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Title: Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films

Authors:
 [1];  [1]
  1. Departments of Materials Science and Chemistry, University of Illinois, Urbana, Illinois 61801, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1234109
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Name: Journal of Chemical Physics Journal Volume: 143 Journal Issue: 24; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Mirigian, Stephen, and Schweizer, Kenneth S. Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films. United States: N. p., 2015. Web. doi:10.1063/1.4937953.
Mirigian, Stephen, & Schweizer, Kenneth S. Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films. United States. doi:10.1063/1.4937953.
Mirigian, Stephen, and Schweizer, Kenneth S. Mon . "Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films". United States. doi:10.1063/1.4937953.
@article{osti_1234109,
title = {Theory of activated glassy relaxation, mobility gradients, surface diffusion, and vitrification in free standing thin films},
author = {Mirigian, Stephen and Schweizer, Kenneth S.},
abstractNote = {},
doi = {10.1063/1.4937953},
journal = {Journal of Chemical Physics},
number = 24,
volume = 143,
place = {United States},
year = {2015},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1063/1.4937953

Citation Metrics:
Cited by: 25 works
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Works referenced in this record:

Size-Dependent Depression of the Glass Transition Temperature in Polymer Films
journal, July 1994


Model polymer nanocomposites provide an understanding of confinement effects in real nanocomposites
journal, March 2007

  • Rittigstein, Perla; Priestley, Rodney D.; Broadbelt, Linda J.
  • Nature Materials, Vol. 6, Issue 4
  • DOI: 10.1038/nmat1870

Molecular Simulation of Ultrathin Polymeric Films near the Glass Transition
journal, October 2000


Cooperative strings and glassy interfaces
journal, June 2015

  • Salez, Thomas; Salez, Justin; Dalnoki-Veress, Kari
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 27
  • DOI: 10.1073/pnas.1503133112

Surface Self-Diffusion of Organic Glasses
journal, August 2013

  • Brian, Caleb W.; Yu, Lian
  • The Journal of Physical Chemistry A, Vol. 117, Issue 50
  • DOI: 10.1021/jp404944s

Comparing surface and bulk flow of a molecular glass former
journal, January 2012

  • Daley, C. R.; Fakhraai, Z.; Ediger, M. D.
  • Soft Matter, Vol. 8, Issue 7
  • DOI: 10.1039/c2sm06826e

A Direct Quantitative Measure of Surface Mobility in a Glassy Polymer
journal, February 2014


Dynamics of glass‐forming liquids. I. Temperature‐derivative analysis of dielectric relaxation data
journal, April 1995

  • Stickel, F.; Fischer, E. W.; Richert, R.
  • The Journal of Chemical Physics, Vol. 102, Issue 15
  • DOI: 10.1063/1.469071

Colloquium : The glass transition and elastic models of glass-forming liquids
journal, September 2006


Glass Transition Dynamics and Fragility of Ultrathin Miscible Polymer Blend Films
journal, September 2015


Lattice model of mobility at interfaces: free surfaces, substrates, and bilayers
journal, January 2013

  • Tito, Nicholas B.; Lipson, Jane E. G.; Milner, Scott T.
  • Soft Matter, Vol. 9, Issue 39
  • DOI: 10.1039/c3sm51287h

Measuring the Surface Dynamics of Glassy Polymers
journal, February 2008


Theoretical perspective on the glass transition and amorphous materials
journal, June 2011


Direct Measurement of Molecular Motion in Freestanding Polystyrene Thin Films
journal, June 2011

  • Paeng, Keewook; Swallen, Stephen F.; Ediger, M. D.
  • Journal of the American Chemical Society, Vol. 133, Issue 22
  • DOI: 10.1021/ja2022834

Slow dynamics near glass transitions in thin polymer films
journal, June 2001


Local and Average Glass Transitions in Polymer Thin Films
journal, December 2010

  • Lipson, Jane E. G.; Milner, Scott T.
  • Macromolecules, Vol. 43, Issue 23
  • DOI: 10.1021/ma101099n

Perspective: Supercooled liquids and glasses
journal, August 2012

  • Ediger, M. D.; Harrowell, Peter
  • The Journal of Chemical Physics, Vol. 137, Issue 8
  • DOI: 10.1063/1.4747326

The Relaxation Dynamics of a Supercooled Liquid Confined by Rough Walls
journal, May 2004

  • Scheidler, Peter; Kob, Walter; Binder, Kurt
  • The Journal of Physical Chemistry B, Vol. 108, Issue 21
  • DOI: 10.1021/jp036593s

The glass transition in thin polymer films
journal, November 2001


Organic Glasses with Exceptional Thermodynamic and Kinetic Stability
journal, January 2007


