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Title: Defect-Reduction Mechanism for Improving Radiative Efficiency in InGaN/GaN Light-Emitting Diodes using InGaN Underlayers

Abstract

The influence of a dilute InxGa1-xN (x~0.03) underlayer (UL) grown below a single In0.16Ga0.84N quantum well (SQW), within a light-emitting diode(LED), on the radiative efficiency and deep level defect properties was studied using differential carrier lifetime (DCL) measurements and deep level optical spectroscopy (DLOS). DCL measurements found that inclusion of the UL significantly improved LED radiative efficiency. At low current densities, the non-radiative recombination rate of the LED with an UL was found to be 3.9 times lower than theLED without an UL, while the radiative recombination rates were nearly identical. This, then, suggests that the improved radiative efficiency resulted from reduced non-radiative defect concentration within the SQW. DLOS measurement found the same type of defects in the InGaN SQWs with and without ULs. However, lighted capacitance-voltage measurements of the LEDs revealed a 3.4 times reduction in a SQW-related near-mid-gap defect state for the LED with an UL. Furthermore, quantitative agreement in the reduction of both the non-radiative recombination rate (3.9×) and deep level density (3.4×) upon insertion of an UL corroborates deep level defect reduction as the mechanism for improved LED efficiency.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Energy Frontier Research Centers (EFRC) (United States). EFRC for Solid State Lighting Science (SSLS)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1235263
Alternate Identifier(s):
OSTI ID: 1228147
Report Number(s):
SAND2015-0751J
Journal ID: ISSN 0021-8979; 562690
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 117; Journal Issue: 13; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY

Citation Formats

Armstrong, Andrew M., Bryant, Benjamin N., Crawford, Mary H., Koleske, Daniel D., Lee, Stephen R., and Wierer, Jr., Jonathan J. Defect-Reduction Mechanism for Improving Radiative Efficiency in InGaN/GaN Light-Emitting Diodes using InGaN Underlayers. United States: N. p., 2015. Web. doi:10.1063/1.4916727.
Armstrong, Andrew M., Bryant, Benjamin N., Crawford, Mary H., Koleske, Daniel D., Lee, Stephen R., & Wierer, Jr., Jonathan J. Defect-Reduction Mechanism for Improving Radiative Efficiency in InGaN/GaN Light-Emitting Diodes using InGaN Underlayers. United States. https://doi.org/10.1063/1.4916727
Armstrong, Andrew M., Bryant, Benjamin N., Crawford, Mary H., Koleske, Daniel D., Lee, Stephen R., and Wierer, Jr., Jonathan J. Wed . "Defect-Reduction Mechanism for Improving Radiative Efficiency in InGaN/GaN Light-Emitting Diodes using InGaN Underlayers". United States. https://doi.org/10.1063/1.4916727. https://www.osti.gov/servlets/purl/1235263.
@article{osti_1235263,
title = {Defect-Reduction Mechanism for Improving Radiative Efficiency in InGaN/GaN Light-Emitting Diodes using InGaN Underlayers},
author = {Armstrong, Andrew M. and Bryant, Benjamin N. and Crawford, Mary H. and Koleske, Daniel D. and Lee, Stephen R. and Wierer, Jr., Jonathan J.},
abstractNote = {The influence of a dilute InxGa1-xN (x~0.03) underlayer (UL) grown below a single In0.16Ga0.84N quantum well (SQW), within a light-emitting diode(LED), on the radiative efficiency and deep level defect properties was studied using differential carrier lifetime (DCL) measurements and deep level optical spectroscopy (DLOS). DCL measurements found that inclusion of the UL significantly improved LED radiative efficiency. At low current densities, the non-radiative recombination rate of the LED with an UL was found to be 3.9 times lower than theLED without an UL, while the radiative recombination rates were nearly identical. This, then, suggests that the improved radiative efficiency resulted from reduced non-radiative defect concentration within the SQW. DLOS measurement found the same type of defects in the InGaN SQWs with and without ULs. However, lighted capacitance-voltage measurements of the LEDs revealed a 3.4 times reduction in a SQW-related near-mid-gap defect state for the LED with an UL. Furthermore, quantitative agreement in the reduction of both the non-radiative recombination rate (3.9×) and deep level density (3.4×) upon insertion of an UL corroborates deep level defect reduction as the mechanism for improved LED efficiency.},
doi = {10.1063/1.4916727},
journal = {Journal of Applied Physics},
number = 13,
volume = 117,
place = {United States},
year = {Wed Apr 01 00:00:00 EDT 2015},
month = {Wed Apr 01 00:00:00 EDT 2015}
}

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Works referenced in this record:

High luminescent efficiency of InGaN multiple quantum wells grown on InGaN underlying layers
journal, October 2004

  • Akasaka, Tetsuya; Gotoh, Hideki; Saito, Tadashi
  • Applied Physics Letters, Vol. 85, Issue 15
  • DOI: 10.1063/1.1804607

Effects of an InGaN prelayer on the properties of InGaN/GaN quantum well structures: Effects of an InGaN prelayer on the properties of InGaN/GaN quantum well structures
journal, January 2014

