Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films
- Authors:
-
- Departments of Materials Science and Chemistry, University of Illinois, Urbana, Illinois 61801, USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1234109
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Chemical Physics
- Additional Journal Information:
- Journal Name: Journal of Chemical Physics Journal Volume: 143 Journal Issue: 24; Journal ID: ISSN 0021-9606
- Publisher:
- American Institute of Physics
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Mirigian, Stephen, and Schweizer, Kenneth S. Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films. United States: N. p., 2015.
Web. doi:10.1063/1.4937953.
Mirigian, Stephen, & Schweizer, Kenneth S. Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films. United States. https://doi.org/10.1063/1.4937953
Mirigian, Stephen, and Schweizer, Kenneth S. Mon .
"Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films". United States. https://doi.org/10.1063/1.4937953.
@article{osti_1234109,
title = {Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films},
author = {Mirigian, Stephen and Schweizer, Kenneth S.},
abstractNote = {},
doi = {10.1063/1.4937953},
journal = {Journal of Chemical Physics},
number = 24,
volume = 143,
place = {United States},
year = {Mon Dec 28 00:00:00 EST 2015},
month = {Mon Dec 28 00:00:00 EST 2015}
}
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https://doi.org/10.1063/1.4937953
https://doi.org/10.1063/1.4937953
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Cited by: 56 works
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Works referenced in this record:
Size-Dependent Depression of the Glass Transition Temperature in Polymer Films
journal, July 1994
- Keddie, J. L.; Jones, R. A. L.; Cory, R. A.
- Europhysics Letters (EPL), Vol. 27, Issue 1
Model polymer nanocomposites provide an understanding of confinement effects in real nanocomposites
journal, March 2007
- Rittigstein, Perla; Priestley, Rodney D.; Broadbelt, Linda J.
- Nature Materials, Vol. 6, Issue 4
Molecular Simulation of Ultrathin Polymeric Films near the Glass Transition
journal, October 2000
- Torres, J. A.; Nealey, P. F.; de Pablo, J. J.
- Physical Review Letters, Vol. 85, Issue 15
Cooperative strings and glassy interfaces
journal, June 2015
- Salez, Thomas; Salez, Justin; Dalnoki-Veress, Kari
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 27
Surface Self-Diffusion of Organic Glasses
journal, August 2013
- Brian, Caleb W.; Yu, Lian
- The Journal of Physical Chemistry A, Vol. 117, Issue 50
Comparing surface and bulk flow of a molecular glass former
journal, January 2012
- Daley, C. R.; Fakhraai, Z.; Ediger, M. D.
- Soft Matter, Vol. 8, Issue 7
A Direct Quantitative Measure of Surface Mobility in a Glassy Polymer
journal, February 2014
- Chai, Y.; Salez, T.; McGraw, J. D.
- Science, Vol. 343, Issue 6174
Dynamics of glass‐forming liquids. I. Temperature‐derivative analysis of dielectric relaxation data
journal, April 1995
- Stickel, F.; Fischer, E. W.; Richert, R.
- The Journal of Chemical Physics, Vol. 102, Issue 15
Glass Transition Dynamics and Fragility of Ultrathin Miscible Polymer Blend Films
journal, September 2015
- Glor, Ethan C.; Composto, Russell J.; Fakhraai, Zahra
- Macromolecules, Vol. 48, Issue 18
Lattice model of mobility at interfaces: free surfaces, substrates, and bilayers
journal, January 2013
- Tito, Nicholas B.; Lipson, Jane E. G.; Milner, Scott T.
- Soft Matter, Vol. 9, Issue 39
Measuring the Surface Dynamics of Glassy Polymers
journal, February 2008
- Fakhraai, Z.; Forrest, J. A.
- Science, Vol. 319, Issue 5863
Theoretical perspective on the glass transition and amorphous materials
journal, June 2011
- Berthier, Ludovic; Biroli, Giulio
- Reviews of Modern Physics, Vol. 83, Issue 2
Direct Measurement of Molecular Motion in Freestanding Polystyrene Thin Films
journal, June 2011
- Paeng, Keewook; Swallen, Stephen F.; Ediger, M. D.