Fast Surface Diffusion of Amorphous o -Terphenyl and Its Competition with Viscous Flow in Surface Evolution
journal, April 2015

  • Zhang, Wei; Brian, Caleb W.; Yu, Lian
  • The Journal of Physical Chemistry B, Vol. 119, Issue 15
  • DOI: 10.1021/jp5127464

Dynamics near Free Surfaces and the Glass Transition in Thin Polymer Films: A View to the Future
journal, November 2013

  • Ediger, M. D.; Forrest, J. A.
  • Macromolecules, Vol. 47, Issue 2
  • DOI: 10.1021/ma4017696

Surface Self-Diffusion of an Organic Glass
journal, June 2011


Measuring surface and bulk relaxation in glassy polymers
journal, June 2011


Facilitation of interfacial dynamics in entangled polymer films
journal, November 2014

  • Glor, Ethan C.; Fakhraai, Zahra
  • The Journal of Chemical Physics, Vol. 141, Issue 19
  • DOI: 10.1063/1.4901512

Glassy Dynamics and Glass Transition in Nanometric Thin Layers of Polystyrene
journal, December 2010

  • Tress, Martin; Erber, Michael; Mapesa, Emmanuel U.
  • Macromolecules, Vol. 43, Issue 23
  • DOI: 10.1021/ma102031k

Communication: Slow relaxation, spatial mobility gradients, and vitrification in confined films
journal, October 2014

  • Mirigian, Stephen; Schweizer, Kenneth S.
  • The Journal of Chemical Physics, Vol. 141, Issue 16
  • DOI: 10.1063/1.4900507

Glass transitions in thin polymer films
journal, July 2000

  • de Gennes, P. G.
  • The European Physical Journal E, Vol. 2, Issue 3
  • DOI: 10.1007/PL00013665

On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids
journal, July 1965

  • Adam, Gerold; Gibbs, Julian H.
  • The Journal of Chemical Physics, Vol. 43, Issue 1
  • DOI: 10.1063/1.1696442

Tg depression and invariant segmental dynamics in polystyrene thin films
journal, January 2012

  • Boucher, Virginie M.; Cangialosi, Daniele; Yin, Huajie
  • Soft Matter, Vol. 8, Issue 19
  • DOI: 10.1039/c2sm25419k

Glass Transition Dynamics and Surface Layer Mobility in Unentangled Polystyrene Films
journal, June 2010


The distribution of glass-transition temperatures in nanoscopically confined glass formers
journal, September 2003

  • Ellison, Christopher J.; Torkelson, John M.
  • Nature Materials, Vol. 2, Issue 10
  • DOI: 10.1038/nmat980

Effects of confinement on material behaviour at the nanometre size scale
journal, April 2005


Exceptional Property Changes in Ultrathin Films of Polycarbonate: Glass Temperature, Rubbery Stiffening, and Flow
journal, February 2012

  • O’Connell, Paul A.; Wang, Jian; Ishola, T. Adeniyi
  • Macromolecules, Vol. 45, Issue 5
  • DOI: 10.1021/ma300098h

Interfacial mobility scale determines the scale of collective motion and relaxation rate in polymer films
journal, June 2014

  • Hanakata, Paul Z.; Douglas, Jack F.; Starr, Francis W.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5163

The origin of glassy dynamics in the 2D facilitated kinetic Ising model
journal, September 1991

  • Butler, Scott; Harrowell, Peter
  • The Journal of Chemical Physics, Vol. 95, Issue 6
  • DOI: 10.1063/1.461768

Glass Transition Temperature of Polymer Nanoparticles under Soft and Hard Confinement
journal, May 2011

  • Zhang, Chuan; Guo, Yunlong; Priestley, Rodney D.
  • Macromolecules, Vol. 44, Issue 10
  • DOI: 10.1021/ma1026862

Influence of Backbone Rigidity on Nanoscale Confinement Effects in Model Glass-Forming Polymers
journal, June 2013

  • Shavit, Amit; Riggleman, Robert A.
  • Macromolecules, Vol. 46, Issue 12
  • DOI: 10.1021/ma400210w

Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time
journal, October 2013

  • Mirigian, Stephen; Schweizer, Kenneth S.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 21
  • DOI: 10.1021/jz4018943

Self-diffusion of the amorphous pharmaceutical indomethacin near Tg
journal, January 2011

  • Swallen, Stephen F.; Ediger, M. D.
  • Soft Matter, Vol. 7, Issue 21
  • DOI: 10.1039/c1sm06283b

Percolation model of interfacial effects in polymeric glasses
journal, October 2009


