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Title: Broadband optical absorption by tunable Mie resonances in silicon nanocone arrays

Abstract

Nanostructure arrays such as nanowire, nanopillar, and nanocone arrays have been proposed to be promising antireflection structures for photovoltaic applications due to their great light trapping ability. In this paper, the optical properties of Si nanopillar and nanocone arrays in visible and infrared region were studied by both theoretical calculations and experiments. The results show that the Mie resonance can be continuously tuned across a wide range of wavelength by varying the diameter of the nanopillars. However, Si nanopillar array with uniform diameter exhibits only discrete resonance mode, thus can't achieve a high broadband absorption. On the other hand, the Mie resonance wavelength in a Si nanocone array can vary continuously as the diameters of the cross sections increase from the apex to the base. Therefore Si nanocone arrays can strongly interact with the incident light in the broadband spectrum and the absorbance by Si nanocone arrays is higher than 95% over the wavelength from 300 to 2000 nm. In addition to the Mie resonance, the broadband optical absorption of Si nanocone arrays is also affected by Wood-Rayleigh anomaly effect and metal impurities introduced in the fabrication process.

Authors:
 [1];  [1];  [2];  [1];  [3];  [1];  [1];  [4];  [4];  [4]
  1. Fudan Univ., Shanghai (China)
  2. Fudan Univ., Shanghai (China); Key Lab. for Information Science of Electromagnetic Waves (MoE), Shanghai (China); Ames Lab., Ames, IA (United States)
  3. Chinese Academy of Sciences, Shanghai (China)
  4. Ames Lab., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1193750
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 5; Journal Issue: 3; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats

Wang, Z. Y., Zhang, R. J., Wang, S. Y., Lu, M., Chen, X., Zheng, Y. X., Chen, L. Y., Ye, Z., Wang, C. Z., and Ho, K. M. Broadband optical absorption by tunable Mie resonances in silicon nanocone arrays. United States: N. p., 2015. Web. doi:10.1038/srep07810.
Wang, Z. Y., Zhang, R. J., Wang, S. Y., Lu, M., Chen, X., Zheng, Y. X., Chen, L. Y., Ye, Z., Wang, C. Z., & Ho, K. M. Broadband optical absorption by tunable Mie resonances in silicon nanocone arrays. United States. https://doi.org/10.1038/srep07810
Wang, Z. Y., Zhang, R. J., Wang, S. Y., Lu, M., Chen, X., Zheng, Y. X., Chen, L. Y., Ye, Z., Wang, C. Z., and Ho, K. M. Thu . "Broadband optical absorption by tunable Mie resonances in silicon nanocone arrays". United States. https://doi.org/10.1038/srep07810. https://www.osti.gov/servlets/purl/1193750.
@article{osti_1193750,
title = {Broadband optical absorption by tunable Mie resonances in silicon nanocone arrays},
author = {Wang, Z. Y. and Zhang, R. J. and Wang, S. Y. and Lu, M. and Chen, X. and Zheng, Y. X. and Chen, L. Y. and Ye, Z. and Wang, C. Z. and Ho, K. M.},
abstractNote = {Nanostructure arrays such as nanowire, nanopillar, and nanocone arrays have been proposed to be promising antireflection structures for photovoltaic applications due to their great light trapping ability. In this paper, the optical properties of Si nanopillar and nanocone arrays in visible and infrared region were studied by both theoretical calculations and experiments. The results show that the Mie resonance can be continuously tuned across a wide range of wavelength by varying the diameter of the nanopillars. However, Si nanopillar array with uniform diameter exhibits only discrete resonance mode, thus can't achieve a high broadband absorption. On the other hand, the Mie resonance wavelength in a Si nanocone array can vary continuously as the diameters of the cross sections increase from the apex to the base. Therefore Si nanocone arrays can strongly interact with the incident light in the broadband spectrum and the absorbance by Si nanocone arrays is higher than 95% over the wavelength from 300 to 2000 nm. In addition to the Mie resonance, the broadband optical absorption of Si nanocone arrays is also affected by Wood-Rayleigh anomaly effect and metal impurities introduced in the fabrication process.},
doi = {10.1038/srep07810},
journal = {Scientific Reports},
number = 3,
volume = 5,
place = {United States},
year = {Thu Jan 15 00:00:00 EST 2015},
month = {Thu Jan 15 00:00:00 EST 2015}
}