- Journal of the American Chemical Society, Vol. 133, Issue 22
Slow dynamics near glass transitions in thin polymer films
journal, June 2001
- Fukao, Koji; Miyamoto, Yoshihisa
- Physical Review E, Vol. 64, Issue 1
Local and Average Glass Transitions in Polymer Thin Films
journal, December 2010
- Lipson, Jane E. G.; Milner, Scott T.
- Macromolecules, Vol. 43, Issue 23
Perspective: Supercooled liquids and glasses
journal, August 2012
- Ediger, M. D.; Harrowell, Peter
- The Journal of Chemical Physics, Vol. 137, Issue 8
The Relaxation Dynamics of a Supercooled Liquid Confined by Rough Walls †
journal, May 2004
- Scheidler, Peter; Kob, Walter; Binder, Kurt
- The Journal of Physical Chemistry B, Vol. 108, Issue 21
The glass transition in thin polymer films
journal, November 2001
- Forrest, James A.; Dalnoki-Veress, Kari
- Advances in Colloid and Interface Science, Vol. 94, Issue 1-3
Organic Glasses with Exceptional Thermodynamic and Kinetic Stability
journal, January 2007
- Swallen, S. F.; Kearns, K. L.; Mapes, M. K.
- Science, Vol. 315, Issue 5810
Fast Surface Diffusion of Amorphous o -Terphenyl and Its Competition with Viscous Flow in Surface Evolution
journal, April 2015
- Zhang, Wei; Brian, Caleb W.; Yu, Lian
- The Journal of Physical Chemistry B, Vol. 119, Issue 15
Dynamics near Free Surfaces and the Glass Transition in Thin Polymer Films: A View to the Future
journal, November 2013
- Ediger, M. D.; Forrest, J. A.
- Macromolecules, Vol. 47, Issue 2
Surface Self-Diffusion of an Organic Glass
journal, June 2011
- Zhu, L.; Brian, C. W.; Swallen, S. F.
- Physical Review Letters, Vol. 106, Issue 25
Measuring surface and bulk relaxation in glassy polymers
journal, June 2011
- Qi, D.; Ilton, M.; Forrest, J. A.
- The European Physical Journal E, Vol. 34, Issue 6
Interfacial Dynamic Length Scales in the Glass Transition of a Model Freestanding Polymer Film and Their Connection to Cooperative Motion
journal, December 2013
- Lang, Ryan J.; Simmons, David S.
- Macromolecules, Vol. 46, Issue 24
Facilitation of interfacial dynamics in entangled polymer films
journal, November 2014
- Glor, Ethan C.; Fakhraai, Zahra
- The Journal of Chemical Physics, Vol. 141, Issue 19
Glassy Dynamics and Glass Transition in Nanometric Thin Layers of Polystyrene
journal, December 2010
- Tress, Martin; Erber, Michael; Mapesa, Emmanuel U.
- Macromolecules, Vol. 43, Issue 23
Communication: Slow relaxation, spatial mobility gradients, and vitrification in confined films
journal, October 2014
- Mirigian, Stephen; Schweizer, Kenneth S.
- The Journal of Chemical Physics, Vol. 141, Issue 16
Glass transitions in thin polymer films
journal, July 2000
- de Gennes, P. G.
- The European Physical Journal E, Vol. 2, Issue 3
On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids
journal, July 1965
- Adam, Gerold; Gibbs, Julian H.
- The Journal of Chemical Physics, Vol. 43, Issue 1
Tg depression and invariant segmental dynamics in polystyrene thin films
journal, January 2012
- Boucher, Virginie M.; Cangialosi, Daniele; Yin, Huajie
- Soft Matter, Vol. 8, Issue 19
Physical Aging in Ultrathin Polystyrene Films: Evidence of a Gradient in Dynamics at the Free Surface and Its Connection to the Glass Transition Temperature Reductions
journal, October 2010
- Pye, Justin E.; Rohald, Kate A.; Baker, Elizabeth A.