Dynamics on the Way to Forming Glass: Bubbles in Space-Time
journal, March 2010


Dynamics of Nanoconfined Supercooled Liquids
journal, May 2011


Character of the glass transition in thin supported polymer films
journal, January 2001


The Descent into Glass Formation in Polymer Fluids
journal, March 2011

  • Freed, Karl F.
  • Accounts of Chemical Research, Vol. 44, Issue 3
  • DOI: 10.1021/ar100122w

What can we learn about a dynamical length scale in glasses from measurements of surface mobility?
journal, August 2013

  • Forrest, J. A.
  • The Journal of Chemical Physics, Vol. 139, Issue 8
  • DOI: 10.1063/1.4818989

Quantifying glass transition behavior in ultrathin free-standing polymer films
journal, October 2000


Substrate and Chain Size Dependence of Near Surface Dynamics of Glassy Polymers
journal, August 2008


Combined Dependence of Nanoconfined T g on Interfacial Energy and Softness of Confinement
journal, July 2014

  • Lang, Ryan J.; Merling, Weston L.; Simmons, David S.
  • ACS Macro Letters, Vol. 3, Issue 8
  • DOI: 10.1021/mz500361v

Quantitative equivalence between polymer nanocomposites and thin polymer films
journal, August 2005

  • Bansal, Amitabh; Yang, Hoichang; Li, Chunzhao
  • Nature Materials, Vol. 4, Issue 9
  • DOI: 10.1038/nmat1447

Effect of Free Surfaces on the Glass Transition Temperature of Thin Polymer Films
journal, September 1996


Hiking down the Energy Landscape:  Progress Toward the Kauzmann Temperature via Vapor Deposition
journal, April 2008

  • Kearns, Kenneth L.; Swallen, Stephen F.; Ediger, M. D.
  • The Journal of Physical Chemistry B, Vol. 112, Issue 16
  • DOI: 10.1021/jp7113384

When Does a Glass Transition Temperature Not Signify a Glass Transition?
journal, March 2014

  • Forrest, J. A.; Dalnoki-Veress, K.
  • ACS Macro Letters, Vol. 3, Issue 4
  • DOI: 10.1021/mz4006217

Physical vapor deposition as a route to hidden amorphous states
journal, July 2009

  • Dawson, K. J.; Kearns, K. L.; Yu, L.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 36
  • DOI: 10.1073/pnas.0901469106

Molecular mobility in supported thin films of polystyrene, poly(methyl methacrylate), and poly(2-vinyl pyridine) probed by dye reorientation
journal, January 2012

  • Paeng, Keewook; Richert, Ranko; Ediger, M. D.
  • Soft Matter, Vol. 8, Issue 3
  • DOI: 10.1039/C1SM06501G

Evidence for the Shift of the Glass Transition near the Particles in Silica-Filled Elastomers
journal, December 2002

  • Berriot, Julien; Montes, Hélène; Lequeux, François
  • Macromolecules, Vol. 35, Issue 26
  • DOI: 10.1021/ma0212700

Dynamical Theory of Segmental Relaxation and Emergent Elasticity in Supercooled Polymer Melts
journal, March 2015

  • Mirigian, Stephen; Schweizer, Kenneth S.
  • Macromolecules, Vol. 48, Issue 6
  • DOI: 10.1021/ma5022083

On the surface of glasses
journal, December 2008

  • Stevenson, Jacob D.; Wolynes, Peter G.
  • The Journal of Chemical Physics, Vol. 129, Issue 23
  • DOI: 10.1063/1.3041651

Impacts of Polystyrene Molecular Weight and Modification to the Repeat Unit Structure on the Glass Transition−Nanoconfinement Effect and the Cooperativity Length Scale
journal, March 2005

  • Ellison, Christopher J.; Mundra, Manish K.; Torkelson, John M.
  • Macromolecules, Vol. 38, Issue 5
  • DOI: 10.1021/ma047846y

Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. I. General formulation and application to hard sphere fluids
journal, May 2014

  • Mirigian, Stephen; Schweizer, Kenneth S.
  • The Journal of Chemical Physics, Vol. 140, Issue 19
  • DOI: 10.1063/1.4874842

Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. II. Thermal liquids
journal, May 2014

  • Mirigian, Stephen; Schweizer, Kenneth S.
  • The Journal of Chemical Physics, Vol. 140, Issue 19
  • DOI: 10.1063/1.4874843

S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS
journal, October 2000


Glass Transitions in Highly Attractive Highly Filled Polymer Nanocomposites
journal, January 2012

  • Moll, Joseph; Kumar, Sanat K.
  • Macromolecules, Vol. 45, Issue 2
  • DOI: 10.1021/ma202218x