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Title: Anisotropy induced anomalies in Dy 1$-$xTb xAl 2

The Dy 1$-$xTb xAl 2 alloys have been investigated by X-ray powder diffraction, heat capacity, and magnetic measurements. All samples exhibit cubic Laves phase crystal structure at room temperature but at T C, DyAl2 and TbAl 2 show tetragonal and rhombohedral distortions, respectively. First order phase transitions are observed below T C (at the spin-reorientation transition, T SR) in the alloys with 0.15 ≤ x ≤ 0.35. These transitions are signified by sharp heat capacity peaks and corresponding anomalies in the magnetization and ac magnetic susceptibility data. The observations are interpreted by taking into consideration the differences in easy magnetization directions of DyAl 2 and TbAl 2. Due to the competing magnetic structures, the anisotropy-related instability and magnetic frustrations are prominent in the Dy 1$-$xTb xAl 2 alloys at certain concentrations resulting in the first order transitions.
Authors:
 [1] ;  [2] ;  [1] ;  [1] ;  [3] ;  [3]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
  2. (United States) . Dept. of Physics
  3. Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering
Publication Date:
Report Number(s):
IS-J-9258
Journal ID: ISSN 2050-7526; JMCCCX
Grant/Contract Number:
AC02-07CH11358
Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. C
Additional Journal Information:
Journal Volume: 5; Journal Issue: 4; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1355404

Khan, M., Miami Univ., Oxford, OH, Pathak, A. K., Mudryk, Y., Gschneidner, Jr., K. A., and Pecharsky, V. K.. Anisotropy induced anomalies in Dy1$-$xTbxAl2. United States: N. p., Web. doi:10.1039/C6TC05384J.
Khan, M., Miami Univ., Oxford, OH, Pathak, A. K., Mudryk, Y., Gschneidner, Jr., K. A., & Pecharsky, V. K.. Anisotropy induced anomalies in Dy1$-$xTbxAl2. United States. doi:10.1039/C6TC05384J.
Khan, M., Miami Univ., Oxford, OH, Pathak, A. K., Mudryk, Y., Gschneidner, Jr., K. A., and Pecharsky, V. K.. 2017. "Anisotropy induced anomalies in Dy1$-$xTbxAl2". United States. doi:10.1039/C6TC05384J. https://www.osti.gov/servlets/purl/1355404.
@article{osti_1355404,
title = {Anisotropy induced anomalies in Dy1$-$xTbxAl2},
author = {Khan, M. and Miami Univ., Oxford, OH and Pathak, A. K. and Mudryk, Y. and Gschneidner, Jr., K. A. and Pecharsky, V. K.},
abstractNote = {The Dy1$-$xTbxAl2 alloys have been investigated by X-ray powder diffraction, heat capacity, and magnetic measurements. All samples exhibit cubic Laves phase crystal structure at room temperature but at TC, DyAl2 and TbAl2 show tetragonal and rhombohedral distortions, respectively. First order phase transitions are observed below TC (at the spin-reorientation transition, TSR) in the alloys with 0.15 ≤ x ≤ 0.35. These transitions are signified by sharp heat capacity peaks and corresponding anomalies in the magnetization and ac magnetic susceptibility data. The observations are interpreted by taking into consideration the differences in easy magnetization directions of DyAl2 and TbAl2. Due to the competing magnetic structures, the anisotropy-related instability and magnetic frustrations are prominent in the Dy1$-$xTbxAl2 alloys at certain concentrations resulting in the first order transitions.},
doi = {10.1039/C6TC05384J},
journal = {Journal of Materials Chemistry. C},
number = 4,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}