Dy-V magnetic interaction and local structure bias on the complex spin and orbital ordering in Dy₁₋xTbxVO₃ (x=0 and 0.2)

Yan, J.-Q.; Cao, H. B.; McGuire, M. A.; Ren, Y.; Sales, B. C.; Mandrus, D. G.

doi:10.1103/PhysRevB.87.224404

Title: Dy-V magnetic interaction and local structure bias on the complex spin and orbital ordering in Dy₁₋_xTb_xVO₃ (x=0 and 0.2)

Abstract

The spin and orbital ordering in Dy₁₋_xTb_xVO₃ (x=0 and 0.2) was studied by measuring x-ray powder diffraction, magnetization, specific heat, and neutron single-crystal diffraction. The results show that G-OO/C-AF and C-OO/G-AF phases coexist in Dy_0.8Tb_0.20VO₃ in the temperature range 2–60 K, and the volume fraction of each phase is temperature and field dependent. The ordering of Dy moments at T* = 12 K induces a transition from G-OO/C-AF to a C-OO/G-AF phase. Magnetic fields suppress the long-range order of Dy moments and thus the C-OO/G-AF phase below T*. The polarized moments induced at the Dy sublattice by external magnetic fields couple to the V 3d moments, and this coupling favors the G-OO/C-AF state. Also discussed is the effect of the Dy-V magnetic interaction and local structure distortion on the spin and orbital ordering in Dy₁₋_xTb_xVO₃.

Authors:: Yan, J.-Q.; Cao, H. B.; McGuire, M. A.; Ren, Y.; Sales, B. C.; Mandrus, D. G.

Publication Date:: Mon Jun 10 00:00:00 EDT 2013

Sponsoring Org.:: USDOE

OSTI Identifier:: 1114970

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review. B, Condensed Matter and Materials Physics

Additional Journal Information:: Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Volume: 87 Journal Issue: 22; Journal ID: ISSN 1098-0121

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Yan, J.-Q., Cao, H. B., McGuire, M. A., Ren, Y., Sales, B. C., and Mandrus, D. G. Dy-V magnetic interaction and local structure bias on the complex spin and orbital ordering in Dy₁₋xTbxVO₃ (x=0 and 0.2).  United States: N. p., 2013. 
Web.  doi:10.1103/PhysRevB.87.224404.

Copy to clipboard


                    Yan, J.-Q., Cao, H. B., McGuire, M. A., Ren, Y., Sales, B. C., & Mandrus, D. G. Dy-V magnetic interaction and local structure bias on the complex spin and orbital ordering in Dy₁₋xTbxVO₃ (x=0 and 0.2).  United States.  https://doi.org/10.1103/PhysRevB.87.224404

Copy to clipboard


                    Yan, J.-Q., Cao, H. B., McGuire, M. A., Ren, Y., Sales, B. C., and Mandrus, D. G. Mon .  
"Dy-V magnetic interaction and local structure bias on the complex spin and orbital ordering in Dy₁₋xTbxVO₃ (x=0 and 0.2)".  United States.  https://doi.org/10.1103/PhysRevB.87.224404.

Copy to clipboard


                    
@article{osti_1114970,

  title        = {Dy-V magnetic interaction and local structure bias on the complex spin and orbital ordering in Dy₁₋xTbxVO₃ (x=0 and 0.2)},

  author       = {Yan, J.-Q. and Cao, H. B. and McGuire, M. A. and Ren, Y. and Sales, B. C. and Mandrus, D. G.},

  abstractNote = {The spin and orbital ordering in Dy₁₋xTbxVO₃ (x=0 and 0.2) was studied by measuring x-ray powder diffraction, magnetization, specific heat, and neutron single-crystal diffraction. The results show that G-OO/C-AF and C-OO/G-AF phases coexist in Dy0.8Tb0.20VO3 in the temperature range 2–60 K, and the volume fraction of each phase is temperature and field dependent. The ordering of Dy moments at T* = 12 K induces a transition from G-OO/C-AF to a C-OO/G-AF phase. Magnetic fields suppress the long-range order of Dy moments and thus the C-OO/G-AF phase below T*. The polarized moments induced at the Dy sublattice by external magnetic fields couple to the V 3d moments, and this coupling favors the G-OO/C-AF state. Also discussed is the effect of the Dy-V magnetic interaction and local structure distortion on the spin and orbital ordering in Dy₁₋xTbxVO₃.},

  doi          = {10.1103/PhysRevB.87.224404},

  journal      = {Physical Review. B, Condensed Matter and Materials Physics},

  number       = 22,

  volume       = 87,

  place        = {United States},

  year         = {Mon Jun 10 00:00:00 EDT 2013},

  month        = {Mon Jun 10 00:00:00 EDT 2013}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1103/PhysRevB.87.224404