- Macromolecules, Vol. 43, Issue 19
Glass Transition Dynamics and Surface Layer Mobility in Unentangled Polystyrene Films
journal, June 2010
- Yang, Z.; Fujii, Y.; Lee, F. K.
- Science, Vol. 328, Issue 5986
The distribution of glass-transition temperatures in nanoscopically confined glass formers
journal, September 2003
- Ellison, Christopher J.; Torkelson, John M.
- Nature Materials, Vol. 2, Issue 10
Exceptional Property Changes in Ultrathin Films of Polycarbonate: Glass Temperature, Rubbery Stiffening, and Flow
journal, February 2012
- O’Connell, Paul A.; Wang, Jian; Ishola, T. Adeniyi
- Macromolecules, Vol. 45, Issue 5
Interfacial mobility scale determines the scale of collective motion and relaxation rate in polymer films
journal, June 2014
- Hanakata, Paul Z.; Douglas, Jack F.; Starr, Francis W.
- Nature Communications, Vol. 5, Issue 1
The origin of glassy dynamics in the 2D facilitated kinetic Ising model
journal, September 1991
- Butler, Scott; Harrowell, Peter
- The Journal of Chemical Physics, Vol. 95, Issue 6
Glass Transition Temperature of Polymer Nanoparticles under Soft and Hard Confinement
journal, May 2011
- Zhang, Chuan; Guo, Yunlong; Priestley, Rodney D.
- Macromolecules, Vol. 44, Issue 10
Influence of Backbone Rigidity on Nanoscale Confinement Effects in Model Glass-Forming Polymers
journal, June 2013
- Shavit, Amit; Riggleman, Robert A.
- Macromolecules, Vol. 46, Issue 12
Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time
journal, October 2013
- Mirigian, Stephen; Schweizer, Kenneth S.
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 21
Self-diffusion of the amorphous pharmaceutical indomethacin near Tg
journal, January 2011
- Swallen, Stephen F.; Ediger, M. D.
- Soft Matter, Vol. 7, Issue 21
Percolation model of interfacial effects in polymeric glasses
journal, October 2009
- Lipson, J. E. G.; Milner, S. T.
- The European Physical Journal B, Vol. 72, Issue 1
Dynamics on the Way to Forming Glass: Bubbles in Space-Time
journal, March 2010
- Chandler, David; Garrahan, Juan P.
- Annual Review of Physical Chemistry, Vol. 61, Issue 1
Dynamics of Nanoconfined Supercooled Liquids
journal, May 2011
- Richert, R.
- Annual Review of Physical Chemistry, Vol. 62, Issue 1
Character of the glass transition in thin supported polymer films
journal, January 2001
- Kawana, Shin; Jones, Richard A. L.
- Physical Review E, Vol. 63, Issue 2
The Descent into Glass Formation in Polymer Fluids
journal, March 2011
- Freed, Karl F.
- Accounts of Chemical Research, Vol. 44, Issue 3
What can we learn about a dynamical length scale in glasses from measurements of surface mobility?
journal, August 2013
- Forrest, J. A.
- The Journal of Chemical Physics, Vol. 139, Issue 8
Quantifying glass transition behavior in ultrathin free-standing polymer films
journal, October 2000
- Mattsson, J.; Forrest, J. A.; Börjesson, L.
- Physical Review E, Vol. 62, Issue 4
Substrate and Chain Size Dependence of Near Surface Dynamics of Glassy Polymers
journal, August 2008
- Qi, D.; Fakhraai, Z.; Forrest, J. A.
- Physical Review Letters, Vol. 101, Issue 9
Combined Dependence of Nanoconfined T g on Interfacial Energy and Softness of Confinement
journal, July 2014
- Lang, Ryan J.; Merling, Weston L.; Simmons, David S.
