Communication: Slow relaxation, spatial mobility gradients, and vitrification in confined films
- Authors:
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1224269
- Alternate Identifier(s):
- OSTI ID: 1416454
- Resource Type:
- Published Article
- Journal Name:
- Journal of Chemical Physics
- Additional Journal Information:
- Journal Name: Journal of Chemical Physics Journal Volume: 141 Journal Issue: 16; Journal ID: ISSN 0021-9606
- Publisher:
- American Institute of Physics
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Mirigian, Stephen, and Schweizer, Kenneth S. Communication: Slow relaxation, spatial mobility gradients, and vitrification in confined films. United States: N. p., 2014.
Web. doi:10.1063/1.4900507.
Mirigian, Stephen, & Schweizer, Kenneth S. Communication: Slow relaxation, spatial mobility gradients, and vitrification in confined films. United States. https://doi.org/10.1063/1.4900507
Mirigian, Stephen, and Schweizer, Kenneth S. Tue .
"Communication: Slow relaxation, spatial mobility gradients, and vitrification in confined films". United States. https://doi.org/10.1063/1.4900507.
@article{osti_1224269,
title = {Communication: Slow relaxation, spatial mobility gradients, and vitrification in confined films},
author = {Mirigian, Stephen and Schweizer, Kenneth S.},
abstractNote = {},
doi = {10.1063/1.4900507},
journal = {Journal of Chemical Physics},
number = 16,
volume = 141,
place = {United States},
year = {Tue Oct 28 00:00:00 EDT 2014},
month = {Tue Oct 28 00:00:00 EDT 2014}
}
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https://doi.org/10.1063/1.4900507
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Works referenced in this record:
Size-Dependent Depression of the Glass Transition Temperature in Polymer Films
journal, July 1994
- Keddie, J. L.; Jones, R. A. L.; Cory, R. A.
- Europhysics Letters (EPL), Vol. 27, Issue 1
Model polymer nanocomposites provide an understanding of confinement effects in real nanocomposites
journal, March 2007
- Rittigstein, Perla; Priestley, Rodney D.; Broadbelt, Linda J.
- Nature Materials, Vol. 6, Issue 4
Comparing surface and bulk flow of a molecular glass former
journal, January 2012
- Daley, C. R.; Fakhraai, Z.; Ediger, M. D.
- Soft Matter, Vol. 8, Issue 7
A Direct Quantitative Measure of Surface Mobility in a Glassy Polymer
journal, February 2014
- Chai, Y.; Salez, T.; McGraw, J. D.
- Science, Vol. 343, Issue 6174
Role of Polymer Chain Flexibility on the Viscoelasticity of Amorphous Polymers around the Glass Transition Zone
journal, January 1996
- Inoue, Tadashi; Osaki, K.
- Macromolecules, Vol. 29, Issue 5
Self-Concentrations and Effective Glass Transition Temperatures in Polymer Blends
journal, July 2000
- Lodge, Timothy P.; McLeish, Thomas C. B.
- Macromolecules, Vol. 33, Issue 14
Measuring the Surface Dynamics of Glassy Polymers
journal, February 2008
- Fakhraai, Z.; Forrest, J. A.
- Science, Vol. 319, Issue 5863
Theoretical perspective on the glass transition and amorphous materials
journal, June 2011
- Berthier, Ludovic; Biroli, Giulio
- Reviews of Modern Physics, Vol. 83, Issue 2
Direct Measurement of Molecular Motion in Freestanding Polystyrene Thin Films
journal, June 2011
- Paeng, Keewook; Swallen, Stephen F.; Ediger, M. D.
- Journal of the American Chemical Society, Vol. 133, Issue 22
Local and Average Glass Transitions in Polymer Thin Films
journal, December 2010
- Lipson, Jane E. G.; Milner, Scott T.
- Macromolecules, Vol. 43, Issue 23
Perspective: Supercooled liquids and glasses
journal, August 2012
- Ediger, M. D.; Harrowell, Peter
- The Journal of Chemical Physics, Vol. 137, Issue 8
Dynamics near Free Surfaces and the Glass Transition in Thin Polymer Films: A View to the Future
journal, November 2013
- Ediger, M. D.; Forrest, J. A.
- Macromolecules, Vol. 47, Issue 2
Measuring surface and bulk relaxation in glassy polymers
journal, June 2011
- Qi, D.; Ilton, M.; Forrest, J. A.
- The European Physical Journal E, Vol. 34, Issue 6
Glassy Dynamics and Glass Transition in Nanometric Thin Layers of Polystyrene
journal, December 2010
- Tress, Martin; Erber, Michael; Mapesa, Emmanuel U.
- Macromolecules, Vol. 43, Issue 23
Glass transitions in thin polymer films
journal, July 2000
- de Gennes, P. G.
- The European Physical Journal E, Vol. 2, Issue 3
Tg depression and invariant segmental dynamics in polystyrene thin films
journal, January 2012
- Boucher, Virginie M.; Cangialosi, Daniele; Yin, Huajie
- Soft Matter, Vol. 8, Issue 19
Glass Transition Dynamics and Surface Layer Mobility in Unentangled Polystyrene Films
journal, June 2010
- Yang, Z.; Fujii, Y.; Lee, F. K.