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Orbital Fluctuations and Orbital Flipping in $R {VO}_{3}$ Perovskites
journal, November 2007

Yan, J. -Q.; Zhou, J. -S.; Goodenough, J. B.
Physical Review Letters, Vol. 99, Issue 19
DOI: 10.1103/PhysRevLett.99.197201

Spin and orbital ordering in Y $_{1 - x}$ La $_{x}$ VO $_{3}$
journal, December 2011

Yan, J. -Q.; Zhou, J. -S.; Cheng, J. G.
Physical Review B, Vol. 84, Issue 21
DOI: 10.1103/PhysRevB.84.214405

Neutron diffraction, x-ray diffraction, and specific heat studies of orbital ordering in ${YVO}_{3}$
journal, April 2002

Blake, G. R.; Palstra, T. T. M.; Ren, Y.
Physical Review B, Vol. 65, Issue 17
DOI: 10.1103/PhysRevB.65.174112

Interplay between orbital ordering and lattice distortions in ${LaMnO}_{3},$ ${YVO}_{3},$ and ${YTiO}_{3}$
journal, September 1999

Mizokawa, T.; Khomskii, D. I.; Sawatzky, G. A.
Physical Review B, Vol. 60, Issue 10
DOI: 10.1103/PhysRevB.60.7309

Transition between Orbital Orderings in ${YVO}_{3}$
journal, November 2001

Blake, G. R.; Palstra, T. T. M.; Ren, Y.
Physical Review Letters, Vol. 87, Issue 24
DOI: 10.1103/PhysRevLett.87.245501

Spin-orbital phase diagram of perovskite-type $R {VO}_{3}$ $(R = rare$ -earth ion or Y)
journal, September 2003

Miyasaka, S.; Okimoto, Y.; Iwama, M.
Physical Review B, Vol. 68, Issue 10
DOI: 10.1103/PhysRevB.68.100406

Superexchange interaction and symmetry properties of electron orbitals
journal, July 1959

Kanamori, Junjiro
Journal of Physics and Chemistry of Solids, Vol. 10, Issue 2-3
DOI: 10.1016/0022-3697(59)90061-7

Effects of cation-size variance on spin and orbital orders in Eu $_{1 - x}$ (La $_{0.254}$ Y $_{0.746}$ ) $_{x}$ VO $_{3}$
journal, October 2011

Fukuta, R.; Miyasaka, S.; Hemmi, K.
Physical Review B, Vol. 84, Issue 14
DOI: 10.1103/PhysRevB.84.140409

Superexchange Interaction in Orbitally Fluctuating $R {VO}_{3}$
journal, October 2007

Zhou, J. -S.; Goodenough, J. B.; Yan, J. -Q.
Physical Review Letters, Vol. 99, Issue 15
DOI: 10.1103/PhysRevLett.99.156401

Magnetic properties of YVO3 single crystals
journal, September 2000

Ren, Y.; Palstra, T.; Khomskii, D.
Physical Review B, Vol. 62, Issue 10
DOI: 10.1103/PhysRevB.62.6577

Magnetic Field Switching between the Two Orbital-Ordered States in ${DyVO}_{3}$
journal, November 2007

Miyasaka, S.; Yasue, T.; Fujioka, J.
Physical Review Letters, Vol. 99, Issue 21
DOI: 10.1103/PhysRevLett.99.217201

Unusually Strong Orbit-Lattice Interactions in the $R V O_{3}$ Perovskites
journal, November 2004

Yan, J. -Q.; Zhou, J. -S.; Goodenough, J. B.
Physical Review Letters, Vol. 93, Issue 23
DOI: 10.1103/PhysRevLett.93.235901

Critical competition between two distinct orbital-spin ordered states in perovskite vanadates
journal, October 2010

Fujioka, J.; Yasue, T.; Miyasaka, S.
Physical Review B, Vol. 82, Issue 14
DOI: 10.1103/PhysRevB.82.144425