- ACS Macro Letters, Vol. 3, Issue 8
Quantitative equivalence between polymer nanocomposites and thin polymer films
journal, August 2005
- Bansal, Amitabh; Yang, Hoichang; Li, Chunzhao
- Nature Materials, Vol. 4, Issue 9
Effect of Free Surfaces on the Glass Transition Temperature of Thin Polymer Films
journal, September 1996
- Forrest, J. A.; Dalnoki-Veress, K.; Stevens, J. R.
- Physical Review Letters, Vol. 77, Issue 10
Hiking down the Energy Landscape: Progress Toward the Kauzmann Temperature via Vapor Deposition
journal, April 2008
- Kearns, Kenneth L.; Swallen, Stephen F.; Ediger, M. D.
- The Journal of Physical Chemistry B, Vol. 112, Issue 16
When Does a Glass Transition Temperature Not Signify a Glass Transition?
journal, March 2014
- Forrest, J. A.; Dalnoki-Veress, K.
- ACS Macro Letters, Vol. 3, Issue 4
Physical vapor deposition as a route to hidden amorphous states
journal, July 2009
- Dawson, K. J.; Kearns, K. L.; Yu, L.
- Proceedings of the National Academy of Sciences, Vol. 106, Issue 36
Molecular mobility in supported thin films of polystyrene, poly(methyl methacrylate), and poly(2-vinyl pyridine) probed by dye reorientation
journal, January 2012
- Paeng, Keewook; Richert, Ranko; Ediger, M. D.
- Soft Matter, Vol. 8, Issue 3
Evidence for the Shift of the Glass Transition near the Particles in Silica-Filled Elastomers
journal, December 2002
- Berriot, Julien; Montes, Hélène; Lequeux, François
- Macromolecules, Vol. 35, Issue 26
Dynamical Theory of Segmental Relaxation and Emergent Elasticity in Supercooled Polymer Melts
journal, March 2015
- Mirigian, Stephen; Schweizer, Kenneth S.
- Macromolecules, Vol. 48, Issue 6
Molecular Motion in Free-Standing Thin Films of Poly(methyl methacrylate), Poly(4- tert -butylstyrene), Poly(α-methylstyrene), and Poly(2-vinylpyridine)
journal, September 2011
- Paeng, Keewook; Ediger, M. D.
- Macromolecules, Vol. 44, Issue 17
On the surface of glasses
journal, December 2008
- Stevenson, Jacob D.; Wolynes, Peter G.
- The Journal of Chemical Physics, Vol. 129, Issue 23
Impacts of Polystyrene Molecular Weight and Modification to the Repeat Unit Structure on the Glass Transition−Nanoconfinement Effect and the Cooperativity Length Scale
journal, March 2005
- Ellison, Christopher J.; Mundra, Manish K.; Torkelson, John M.
- Macromolecules, Vol. 38, Issue 5
Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. I. General formulation and application to hard sphere fluids
journal, May 2014
- Mirigian, Stephen; Schweizer, Kenneth S.
- The Journal of Chemical Physics, Vol. 140, Issue 19
Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. II. Thermal liquids
journal, May 2014
- Mirigian, Stephen; Schweizer, Kenneth S.
- The Journal of Chemical Physics, Vol. 140, Issue 19
Two Simultaneous Mechanisms Causing Glass Transition Temperature Reductions in High Molecular Weight Freestanding Polymer Films as Measured by Transmission Ellipsometry
journal, November 2011
- Pye, Justin E.; Roth, Connie B.
- Physical Review Letters, Vol. 107, Issue 23
S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS
journal, October 2000
- Ediger, M. D.
- Annual Review of Physical Chemistry, Vol. 51, Issue 1
Glass Transitions in Highly Attractive Highly Filled Polymer Nanocomposites
journal, January 2012
- Moll, Joseph; Kumar, Sanat K.
- Macromolecules, Vol. 45, Issue 2