  • Davies, Matthew J.; Massabuau, Fabien C. -P.; Dawson, Philip
  • physica status solidi (c), Vol. 11, Issue 3-4
  • DOI: 10.1002/pssc.201300451

The effects of Si-doped prelayers on the optical properties of InGaN/GaN single quantum well structures
journal, September 2014

  • Davies, M. J.; Dawson, P.; Massabuau, F. C. -P.
  • Applied Physics Letters, Vol. 105, Issue 9
  • DOI: 10.1063/1.4894834

The effect of InGaN underlayers on the electronic and optical properties of InGaN/GaN quantum wells
journal, January 2013

  • Li, T.; Wei, Q. Y.; Fischer, A. M.
  • Applied Physics Letters, Vol. 102, Issue 4
  • DOI: 10.1063/1.4789758

Enhanced luminescence of InGaN/GaN multiple quantum wells by strain reduction
journal, June 2007


Electroluminescence efficiency of blue InGaN∕GaN quantum-well diodes with and without an n-InGaN electron reservoir layer
journal, January 2006

  • Otsuji, N.; Fujiwara, K.; Sheu, J. K.
  • Journal of Applied Physics, Vol. 100, Issue 11
  • DOI: 10.1063/1.2398690

Enhanced optical properties of InGaN MQWs with InGaN underlying layers
journal, January 2006


Effect of InGaN underneath layer on MOVPE-grown InGaN/GaN blue LEDs
journal, November 2008


InGaN quantum wells with small potential fluctuation grown on InGaN underlying layers
journal, September 2006

  • Akasaka, Tetsuya; Gotoh, Hideki; Kobayashi, Yasuyuki
  • Applied Physics Letters, Vol. 89, Issue 10
  • DOI: 10.1063/1.2347115

Improved quality of InGaN/GaN multiple quantum wells by a strain relief layer
journal, January 2006


Effect of indium doping on the transient optical properties of GaN films
journal, November 1999

  • Kumano, Hidekazu; Hoshi, Ken-ichi; Tanaka, Satoru
  • Applied Physics Letters, Vol. 75, Issue 19
  • DOI: 10.1063/1.125178

Deep-level optical spectroscopy in GaAs
journal, May 1981


Droop in InGaN light-emitting diodes: A differential carrier lifetime analysis
journal, March 2010

  • David, Aurélien; Grundmann, Michael J.
  • Applied Physics Letters, Vol. 96, Issue 10
  • DOI: 10.1063/1.3330870

Determination of the indium content and layer thicknesses in InGaN/GaN quantum wells by x-ray scattering
journal, August 2003

  • Vickers, M. E.; Kappers, M. J.; Smeeton, T. M.
  • Journal of Applied Physics, Vol. 94, Issue 3
  • DOI: 10.1063/1.1587251

Effect of interface grading and lateral thickness variation on x-ray diffraction by InGaN/GaN multiple quantum wells
journal, September 2012


Critical thickness calculations for InGaN/GaN
journal, May 2007


Defects in epitaxial multilayers: I. Misfit dislocations
journal, December 1974


Optical cavity effects in InGaN/GaN quantum-well-heterostructure flip-chip light-emitting diodes
journal, April 2003

  • Shen, Y. C.; Wierer, J. J.; Krames, M. R.
  • Applied Physics Letters, Vol. 82, Issue 14
  • DOI: 10.1063/1.1566098

Performance of high-power III-nitride light emitting diodes
journal, May 2008


The use of short-period InGaN/GaN superlattices in blue-region light-emitting diodes
journal, July 2010


Quantitative and depth-resolved deep level defect distributions in InGaN/GaN light emitting diodes
journal, January 2012

  • Armstrong, A.; Henry, T. A.; Koleske, D. D.
  • Optics Express, Vol. 20, Issue S6
  • DOI: 10.1364/OE.20.00A812

Contribution of deep-level defects to decreasing radiative efficiency of InGaN/GaN quantum wells with increasing emission wavelength
journal, March 2014

  • Armstrong, Andrew M.; Crawford, Mary H.; Koleske, Daniel D.
  • Applied Physics Express, Vol. 7, Issue 3
  • DOI: 10.7567/APEX.7.032101

Dependence of radiative efficiency and deep level defect incorporation on threading dislocation density for InGaN/GaN light emitting diodes
journal, October 2012

  • Armstrong, A.; Henry, T. A.; Koleske, D. D.
  • Applied Physics Letters, Vol. 101, Issue 16
  • DOI: 10.1063/1.4759003

Measurement of deep-level spatial distributions
journal, April 1976


A method to determine deep level profiles in highly compensated, wide band gap semiconductors
journal, April 2005

  • Armstrong, A.; Arehart, A. R.; Ringel, S. A.
  • Journal of Applied Physics, Vol. 97, Issue 8
  • DOI: 10.1063/1.1862321

Defects in epitaxial multilayers
journal, February 1976


Optical cavity effects in InGaN/GaN quantum-well-heterostructure flip-chip light-emitting diodes
conference, June 2004