Electronic structure and orbital ordering in perovskite-type 3 d transition-metal oxides studied by Hartree-Fock band-structure calculations
journal, August 1996

Mizokawa, T.; Fujimori, A.
Physical Review B, Vol. 54, Issue 8
DOI: 10.1103/PhysRevB.54.5368

Structural and magnetic phase transitions of the orthovanadates $R$ VO $_{3}$ ( $R$ $=$ Dy, Ho, Er) as seen via neutron diffraction
journal, February 2011

Reehuis, M.; Ulrich, C.; Prokeš, K.
Physical Review B, Vol. 83, Issue 6
DOI: 10.1103/PhysRevB.83.064404

Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor
journal, May 2011

Chakoumakos, Bryan C.; Cao, Huibo; Ye, Feng
Journal of Applied Crystallography, Vol. 44, Issue 3
DOI: 10.1107/S0021889811012301

Opposing spin-canting mechanism in single-crystal $Lu V O_{3}$ and $Y V O_{3}$
journal, September 2005

Yan, J. -Q.; Zhou, J. -S.; Goodenough, J. B.
Physical Review B, Vol. 72, Issue 9
DOI: 10.1103/PhysRevB.72.094412

Orbital Physics in Transition-Metal Oxides
journal, April 2000

Tokura, Y.
Science, Vol. 288, Issue 5465
DOI: 10.1126/science.288.5465.462

Orbital hybridization in $R {VO}_{3}$ perovskites: A high-pressure study
journal, December 2009

Zhou, J. -S.; Goodenough, J. B.; Yan, J. -Q.
Physical Review B, Vol. 80, Issue 22
DOI: 10.1103/PhysRevB.80.224422

Orbital-ordering-induced phase transition in ${LaVO}_{3}$ and ${CeVO}_{3}$
journal, January 2003

Ren, Y.; Nugroho, A. A.; Menovsky, A. A.
Physical Review B, Vol. 67, Issue 1
DOI: 10.1103/PhysRevB.67.014107

Similar Records in DOE PAGES and OSTI.GOV collections:

Structural, Magnetic, and Magentostrictive Properties of Dy{sub 1−x}(Tb{sub 0.2}Pr{sub 0.8}){sub x}Fe{sub 1.93} (0≤ x ≤ 0.5) Compounds

Journal Article Zhang, G. B. ; Zheng, W. G. ; Cui, Y. ; ... - Journal of Superconductivity and Novel Magnetism

The structural, magnetic, and magnetostrictive properties of light rare earth Pr-contained Dy{sub 1−x}(Tb{sub 0.2}Pr{sub 0.8}){sub x}Fe{sub 1.93} (0≤ x ≤ 0.5) compounds were investigated by means of X-ray diffraction, vibrating sample magnetometer and strain gauge technique. A single Laves phase with MgCu{sub 2}-type structure was obtained in the composition range of 0.0≤ x ≤ 0.25. The lattice parameter of the Lave phase increases with increasing x due to the large radius of Pr{sup 3+} and Tb{sup 3+}. The Curie temperature of the Laves phase decreases with increasing x, indicating weakening strength of 3d-4f coupling. The saturation magnetization decreases with increasing x, whichmore »« less
https://doi.org/10.1007/S10948-017-4486-6
Mo{sub 2}NiB{sub 2}-type (Gd, Tb, Dy){sub 2}Ni{sub 2.35}Si{sub 0.65} and La{sub 2}Ni{sub 3}-type (Dy, Ho){sub 2}Ni{sub 2.5}Si{sub 0.5} compounds: Crystal structure and magnetic properties

Journal Article Morozkin, A.V., E-mail: morozkin@tech.chem.msu.ru ; Isnard, O. ; Université Grenoble Alpes, Inst. Néel, F-38042 Grenoble ; ... - Journal of Solid State Chemistry

