Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface
Abstract
We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquid and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²⁺ and Pt⁴⁺ interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China)
- VG Scienta,Uppsala (Sweden)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Shanghai Tech Univ., Shanghai (China)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1187106
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 5; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; batteries; surface spectroscopy; electrocatalysis
Citation Formats
Axnanda, Stephanus, Crumlin, Ethan J., Mao, Baohua, Rani, Sana, Chang, Rui, Karlsson, Patrik G., Edwards, Mårten O. M., Lundqvist, Måns, Moberg, Robert, Ross, Phil, Hussain, Zahid, and Liu, Zhi. Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface. United States: N. p., 2015.
Web. doi:10.1038/srep09788.
Axnanda, Stephanus, Crumlin, Ethan J., Mao, Baohua, Rani, Sana, Chang, Rui, Karlsson, Patrik G., Edwards, Mårten O. M., Lundqvist, Måns, Moberg, Robert, Ross, Phil, Hussain, Zahid, & Liu, Zhi. Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface. United States. https://doi.org/10.1038/srep09788
Axnanda, Stephanus, Crumlin, Ethan J., Mao, Baohua, Rani, Sana, Chang, Rui, Karlsson, Patrik G., Edwards, Mårten O. M., Lundqvist, Måns, Moberg, Robert, Ross, Phil, Hussain, Zahid, and Liu, Zhi. Thu .
"Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface". United States. https://doi.org/10.1038/srep09788. https://www.osti.gov/servlets/purl/1187106.
@article{osti_1187106,
title = {Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface},
author = {Axnanda, Stephanus and Crumlin, Ethan J. and Mao, Baohua and Rani, Sana and Chang, Rui and Karlsson, Patrik G. and Edwards, Mårten O. M. and Lundqvist, Måns and Moberg, Robert and Ross, Phil and Hussain, Zahid and Liu, Zhi},
abstractNote = {We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquid and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²⁺ and Pt⁴⁺ interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.},
doi = {10.1038/srep09788},
journal = {Scientific Reports},
number = 5,
volume = 5,
place = {United States},
year = {Thu May 07 00:00:00 EDT 2015},
month = {Thu May 07 00:00:00 EDT 2015}
}
Web of Science
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2D oxides on metal materials: concepts, status, and perspectives
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- Barcaro, Giovanni; Fortunelli, Alessandro
- Physical Chemistry Chemical Physics, Vol. 21, Issue 22
The effect of grain size on the hydration of BaZr 0.9 Y 0.1 O 3−δ proton conductor studied by ambient pressure X-ray photoelectron spectroscopy
journal, January 2020
- Jarry, Angelique; Jackson, Gregory S.; Crumlin, Ethan J.
- Physical Chemistry Chemical Physics, Vol. 22, Issue 1
Atmospheric pressure X-ray photoelectron spectroscopy apparatus: Bridging the pressure gap
journal, May 2016
- Velasco-Vélez, J. J.; Pfeifer, V.; Hävecker, M.
- Review of Scientific Instruments, Vol. 87, Issue 5
Advances in liquid phase soft-x-ray photoemission spectroscopy: A new experimental setup at BESSY II
journal, July 2017
- Seidel, Robert; Pohl, Marvin N.; Ali, Hebatallah
- Review of Scientific Instruments, Vol. 88, Issue 7
Revealing the formation dynamics of the electric double layer by means of in - situ Rutherford backscattering spectrometry
journal, August 2019
- Khojasteh, Nasrin B.; Apelt, Sabine; Bergmann, Ute
- Review of Scientific Instruments, Vol. 90, Issue 8
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission
journal, March 2017
- Hävecker, Michael; Düngen, Pascal; Buller, Saskia
- Catalysis, Structure & Reactivity, Vol. 3, Issue 1-2
Ambient pressure photoelectron spectroscopy: Practical considerations and experimental frontiers
journal, December 2016
- Trotochaud, Lena; Head, Ashley R.; Karslıoğlu, Osman
- Journal of Physics: Condensed Matter, Vol. 29, Issue 5
The offset droplet: a new methodology for studying the solid/water interface using x-ray photoelectron spectroscopy
journal, October 2017
- Booth, S. G.; Tripathi, A. M.; Strashnov, I.
