Linking local structure and properties in perovskites containing equal concentrations of manganese and ruthenium

King, Graham; Ricciardo, Rebecca A.; Soliz, Jennifer R.; Woodward, Patrick M.; Llobet, Anna

doi:10.1103/PhysRevB.83.134123

Title: Linking local structure and properties in perovskites containing equal concentrations of manganese and ruthenium

Full Record
Other Related Research

Authors:: King, Graham; Ricciardo, Rebecca A.; Soliz, Jennifer R.; Woodward, Patrick M.; Llobet, Anna

Publication Date:: Tue Apr 26 00:00:00 EDT 2011

Sponsoring Org.:: USDOE

OSTI Identifier:: 1100330

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 83; Journal Issue: 13; Journal ID: ISSN 1098-0121

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    King, Graham, Ricciardo, Rebecca A., Soliz, Jennifer R., Woodward, Patrick M., and Llobet, Anna. Linking local structure and properties in perovskites containing equal concentrations of manganese and ruthenium.  United States: N. p., 2011. 
Web.  doi:10.1103/PhysRevB.83.134123.

Copy to clipboard


                    King, Graham, Ricciardo, Rebecca A., Soliz, Jennifer R., Woodward, Patrick M., & Llobet, Anna. Linking local structure and properties in perovskites containing equal concentrations of manganese and ruthenium.  United States.  https://doi.org/10.1103/PhysRevB.83.134123

Copy to clipboard


                    King, Graham, Ricciardo, Rebecca A., Soliz, Jennifer R., Woodward, Patrick M., and Llobet, Anna. Tue .  
"Linking local structure and properties in perovskites containing equal concentrations of manganese and ruthenium".  United States.  https://doi.org/10.1103/PhysRevB.83.134123.

Copy to clipboard


                    
@article{osti_1100330,

  title        = {Linking local structure and properties in perovskites containing equal concentrations of manganese and ruthenium},

  author       = {King, Graham and Ricciardo, Rebecca A. and Soliz, Jennifer R. and Woodward, Patrick M. and Llobet, Anna},

  abstractNote = {},

  doi          = {10.1103/PhysRevB.83.134123},

  journal      = {Physical Review B},

  number       = 13,

  volume       = 83,

  place        = {United States},

  year         = {Tue Apr 26 00:00:00 EDT 2011},

  month        = {Tue Apr 26 00:00:00 EDT 2011}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1103/PhysRevB.83.134123

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 3 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Linking local structure and properties in perovskites containing equal concentrations of manganese and ruthenium

Journal Article King, Graham ; Ricciardo, Rebecca A ; Soliz, Jennifer R ; ... - Phys. Rev. B

The local structures of six perovskite compounds containing equal amounts of manganese and ruthenium on the B-site have been investigated by neutron and x-ray pair distribution function analysis. The compounds SrMn{sub 0.5}Ru{sub 0.5}O{sub 3}, Sr{sub 0.5}Ca{sub 0.5}Mn{sub 0.5}Ru{sub 0.5}O{sub 3}, and CaMn{sub 0.5}Ru{sub 0.5}O{sub 3} were studied to investigate the effects of pure chemical pressure on the local structure and valency ratio between Mn{sup 3+}/Ru{sup 5+} and Mn{sup 4+}/Ru{sup 4+}. Reverse Monte Carlo simulations confirm that there is a shift in the B-site cation charge distribution from nearly equal amounts of Mn{sup 3+}, Ru{sup 5+}, Mn{sup 4+}, and Ru{sup 4+}more »« less
https://doi.org/10.1103/PhysRevB.83.134123
Charge localization, magnetic order, structural behavior, and spin dynamics of (La-Tb){sub 2/3}Ca{sub 1/3}MnO{sub 3} manganese perovskites probed by neutron diffraction and muon spin relaxation

Journal Article De Teresa, J M ; Ritter, C ; Ibarra, M R ; ... - Physical Review, B: Condensed Matter

Two microscopic techniques, muon spin relaxation and neutron diffraction, including small-angle neutron scattering (SANS), have been used to probe into the relevant mechanisms that determine the macroscopic behavior in the series (La{sub 1{minus}x}Tb{sub x}){sub 2/3}Ca{sub 1/3}MnO{sub 3}. The magnetic ground state at low temperatures evolves from ferromagnetic for x{le}0.25 to spin glass for 0.33{le}x{le}0.75 and finally antiferromagnetic for x=1. Spin-glass regions were observed for x{ge}0.25. We propose the existence of two different volume states associated with the metalliclike ferromagnetic state and the semiconductorlike paramagnetic, spin-glass, or antiferromagnetic states, respectively. SANS experiments reveal the existence of magnetic clusters for x{le}0.33. Themore »« less
https://doi.org/10.1103/PhysRevB.56.3317
Interplay of local structure, charge, and spin in bilayered manganese perovskites

Journal Article Rybicki, Damian ; Sikora, Marcin ; Przewoznik, Janusz ; ... - Physical Review B

Chemical doping is a reliable method of modification of the electronic properties of transition metal compounds. In manganese perovskites, it leads to charge transfer and peculiar ordering phenomena. However, depending on the interplay of the local crystal structure and electronic properties, synthesis of stable compounds in the entire doping range is often impossible. In this paper, we show results of high-energy resolution x-ray absorption and emission spectroscopies on amore »« less
Cited by 5
https://doi.org/10.1103/PhysRevB.97.115158

Full Text Available
Structural Diversity and Magnetic Properties of Hybrid Ruthenium Halide Perovskites and Related Compounds

Journal Article Vishnoi, Pratap ; Zuo, Julia L. ; Strom, T. Amanda ; ... - Angewandte Chemie

Abstract There has been a great deal of recent interest in extended compounds containing Ru ³⁺ and Ru ⁴⁺ in light of their range of unusual physical properties. Many of these properties are displayed in compounds with the perovskite and related structures. Here we report an array of structurally diverse hybrid ruthenium halide perovskites and related compounds: MA ₂ Ru X ₆ ( X =Cl or Br), MA ₂ M RuX ₆ ( M =Na, K or Ag; X =Cl or Br) and MA ₃ Ru ₂ X ₉ ( X =Br) based upon the use of methylammonium (MA=CH ₃more »« less
https://doi.org/10.1002/ange.202003095
Structural Diversity and Magnetic Properties of Hybrid Ruthenium Halide Perovskites and Related Compounds

Journal Article Vishnoi, Pratap ; Zuo, Julia L. ; Strom, T. Amanda ; ... - Angewandte Chemie (International Edition)

Abstract There has been a great deal of recent interest in extended compounds containing Ru ³⁺ and Ru ⁴⁺ in light of their range of unusual physical properties. Many of these properties are displayed in compounds with the perovskite and related structures. Here we report an array of structurally diverse hybrid ruthenium halide perovskites and related compounds: MA ₂ Ru X ₆ ( X =Cl or Br), MA ₂ M RuX ₆ ( M =Na, K or Ag; X =Cl or Br) and MA ₃ Ru ₂ X ₉ ( X =Br) based upon the use of methylammonium (MA=CH ₃more »« less
Cited by 22
https://doi.org/10.1002/anie.202003095

Full Text Available

Similar Records