  • Shen, Yu C.; Wierer, Jonathan J.; Krames, Michael R.
  • Integrated Optoelectronic Devices 2004, SPIE Proceedings
  • DOI: 10.1117/12.520571

Defects in epitaxial multilayers: II. Dislocation pile-ups, threading dislocations, slip lines and cracks
journal, July 1975


Works referencing / citing this record:

Efficiency Enhancement Mechanism of an Underlying Layer in GaInN‐Based Green Light–Emitting Diodes
journal, December 2019

  • Han, Dong-Pyo; Ishimoto, Seiji; Mano, Ryoya
  • physica status solidi (a), Vol. 217, Issue 7
  • DOI: 10.1002/pssa.201900713

Calcium impurity as a source of non-radiative recombination in (In,Ga)N layers grown by molecular beam epitaxy
journal, November 2016

  • Young, E. C.; Grandjean, N.; Mates, T. E.
  • Applied Physics Letters, Vol. 109, Issue 21
  • DOI: 10.1063/1.4968586

Burying non-radiative defects in InGaN underlayer to increase InGaN/GaN quantum well efficiency
journal, December 2017

  • Haller, C.; Carlin, J. -F.; Jacopin, G.
  • Applied Physics Letters, Vol. 111, Issue 26
  • DOI: 10.1063/1.5007616

Spatially dependent carrier dynamics in single InGaN/GaN core-shell microrod by time-resolved cathodoluminescence
journal, January 2018

  • Liu, W.; Mounir, C.; Rossbach, G.
  • Applied Physics Letters, Vol. 112, Issue 5
  • DOI: 10.1063/1.5009728

Experimental characterization of impact ionization coefficients for electrons and holes in GaN grown on bulk GaN substrates
journal, June 2018

  • Cao, Lina; Wang, Jingshan; Harden, Galen
  • Applied Physics Letters, Vol. 112, Issue 26
  • DOI: 10.1063/1.5031785

GaN surface as the source of non-radiative defects in InGaN/GaN quantum wells
journal, September 2018

  • Haller, C.; Carlin, J. -F.; Jacopin, G.
  • Applied Physics Letters, Vol. 113, Issue 11
  • DOI: 10.1063/1.5048010

Challenges for reliable internal quantum efficiency determination in AlGaN-based multi-quantum-well structures posed by carrier transport effects and morphology issues
journal, August 2019

  • Frankerl, Christian; Hoffmann, Marc P.; Nippert, Felix
  • Journal of Applied Physics, Vol. 126, Issue 7
  • DOI: 10.1063/1.5100498

Effects of InAlN underlayer on deep traps detected in near-UV InGaN/GaN single quantum well light-emitting diodes
journal, September 2019

  • Polyakov, A. Y.; Haller, C.; Smirnov, N. B.
  • Journal of Applied Physics, Vol. 126, Issue 12
  • DOI: 10.1063/1.5122314

Determination of electronic band structure by electron holography of etched-and-regrown interfaces in GaN p-i-n diodes
journal, November 2019

  • Alugubelli, Shanthan R.; Fu, Houqiang; Fu, Kai
  • Applied Physics Letters, Vol. 115, Issue 20
  • DOI: 10.1063/1.5127014

Total-InGaN-thickness dependent Shockley-Read-Hall recombination lifetime in InGaN quantum wells
journal, January 2020

  • Zhou, Renlin; Ikeda, Masao; Zhang, Feng
  • Journal of Applied Physics, Vol. 127, Issue 1
  • DOI: 10.1063/1.5131716

Impact of alloy disorder on Auger recombination in single InGaN/GaN core-shell microrods
journal, December 2019


Review—The Physics of Recombinations in III-Nitride Emitters
journal, January 2020

  • David, Aurelien; Young, Nathan G.; Lund, Cory
  • ECS Journal of Solid State Science and Technology, Vol. 9, Issue 1
  • DOI: 10.1149/2.0372001jss

Performance improvement of InGaN-based laser grown on Si by suppressing point defects
journal, January 2019


Effects of a Si-doped InGaN Underlayer on the Optical Properties of InGaN/GaN Quantum Well Structures with Different Numbers of Quantum Wells
journal, September 2018

  • Christian, George; Kappers, Menno; Massabuau, Fabien
  • Materials, Vol. 11, Issue 9
  • DOI: 10.3390/ma11091736

An InGaN/GaN Superlattice to Enhance the Performance of Green LEDs: Exploring the Role of V-Pits
journal, June 2018

  • Liu, Mengling; Zhao, Jie; Zhou, Shengjun
  • Nanomaterials, Vol. 8, Issue 7
  • DOI: 10.3390/nano8070450

An InGaN/GaN Superlattice to Enhance the Performance of Green LEDs: Exploring the Role of V-Pits
journal, June 2018

  • Liu, Mengling; Zhao, Jie; Zhou, Shengjun
  • Nanomaterials, Vol. 8, Issue 7
  • DOI: 10.3390/nano8070450