- Journal of Physics: Condensed Matter, Vol. 29, Issue 45
Beyond Koopmans’ theorem: electron binding energies in disordered materials
journal, December 2018
- Muchová, Eva; Slavíček, Petr
- Journal of Physics: Condensed Matter, Vol. 31, Issue 4
In-depth study of the chemical/electronic structures of two-dimensional molybdenum disulfide materials with sub-micrometer-resolution scanning photoelectron microscopy
journal, January 2020
- Yun, Dong-Jin; Lee, Hyangsook; Baik, Jaeyoon
- 2D Materials, Vol. 7, Issue 2
Water-mediated photo-induced reduction of platinum films
journal, June 2019
- Fraxedas, Jordi; Zhang, Kuan; Sepúlveda, Borja
- Journal of Synchrotron Radiation, Vol. 26, Issue 4
Perovskites in catalysis and electrocatalysis
journal, November 2017
- Hwang, Jonathan; Rao, Reshma R.; Giordano, Livia
- Science, Vol. 358, Issue 6364
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars
text, January 2019
- Amann, Peter; Degerman, David; Lee, Ming-Tao
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Interface Science Using Ambient Pressure Hard X-ray Photoelectron Spectroscopy
journal, January 2019
- Favaro, Marco; Abdi, Fatwa; Crumlin, Ethan
- Surfaces, Vol. 2, Issue 1
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars
journal, October 2019
- Amann, Peter; Degerman, David; Lee, Ming-Tao
- Review of Scientific Instruments, Vol. 90, Issue 10
Water-mediated photo-induced reduction of platinum films
text, January 2019
- Fraxedas, Jordi; Zhang, Kuan; Sepúlveda, Borja
- International Union of Crystallography (IUCr)
Probing a battery electrolyte drop with ambient pressure photoelectron spectroscopy
text, January 2019
- Maibach, Julia; Källquist, Ida; Andersson, Margit
- Karlsruhe
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission
text, January 2017
- Hävecker, Michael; Düngen, Pascal; Buller, Saskia
- Taylor & Francis
A high-pressure x-ray photoelectron spectroscopy instrument for studies of industrially relevant catalytic reactions at pressures of several bars
text, January 2019
- Amann, Peter; Degerman, David; Lee, Ming-Tao
- Deutsches Elektronen-Synchrotron, DESY, Hamburg
Restructuring of silica supported vanadia during propane oxidative dehydrogenation studied by combined synchrotron radiation based in situ soft X-ray absorption and photoemission
text, January 2017
- Hävecker, Michael; Düngen, Pascal; Buller, Saskia
- Taylor & Francis
Nanocarbon-Edge-Anchored High-Density Pt Atoms for 3-nitrostyrene Hydrogenation: Strong Metal-Carbon Interaction
journal, March 2019
- Lou, Yang; Wu, Honglu; Liu, Jingyue
- iScience, Vol. 13
The Oxidation of Platinum under Wet Conditions Observed by Electrochemical X-ray Photoelectron Spectroscopy
journal, March 2019
- Mom, Rik; Frevel, Lorenz; Velasco-Vélez, Juan-Jesús
- Journal of the American Chemical Society, Vol. 141, Issue 16
Unravelling the electrochemical double layer by direct probing of the solid/liquid interface
journal, August 2016
- Favaro, Marco; Jeong, Beomgyun; Ross, Philip N.
- Nature Communications, Vol. 7, Issue 1
Probing a battery electrolyte drop with ambient pressure photoelectron spectroscopy
text, January 2019
- Maibach, Julia; Källquist, Ida; Andersson, Margit
- Karlsruhe