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Works referenced in this record:

Magnetic dipole radiation tailored by substrates: numerical investigation
journal, January 2014

  • Markovich, D. L.; Ginzburg, P.; Samusev, A. K.
  • Optics Express, Vol. 22, Issue 9
  • DOI: 10.1364/OE.22.010693

Light propagation in nanorod arrays
journal, February 2007

  • Rahachou, A. I.; Zozoulenko, I. V.
  • Journal of Optics A: Pure and Applied Optics, Vol. 9, Issue 3
  • DOI: 10.1088/1464-4258/9/3/010

Selenium (Se)
book, January 1998


III. Note on the remarkable case of diffraction spectra described by Prof. Wood
journal, July 1907

  • Rayleigh, Lord
  • The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 14, Issue 79
  • DOI: 10.1080/14786440709463661

Higher-order incidence transfer matrix method used in three-dimensional photonic crystal coupled-resonator array simulation
journal, January 2006


Demonstration of Magnetic Dipole Resonances of Dielectric Nanospheres in the Visible Region
journal, June 2012

  • Evlyukhin, Andrey B.; Novikov, Sergey M.; Zywietz, Urs
  • Nano Letters, Vol. 12, Issue 7, p. 3749-3755
  • DOI: 10.1021/nl301594s

Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures
journal, December 2007

  • Huang, Yi-Fan; Chattopadhyay, Surojit; Jen, Yi-Jun
  • Nature Nanotechnology, Vol. 2, Issue 12, p. 770-774
  • DOI: 10.1038/nnano.2007.389

Broadband omnidirectional antireflection coating based on subwavelength surface Mie resonators
journal, January 2012

  • Spinelli, P.; Verschuuren, M. A.; Polman, A.
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1691

III. Note on the remarkable case of diffraction spectra described by Prof. Wood
journal, July 1907

  • Rayleigh, Lord
  • The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 14, Issue 79
  • DOI: 10.1080/14786440709463661

Optical Absorption Enhancement in Amorphous Silicon Nanowire and Nanocone Arrays
journal, December 2008

  • Zhu, Jia; Yu, Zongfu; Burkhard, George F.
  • Nano Letters, Vol. 9, Issue 1, p. 279-282
  • DOI: 10.1021/nl802886y

Rational geometrical design of multi-diameter nanopillars for efficient light harvesting
journal, September 2013


High-performance Si microwire photovoltaics
journal, January 2011

  • Kelzenberg, Michael D.; Turner-Evans, Daniel B.; Putnam, Morgan C.
  • Energy & Environmental Science, Vol. 4, Issue 3
  • DOI: 10.1039/c0ee00549e

Silicon nanowire array photoelectrochemical solar cells
journal, April 2008

  • Peng, Kuiqing; Wang, Xin; Lee, Shuit-Tong
  • Applied Physics Letters, Vol. 92, Issue 16
  • DOI: 10.1063/1.2909555

Light Trapping in Silicon Nanowire Solar Cells
journal, January 2010

  • Garnett, Erik; Yang, Peidong
  • Nano Letters, Vol. 10, Issue 3, p. 1082-1087
  • DOI: 10.1021/nl100161z

Demonstration of Magnetic Dipole Resonances of Dielectric Nanospheres in the Visible Region
journal, June 2012