The crystal structure of new Mo{sub 2}NiB{sub 2}-type (Gd, Tb, Dy){sub 2}Ni{sub 2.35}Si{sub 0.65} (Immm, No. 71, oI10) and La{sub 2}Ni{sub 3}-type (Dy, Ho){sub 2}Ni{sub 2.5}Si{sub 0.5} (Cmce No. 64, oC20) compounds has been established using powder X-ray diffraction studies. Magnetization measurements show that the Mo{sub 2}NiB{sub 2}-type Gd{sub 2}Ni{sub 2.35}Si{sub 0.65} undergoes a ferromagnetic transition at ~66 K, whereas isostructural Tb{sub 2}Ni{sub 2.35}Si{sub 0.65} shows an antiferromagnetic transition at ~52 K and a field-induced metamagnetic transition at low temperatures. Neutron diffraction study shows that, in zero applied field, Tb{sub 2}Ni{sub 2.35}Si{sub 0.65} exhibits c-axis antiferromagnetic order with propagation vectormore »« less
https://doi.org/10.1016/J.JSSC.2015.01.017
Anisotropy induced anomalies in Dy_1$$-$$xTb_xAl₂

Journal Article Khan, M. ; Miami Univ., Oxford, OH ; Pathak, A. K. ; ... - Journal of Materials Chemistry. C

The Dy_{1more » $$-$$x}Tb_xAl₂ alloys have been investigated by X-ray powder diffraction, heat capacity, and magnetic measurements. All samples exhibit cubic Laves phase crystal structure at room temperature but at T_C, DyAl2 and TbAl₂ show tetragonal and rhombohedral distortions, respectively. First order phase transitions are observed below T_C (at the spin-reorientation transition, T_SR) in the alloys with 0.15 ≤ x ≤ 0.35. These transitions are signified by sharp heat capacity peaks and corresponding anomalies in the magnetization and ac magnetic susceptibility data. The observations are interpreted by taking into consideration the differences in easy magnetization directions of DyAl₂ and TbAl₂. Due to the competing magnetic structures, the anisotropy-related instability and magnetic frustrations are prominent in the Dy_1$$-$$xTb_xAl₂ alloys at certain concentrations resulting in the first order transitions.« less
Cited by 7
https://doi.org/10.1039/C6TC05384J

Full Text Available
The orbital effect on the anomalous magnetism and evolution in La_$$x$$Y_1-$$x$$VO₃ (0 ≤ $$x$$ ≤ 0.2) single crystals

Journal Article Wan, Yan ; Jiao, Jinlong ; Lin, Gaoting ; ... - Journal of Alloys and Compounds

The orbital effect on the anomalous magnetism and evolution of single crystals with low La doping, La_{more » $$x$$}Y_1-$$x$$VO₃ ($$x$$ = 0, 0.1, and 0.2), has been studied using single-crystal X-ray diffraction, specific heat, magnetization, and Raman-scattering techniques. It is found that substituting Y³⁺ by La³⁺ increases the degeneracy of the $yz/zx$ orbitals and decreases the Jahn-Teller distortion. These weakens the G-type (antiphase ordering along the c axis) orbital ordering phase. Meanwhile, the substituting decreases the magnetism entropy, indicating the shrinking of the t_2g and e_g orbital hybridization, eventually destabilizing the C-type (in-phase ordering along the c axis) antiferromagnetic ordering phase. In addition, the mechanism for the shrinking of the diamagnetism with increasing $$x$$ is analyzed. In conclusion, it may attribute to the competition between the antisymmetric Dzyaloshinsky–Moriya interaction and the single-ion anisotropy.« less
https://doi.org/10.1016/j.jallcom.2022.167526

Full Text Available
Y_1-xLa_xVO₃: Effects of doping on orbital ordering

Journal Article Yano, S. ; Louca, Despina ; Neuefeind, Joerg C. ; ... - Physical Review B

For this research, the effects of isovalent doping on orbital ordering in the perovskite Y_1-xLa_xVO₃ were investigated using neutron diffraction and the pair distribution function analysis. YVO₃ is a prototype for orbital ordering, exhibiting two consecutive transitions to G-type and C-type ordering with decreasing temperature. Evidence for local orbital ordering above the transition temperature of T_OO~200 K is presented, obtained from the temperature dependence of the oxygen-oxygen octahedral correlations. This suggests that locally, G-type orbital ordering is present above the T_OO temperature but it is short range. With doping, it is expected that orbital ordering disappears altogether. In conclusion, bymore »« less
https://doi.org/10.1103/PhysRevB.90.214111

Similar Records

Title: Dy-V magnetic interaction and local structure bias on the complex spin and orbital ordering in Dy₁₋xTbxVO₃ (x=0 and 0.2)

Abstract

Citation Formats

Orbital Fluctuations and Orbital Flipping in R VO 3 Perovskites journal, November 2007