- Science, Vol. 328, Issue 5986
The distribution of glass-transition temperatures in nanoscopically confined glass formers
journal, September 2003
- Ellison, Christopher J.; Torkelson, John M.
- Nature Materials, Vol. 2, Issue 10
Exceptional Property Changes in Ultrathin Films of Polycarbonate: Glass Temperature, Rubbery Stiffening, and Flow
journal, February 2012
- O’Connell, Paul A.; Wang, Jian; Ishola, T. Adeniyi
- Macromolecules, Vol. 45, Issue 5
Glass Transition Temperature of Polymer Nanoparticles under Soft and Hard Confinement
journal, May 2011
- Zhang, Chuan; Guo, Yunlong; Priestley, Rodney D.
- Macromolecules, Vol. 44, Issue 10
Influence of Backbone Rigidity on Nanoscale Confinement Effects in Model Glass-Forming Polymers
journal, June 2013
- Shavit, Amit; Riggleman, Robert A.
- Macromolecules, Vol. 46, Issue 12
Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time
journal, October 2013
- Mirigian, Stephen; Schweizer, Kenneth S.
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 21
Dynamics of Nanoconfined Supercooled Liquids
journal, May 2011
- Richert, R.
- Annual Review of Physical Chemistry, Vol. 62, Issue 1
Character of the glass transition in thin supported polymer films
journal, January 2001
- Kawana, Shin; Jones, Richard A. L.
- Physical Review E, Vol. 63, Issue 2
What can we learn about a dynamical length scale in glasses from measurements of surface mobility?
journal, August 2013
- Forrest, J. A.
- The Journal of Chemical Physics, Vol. 139, Issue 8
Quantifying glass transition behavior in ultrathin free-standing polymer films
journal, October 2000
- Mattsson, J.; Forrest, J. A.; Börjesson, L.
- Physical Review E, Vol. 62, Issue 4
Quantitative equivalence between polymer nanocomposites and thin polymer films
journal, August 2005
- Bansal, Amitabh; Yang, Hoichang; Li, Chunzhao
- Nature Materials, Vol. 4, Issue 9
Effect of Free Surfaces on the Glass Transition Temperature of Thin Polymer Films
journal, September 1996
- Forrest, J. A.; Dalnoki-Veress, K.; Stevens, J. R.
- Physical Review Letters, Vol. 77, Issue 10
Hiking down the Energy Landscape: Progress Toward the Kauzmann Temperature via Vapor Deposition
journal, April 2008
- Kearns, Kenneth L.; Swallen, Stephen F.; Ediger, M. D.
- The Journal of Physical Chemistry B, Vol. 112, Issue 16
When Does a Glass Transition Temperature Not Signify a Glass Transition?
journal, March 2014
- Forrest, J. A.; Dalnoki-Veress, K.
- ACS Macro Letters, Vol. 3, Issue 4
Evidence for the Shift of the Glass Transition near the Particles in Silica-Filled Elastomers
journal, December 2002
- Berriot, Julien; Montes, Hélène; Lequeux, François
- Macromolecules, Vol. 35, Issue 26
Molecular Motion in Free-Standing Thin Films of Poly(methyl methacrylate), Poly(4- tert -butylstyrene), Poly(α-methylstyrene), and Poly(2-vinylpyridine)
journal, September 2011
- Paeng, Keewook; Ediger, M. D.
- Macromolecules, Vol. 44, Issue 17
On the surface of glasses
journal, December 2008
- Stevenson, Jacob D.; Wolynes, Peter G.
- The Journal of Chemical Physics, Vol. 129, Issue 23
Impacts of Polystyrene Molecular Weight and Modification to the Repeat Unit Structure on the Glass Transition−Nanoconfinement Effect and the Cooperativity Length Scale
journal, March 2005
- Ellison, Christopher J.; Mundra, Manish K.; Torkelson, John M.
- Macromolecules, Vol. 38, Issue 5
Theory of dynamic barriers, activated hopping, and the glass transition in polymer melts
journal, July 2004
- Schweizer, Kenneth S.; Saltzman, Erica J.
- The Journal of Chemical Physics, Vol. 121, Issue 4
Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. I. General formulation and application to hard sphere fluids
journal, May 2014
- Mirigian, Stephen; Schweizer, Kenneth S.
- The Journal of Chemical Physics, Vol. 140, Issue 19
Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. II. Thermal liquids
journal, May 2014
- Mirigian, Stephen; Schweizer, Kenneth S.
- The Journal of Chemical Physics, Vol. 140, Issue 19
Delayed Glassification Model for Free-Surface Suppression of T g in Polymer Glasses
journal, December 2010
- Milner, Scott T.; Lipson, Jane E. G.
- Macromolecules, Vol. 43, Issue 23
Glass Transitions in Highly Attractive Highly Filled Polymer Nanocomposites
journal, January 2012
- Moll, Joseph; Kumar, Sanat K.
- Macromolecules, Vol. 45, Issue 2