  • Evlyukhin, Andrey B.; Novikov, Sergey M.; Zywietz, Urs
  • Nano Letters, Vol. 12, Issue 7, p. 3749-3755
  • DOI: 10.1021/nl301594s

Multipole analysis of light scattering by arbitrary-shaped nanoparticles on a plane surface
journal, January 2013

  • Evlyukhin, Andrey B.; Reinhardt, Carsten; Evlyukhin, Egor
  • Journal of the Optical Society of America B, Vol. 30, Issue 10
  • DOI: 10.1364/JOSAB.30.002589

Optical Absorption Enhancement in Amorphous Silicon Nanowire and Nanocone Arrays
journal, December 2008

  • Zhu, Jia; Yu, Zongfu; Burkhard, George F.
  • Nano Letters, Vol. 9, Issue 1, p. 279-282
  • DOI: 10.1021/nl802886y

Anti-reflecting and photonic nanostructures
journal, June 2010

  • Chattopadhyay, S.; Huang, Y. F.; Jen, Y. J.
  • Materials Science and Engineering: R: Reports, Vol. 69, Issue 1-3
  • DOI: 10.1016/j.mser.2010.04.001

Dielectric properties of heavily doped crystalline and amorphous silicon from 1.5 to 6.0 eV
journal, January 1984


A close to unity and all-solar-spectrum absorption by ion-sputtering induced Si nanocone arrays
journal, January 2012


Enhanced absorption in silicon nanocone arrays for photovoltaics
journal, April 2012


Substrate-modified scattering properties of silicon nanostructures for solar energy applications
journal, January 2013


Optical response features of Si-nanoparticle arrays
journal, July 2010


Semiconductor Nanowire Optical Antenna Solar Absorbers
journal, February 2010

  • Cao, Linyou; Fan, Pengyu; Vasudev, Alok P.
  • Nano Letters, Vol. 10, Issue 2
  • DOI: 10.1021/nl9036627

Magnetic dipole radiation tailored by substrates: numerical investigation
preprint, January 2014


Self-organized antireflecting nano-cone arrays on Si (100) induced by ion bombardment
journal, March 2011

  • Hildebrandt, Meret
  • Journal of Applied Physics, Vol. 109, Issue 5
  • DOI: 10.1063/1.3560539

Semiconductor Nanowire Optical Antenna Solar Absorbers
journal, February 2010

  • Cao, Linyou; Fan, Pengyu; Vasudev, Alok P.
  • Nano Letters, Vol. 10, Issue 2
  • DOI: 10.1021/nl9036627

High-Efficiency Amorphous Silicon Solar Cell on a Periodic Nanocone Back Reflector
journal, April 2012

  • Hsu, Ching-Mei; Battaglia, Corsin; Pahud, Celine
  • Advanced Energy Materials, Vol. 2, Issue 6
  • DOI: 10.1002/aenm.201100514

Mie resonance-enhanced light absorption in periodic silicon nanopillar arrays
journal, January 2013

  • Bezares, Francisco J.; Long, James P.; Glembocki, Orest J.
  • Optics Express, Vol. 21, Issue 23
  • DOI: 10.1364/OE.21.027587

Design of Light Scattering in Nanowire Materials for Photovoltaic Applications
journal, September 2008

  • Muskens, Otto L.; Rivas, Jaime Gómez; Algra, Rienk E.
  • Nano Letters, Vol. 8, Issue 9, p. 2638-2642
  • DOI: 10.1021/nl0808076

Enhanced absorption in silicon nanocone arrays for photovoltaics
journal, April 2012


Periodic Si nanopillar arrays by anodic aluminum oxide template and catalytic etching for broadband and omnidirectional light harvesting
journal, December 2011

  • Wang, Hsin-Ping; Tsai, Kun-Tong; Lai, Kun-Yu
  • Optics Express, Vol. 20, Issue S1
  • DOI: 10.1364/oe.20.000a94

Optical thin-film materials with low refractive index for broadband elimination of Fresnel reflection
journal, March 2007


