemSusChem, Vol. 9, Issue 20
Ion Dynamics in Ionic-Liquid-Based Li-Ion Electrolytes Investigated by Neutron Scattering and Dielectric Spectroscopy
journal, September 2018
- Jafta, Charl J.; Bridges, Craig; Haupt, Leon
- ChemSusChem, Vol. 11, Issue 19
Design and modification of cathode materials for high energy density aluminum-ion batteries: a review
journal, June 2018
- Li, Changgang; Zhang, Xudong; He, Wen
- Journal of Materials Science: Materials in Electronics, Vol. 29, Issue 16
The O 2 -assisted Al/CO 2 electrochemical cell: A system for CO 2 capture/conversion and electric power generation
journal, July 2016
- Al Sadat, Wajdi I.; Archer, Lynden A.
- Science Advances, Vol. 2, Issue 7