Spin and orbital ordering in Y 1 − x La x VO 3 journal, December 2011

Neutron diffraction, x-ray diffraction, and specific heat studies of orbital ordering in YVO 3 journal, April 2002

Interplay between orbital ordering and lattice distortions in LaMnO 3 , YVO 3 , and YTiO 3 journal, September 1999

Transition between Orbital Orderings in YVO 3 journal, November 2001

Spin-orbital phase diagram of perovskite-type R VO 3 ( R = rare -earth ion or Y) journal, September 2003

Superexchange interaction and symmetry properties of electron orbitals journal, July 1959

Effects of cation-size variance on spin and orbital orders in Eu 1 − x (La 0.254 Y 0.746 ) x VO 3 journal, October 2011

Superexchange Interaction in Orbitally Fluctuating R VO 3 journal, October 2007

Magnetic properties of YVO3 single crystals journal, September 2000

Magnetic Field Switching between the Two Orbital-Ordered States in DyVO 3 journal, November 2007

Unusually Strong Orbit-Lattice Interactions in the R V O 3 Perovskites journal, November 2004

Critical competition between two distinct orbital-spin ordered states in perovskite vanadates journal, October 2010

Electronic structure and orbital ordering in perovskite-type 3 d transition-metal oxides studied by Hartree-Fock band-structure calculations journal, August 1996

Structural and magnetic phase transitions of the orthovanadates R VO 3 ( R = Dy, Ho, Er) as seen via neutron diffraction journal, February 2011

Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor journal, May 2011

Opposing spin-canting mechanism in single-crystal Lu V O 3 and Y V O 3 journal, September 2005

Orbital Physics in Transition-Metal Oxides journal, April 2000

Orbital hybridization in R VO 3 perovskites: A high-pressure study journal, December 2009

Orbital-ordering-induced phase transition in LaVO 3 and CeVO 3 journal, January 2003

Title: Dy-V magnetic interaction and local structure bias on the complex spin and orbital ordering in Dy₁₋_xTb_xVO₃ (x=0 and 0.2)

Orbital Fluctuations and Orbital Flipping in $R {VO}_{3}$ Perovskites
journal, November 2007

Spin and orbital ordering in Y $_{1 - x}$ La $_{x}$ VO $_{3}$
journal, December 2011

Neutron diffraction, x-ray diffraction, and specific heat studies of orbital ordering in ${YVO}_{3}$
journal, April 2002

Interplay between orbital ordering and lattice distortions in ${LaMnO}_{3},$ ${YVO}_{3},$ and ${YTiO}_{3}$
journal, September 1999

Transition between Orbital Orderings in ${YVO}_{3}$
journal, November 2001

Spin-orbital phase diagram of perovskite-type $R {VO}_{3}$ $(R = rare$ -earth ion or Y)
journal, September 2003

Superexchange interaction and symmetry properties of electron orbitals
journal, July 1959

Effects of cation-size variance on spin and orbital orders in Eu $_{1 - x}$ (La $_{0.254}$ Y $_{0.746}$ ) $_{x}$ VO $_{3}$
journal, October 2011

Superexchange Interaction in Orbitally Fluctuating $R {VO}_{3}$
journal, October 2007

Magnetic properties of YVO3 single crystals
journal, September 2000

Magnetic Field Switching between the Two Orbital-Ordered States in ${DyVO}_{3}$
journal, November 2007

Unusually Strong Orbit-Lattice Interactions in the $R V O_{3}$ Perovskites
journal, November 2004

Critical competition between two distinct orbital-spin ordered states in perovskite vanadates
journal, October 2010

Electronic structure and orbital ordering in perovskite-type 3 d transition-metal oxides studied by Hartree-Fock band-structure calculations
journal, August 1996

Structural and magnetic phase transitions of the orthovanadates $R$ VO $_{3}$ ( $R$ $=$ Dy, Ho, Er) as seen via neutron diffraction
journal, February 2011

Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor
journal, May 2011

Opposing spin-canting mechanism in single-crystal $Lu V O_{3}$ and $Y V O_{3}$
journal, September 2005

Orbital Physics in Transition-Metal Oxides
journal, April 2000

Orbital hybridization in $R {VO}_{3}$ perovskites: A high-pressure study
journal, December 2009

Orbital-ordering-induced phase transition in ${LaVO}_{3}$ and ${CeVO}_{3}$
journal, January 2003