Broadband omnidirectional antireflection coating based on subwavelength surface Mie resonators
journal, January 2012

  • Spinelli, P.; Verschuuren, M. A.; Polman, A.
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1691

Multipole light scattering by nonspherical nanoparticles in the discrete dipole approximation
journal, December 2011

  • Evlyukhin, Andrey B.; Reinhardt, Carsten; Chichkov, Boris N.
  • Physical Review B, Vol. 84, Issue 23
  • DOI: 10.1103/PhysRevB.84.235429

User Guide for the Discrete Dipole Approximation Code DDSCAT 7.2
preprint, January 2012


Absorption and Scattering of Light by Small Particles
book, April 1998


Designing dielectric resonators on substrates: Combining magnetic and electric resonances
journal, January 2013


Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures
journal, December 2007

  • Huang, Yi-Fan; Chattopadhyay, Surojit; Jen, Yi-Jun
  • Nature Nanotechnology, Vol. 2, Issue 12, p. 770-774
  • DOI: 10.1038/nnano.2007.389

Design of Light Scattering in Nanowire Materials for Photovoltaic Applications
journal, September 2008

  • Muskens, Otto L.; Rivas, Jaime Gómez; Algra, Rienk E.
  • Nano Letters, Vol. 8, Issue 9, p. 2638-2642
  • DOI: 10.1021/nl0808076

Light Trapping in Silicon Nanowire Solar Cells
journal, January 2010

  • Garnett, Erik; Yang, Peidong
  • Nano Letters, Vol. 10, Issue 3, p. 1082-1087
  • DOI: 10.1021/nl100161z

Magnetic light
journal, July 2012

  • Kuznetsov, Arseniy I.; Miroshnichenko, Andrey E.; Fu, Yuan Hsing
  • Scientific Reports, Vol. 2, Issue 1
  • DOI: 10.1038/srep00492

Works referencing / citing this record:

An Ingenious Super Light Trapping Surface Templated from Butterfly Wing Scales
journal, August 2015


A Broadband Plasmonic Metasurface Superabsorber at Optical Frequencies: Analytical Design Framework and Demonstration
journal, June 2018

  • Nagarajan, Arvind; Vivek, Kumar; Shah, Manav
  • Advanced Optical Materials, Vol. 6, Issue 16
  • DOI: 10.1002/adom.201800253

An Investigation on a Crystalline-Silicon Solar Cell with Black Silicon Layer at the Rear
journal, December 2017


Fabrication of Ag‐modified nanocone frustum arrays with controlled shape as active substrates for surface‐enhanced Raman scattering
journal, July 2019

  • Mehrvar, Leila; Sadeghipari, Mehrnoosh; Tavassoli, Seyed Hassan
  • Journal of Raman Spectroscopy, Vol. 50, Issue 10
  • DOI: 10.1002/jrs.5662

Localized photodeposition of catalysts using nanophotonic resonances in silicon photocathodes
journal, January 2018

  • Kontoleta, Evgenia; Askes, Sven H. C.; Lai, Lai-Hung
  • Beilstein Journal of Nanotechnology, Vol. 9
  • DOI: 10.3762/bjnano.9.198

Perovskite/c-Si tandem solar cell with inverted nanopyramids: realizing high efficiency by controllable light trapping
journal, November 2015

  • Shi, Dai; Zeng, Yang; Shen, Wenzhong
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep16504

An Ingenious Super Light Trapping Surface Templated from Butterfly Wing Scales
journal, August 2015


Nanodome Structured BiVO 4 /GaO x N 1− x Photoanode for Solar Water Oxidation
journal, July 2017

  • Kang, Bong Kyun; Han, Gill Sang; Baek, Ji Hyun
  • Advanced Materials Interfaces, Vol. 4, Issue 17
  • DOI: 10.1002/admi.201700323

Black silicon Schottky photodetector in sub-bandgap near-infrared regime
journal, January 2019


Far-field and near-field monitoring of hybridized optical modes from Au nanoprisms suspended on a graphene/Si nanopillar array
journal, January 2017

  • Nien, Li-Wei; Chen, Kai; Dao, Thang Duy
  • Nanoscale, Vol. 9, Issue 43
  • DOI: 10.1039/c7nr05988d

Large-Area Wide-Incident-Angle Metasurface Perfect Absorber in Total Visible Band Based on Coupled Mie Resonances
journal, May 2017


Thin cylindrical slot in an optical microdisk cavity for sensing biomaterials
journal, March 2017


Broadband Perfect Absorber Based on TiN-Nanocone Metasurface
journal, July 2018

  • Huo, Dewang; Zhang, Jingwen; Wang, Yingce
  • Nanomaterials, Vol. 8, Issue 7
  • DOI: 10.3390/nano8070485

Compact nanocavity with elliptical slot inside photonic wire bandgap materials including sidewalls gratings for biosensing
journal, June 2016


Localized photodeposition of catalysts using nanophotonic resonances in silicon photocathodes
journal, January 2018

  • Kontoleta, Evgenia; Askes, Sven H. C.; Lai, Lai-Hung
  • Beilstein Journal of Nanotechnology, Vol. 9
  • DOI: 10.3762/bjnano.9.198

Enhanced Tunable Light Absorption in Nanostructured Si Arrays Based on Double‐Quarter‐Wavelength Resonance
journal, August 2019

  • Li, Zhigang; Feng, Shangshen; Liu, Yanping
  • Advanced Optical Materials, Vol. 7, Issue 22
  • DOI: 10.1002/adom.201900845

Resonant Optical Absorption and Photothermal Process in High Refractive Index Germanium Nanoparticles
journal, February 2017

  • Ishii, Satoshi; Chen, Kai; Okuyama, Hideo
  • Advanced Optical Materials, Vol. 5, Issue 5
  • DOI: 10.1002/adom.201600902

Superhydrophobic waveguide: Liquid-core air-cladding waveguide platform for optofluidics
journal, October 2018

  • Du, Ke; Wathuthanthri, Ishan; Ding, Junjun
  • Applied Physics Letters, Vol. 113, Issue 14
  • DOI: 10.1063/1.5049692

Broadband Perfect Absorber Based on TiN-Nanocone Metasurface
journal, July 2018

  • Huo, Dewang; Zhang, Jingwen; Wang, Yingce
  • Nanomaterials, Vol. 8, Issue 7
  • DOI: 10.3390/nano8070485

Large-Area Ultrabroadband Absorber for Solar Thermophotovoltaics Based on 3D Titanium Nitride Nanopillars
journal, September 2017

  • Chirumamilla, Manohar; Chirumamilla, Anisha; Yang, Yuanqing
  • Advanced Optical Materials, Vol. 5, Issue 22
  • DOI: 10.1002/adom.201700552

Self-catalytic-grown SnO x nanocones for light outcoupling enhancement in organic light-emitting diodes
journal, January 2020


Visualization of UV by Nanopatterned Down‐Shifting Materials Mimicking Human Retinal Cone Cells
journal, October 2019

  • Sohn, Wonbae; Park, Heeyeon; Yoo, Gang Yeol
  • Advanced Functional Materials, Vol. 30, Issue 1
  • DOI: 10.1002/adfm.201905131

Mie resonance-mediated antireflection effects of Si nanocone arrays fabricated on 8-in. wafers using a nanoimprint technique
journal, April 2015


Optical properties and fabrication of dielectric metasurfaces based on amorphous silicon nanodisk arrays
journal, January 2019

  • Visser, D.; Basuvalingam, S. B.; Désières, Y.
  • Optics Express, Vol. 27, Issue 4
  • DOI: 10.1364/oe.27.005353